Regular ArticleExcess enthalpies for mixtures of 1,4-dicyanobutane and an aromatic hydrocarbon atT = 298.15 K andp = 101325 Pa-Science-Chemical Encyclopedia-lookchem

Regular ArticleExcess enthalpies for mixtures of 1,4-Dicyanobutane (cas 111-69-3) and an aromatic hydrocarbon atT = 298.15 K andp = 101325 Pa
Add time:08/23/2019 Source:sciencedirect.com

Excess molar enthalpies for (1,4-Dicyanobutane (cas 111-69-3) + benzene, or methyl benzene, or 1,2-dimethyl benzene, or 1,3-dimethyl benzene, or 1,4-dimethyl benzene, or ethyl benzene) atT = 298.15 K and p = 101325 Pa are presented. The excess enthalpy ranges from a maximum of 246 J · mol − 1for ethyl benzene to a minimum of − 17 J · mol − 1for benzene. The Redlich–Kister equation, the NRTL and UNIQUAC models were used to correlate the data. The contributions of π–π interactions and steric hindrance to the results are discussed.

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