Nickel(0) catalyzed oxidation of organosilanes to disiloxanes by air as an oxidant-Science-Chemical Encyclopedia-lookchem

Nickel(0) catalyzed oxidation of organosilanes to disiloxane (cas 13597-73-4)s by air as an oxidant
Add time:08/26/2019 Source:sciencedirect.com

We report here an efficient non-aqueous route to symmetrical disiloxanes from their corresponding organosilanes using Ni(COD)2 with 3,4,7,8-tetramethyl-1,10-phenanthroline in air. Our methodology is very simple and high yielding. The reaction mechanism is also proposed.

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