Practical stereoselective synthesis of α-linked C-glucosamine propionic acid esters: conversion to GLA-60 derivatives-Science-Chemical Encyclopedia-lookchem

Practical stereoselective synthesis of α-linked C-glucosamine propionic acid esters: conversion to GLA-60 derivatives
Add time:09/02/2019 Source:sciencedirect.com

Radical C-glycosylation of glucosamine derivatives by acrylic acid esters gave the corresponding 3-(α-C-glucosyl)-propionate derivatives in moderate yields. One of them was used as a versatile synthon for GLA-60 derivatives. However, the biological activity of these compounds as LPS-antagonists was disappointing.

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