Synthetic studies towards carzinophilin: Synthesis and ammonium hydroxide-induced rearrangement of the epoxi-acid fragment-Science-Chemical Encyclopedia-lookchem

Synthetic studies towards carzinophilin (cas 1403-28-7): Synthesis and ammonium hydroxide-induced rearrangement of the epoxi-acid fragment
Add time:09/06/2019 Source:sciencedirect.com

An efficient synthesis of the epoxide-containing fragment 4 of carzinophilin has been completed. Intramolecular acyl transfer of a related epoxide afforded amide 16. Comparison by 1H NMR of 4 and 16 with authentic natural product provides further evidence for structural revision of carzinophilin.

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