Add time:09/05/2019         Source:sciencedirect.com

In this work, guided by a pyridoxal derived Schiff base ligand, H2PydChda [5-Hydroxymethyl-4-({2-[5-hydroxymethyl-2-methylpyridin-3-hydroxy-4-ylethylene)-amino]-cyclohexylimino}-methyl)-2-methylpyridin-3-ol], a new copper(II) complex, [Cu(PydChda-2H+)]2·4ClO4·2H2O was constructed and structurally characterized by single crystal X-ray diffraction study. DFT calculations further substantiate the experimental features. Additionally, experiments were performed to demonstrate the accessibility to any enzymatic activity and the complex provides positive response for phosphatase activity towards 4-NPP substrate.

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