Add time:09/04/2019 Source:sciencedirect.com
Treatment of the 1,3-bis(trimethylsilyl)propene by Li2PdCl4 (1 equiv.) in methanol affords the bis[η3-(1-trimethylsilylallyl)chloropalladium] complex. Alkylation of this derivative with sodium malonates leads to (E)-vinylsilanes.
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