Add time:09/09/2019         Source:sciencedirect.com

Publisher SummaryThis chapter discusses the metal borates. The chemistry of metal borates is surprisingly intricate. Early work was essentially of a synthetic nature, and it was the development of spectroscopic and X-ray crystallographic techniques that demonstrated the complexity of boron systems. During the past decade, crystal structures of metal borates have been determined at a rapid rate, and several novel types of borate anions have come to light. Concurrently, great advances in the understanding of the nature of borate ions in solution have been made through use of Raman, infrared (IR), and nuclear magnetic resonance (NMR) spectroscopic techniques. This chapter is concerned with the hydrated metal borates, their interactions in solution, and their synthesis. Thus the properties of boric acid, and formation of sulfatoborates, perborates, arsenatoborates, metal borate-organic complexes, glasses, and melts are omitted.

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