Add time:09/08/2019 Source:sciencedirect.com
Carbon dioxide has been coverted into methanol with an electrochemical photocell. The electrocatalytic reduction of CO2 proceeds via a surface-confined metal complex in the presence of homogeneous catalysts consisting of a metal complex and a primary alcohol. Electrons for the surface-confined metal complex were provided by a photocell in which n-CdS and Everitt's salt-modified platinum electrodes operated as the photoanode and the cathode, respectively. The current efficiencies of methanol formation in the presence of pentacyanoferrate(II), pentachlorochromate(III), bis(oxalato)chromate(III) and amminepentacyanoferrate(II) were 86.6, 83.3, 96.8 And 61.7%, respectively.
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