Add time:09/28/2019 Source:sciencedirect.com
In this work, graphene oxide (GO)-supported ruthenium nanomaterials ([email protected] NPs) were used as catalysts in Dimethylamine (cas 124-40-3) borane (DMAB) dehydrogenation. Raman spectroscopy, X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) have been used for the characterization of prepared nanomaterials. The produced nanomaterials show high efficiency and reusability in addition to very good catalytic activities recorded at low temperatures and at low concentrations for the dehydrogenation of dimethylamine borane (DMAB). [email protected] NPs have a significantly high turnover frequency (TOF) (410.01 h− 1) and low activation energy (Ea) (44.67 ± 2 kJ mol− 1) for dehydrogenation of DMAB.
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