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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine c

3'-Bromoacetophenone 2142-63-4 /manufacturer/low price/high quality/in stock

Cas:2142-63-4

Min.Order:1 Kilogram

FOB Price: $11.0 / 12.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 3'-Bromoacetophenone supplier in China

Cas:2142-63-4

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 3'-bromoacetophenone

Cas:2142-63-4

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 2142-63-4 Ethanone, 1-(3-bromophenyl)-

Cas:2142-63-4

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

3'-Bromoacetophenone CAS 2142-63-4

Cas:2142-63-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

2142-63-4 3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 2142-63-4 with best quality

Cas:2142-63-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

3'-Bromoacetophenone/ LIDE PHARMA- Factory supply / Best price

Cas:2142-63-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Product name M-bromoacetophenone CAS NO. 2142-63-4 Molecular formula C8H7BrO Quality standard

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Ethanone, 1-(3-bromophenyl)- 2142-63-4

Cas:2142-63-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 3'-Bromoacetophenone Synonyms: 1-(3-bromophenyl)-ethanon;3-bromoacetephenone;Acetophenone, 3'-bromo-;Ethanone, 1-(3-bromophenyl)-;M-BROMOACETOPHENONE;M-BROMOPHENYL METHYL KETONE;BROMOACETOPHENONE-3;1-ACETYL-3-BROMOBENZENE CA

3'-Bromoacetophenone 2142-63-4 TOP QUALITY

Cas:2142-63-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Chemical Intermediate,3'-Bromoacetophenone CAS:2142-63-4

Cas:2142-63-4

Min.Order:1 Kilogram

FOB Price: $20.0 / 24.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

3'-Bromoacetophenone CAS:2142-63-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

3'-Bromoacetophenone CAS:2142-63-4

Cas:2142-63-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Ethanone, 1-(3-bromophenyl)-

Cas:2142-63-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

3'-Bromoacetophenone CAS NO.2142-63-4

Cas:2142-63-4

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:2142-63-4

Cas:2142-63-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

1-(3-BROMOPHENYL)ETHANONE

Cas:2142-63-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

3'-BromoacetophenoneAppearance:Pls see the Details Storage:Keep away of light, hot, water, Store in dry, dark and ventilated place Package:according to customers' requirements Application:Steroids, Cosmetics Ingredients, APIs, Intermediates, OLED&Bat

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

3'-Bromoacetophenone

Cas:2142-63-4

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Synthetic route

1-(3-bromophenyl)ethanol
52780-14-0

1-(3-bromophenyl)ethanol

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With C53H46ClN3P2Ru; potassium tert-butylate; acetone at 56℃; under 750.075 Torr; for 0.166667h; Oppenauer Oxidation;98%
With [(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine)RuCl2(PPh3)]; potassium tert-butylate; acetone In methanol at 56℃; under 750.075 Torr; for 0.05h; Catalytic behavior; Oppenauer Oxidation; Inert atmosphere;97%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; potassium tert-butylate; copper(I) triflate; 5-[(2S)-pyrrolidine-2-yl]-1H-tetrazole In N,N-dimethyl-formamide at 25℃; for 1h; Catalytic behavior;97%
3-bromostyrene
2039-86-3

3-bromostyrene

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With iron(II) chloride In ethanol at 80℃; for 6h;95%
With manganese(II) bromide; water; lithium perchlorate; copper dichloride In acetonitrile at 60℃; for 8h; Wacker-Tsuji Olefin Oxidation; Sealed tube; Inert atmosphere; Electrochemical reaction; regioselective reaction;70%
With dihydrogen peroxide In water; acetonitrile at 55℃; for 12h; Wacker Oxidation;66%
Multi-step reaction with 2 steps
1: lithium aluminium tetrahydride; iron(III) chloride; hydrogen / tetrahydrofuran / 24 h / 23 °C
2: NADPH; 9-(2-mesityl)-10-methylacridinium perchlorate; oxygen; ketoreductase-P1-B12 / acetonitrile; water / 24 h / 23 °C / Irradiation; Enzymatic reaction
View Scheme
With oxygen; potassium carbonate; isopropyl alcohol at 150℃; under 3000.3 Torr; for 6h; regioselective reaction;70.5 %Chromat.
3-bromophenylacetylene
766-81-4

3-bromophenylacetylene

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I) In methanol; water at 110℃; for 6h; Schlenk technique; regioselective reaction;93%
With chloro(1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene)gold(I); water In methanol at 110℃; for 6h;93%
With tropylium tetrafluoroborate; water; acetic acid at 130℃; for 48h; Inert atmosphere;64%
acetophenone
98-86-2

acetophenone

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With bromine fluoride In ethanol; chloroform at -40℃; for 0.0833333h;92%
Stage #1: acetophenone With potassium bromate In methanol; water
Stage #2: With sodium hydrogensulfite In methanol; water at 45℃; for 5h; Reagent/catalyst;
87.5%
With 1,3-di-n-butyl-1H-imidazol-3-ium tribromide at 20℃; for 0.166667h; Neat (no solvent); regioselective reaction;83%
N-[1-(3-bromophenyl)ethylidene]hydroxyl amine
24280-05-5

N-[1-(3-bromophenyl)ethylidene]hydroxyl amine

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With formic acid; silica gel for 0.05h; microwave irradiation;92%
With oxygen In acetonitrile at 22 - 35℃; under 760.051 Torr; for 6h; Irradiation;100 %Chromat.
With oxygen In acetonitrile under 760.051 Torr; for 48h; Irradiation;74 %Chromat.
m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

methyllithium
917-54-4

methyllithium

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
Stage #1: methyllithium With copper(l) cyanide In diethyl ether at 0℃; for 0.0833333h; Inert atmosphere;
Stage #2: m-bromobenzoic acid In diethyl ether at 0 - 20℃; for 15h; Inert atmosphere;
92%
3-bromobenzenesulfonyl hydrazide
89862-26-0

3-bromobenzenesulfonyl hydrazide

acetonitrile
75-05-8

acetonitrile

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With 1,10-Phenanthroline; water; palladium diacetate at 100℃; under 760.051 Torr; for 6h;88%
1-(3-bromophenyl)ethanol
52780-14-0

1-(3-bromophenyl)ethanol

B

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

C

(S)-1-(3-bromophenyl)ethan-1-ol
134615-22-8

(S)-1-(3-bromophenyl)ethan-1-ol

Conditions
ConditionsYield
With Arthrobacter atrocyaneus In N,N-dimethyl-formamide at 32℃; for 72h; Microbiological reaction; enantioselective reaction;A n/a
B n/a
C 86%
Stage #1: 1-(3-bromophenyl)ethanol With C32H40MnN2O6(1+)*Cl(1-) In dichloromethane; water for 0.0833333h; Resolution of racemate;
Stage #2: With [bis(acetoxy)iodo]benzene; tetraethylammonium bromide In dichloromethane; water at 0℃; for 0.5h; Overall yield = 40 %; Optical yield = 88 %ee; enantioselective reaction;
1-(3-bromophenyl)ethanamine
74877-08-0

1-(3-bromophenyl)ethanamine

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With 4-phenylnaphthalene-1,2-dione In acetonitrile at 80℃; for 36h;85%
2-(3-bromophenyl)-2-propanol
30951-66-7

2-(3-bromophenyl)-2-propanol

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With bismuth(lll) trifluoromethanesulfonate; dipotassium peroxodisulfate; silver nitrate In water at 30℃; for 24h; Inert atmosphere; Green chemistry;79%
1-bromo-3-ethylbenzene
2725-82-8

1-bromo-3-ethylbenzene

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With tert.-butylhydroperoxide; phosphomolybdic acid; copper(II) acetate monohydrate In water; acetonitrile at 90℃; for 10h; Sealed tube;78%
With FeH6Mo6O24(3-)*3H3N*3H(1+)*7H2O; tetrabutylammomium bromide; dihydrogen peroxide In 1,4-dioxane at 70℃; for 24h;75%
With 2-Picolinic acid; sodium tetrahydroborate; bismuth(III) oxide; tert.-butylhydroperoxide In pyridine; water; acetic acid at 100℃; for 16h;71%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

N-Methoxy-N-methylacetamide
78191-00-1

N-Methoxy-N-methylacetamide

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
Stage #1: 1,3-dibromobenzene With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: N-Methoxy-N-methylacetamide In tetrahydrofuran at -78℃;
74%
Li(1+)*Zn(2+)*3CH3(1-)=LiZn(CH3)3

Li(1+)*Zn(2+)*3CH3(1-)=LiZn(CH3)3

m-bromobenzoic acid
585-76-2

m-bromobenzoic acid

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
Stage #1: m-bromobenzoic acid With methyllithium In tetrahydrofuran; diethyl ether at -78℃; for 1h; Schlenk technique; Inert atmosphere;
Stage #2: Li(1+)*Zn(2+)*3CH3(1-)=LiZn(CH3)3 In tetrahydrofuran; diethyl ether at 50℃; for 5h; Schlenk technique; Inert atmosphere; chemoselective reaction;
60%
1-(3-bromophenyl)ethanol
52780-14-0

1-(3-bromophenyl)ethanol

A

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

B

(S)-1-(3-bromophenyl)ethan-1-ol
134615-22-8

(S)-1-(3-bromophenyl)ethan-1-ol

Conditions
ConditionsYield
With Arthrobacter atrocyaneus In N,N-dimethyl-formamide at 32℃; for 48h; Microbiological reaction; enantioselective reaction;A n/a
B 55%
1-(3-aminophenyl)ethanone
99-03-6

1-(3-aminophenyl)ethanone

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
Stage #1: 1-(3-aminophenyl)ethanone With sulfuric acid; copper; copper(II) sulfate; potassium bromide In water for 2h; Reflux;
Stage #2: With sodium nitrite In water at 80 - 90℃;
52%
With hydrogen bromide; copper(I) bromide
3-bromo-N,N-dimethylbenzamide
15930-59-3

3-bromo-N,N-dimethylbenzamide

methyllithium
917-54-4

methyllithium

A

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

B

N,N-Diethyl-5-bromo-2-fluoreneone carboxamide

N,N-Diethyl-5-bromo-2-fluoreneone carboxamide

C

3-Bromo-2-<2-(3-bromophenyl)-2-oxo-ethyl>-N,N-diethylbenzamide

3-Bromo-2-<2-(3-bromophenyl)-2-oxo-ethyl>-N,N-diethylbenzamide

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether at -63℃; for 0.05h;A 48%
B 6%
C 7%
3-bromo-N,N-dimethylbenzamide
15930-59-3

3-bromo-N,N-dimethylbenzamide

A

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

B

N,N-Diethyl-5-bromo-2-fluoreneone carboxamide

N,N-Diethyl-5-bromo-2-fluoreneone carboxamide

C

3-Bromo-2-<2-(3-bromophenyl)-2-oxo-ethyl>-N,N-diethylbenzamide

3-Bromo-2-<2-(3-bromophenyl)-2-oxo-ethyl>-N,N-diethylbenzamide

Conditions
ConditionsYield
With methyllithium In tetrahydrofuran; diethyl ether at -63℃; for 0.05h;A 48%
B 6%
C 7%
With methyllithium In tetrahydrofuran; diethyl ether at -63℃; for 0.05h;A 48%
B 6%
C 7%
1-bromo-3-(2',2'-dibromovinyl)benzene

1-bromo-3-(2',2'-dibromovinyl)benzene

A

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

B

acetophenone
98-86-2

acetophenone

Conditions
ConditionsYield
With water; zinc at 275℃; for 4h;A 48%
B 28%
1-bromo-3-isopropylbenzene
5433-01-2

1-bromo-3-isopropylbenzene

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With hydrogenchloride; sodium nitrite In water at 23℃; for 3h; Sealed tube;44%
1-(3-bromophenyl)ethanol
52780-14-0

1-(3-bromophenyl)ethanol

B

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With C50H42ClN2O3Ru In chloroform at 25℃; Kinetics; Molecular sieve; Resolution of racemate; enantioselective reaction;A 41.9%
B n/a
With Nocardia corallina B-276 In octane; N,N-dimethyl-formamide at 28 - 30℃; for 25h; Enzymatic reaction;
Stage #1: 1-(3-bromophenyl)ethanol With Zr6O4(OH)4(12+)*0.7C21H14O4(2-)*5.3C30H34N2O6(4-)*H2O*9C3H7NO*5.3Mn(3+)*5.3Cl(1-) In dichloromethane; water for 0.0833333h; Resolution of racemate;
Stage #2: With [bis(acetoxy)iodo]benzene; tetraethylammonium bromide In dichloromethane; water at 0℃; for 0.5h; Kinetics; Resolution of racemate; enantioselective reaction;
A n/a
B n/a
acetophenone
98-86-2

acetophenone

A

2,2-dibromoacetophenone
13665-04-8

2,2-dibromoacetophenone

B

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

C

α-bromoacetophenone
70-11-1

α-bromoacetophenone

Conditions
ConditionsYield
With N-Bromosuccinimide; silica gel In acetonitrile for 3h; Temperature; Reflux;A n/a
B n/a
C 35%
With N-Bromosuccinimide; silica gel In diethyl ether for 0.25h; Catalytic behavior; Solvent; Temperature; Reflux;A n/a
B n/a
C 24%
1-(4-amino-3-bromophenyl)-ethanone
56759-32-1

1-(4-amino-3-bromophenyl)-ethanone

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With ethanol; sulfuric acid
3-(3-Bromo-phenyl)-3,4,4-trimethyl-[1,2]dioxetane
108773-72-4

3-(3-Bromo-phenyl)-3,4,4-trimethyl-[1,2]dioxetane

A

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
In xylene at 60℃; Thermodynamic data; Ea;
(3S,4R)-3,4-Bis-(3-bromo-phenyl)-3,4-dimethyl-[1,2]dioxetane
108773-78-0

(3S,4R)-3,4-Bis-(3-bromo-phenyl)-3,4-dimethyl-[1,2]dioxetane

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
In xylene at 60℃; Rate constant; Thermodynamic data; Ea;
(3R,4R)-3,4-Bis-(3-bromo-phenyl)-3,4-dimethyl-[1,2]dioxetane
108773-78-0, 108773-79-1

(3R,4R)-3,4-Bis-(3-bromo-phenyl)-3,4-dimethyl-[1,2]dioxetane

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
In xylene at 60℃; Thermodynamic data; Ea;
3-methyl-3-(m-bromophenyl)-1,2-dioxetane
81815-14-7

3-methyl-3-(m-bromophenyl)-1,2-dioxetane

A

formaldehyd
50-00-0

formaldehyd

B

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With 9,10-Dibromoanthracene In benzene at 45℃; Product distribution; Mechanism; Thermodynamic data; rate coefficients, log A, ΔS(excit), total and specific triplet and singlet efficiencies for the products of the thermolysis;
3,3-(2,2'-biphenyldiyl)-4-methyl-4-(m-bromphenyl)-1,2-dioxetane
96258-30-9

3,3-(2,2'-biphenyldiyl)-4-methyl-4-(m-bromphenyl)-1,2-dioxetane

A

9-fluorenone
486-25-9

9-fluorenone

B

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
In benzene at 60.5℃; Rate constant; Thermodynamic data; Ea;
acetophenone
98-86-2

acetophenone

A

2-bromophenyl methyl ketone
2142-69-0

2-bromophenyl methyl ketone

B

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With potassium bromate; sulfuric acid In water Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
1-bromo-3-(1,1-dimethoxyethyl)benzene
159684-74-9

1-bromo-3-(1,1-dimethoxyethyl)benzene

A

methanol
67-56-1

methanol

B

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With hydrogenchloride In water Rate constant; also for reaction catalysed with various bases;
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

1-(3-bromophenyl)ethanol
52780-14-0

1-(3-bromophenyl)ethanol

Conditions
ConditionsYield
With sodium tetrahydroborate In ethanol at 20℃; Solvent; Temperature;100%
Stage #1: 1-(3-Bromophenyl)ethanone With C107H90Cl2N10P4Ru2(2+)*2Cl(1-) In isopropyl alcohol at 82℃; for 0.166667h; Inert atmosphere;
Stage #2: With potassium isopropoxide In isopropyl alcohol for 2h; Catalytic behavior; Inert atmosphere;
100%
With C37H28Cl2N5PRu; isopropyl alcohol; sodium hydroxide at 82℃; under 750.075 Torr; for 0.00833333h; Catalytic behavior; Inert atmosphere;99%
pyridine
110-86-1

pyridine

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

1-(2-(3-bromophenyl)-2-oxoethyl)pyridin-1-ium iodide

1-(2-(3-bromophenyl)-2-oxoethyl)pyridin-1-ium iodide

Conditions
ConditionsYield
With iodine for 16h; Reflux; Inert atmosphere;100%
With iodine for 2h; Heating;91%
With iodine at 80℃; for 6h;78%
ethylene glycol
107-21-1

ethylene glycol

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

2-(3-bromophenyl)-2-methyl-[1,3]dioxolane
39172-32-2

2-(3-bromophenyl)-2-methyl-[1,3]dioxolane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In benzene Heating / reflux; water separator;100%
With toluene-4-sulfonic acid In benzene for 20h; Heating;98%
With toluene-4-sulfonic acid In toluene Heating;98%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

4-(3-bromophenyl)-1,2,3-thiadiazole

4-(3-bromophenyl)-1,2,3-thiadiazole

Conditions
ConditionsYield
Stage #1: 1-(3-Bromophenyl)ethanone With polystyrene-sulfonylhydrazide resin; acetic acid In tetrahydrofuran at 50℃; for 4h; Solid phase reaction;
Stage #2: With thionyl chloride In 1,2-dichloro-ethane at 60℃; for 5h; Solid phase reaction; Hurd-Mori cyclization;
100%
With iodine; potassium thioacyanate; toluene-4-sulfonic acid hydrazide; copper dichloride In dimethyl sulfoxide at 100℃; for 1h; Sealed tube;81%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

phenylboronic acid
98-80-6

phenylboronic acid

3-phenylacetophenone
3112-01-4

3-phenylacetophenone

Conditions
ConditionsYield
With potassium phosphate; 3-(2,6-diisopropylphenyl)-1-(2-diphenylphosphanylbenzyl)-3H-imidazol-1-ium chloride; bis(η3-allyl-μ-chloropalladium(II)) In 1,4-dioxane at 80℃; for 6h; Suzuki cross-coupling;100%
With caesium carbonate; [PdCl(NNCNHC-nBu)]BF4 In water; N,N-dimethyl-formamide at 80℃; for 0.5h; Suzuki-Miyaura reaction;99%
With potassium phosphate; [Pd2(3,4-dichloroacetophenone thiosemicarbazone)2(bis(diphenylphosphino)ferrocene)] In N,N-dimethyl-formamide at 130℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;99%
3-pyridylboronic acid
1692-25-7

3-pyridylboronic acid

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

3-(pyridin-3-yl)acetophenone
171092-38-9

3-(pyridin-3-yl)acetophenone

Conditions
ConditionsYield
With sodium tetrachloropalladate(II); 3-(di-tert-butylphosphino)-propane-1-sulfonic acid; sodium carbonate In 2-methyltetrahydrofuran at 80℃; for 4h; Inert atmosphere;100%
With potassium phosphate; palladium dichloride; S-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine In butan-1-ol at 100℃; for 20h; Suzuki coupling; Inert atmosphere;90%
3-methoxyphenyl bromide
2398-37-0

3-methoxyphenyl bromide

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

1-(3-bromo-phenyl)-1-(3-methoxy-phenyl)-ethanol
1180015-29-5

1-(3-bromo-phenyl)-1-(3-methoxy-phenyl)-ethanol

Conditions
ConditionsYield
Stage #1: 3-methoxyphenyl bromide With bromine; magnesium In diethyl ether at 20℃;
Stage #2: 1-(3-Bromophenyl)ethanone In diethyl ether for 3h; Reflux;
100%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

ethyl 4-(3-bromophenyl)-2,4-dioxobutanoate
473537-92-7

ethyl 4-(3-bromophenyl)-2,4-dioxobutanoate

Conditions
ConditionsYield
Stage #1: With sodium In ethanol at 0℃;
Stage #2: 1-(3-Bromophenyl)ethanone In ethanol at 10℃; for 2h;
Stage #3: oxalic acid diethyl ester In ethanol at 20℃; for 1.5h;
100%
Stage #1: 1-(3-Bromophenyl)ethanone With sodium ethanolate In ethanol at 0℃; for 1h;
Stage #2: oxalic acid diethyl ester In ethanol at 20℃; for 12h;
74%
With ethanol; sodium In diethyl ether at 20℃; for 0.25h;
With sodium In diethyl ether; ethanol at 20℃; for 0.25h;
With ethanol; sodium at 0 - 20℃; for 4h; Aldol Addition;
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

N-[1-(3-bromophenyl)ethylidene]hydroxyl amine
24280-05-5

N-[1-(3-bromophenyl)ethylidene]hydroxyl amine

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium acetate In ethanol; water at 95℃;100%
With pyridine; hydroxylamine hydrochloride at 80℃; for 0.25h;99%
With hydroxylamine hydrochloride; sodium hydroxide In methanol at 20℃; Green chemistry;91%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Diethyl carbonate
105-58-8

Diethyl carbonate

ethyl 3-bromobenzoylacetate
21575-91-7

ethyl 3-bromobenzoylacetate

Conditions
ConditionsYield
With sodium hydride In benzene Heating;99%
With sodium hydride In diethyl ether at 35 - 40℃;80%
Stage #1: Diethyl carbonate With sodium hydride In toluene; mineral oil Reflux;
Stage #2: 1-(3-Bromophenyl)ethanone In toluene; mineral oil Reflux;
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

1-(3-bromophenyl)-2-chloroethan-1-one
21886-58-8

1-(3-bromophenyl)-2-chloroethan-1-one

Conditions
ConditionsYield
With N,N,N-trimethylbenzenemethanaminium dichloroiodate In tetrahydrofuran at 20 - 25℃; for 72h; Inert atmosphere;99%
With N,N,N-trimethylbenzenemethanaminium dichloroiodate In methanol; 1,2-dichloro-ethane for 5h; Heating;66%
With potassium peroxymonosulfate; ammonium chloride In methanol for 3h; Reflux;98 %Chromat.
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; C45H58NP; potassium tert-butylate; hydrogen In propan-1-ol at 25 - 30℃; under 4560.31 Torr; for 0.166667h; Autoclave; optical yield given as %ee; enantioselective reaction;99%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (SC,SC,RFC)-1-(diphenylphosphino)-2-[1-N-((4S)-4-tert-butyl-2-oxazolinyl-2-ylmethyl)ethyl]ferrocene; hydrogen; potassium carbonate In isopropyl alcohol at 25℃; under 15201 Torr; for 2h; Glovebox; Autoclave; enantioselective reaction;99%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; f-ampha; hydrogen; lithium tert-butoxide In isopropyl alcohol at 25 - 30℃; under 15201 Torr; for 6h; Inert atmosphere; Autoclave; enantioselective reaction;99%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

2,3'-dibromoacetophenone
18523-22-3

2,3'-dibromoacetophenone

Conditions
ConditionsYield
With N-Bromosuccinimide; toluene-4-sulfonic acid In dichloromethane at 40℃; for 0.25h; Microwave irradiation; Green chemistry;99%
With hydrogen bromide; oxygen; 2-methylpyridinium nitrate In water at 60℃; for 10h;84%
With 1,4-dioxane dibromide; silica gel for 0.0166667h; microwave irradiation;83%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

(S)-1-(3-bromophenyl)ethan-1-ol
134615-22-8

(S)-1-(3-bromophenyl)ethan-1-ol

Conditions
ConditionsYield
With sodium formate; cetyltrimethylammonium chloride at 45℃; for 24h; enantioselective reaction;99%
With D-glucose In aq. phosphate buffer at 25℃; for 24h; pH=7.0; Reagent/catalyst; Temperature; pH-value; stereoselective reaction;99%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; C53H73FeN2O2PS; hydrogen; lithium tert-butoxide In isopropyl alcohol at 25 - 30℃; under 22801.5 Torr; for 12h; Autoclave; enantioselective reaction;99%
semicarbazide hydrochloride
563-41-7

semicarbazide hydrochloride

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

1-(1-(3-bromophenyl)ethylidene)semicarbazide
99847-76-4

1-(1-(3-bromophenyl)ethylidene)semicarbazide

Conditions
ConditionsYield
With sodium acetate In ethanol; water at 20℃;99%
Stage #1: semicarbazide hydrochloride With sodium acetate In ethanol at 20℃; for 0.25h;
Stage #2: 1-(3-Bromophenyl)ethanone In ethanol at 20℃;
91%
Stage #1: semicarbazide hydrochloride With sodium acetate In ethanol for 0.75h; Heating;
Stage #2: 1-(3-Bromophenyl)ethanone In ethanol for 1h; Heating;
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

3-Hydroxyacetophenone
121-71-1

3-Hydroxyacetophenone

Conditions
ConditionsYield
With copper acetylacetonate; N1-(4-hydroxy-2,6-dimethylphenyl)-N2-(4-hydroxy-3,5-dimethylphenyl)oxalamide; water In water; dimethyl sulfoxide at 80℃; for 24h; Schlenk technique; Inert atmosphere;99%
With potassium hydroxide; tris-(dibenzylideneacetone)dipalladium(0); tert-butyl XPhos In 1,4-dioxane; water at 80℃; for 14h;96%
With bis(η3-allyl-μ-chloropalladium(II)); t-BuBrettPhos; p-methylbenzaldehyde oxime; caesium carbonate In N,N-dimethyl-formamide at 90℃; for 5h; Catalytic behavior; Solvent; Reagent/catalyst; Inert atmosphere;90%
With tris(6,6'-diamino-2,2'-bipyridine); 4,4-diphenyl-1,3,5,7,8-pentamethyl-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene; Br2Ni*3H2O; water; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide; acetonitrile at 20℃; for 24h; Glovebox; Irradiation; Inert atmosphere;88%
With dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine; boric acid; palladium diacetate; caesium carbonate In 1-methyl-pyrrolidin-2-one at 80℃; for 24h; Schlenk technique; Inert atmosphere;72%
methylmagnesium bromide
75-16-1

methylmagnesium bromide

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

2-(3-bromophenyl)-2-propanol
30951-66-7

2-(3-bromophenyl)-2-propanol

Conditions
ConditionsYield
In diethyl ether at 0℃;99%
In diethyl ether at 0 - 20℃; for 4h;90%
Stage #1: methylmagnesium bromide; 1-(3-Bromophenyl)ethanone In diethyl ether at 0 - 20℃; for 4h;
Stage #2: With water In diethyl ether; ethyl acetate
90%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

2,6-dimethoxypyridine-3-boronic acid
221006-70-8

2,6-dimethoxypyridine-3-boronic acid

1-[3-(2,6-dimethoxy-3-pyridinyl)phenyl]ethanone
1169827-05-7

1-[3-(2,6-dimethoxy-3-pyridinyl)phenyl]ethanone

Conditions
ConditionsYield
With potassium phosphate; palladium dichloride; S-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine In butan-1-ol at 100℃; for 2h; Suzuki coupling; Inert atmosphere;99%
sodium cyanide
773837-37-9

sodium cyanide

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

3-acethylbenzonitrile
6136-68-1

3-acethylbenzonitrile

Conditions
ConditionsYield
With calcium dihydride; tri-tert-butyl phosphine; [Pd2(dba)5] In tetrahydrofuran; acetonitrile at 70℃; for 2h;99%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

phosphonic acid diethyl ester
762-04-9

phosphonic acid diethyl ester

C12H18BrO4P
710973-13-0

C12H18BrO4P

Conditions
ConditionsYield
With C46H76N5Si2Sm In toluene at 20℃; Schlenk technique; Inert atmosphere;99%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

2-bromo-4-(1,1-diethoxyethyl)benzene
480439-43-8

2-bromo-4-(1,1-diethoxyethyl)benzene

Conditions
ConditionsYield
With hydrogenchloride In ethanol; water for 4h; Inert atmosphere; Schlenk technique; Reflux;99%
potassium cyanide

potassium cyanide

ammonium carbonate
506-87-6

ammonium carbonate

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

(RS)-5-(3-bromo-phenyl)-5-methyl-imidazolidine-2,4-dione
6943-33-5

(RS)-5-(3-bromo-phenyl)-5-methyl-imidazolidine-2,4-dione

Conditions
ConditionsYield
In ethanol at 120℃; for 16h; autoclave;98.6%
With ethanol at 120℃; for 16h; autoclave;98.6%
In ethanol at 120℃; for 16h; Autoclave;98.6%
ammonium carbonate

ammonium carbonate

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

(RS)-5-(3-bromo-phenyl)-5-methyl-imidazolidine-2,4-dione
6943-33-5

(RS)-5-(3-bromo-phenyl)-5-methyl-imidazolidine-2,4-dione

Conditions
ConditionsYield
With potassium cyanide In ethanol at 120℃; for 16h; Autoclave;98.6%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

allyl bromide
106-95-6

allyl bromide

(R)-(+)-2-(3-bromophenyl)pent-4-en-2-ol

(R)-(+)-2-(3-bromophenyl)pent-4-en-2-ol

Conditions
ConditionsYield
Stage #1: allyl bromide With chromium chloride; manganese; (10,10-dimethyl-5-(pyridin-2-yl)-6-azatricyclo[7.1.1.02,7]undeca-2(7),3,5-trien-8-yl)diphenylmethanol; triethylamine In tetrahydrofuran at 20℃; for 1h;
Stage #2: 1-(3-Bromophenyl)ethanone With chloro-trimethyl-silane In tetrahydrofuran at 20℃; for 36h;
Stage #3: With tetrabutyl ammonium fluoride In tetrahydrofuran for 0.25h; Nozaki-Hiyama-Kishi Reaction; enantioselective reaction;
98.2%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

1-(3-bromophenyl)ethanol

1-(3-bromophenyl)ethanol

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (R)-N-(3-methylpyridine-2-methyl)-7-bis-(3,5-di-tert-butylphenyl)phosphino-7′-amino-1,1′-spirodihydroindane; potassium tert-butylate; hydrogen In ethanol at 20℃; under 6080.41 - 7600.51 Torr; for 0.833333h; Inert atmosphere; Sealed tube;98%
With 9,9-dimethylxanthene-4,5-diyl-bis{[chiral-BINOL]phosphonite}; potassium tert-butylate; isopropyl alcohol; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 at 40℃; for 28h;
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

1-(4'-methyl-[1,1'-biphenyl]-3-yl)ethan-1-one

1-(4'-methyl-[1,1'-biphenyl]-3-yl)ethan-1-one

Conditions
ConditionsYield
With caesium carbonate; [PdCl(NNCNHC-nBu)]BF4 In water; N,N-dimethyl-formamide at 80℃; for 0.5h; Suzuki-Miyaura reaction;98%
With C52H80N2O39Pd; potassium carbonate In water at 60℃; for 1h; Suzuki-Miyaura Coupling;93%
With potassium phosphate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole In 1,4-dioxane; water at 70℃; for 1h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube; chemoselective reaction;91%
With water; triethylamine; Pd(OAc)2EnCatTM In N,N-dimethyl-formamide at 85℃; for 5h; Suzuki-Miyaura reaction;
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

thiourea
17356-08-0

thiourea

2-amino-4-(m-bromophenyl)thiazole
105512-81-0

2-amino-4-(m-bromophenyl)thiazole

Conditions
ConditionsYield
With iodine at 100℃;98%
With iodine at 110℃; for 16h;71.2%
With iodine at 110℃; for 16h;71.2%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

(E)-1-(3-bromophenyl)ethan-1-one oxime
187672-17-9

(E)-1-(3-bromophenyl)ethan-1-one oxime

Conditions
ConditionsYield
With hydroxylamine hydrochloride; sodium hydrogencarbonate In methanol for 1.5h; Heating / reflux;98%
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water at 20℃; for 24h; pH=9; Cooling with ice;91%
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water at 0 - 20℃; for 24h; pH=9;91%
1-(3-Bromophenyl)ethanone
2142-63-4

1-(3-Bromophenyl)ethanone

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

1-(3-((trimethylsilyl)ethynyl)phenyl)ethan-1-one
141697-43-0

1-(3-((trimethylsilyl)ethynyl)phenyl)ethan-1-one

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran at 50℃; for 6h; Sonogashira Cross-Coupling; Inert atmosphere; Schlenk technique;98%
copper(I) iodide In bis(triphenylphosphine)palladium(II) dichloride
With copper(l) iodide; trans-bis(triphenylphosphine)palladium dichloride; triethylamine In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;
With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); triethylamine In tetrahydrofuran at 100℃; for 12h; Glovebox; Inert atmosphere;
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 50℃; for 16h; Inert atmosphere;

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