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inquiryProduct Name 2'-Bromoacetophenone CAS 2142-69-0 Molecular formula C8H7BrO Molecular weight 199.04 EINECS 218-
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inquiryProduct Name: 2'-Bromoacetophenone Synonyms: Acetophenone, o-bromo-;ETHANONE, 1-(2-BROMOPHENYL)-;AKOS BBS-00004325;1-(2-BROMOPHENYL)ETHANONE;1-(2-BROMOMPHENYL)ETHANONE;1-ACETYL-2-BROMOBENZENE;O-BROMOACETOPHENONE;O-BROMOPHENYL METHYL KETONE CA
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inquiry(1-(2-bromophenyl)ethoxy)trimethylsilane
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With nitrogen dioxide at 20℃; for 1h; | 100% |
Conditions | Yield |
---|---|
With Iron(III) nitrate nonahydrate; 1-hydroxy-pyrrolidine-2,5-dione; oxygen In benzonitrile at 90℃; for 21h; | 99% |
With Iron(III) nitrate nonahydrate; N-hydroxyphthalimide In benzonitrile at 100℃; for 20h; | 95% |
With oxygen; silica gel; 4-aminoperbenzoic acid In dichloromethane at 20℃; for 12h; | 73% |
Conditions | Yield |
---|---|
With hydrogenchloride In tetrahydrofuran; water; toluene at 20 - 25℃; for 2h; Friedel-Crafts Acylation; | 96.5% |
Conditions | Yield |
---|---|
With silica gel; pyridinium chlorochromate In dichloromethane at 20℃; for 2h; Inert atmosphere; | 96% |
With silica gel; pyridinium chlorochromate In dichloromethane at 20℃; for 2h; Inert atmosphere; | 95% |
With C53H46ClN3P2Ru; potassium tert-butylate; acetone at 56℃; under 750.075 Torr; for 3h; Oppenauer Oxidation; | 94% |
Conditions | Yield |
---|---|
With water at 80℃; for 2h; Temperature; Green chemistry; | 86% |
With iron(III) chloride; water; silver(I) triflimide In 1,4-dioxane at 80℃; for 60h; regioselective reaction; | 84% |
With water at 80℃; for 15h; | 84% |
methylmagnesium bromide
2-bromobenzoic acid chloride
A
2-bromophenyl methyl ketone
B
2-Methylacetophenone
Conditions | Yield |
---|---|
With iron(III)-acetylacetonate In tetrahydrofuran at -78℃; | A 85% B 7 % Chromat. |
ortho-bromobenzenesulfonyl hydrazide
acetonitrile
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With 1,10-Phenanthroline; water; palladium diacetate at 100℃; under 760.051 Torr; for 6h; | 82% |
Conditions | Yield |
---|---|
With trifluoromethanesulfonic acid anhydride; magnesium bromide In diethyl ether at 0℃; for 0.166667h; | 79% |
With N-Bromosuccinimide; silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; copper diacetate In 1,2-dichloro-ethane at 120℃; for 21h; Inert atmosphere; regioselective reaction; | 50% |
With tetra-n-butylammonium tribromide In methanol; diethyl ether; dichloromethane | |
With N-Bromosuccinimide; C18H24I2N5Pd(1+) In acetonitrile at 95℃; for 24h; Reagent/catalyst; Sealed tube; | 22 %Chromat. |
With N-Bromosuccinimide; 2Ru(2+)*4F6P(1-)*C47H34N8*Pd(2+)*C2H6OS*2I(1-) In 1,2-dichloro-ethane at 95℃; for 16h; Sealed tube; | 57 %Chromat. |
3-(2-bromophenyl)-3-oxopropionic acid methyl ester
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With hydrogenchloride In methanol; water at 70℃; for 6h; | 76% |
bromobenzene
acetyl chloride
A
2-bromophenyl methyl ketone
B
para-bromoacetophenone
Conditions | Yield |
---|---|
With iron(III) sulfate In hexane at 20℃; for 0.75h; Friedel-Crafts acylation; Sonication; | A 5.2% B 74% |
With poly(4-vinylpyridine) supported trifluoromethanesulfonic acid at 0 - 20℃; for 6h; Friedel-Crafts Acylation; Overall yield = 20 %; |
C10H11BrOS
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran; hexane at -78℃; for 3h; Inert atmosphere; | 74% |
trimethylsiloxyethene
1-Bromo-2-iodobenzene
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With palladium diacetate; triethylamine; triphenylphosphine In dimethyl sulfoxide; N,N-dimethyl-formamide at 20 - 100℃; for 2h; Heck Reaction; Microwave irradiation; regioselective reaction; | 72% |
2-bromo-N-methoxy-N-methylbenzamide
methylmagnesium bromide
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether at 0℃; for 15h; Inert atmosphere; | 72% |
In tetrahydrofuran; diethyl ether at 0 - 20℃; |
2-bromostyrene
A
2-bromophenyl methyl ketone
B
1-(2-bromophenyl)ethanol
Conditions | Yield |
---|---|
With tris(dibenzoylmethano)iron(III); phenylsilane In ethanol at 20℃; for 27h; Reagent/catalyst; Wacker Oxidation; | A 72% B 23% |
With triethylsilane; (1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-Hexadecafluorophthalocyaninato)iron(II); oxygen In ethanol at 20℃; under 760.051 Torr; for 13h; Wacker Oxidation; Sealed tube; Green chemistry; chemoselective reaction; | A 65% B 5% |
ethyl 2-cyanoacetate
(2-bromophenyl)boronic acid
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid; water; palladium diacetate; 2-(3,5-dimethyl-1H-pyrazol-1-yl)pyridine at 60℃; for 5h; regioselective reaction; | 66% |
Conditions | Yield |
---|---|
Stage #1: 2-aminoacetophenone With hydrogen bromide; sodium nitrite In water at 0℃; for 0.333333h; Inert atmosphere; Stage #2: With copper(I) bromide In water Inert atmosphere; | 60% |
With hydrogen bromide; copper(I) bromide | |
With sulfuric acid; copper(I) bromide Diazotization; |
Conditions | Yield |
---|---|
With bismuth(lll) trifluoromethanesulfonate; dipotassium peroxodisulfate; silver nitrate In water at 30℃; for 24h; Inert atmosphere; Green chemistry; | 60% |
1-(2-bromophenyl)ethanol
A
2-bromophenyl methyl ketone
B
(1S)-1-(2-bromophenyl)ethanol
C
(1R)-1-(2-bromophenyl)ethan-1-ol
Conditions | Yield |
---|---|
With sodium hydrogencarbonate; sodium bromide; chiral 4,1'-dinaphthyl-3,2'-cyclo[C(Me)2-N(oxyl)-C(Me)2] In dichloromethane; water at -15℃; for 1.5h; resolution of racemate; Electrolysis; Title compound not separated from byproducts; | A 54% B n/a C n/a |
Stage #1: 1-(2-bromophenyl)ethanol With N,N'-bis(salicylidene)-1,2-cyclohexanediaminomanganese(III) chloride; potassium acetate In dichloromethane; water for 0.0833333h; Stage #2: With N-Bromosuccinimide In dichloromethane; water at 20℃; for 4h; Kinetics; enantioselective reaction; | A n/a B n/a C n/a |
Conditions | Yield |
---|---|
With manganese(IV) oxide; palladium dichloride In water; acetonitrile at 60℃; for 25h; | 53% |
With methanol; oxygen; potassium carbonate at 150℃; under 3000.3 Torr; for 12h; regioselective reaction; | 47.3 %Chromat. |
1-(2-bromophenyl)ethanol
A
2-bromophenyl methyl ketone
B
(1R)-1-(2-bromophenyl)ethan-1-ol
Conditions | Yield |
---|---|
With C50H42ClN2O3Ru In chloroform at 25℃; Kinetics; Molecular sieve; Resolution of racemate; enantioselective reaction; | A n/a B 48.8% |
Stage #1: 1-(2-bromophenyl)ethanol With C28H36ClMnN2O2; potassium acetate In dichloromethane; water for 0.0833333h; Stage #2: With N-Bromosuccinimide In dichloromethane; water at 20℃; for 4h; Kinetics; enantioselective reaction; | A n/a B n/a |
Conditions | Yield |
---|---|
With oxygen at 190℃; under 760.051 Torr; for 24h; Autoclave; | 34% |
o-bromo-α-fluoroacetophenone
A
2-fluoroacetophenone
B
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole; azobisisobutyronitrile In acetonitrile at 90℃; for 1.5h; Rate constant; other temp., other concentration, and time; | A 8.5% B 21.7% |
α-(benzoyloxy)-o-bromoacetophenone
A
phenacyl benzoate
B
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With tris(2,2'-bipyridine)ruthenium(II) perchlorate; 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole In acetonitrile at 20℃; for 13h; Rate constant; Irradiation; other reagents, reaction without irradiation, var. time; | A 15.7% B 12.5% |
diazomethane
2-bromobenzoic acid chloride
2-bromophenyl methyl ketone
methyl magnesium iodide
o-cyanobromobenzene
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With diethyl ether anschliessendes Behandeln mit wss. HCl; |
3-(2-bromophenyl)-3-oxopropionic acid ethyl ester
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With sulfuric acid |
Conditions | Yield |
---|---|
With diethyl (ethoxymagnesio)malonate | |
With dimethylcadmium | |
Multi-step reaction with 3 steps 1: aqueous ammonia 2: thionyl chloride 3: diethyl ether / anschliessendes Behandeln mit wss. HCl View Scheme | |
Multi-step reaction with 2 steps 1: triethylamine / dichloromethane / 1 h / 0 - 20 °C 2: tetrahydrofuran; diethyl ether / 0 - 20 °C View Scheme |
3-methyl-4-(o-bromophenyl)-1,2-dioxetane
A
formaldehyd
B
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With 9,10-Dibromoanthracene; 9,10-diphenylanthracene In tetrachloromethane at 60℃; Rate constant; Thermodynamic data; Ea; ΔH(excit.); ΔS(excit.); ΔG(excit.); |
Conditions | Yield |
---|---|
With potassium bromate; sulfuric acid In water Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
With [{(CH3)2C3HN2-C5H3N-C3H3N2}RuCl2(PPh3)]; potassium isopropoxide; isopropyl alcohol at 82℃; for 0.00277778h; Inert atmosphere; | 100% |
Stage #1: 2-bromophenyl methyl ketone With C107H90Cl2N10P4Ru2(2+)*2Cl(1-) In isopropyl alcohol at 82℃; for 0.166667h; Inert atmosphere; Stage #2: With potassium isopropoxide In isopropyl alcohol for 2h; Catalytic behavior; Inert atmosphere; | 100% |
Stage #1: 2-bromophenyl methyl ketone With sodium tetrahydroborate In methanol at 20℃; for 24h; Stage #2: With water In methanol | 100% |
2-bromophenyl methyl ketone
phenylhydrazine
N-[1-(2-Bromo-phenyl)-eth-(Z)-ylidene]-N'-phenyl-hydrazine
Conditions | Yield |
---|---|
In 1-methyl-pyrrolidin-2-one at 160℃; for 0.166667h; microwave irradiation; | 100% |
In diethyl ether Heating; | |
With acetic acid In ethanol for 0.166667h; Heating; Yield given; |
2-bromophenyl methyl ketone
2-Methylphenylboronic acid
1-(2′-methyl-[1,1′-biphenyl]-2-yl)ethanone
Conditions | Yield |
---|---|
With potassium phosphate; CyJohnPhos; polymer-incarcerated palladium In water; toluene for 2h; Suzuki-Miyaura coupling; Heating; | 100% |
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; ethanol Product distribution; Heating; Suzuki coupling of bromo-acylbenzenes resp. bromo-indole carbaldehydes with boronic acids; | 98% |
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; ethanol rt, 15 min; reflux, 48 h; | 98% |
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
Stage #1: 2-bromophenyl methyl ketone With polystyrene-sulfonylhydrazide resin; acetic acid In tetrahydrofuran at 50℃; for 4h; Solid phase reaction; Stage #2: With thionyl chloride In 1,2-dichloro-ethane at 60℃; for 5h; Solid phase reaction; Hurd-Mori cyclization; | 100% |
Multi-step reaction with 2 steps 1: sulfuric acid / ethanol / 2 h / Reflux 2: thionyl chloride / 2 h / 5 - 60 °C View Scheme | |
Multi-step reaction with 2 steps 1: sulfuric acid / ethanol / 20 °C / Reflux 2: thionyl chloride / 2 h / Reflux View Scheme | |
Multi-step reaction with 2 steps 1: ethanol / 3 h / 80 °C 2: thionyl chloride / 2 h / 80 °C View Scheme |
2-bromophenyl methyl ketone
dimethyl zinc(II)
2-Methylacetophenone
Conditions | Yield |
---|---|
(1,2-bis(diphenylphosphino)ethane)palladium(II) chloride In 1,4-dioxane for 1.5h; Heating; | 100% |
2-bromophenyl methyl ketone
sodium thiomethoxide
2'-(methylthio)acetophenone
Conditions | Yield |
---|---|
In tetrahydrofuran at 75℃; for 10h; | 100% |
In tetrahydrofuran at 75℃; for 12h; | 88% |
In tetrahydrofuran |
2-bromophenyl methyl ketone
2-(2-bromophenyl)-2-oxoacetic acid
Conditions | Yield |
---|---|
With pyridine; selenium(IV) oxide at 100℃; for 2h; | 100% |
With hydrogenchloride; sodium dichromate In water at 95℃; for 6h; | 90% |
With pyridine; selenium(IV) oxide at 120℃; for 18h; Inert atmosphere; | 87% |
2-bromophenyl methyl ketone
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride; sodium acetate In methanol Heating; | 100% |
With hydroxylamine hydrochloride; sodium hydroxide In ethanol; water at 20℃; for 24h; pH=9; Cooling with ice; | 92% |
With hydroxylamine hydrochloride; sodium carbonate In ethanol; water pH=5; Reflux; | 89% |
2-bromophenyl methyl ketone
1-bromo-2-(1,1-difluoroethyl)benzene
Conditions | Yield |
---|---|
With 4-tert-butyl-2,6-dimethylphenylsulfur trifluoride; pyridine hydrofluoride In dichloromethane at 23℃; for 18h; | 100% |
With (bis-(2-methoxyethyl)amino)sulfur trufluoride; methanol at 70℃; for 18h; | 63% |
With morpholinosulfur trifluoride In dichloromethane; water at 20℃; for 672h; | 12% |
2-bromophenyl methyl ketone
1-(tert-butoxycarbonyl)-4-((tert-butoxycarbonyl)amino)piperidine-4-carboxylic acid
4-tert-butoxycarbonylamino-4-(5-phenyl-1H-imidazol-2-yl)-piperidine-1-carboxylic acid tert-butyl ester
Conditions | Yield |
---|---|
Stage #1: 1-(tert-butoxycarbonyl)-4-((tert-butoxycarbonyl)amino)piperidine-4-carboxylic acid With caesium carbonate In methanol for 2h; Stage #2: 2-bromophenyl methyl ketone In N,N-dimethyl-formamide for 2h; Stage #3: With ammonium acetate In xylenes at 20 - 135℃; for 52h; | 100% |
2-bromophenyl methyl ketone
B-allyl-1,3,2-dioxaborinane
(S)-(−)-2-(2-bromophenyl)-pent-4-en-2-ol
Conditions | Yield |
---|---|
Stage #1: B-allyl-1,3,2-dioxaborinane With (S)-3,3'-dibromo-1,1'-bi-2-naphthol In toluene at 135℃; for 1h; Inert atmosphere; Stage #2: 2-bromophenyl methyl ketone In toluene at 35℃; for 120h; Inert atmosphere; | 100% |
With (S)-3,3'-dibromo-1,1'-bi-2-naphthol; tert-butyl alcohol In toluene at 20℃; for 24h; Inert atmosphere; enantioselective reaction; | 95% |
2-bromophenyl methyl ketone
(1R)-1-(2-bromophenyl)ethan-1-ol
Conditions | Yield |
---|---|
With lithium hydroxide; (S)-quinolin-4-yl((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methanamine; hydrogen; triphenylphosphine; iridium In methanol at 30℃; under 45004.5 Torr; for 3h; optical yield given as %ee; enantioselective reaction; | 99% |
With dimethylsulfide borane complex; 3-hydroxy-N-[(1R,2S)-cis-2-hydroxy-2,3-dihydro-1H-inden-1-yl]naphthalene-2-carboxamide In tetrahydrofuran at 65℃; Inert atmosphere; enantioselective reaction; | 99% |
With formic acid; triethylamine In water at 50℃; for 6h; enantioselective reaction; | 98% |
2-bromophenyl methyl ketone
(1S)-1-(2-bromophenyl)ethanol
Conditions | Yield |
---|---|
With hydrogen; potassium hydroxide; 9-amino-9-deoxyepicinchonine In isopropyl alcohol at 40℃; under 45004.5 Torr; for 5h; Autoclave; optical yield given as %ee; enantioselective reaction; | 99% |
With dimethylsulfide borane complex; 3-hydroxy-N-[(2S)-1-hydroxy-1,1,3-triphenylpropan-2-yl]naphthalene-2-carboxamide In tetrahydrofuran at 65℃; Inert atmosphere; enantioselective reaction; | 99% |
With D-glucose In aq. phosphate buffer at 25℃; for 24h; pH=7.0; stereoselective reaction; | 99% |
phthalimide
2-bromophenyl methyl ketone
2-(2-acetylphenyl)-1H-isoindole-1,3(2H)-dione
Conditions | Yield |
---|---|
With copper(I) oxide at 100℃; for 48h; | 99% |
2-bromophenyl methyl ketone
phenylboronic acid
1-([1,1'-biphenyl]-2-yl)ethanone
Conditions | Yield |
---|---|
With palladium diacetate; N,N-diisopropyl-1,1-diphenylphosphanamine; potassium carbonate In tetrahydrofuran for 48h; Suzuki-Miyamura cross-coupling reaction; Heating; | 99% |
With potassium phosphate monohydrate; 1‐ethyl‐2‐(1‐ethylindol-2-yl)benzoimidazole; palladium diacetate In 1,4-dioxane at 60℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique; | 99% |
With Ph2P(CH2CH2O)22CH3; triethylamine; palladium dichloride In water at 100℃; for 1h; Suzuki coupling; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 18h; Suzuki coupling; Inert atmosphere; Reflux; | 99% |
With triethylamine In methanol for 8h; Suzuki Coupling; | 91% |
With C42H48Cl4N4Pd2S2; potassium carbonate In water at 60℃; for 24h; Time; Suzuki-Miyaura Coupling; Inert atmosphere; | 88% |
2-bromophenyl methyl ketone
1,3,5-tris(2’-bromophenyl)benzene
Conditions | Yield |
---|---|
With tetrachlorosilane In ethanol at 20℃; | 99% |
With tetrachlorosilane In ethanol at 0 - 20℃; for 16h; Inert atmosphere; | 97% |
With tetrachlorosilane In ethanol at 0 - 20℃; for 25.5h; Inert atmosphere; | 90% |
2-bromophenyl methyl ketone
ethyltriphenylphosphonium bromide
(E)-1-bromo-2-(but-2-en-2-yl)benzene
Conditions | Yield |
---|---|
Stage #1: ethyltriphenylphosphonium bromide With potassium tert-butylate In toluene at 0 - 23℃; Stage #2: 2-bromophenyl methyl ketone In toluene for 8h; Heating; | 99% |
Conditions | Yield |
---|---|
With KNdF4 for 0.0666667h; Irradiation; | 99% |
With C29H38AlN4O2(1+)*CF3O3S(1-) In neat (no solvent) at 20℃; for 0.5h; Catalytic behavior; Inert atmosphere; Schlenk technique; | 97% |
Fe(Cp)2PF6 at 20℃; for 0.166667h; | 93% |
With R-(+)-α-methylbenzylamine-(2R,3R)-(-)-2,3-dihydroxybutanedioic acid In dichloromethane at 10 - 20℃; for 84h; optical yield given as %ee; |
2-bromophenyl methyl ketone
2-formylbenzene boronic acid
2’acetyl-[1,1'-biphenyl]-2-carbaldehyde
Conditions | Yield |
---|---|
With potassium fluoride; palladium diacetate; 2-[bis(1,1-dimethylethyl)phosphino]-1-phenyl-1H-indole In tetrahydrofuran at 20℃; for 2h; Suzuki-Miyaura coupling; Inert atmosphere; | 99% |
With tris-(dibenzylideneacetone)dipalladium(0); potassium fluoride dihydrate; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran at 40℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; | 99% |
With tris-(dibenzylideneacetone)dipalladium(0); potassium fluoride dihydrate; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran Suzuki-Miyaura coupling; Inert atmosphere; | 95% |
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,3-dioxane at 80℃; for 14h; Inert atmosphere; | 71% |
2-bromophenyl methyl ketone
2-formyl-4,5-(methylenedioxy)benzeneboronic acid
6-(2-acetylphenyl)benzo[d][1,3]dioxole-5-carbaldehyde
Conditions | Yield |
---|---|
With potassium fluoride; palladium diacetate; 2-[bis(1,1-dimethylethyl)phosphino]-1-phenyl-1H-indole In tetrahydrofuran at 20℃; for 2h; Suzuki-Miyaura coupling; Inert atmosphere; | 99% |
2,6-bis(hydrazino)pyridine
2-bromophenyl methyl ketone
C21H19Br2N5
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In benzene Reflux; Inert atmosphere; | 99% |
fur-2-ylboronic acid
2-bromophenyl methyl ketone
1-(2-(furan-2-yl)phenyl)ethan-1-one
Conditions | Yield |
---|---|
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene for 18h; Inert atmosphere; Reflux; | 99% |
Conditions | Yield |
---|---|
Stage #1: 2-bromophenyl methyl ketone With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine at 20℃; for 0.5h; Sealed tube; Inert atmosphere; Stage #2: pent-1-yn-5-ol at 85℃; for 48h; Sealed tube; Inert atmosphere; | 99% |
2-bromophenyl methyl ketone
benzaldehyde
1-(2-bromophenyl)-3-phenylprop-2-en-1-one
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol; water at 25℃; Claisen-Schmidt Condensation; | 98.3% |
With sodium hydroxide In ethanol at 20℃; for 3h; | 91% |
2-bromophenyl methyl ketone
ethylene glycol
2-(2-bromophenyl)-2-methyl-1,3-dioxolane
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene Dean-Stark; Reflux; Inert atmosphere; | 98% |
With toluene-4-sulfonic acid In toluene for 18h; Dean-Stark; Reflux; | 94% |
With toluene-4-sulfonic acid In benzene for 2h; Heating; | 93% |
2-bromophenyl methyl ketone
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
2-(2-bromophenyl)-pent-4-en-2-ol
Conditions | Yield |
---|---|
With indium In water at 30℃; for 24h; Inert atmosphere; | 98% |
With indium iodide In tetrahydrofuran at 40℃; for 24h; | 97% |
Conditions | Yield |
---|---|
With sodium hydroxide In methanol at 20℃; Inert atmosphere; | 98% |
With ethanol; sodium hydroxide at 20℃; for 3h; Claisen Schmidt condensation; | 70% |
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