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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2,6-Dimethylbenzoquinone

Cas:527-61-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:Whit

2,6-DiMethyl-1,4-benzoquinone

Cas:527-61-7

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2,6-Dimethyl-1,4-benzoquinone

Cas:527-61-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company engages in Sodium Tripolyphosphate (STPP) and Sodium Hexametabphosphate (SHMP) production; development of noble metal catalysts, synthesis of electronic chemical materials and general chemicals Imp&Exp trading business. The company

TIANFU-CHEM - 2,6-DIMETHYLBENZOQUINONE

Cas:527-61-7

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 527-61-7 with best quality

Cas:527-61-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2,5-Cyclohexadiene-1,4-dione,2,6-dimethyl- 527-61-7

Cas:527-61-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

2,6-DiMethyl-1,4-benzoquinone CAS NO.527-61-7

Cas:527-61-7

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2,6-DIMETHYLBENZOQUINONE

Cas:527-61-7

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:527-61-7

Cas:527-61-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2,6-DIMETHYLBENZOQUINONE

Cas:527-61-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2,6-Dimethyl-1,4-benzoquinone

Cas:527-61-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,6-Dimethylbenzoquinone

Cas:527-61-7

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2,6-Dimethyl-1,4-Benzoquinone

Cas:527-61-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2,6-Dimethylbenzoquinone

Cas:527-61-7

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

2,6-DiMethylcyclohexa-2,5-diene-1,4-dione

Cas:527-61-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 2,6-Dimethyl-p-benzoquinone 5g

Cas:527-61-7

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2,6-DiMethyl-1,4-benzoquinone

Cas:527-61-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

2,6-Dimethylcyclohexa-2,5-diene-1,4-dione

Cas:527-61-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

2,6-Dimethylbenzoquinone cas 527-61-7Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2,6-Dimethylbenzoquinone cas 527-61-7

Cas:527-61-7

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low priceAppearance:yellow solid Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

2,6-Dimethylbenzoquinone

Cas:527-61-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

2,6-DIMETHYLBENZOQUINONE

Cas:527-61-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Application:Medical or chemical

527-61-7

Cas:527-61-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:White powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutica

2,6-Dimethylbenzoquinone manufacturer

Cas:527-61-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2,6-DIMETHYLBENZOQUINONE

Cas:527-61-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Watson International Ltd

Watson International Ltd' has a very strong R&D and technical capacity supported by FCAD's platform. The subsidiaries under FCAD Group have accumulated much know-how of different fine chemical branches. For example, Apnoke Scientific L

2,6-Dimethylbenzoquinone

Cas:527-61-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

2,6-DiMethyl-1,4-benzoquinone CAS NO.527-61-7 CAS NO.527-61-7

Cas:527-61-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

suzhou BetterBioChem Co., Ltd.

Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

2,6-DIMETHYL-BENZOQUINONE

Cas:527-61-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Yinghao Pharm Co.,Ltd.

Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat

2,6-DIMETHYLBENZOQUINONE

Cas:527-61-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

2,6-DiMethyl-p-benzoquinone

Cas:527-61-7

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 2,6-DIMETHYLBENZOQUINONE, CAS:527-61-7 with the most competitive price and the best q

2,6-DIMETHYLBENZOQUINONE

Cas:527-61-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

1,4-dihydroxy-2,6-dimethylbenzene
654-42-2

1,4-dihydroxy-2,6-dimethylbenzene

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With nitric acid; sodium nitrite In methanol at -10℃;100%
With dihydrogen peroxide; bis-(tributyltin oxide) dioxochromium(VI) In benzene at 50℃; for 2h;91%
With air; cobalt(II) phthalocyanine; Montmorillonite K10 In 1,4-dioxane; water at 20℃; for 6h;90%
2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With titanium superoxide; dihydrogen peroxide; acetic acid In water at 50℃; for 2h;97%
With Oxone; sodium iodide; benzene In water; acetonitrile at 40℃; Reagent/catalyst; Temperature;96%
With [N,N'-bis(salicylidene)ethane-1,2-diaminato]cobalt(II); oxygen In N,N-dimethyl-formamide95%
2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

A

1,4-dihydroxy-2,6-dimethylbenzene
654-42-2

1,4-dihydroxy-2,6-dimethylbenzene

B

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With dihydrogen peroxide; Ti-superoxide In water; acetic acid at 50 - 60℃; for 1.25h; Product distribution / selectivity;A 2%
B 97%
3,5-Dimethylphenol
108-68-9

3,5-Dimethylphenol

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With oxygen In water; acetonitrile at 40℃; under 15001.5 Torr; for 1h; Green chemistry;90%
With tert.-butylhydroperoxide In decane; acetonitrile at 70℃; for 3h; Catalytic behavior; regioselective reaction;88%
With 2,6-dicarboxypyridinium fluorochromate at 20℃; for 0.166667h;86%
4,4-dimethoxy-3,5-dimethylcyclohexa-2,5-dien-1-one
116760-59-9

4,4-dimethoxy-3,5-dimethylcyclohexa-2,5-dien-1-one

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With sulfuric acid In 1,2-dimethoxyethane for 1h; Hydrolysis; Heating;90%
2,6-dimethylaniline
87-62-7

2,6-dimethylaniline

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With cerium(IV) chlorate; 4-amino-phenol In perchloric acid for 2h;88%
Oxydation;
With potassium nitrososulfonate
4-bromo-2,6-dimethyl-phenol
2374-05-2

4-bromo-2,6-dimethyl-phenol

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With oxygen; copper dichloride In water; N,N-dimethyl-formamide at 60℃; for 16h;88%
Mesitol
527-60-6

Mesitol

A

4-hydroxy-3,5-dimethylbenzaldehyde
2233-18-3

4-hydroxy-3,5-dimethylbenzaldehyde

B

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With oxygen; acetone oxime In various solvent(s) at 40℃; under 860.3 Torr; for 6h;A 87%
B 4%
With oxygen In various solvent(s) at 60℃; under 860.3 Torr; for 5h; Product distribution; Mechanism; Rate constant; var. aditives, times, solvents;A 77.7%
B 3.7%
With oxygen; diethylamine In various solvent(s) at 60℃; under 860.3 Torr; for 4h; Product distribution; other amines; variation of condition;
With oxygen; diethylamine In various solvent(s) at 60℃; under 860.3 Torr; for 4h; Yield given. Yields of byproduct given;
2,6-dimethyl-4-chlorophenol
1123-63-3

2,6-dimethyl-4-chlorophenol

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With oxygen In methanol at 21.85℃; Irradiation;86%
2,5-dimethylbenzamide
55321-98-7

2,5-dimethylbenzamide

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With sodium hydrogen sulfate; [bis(acetoxy)iodo]benzene In water; acetonitrile at 20℃; for 0.666667h;85%
2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

A

3,3',5,5'-tetramethyldiphenoquinone
4906-22-3

3,3',5,5'-tetramethyldiphenoquinone

B

4-hydroxy-3,5-dimethylphenyl acetate
880-06-8

4-hydroxy-3,5-dimethylphenyl acetate

C

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With manganese triacetate; ammonium chloride In acetic acid at 100℃; for 0.333333h;A 84%
B 6%
C 2%
Mesitol
527-60-6

Mesitol

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

B

3,3',5,5'-tetramethyl-4,4'-dihydroxybiphenyl
2417-04-1

3,3',5,5'-tetramethyl-4,4'-dihydroxybiphenyl

C

3,3',5,5'-tetramethyl-4,4'-diphenoquinone

3,3',5,5'-tetramethyl-4,4'-diphenoquinone

Conditions
ConditionsYield
With C34H24Cl4Cu2FeN10O4(1-)*C8H20N(1+); oxygen; sodium hydroxide In methanol at 25℃; for 6h;A 80%
B 4%
C 6%
2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

B

3,3',5,5'-tetramethyl-4,4'-diphenoquinone

3,3',5,5'-tetramethyl-4,4'-diphenoquinone

Conditions
ConditionsYield
With C34H22Cl4CoCu2N10O4(1-)*C8H20N(1+); oxygen; sodium hydroxide In methanol at 25℃; for 6h;A 77%
B 10%
With vanadium(V); acetic acid In water at 25℃; Rate constant; Product distribution; Mechanism; effect of substrate, oxidant concentration, acidity, further temperature, solvent;
N-acetyl-3,5-dimethyl-1,4-benzoquinone imine
74827-88-6

N-acetyl-3,5-dimethyl-1,4-benzoquinone imine

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With water In acetone for 6h; Heating;76%
2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

A

3,3',5,5'-tetramethyldiphenoquinone
4906-22-3

3,3',5,5'-tetramethyldiphenoquinone

B

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With cobalt(III) acetate In acetic acid at 70℃; for 5.5h;A 75%
B 23%
With oxygen; NPV6Mo6/C In acetic acid at 60℃; under 760 Torr; for 5h;A 52%
B 29%
With 2(O2) (1); oxygen In chloroform at 25℃; under 735.5 Torr; for 2h; Rate constant; Product distribution; Mechanism; other phenols and catechol;
2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

B

3,3',5,5'-tetramethyl-4,4'-dihydroxybiphenyl
2417-04-1

3,3',5,5'-tetramethyl-4,4'-dihydroxybiphenyl

C

3,3',5,5'-tetramethyl-4,4'-diphenoquinone

3,3',5,5'-tetramethyl-4,4'-diphenoquinone

Conditions
ConditionsYield
With C34H24Cl4Cu2FeN10O4(1-)*C8H20N(1+); oxygen; sodium hydroxide In methanol at 25℃; for 6h;A 73%
B 12%
C 15%
2,6-dimethyl-cyclohex-3-ene-1,2-diol
187873-55-8

2,6-dimethyl-cyclohex-3-ene-1,2-diol

A

1,4-dihydroxy-2,6-dimethylbenzene
654-42-2

1,4-dihydroxy-2,6-dimethylbenzene

B

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With silica gel; pyridinium chlorochromate In dichloromethane at 20℃; for 1h;A 71%
B 6%
4-(hydroxymethyl)-2,6-dimethylphenol
4397-14-2

4-(hydroxymethyl)-2,6-dimethylphenol

A

4-hydroxy-3,5-dimethylbenzaldehyde
2233-18-3

4-hydroxy-3,5-dimethylbenzaldehyde

B

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With oxygen; amine>cobalt In dichloromethane under 2585.7 Torr; for 20h; Ambient temperature;A n/a
B 70%
With K10 montmorillonite; water; dihydrogen peroxide In tetrachloromethane at 22℃; for 2h; Oxidation;A 3 % Chromat.
B 57 % Chromat.
Mesitol
527-60-6

Mesitol

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With oxygen; horseradish peroxidase pH=7; Oxidation; electrolysis after 8 F;70%
Multi-step reaction with 2 steps
1: 5 percent Chromat. / H2O2; K10 montmorillonite; H2O / CCl4 / 2 h / 22 °C
2: 59 percent Chromat. / H2O2; K10 montmorillonite; H2O / CCl4 / 2 h / 22 °C
View Scheme
Multi-step reaction with 2 steps
1: 12 percent Chromat. / H2O2; K10 montmorillonite; H2O / CCl4 / 2 h / 22 °C
2: 5 percent Chromat. / H2O2; K10 montmorillonite; H2O / CCl4 / 2 h / 22 °C
View Scheme
4-hydroxy-3,5-dimethylbenzaldehyde
2233-18-3

4-hydroxy-3,5-dimethylbenzaldehyde

A

1,4-dihydroxy-2,6-dimethylbenzene
654-42-2

1,4-dihydroxy-2,6-dimethylbenzene

B

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; 1,3-dimethyl-5-ethyl-4a-hydroperoxyalloxazine; oxygen; sodium hydrogencarbonate In water; acetonitrile at 20℃; for 3h; Dakin Phenol Oxidation;A 23%
B 65%
Mesitol
527-60-6

Mesitol

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

B

3,3',5,5'-tetramethyl-4,4'-diphenoquinone

3,3',5,5'-tetramethyl-4,4'-diphenoquinone

Conditions
ConditionsYield
With C34H22Cl4CoCu2N10O4(1-)*C8H20N(1+); oxygen; sodium hydroxide In methanol at 25℃; for 6h;A 65%
B 20%
ethylene glycol
107-21-1

ethylene glycol

3,5-Dimethylphenol
108-68-9

3,5-Dimethylphenol

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene In hexane; ethylene glycol 0 deg C; 0 deg C to RT, 2 h;63%
4-Amino-3,5-dimethylphenol hydrochloride
14033-85-3

4-Amino-3,5-dimethylphenol hydrochloride

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

B

3,5-dimethyl-4-diazocyclohexa-2,5-dienone

3,5-dimethyl-4-diazocyclohexa-2,5-dienone

Conditions
ConditionsYield
With sulfuric acid; sodium nitrite at 20℃; for 0.333333h;A n/a
B 61%
3,5-dimethylmethoxybenzene
874-63-5

3,5-dimethylmethoxybenzene

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Conditions
ConditionsYield
With 1,1,1,3',3',3'-hexafluoro-propanol; urea hydrogen peroxide adduct at 45℃; Sealed tube; Green chemistry;57%
With tert.-butylhydroperoxide; ruthenium(III) 1,4,7-triazacyclononane-based catalyst In dichloromethane; 1,2-dichloro-ethane at 20℃; for 14h;15%
With perchloric acid; cerium(IV) perchlorate In acetonitrile at 24.9℃;
m-xylene
108-38-3

m-xylene

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

B

3-methylbenzyl alcohol
587-03-1

3-methylbenzyl alcohol

C

m-tolyl aldehyde
620-23-5

m-tolyl aldehyde

Conditions
ConditionsYield
With cerium(IV) sulphate; sulfuric acid In water at 90℃; for 2h; Kinetics; Mechanism; Rate constant; activation energy, mechanism; other times, other temperatures;A 7.6%
B 16.5%
C 55.5%
With cerium (IV) sulfate; sulfuric acid In water at 90℃;A 7.6%
B 16.5%
C 55.5%
With cerium (IV) sulfate; sulfuric acid In water at 75℃;A 17.3%
B 14.3%
C 48.9%
2,6-dimethylaniline
87-62-7

2,6-dimethylaniline

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

B

2,6-dimethylnitrobenzene
81-20-9

2,6-dimethylnitrobenzene

Conditions
ConditionsYield
With tert.-butylhydroperoxide; salcomine In water; 1,2-dichloro-ethane at 23℃; for 1h;A 27%
B 52%
2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

B

3,5-dimethyl-2-hydroxy-p-benzoquinone
2913-40-8

3,5-dimethyl-2-hydroxy-p-benzoquinone

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII) In acetic acid at 40℃; for 4h;A 50%
B 5%
2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

B

3,5-dimethyl-2-hydroxy-p-benzoquinone
2913-40-8

3,5-dimethyl-2-hydroxy-p-benzoquinone

C

1,7-Dihydroxy-2,6-dioxo-1,3,5,7-tetramethyl-5,8-etheno-1,2,5,6,7,8,4a,8a-octahydro-naphthalin; dimeres 6-Hydroxy-2,6-dimethyl-cyclohexadien-(2,4)-on-(1)
5520-77-4

1,7-Dihydroxy-2,6-dioxo-1,3,5,7-tetramethyl-5,8-etheno-1,2,5,6,7,8,4a,8a-octahydro-naphthalin; dimeres 6-Hydroxy-2,6-dimethyl-cyclohexadien-(2,4)-on-(1)

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII) In acetic acid at 40℃; for 4h;A 50%
B 5%
C 23%
methanol
67-56-1

methanol

2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

(1RS,2RS,3SR,7SR,8SR,10SR)-3,10-dimethoxy-3,5,8,10-tetramethyltricyclo[6.2.2.02,7]dodeca-5,11-diene-4,9-dione

(1RS,2RS,3SR,7SR,8SR,10SR)-3,10-dimethoxy-3,5,8,10-tetramethyltricyclo[6.2.2.02,7]dodeca-5,11-diene-4,9-dione

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene at 20℃; for 1h; Oxidation; cyclization;A 49%
B 16%
methanol
67-56-1

methanol

2.6-dimethylphenol
576-26-1

2.6-dimethylphenol

A

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

B

4,4-dimethoxy-2,6-dimethylcyclohexa-2,5-dienone
57197-12-3

4,4-dimethoxy-2,6-dimethylcyclohexa-2,5-dienone

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene at 20℃; for 1h; Oxidation; Title compound not separated from byproducts;A n/a
B 48%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

1,4-dihydroxy-2,6-dimethylbenzene
654-42-2

1,4-dihydroxy-2,6-dimethylbenzene

Conditions
ConditionsYield
With sodium dithionite In diethyl ether; water100%
With sodium dithionite In diethyl ether; water at 20℃;100%
With isopropyl alcohol; zirconium(IV) oxide for 2h; Heating;99%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

2,6-dimethyldihydroquinone
74894-46-5, 74894-47-6

2,6-dimethyldihydroquinone

Conditions
ConditionsYield
With hydrogen; Pd on C In methanol under 760.051 Torr;100%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

(1SR,4RS,4aSR,8aRS)-4a,6-dimethyl-1,4,4a,8a-tetrahydro-1,4-methanonaphthalene-5,8-dione
108299-53-2, 111555-28-3, 111555-29-4

(1SR,4RS,4aSR,8aRS)-4a,6-dimethyl-1,4,4a,8a-tetrahydro-1,4-methanonaphthalene-5,8-dione

Conditions
ConditionsYield
In dichloromethane for 3h; Diels-Alder Cycloaddition; Reflux;99%
boron trifluoride diethyl etherate In toluene at -78℃; for 1h;92%
With iron(III) chloride In neat (no solvent, solid phase) at 20℃; for 1h; Diels-Alder Cycloaddition;87%
In dichloromethane at 20℃; for 48h; Diels-Alder Cycloaddition; diastereoselective reaction;70%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

(1S,2R,7S,8R)-2,4-dimethyl-tricyclo[6.2.1.02,7]undeca-4,9-diene-3,6-dione

(1S,2R,7S,8R)-2,4-dimethyl-tricyclo[6.2.1.02,7]undeca-4,9-diene-3,6-dione

Conditions
ConditionsYield
(S)-oxazaborolidine-aluminum bromide at -78℃; for 2h; Diels-Alder reaction;99%
3-phenyl-2-butenal
1196-67-4

3-phenyl-2-butenal

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

(S)-3,4a-dimethyl-6-phenyl-4a,5-dihydronaphthalene-1,4-dione
1567408-44-9

(S)-3,4a-dimethyl-6-phenyl-4a,5-dihydronaphthalene-1,4-dione

Conditions
ConditionsYield
With (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; o-fluoro-benzoic acid In chloroform-d1 at 20℃; for 24h; enantioselective reaction;99%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

3-methyl-2-penten-4-yn-1-al
53635-18-0

3-methyl-2-penten-4-yn-1-al

C14H12O2
1567408-52-9

C14H12O2

Conditions
ConditionsYield
With (R)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine; o-fluoro-benzoic acid In chloroform-d1 at 20℃; for 24h; enantioselective reaction;99%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

A

1,4-dihydroxy-2,6-dimethylbenzene
654-42-2

1,4-dihydroxy-2,6-dimethylbenzene

B

1,2,4,6-Tetramethyl-cyclohexa-2,5-diene-1,4-diol

1,2,4,6-Tetramethyl-cyclohexa-2,5-diene-1,4-diol

Conditions
ConditionsYield
With methyllithium In tetrahydrofuran; diethyl ether at -78℃; for 1h;A 2%
B 98%
1-acetoxy-1,3-butadiene
1515-76-0

1-acetoxy-1,3-butadiene

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Acetic acid (1R,4aS,8aS)-4a,6-dimethyl-5,8-dioxo-1,4,4a,5,8,8a-hexahydro-naphthalen-1-yl ester

Acetic acid (1R,4aS,8aS)-4a,6-dimethyl-5,8-dioxo-1,4,4a,5,8,8a-hexahydro-naphthalen-1-yl ester

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In toluene at 0℃; for 1.5h; Diels-Alder reaction; Inert atmosphere;98%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

isoprene
78-79-5

isoprene

C13H16O2
1291100-82-7

C13H16O2

Conditions
ConditionsYield
With aluminum tri-bromide; (S)-3,3-diphenyl-1-(o-tolyl)hexahydropyrrolo[1,2-c]-[1,3,2]oxazaborole In 1,1-Dibromoethane; hexane; dichloromethane at -78℃; for 50h; Diels-Alder reaction; optical yield given as %ee; enantioselective reaction;98%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

(E)-3-methylene-5-styryldihydrofuran-2(3H)-one
106549-54-6

(E)-3-methylene-5-styryldihydrofuran-2(3H)-one

(E)-4-(3, 5-dimethyl-1,4-benzoquinon-2-yl)-2-methylene-6-phenylhex-5-enoic acid

(E)-4-(3, 5-dimethyl-1,4-benzoquinon-2-yl)-2-methylene-6-phenylhex-5-enoic acid

Conditions
ConditionsYield
Stage #1: 2,6-dimethyl-1,4-benzoquinone; (E)-3-methylene-5-styryldihydrofuran-2(3H)-one With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate at 20℃; for 0.5h;
Stage #2: With hafnium tetrakis(trifluoromethanesulfonate) at 25℃; for 2h;
98%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

C13H14O2

C13H14O2

Conditions
ConditionsYield
With (R)-2-(o-methyl)phenyl-CBS-oxazaborolidine; aluminum tri-bromide In dichloromethane; toluene at -78℃; for 2h; Diels-Alder Cycloaddition; Schlenk technique; Inert atmosphere;98%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

4-cyano-3,5-dimethyl-4-trimethylsilyloxycyclohexa-2,5-dien-1-one
42860-69-5

4-cyano-3,5-dimethyl-4-trimethylsilyloxycyclohexa-2,5-dien-1-one

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane for 1h; Heating;97%
With (K-18-crown-6 ether) cyanide In tetrachloromethane 1.) reflux, 10 h, 2.) room temperature;
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

2,6-dimethyl-2,3-epoxy benzoquinone
99595-89-8

2,6-dimethyl-2,3-epoxy benzoquinone

Conditions
ConditionsYield
With HOF* CH3CN at 0℃; for 0.0833333h;97%
1-methylbuta-1,3-diene
2004-70-8

1-methylbuta-1,3-diene

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

2,8,8a-trimethyl-4a,5,8,8a-tetrahydronaphthalene-1,4-dione
51315-87-8

2,8,8a-trimethyl-4a,5,8,8a-tetrahydronaphthalene-1,4-dione

Conditions
ConditionsYield
With titanium tetrachloride In dichloromethane at -78℃; for 0.5h;96%
With lithium perchlorate In diethyl ether for 0.25h; Ambient temperature;80%
In benzene
titanium tetrachloride In dichloromethane at -78℃; for 0.5h;
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

(2S,4aS,8aR)-1,1,4a-Trimethyl-5-vinyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-ol
137325-44-1

(2S,4aS,8aR)-1,1,4a-Trimethyl-5-vinyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-ol

3β-hydroxy-4,4,16,17-tetramethyl-(14β)-D-homo-18-nor-androsta-9(11),16-diene-15,17a-dione
140375-35-5, 140460-63-5

3β-hydroxy-4,4,16,17-tetramethyl-(14β)-D-homo-18-nor-androsta-9(11),16-diene-15,17a-dione

Conditions
ConditionsYield
In benzene for 20h; Heating;96%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

(2S,4aS,8aR)-1,1,4a-Trimethyl-5-vinyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-ol
137325-44-1

(2S,4aS,8aR)-1,1,4a-Trimethyl-5-vinyl-1,2,3,4,4a,7,8,8a-octahydro-naphthalen-2-ol

(4aR,4bR,6aR,8S,10aS,12aS)-8-Hydroxy-2,4a,7,7,10a-pentamethyl-4a,4b,5,6,6a,7,8,9,10,10a,12,12a-dodecahydro-chrysene-1,4-dione

(4aR,4bR,6aR,8S,10aS,12aS)-8-Hydroxy-2,4a,7,7,10a-pentamethyl-4a,4b,5,6,6a,7,8,9,10,10a,12,12a-dodecahydro-chrysene-1,4-dione

Conditions
ConditionsYield
In benzene for 20h; Heating;96%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

methyl (E)-4,6,7-octatrienoate

methyl (E)-4,6,7-octatrienoate

3-((1R,8aR)-4,7,8a-Trimethyl-5,8-dioxo-1,5,8,8a-tetrahydro-naphthalen-1-yl)-propionic acid methyl ester
96302-07-7

3-((1R,8aR)-4,7,8a-Trimethyl-5,8-dioxo-1,5,8,8a-tetrahydro-naphthalen-1-yl)-propionic acid methyl ester

Conditions
ConditionsYield
In benzene at 50℃; for 21h;96%
5-(3,4-dimethoxyphenyl)-oxa-cyclopentan-2-one
14335-78-5

5-(3,4-dimethoxyphenyl)-oxa-cyclopentan-2-one

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

4-(3,5-dimethyl-1,4-benzoquinon-2-yl)-4-(3,4-dimethoxylphenyl)butyric acid

4-(3,5-dimethyl-1,4-benzoquinon-2-yl)-4-(3,4-dimethoxylphenyl)butyric acid

Conditions
ConditionsYield
Stage #1: 5-(3,4-dimethoxyphenyl)-oxa-cyclopentan-2-one; 2,6-dimethyl-1,4-benzoquinone With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate at 20℃; for 0.5h;
Stage #2: With hafnium tetrakis(trifluoromethanesulfonate) at 50℃; for 2h;
96%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

5-(4-bromo-5-chloro-2-thienyl)dihydrofuran-2-one

5-(4-bromo-5-chloro-2-thienyl)dihydrofuran-2-one

4-(3,5-dimethyl-1,4-benzoquinon-2-yl)-4-(4-bromo-5-chlorothiophen-2-yl)butanoic acid

4-(3,5-dimethyl-1,4-benzoquinon-2-yl)-4-(4-bromo-5-chlorothiophen-2-yl)butanoic acid

Conditions
ConditionsYield
Stage #1: 2,6-dimethyl-1,4-benzoquinone; 5-(4-bromo-5-chloro-2-thienyl)dihydrofuran-2-one With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate at 20℃; for 0.5h;
Stage #2: With hafnium tetrakis(trifluoromethanesulfonate) at 50℃; for 2h;
96%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

3-methylene-5-(4-(methylthio)phenyl)dihydrofuran-2(3H)-one

3-methylene-5-(4-(methylthio)phenyl)dihydrofuran-2(3H)-one

4-(3,5-dimethyl-1,4-benzoquinon-2-yl)-2-methylene-4-(4-(methylthio)phenyl)butanoic acid

4-(3,5-dimethyl-1,4-benzoquinon-2-yl)-2-methylene-4-(4-(methylthio)phenyl)butanoic acid

Conditions
ConditionsYield
Stage #1: 2,6-dimethyl-1,4-benzoquinone; 3-methylene-5-(4-(methylthio)phenyl)dihydrofuran-2(3H)-one With diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate at 20℃; for 0.5h;
Stage #2: With hafnium tetrakis(trifluoromethanesulfonate) at 25℃; for 2h;
96%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

sodium (E)-4,6-heptadienoate
86668-96-4

sodium (E)-4,6-heptadienoate

C23H26O6
88710-64-9

C23H26O6

Conditions
ConditionsYield
With sodium hydroxide In water for 2h; Ambient temperature;95%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

ethylene glycol
107-21-1

ethylene glycol

4,4-ethylenedioxy-2,6-dimethyl-2,5-cyclohexadien-1-one
85268-20-8

4,4-ethylenedioxy-2,6-dimethyl-2,5-cyclohexadien-1-one

Conditions
ConditionsYield
With toluene-4-sulfonic acid; trimethyl orthoformate In diethyl ether at 4℃; for 120h;95%
With toluene-4-sulfonic acid; trimethyl orthoformate at 40℃; for 2h;90%
With toluene-4-sulfonic acid; trimethyl orthoformate In benzene at 25℃; for 24h;86%
2-Oxobutyric acid
600-18-0

2-Oxobutyric acid

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

1-(3,6-Dihydroxy-2,4-dimethyl-phenyl)-propan-1-one

1-(3,6-Dihydroxy-2,4-dimethyl-phenyl)-propan-1-one

Conditions
ConditionsYield
With ammonium persulfate; silver nitrate In water; acetonitrile at 70℃; for 2h;95%
bicyclopropylidene
27567-82-4

bicyclopropylidene

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

6,8-dimethyldispiro[2.0.54.33]dodeca-5,8-diene-7,12-dione
1440547-06-7

6,8-dimethyldispiro[2.0.54.33]dodeca-5,8-diene-7,12-dione

Conditions
ConditionsYield
In benzene for 24h; Photolysis; Inert atmosphere; regioselective reaction;95%
phosphorohydrazidic acid diethyl ester
56183-69-8

phosphorohydrazidic acid diethyl ester

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

N'-(3,5-Dimethyl-4-oxo-cyclohexa-2,5-dienylidene)-phosphorohydrazidic acid diethyl ester

N'-(3,5-Dimethyl-4-oxo-cyclohexa-2,5-dienylidene)-phosphorohydrazidic acid diethyl ester

Conditions
ConditionsYield
In benzene at 25℃;94%
Ru(η6-1,3,5-cyclooctatriene)(dimethyl fumarate)2
223249-01-2

Ru(η6-1,3,5-cyclooctatriene)(dimethyl fumarate)2

2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

Ru(η6-cyclooctatriene)(2,6-dimethyl-p-benzoquinone)
490012-81-2

Ru(η6-cyclooctatriene)(2,6-dimethyl-p-benzoquinone)

Conditions
ConditionsYield
In diethyl ether byproducts: CO2MeCHCHCO2Me; mixt. of Ru-complex, ligand and Et2O was refluxed for 4 h under Ar; filtered, rinsed with Et2O, dried under vac.;94%
2,6-dimethyl-1,4-benzoquinone
527-61-7

2,6-dimethyl-1,4-benzoquinone

2-cinnamyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-cinnamyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

(E)-6-cinnamyl-2,6-dimethylcyclohex-2-ene-1,4-dione

(E)-6-cinnamyl-2,6-dimethylcyclohex-2-ene-1,4-dione

Conditions
ConditionsYield
In chloroform-d1 at 20℃; for 24h; Inert atmosphere; stereoselective reaction;94%

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