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inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
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Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
1-methyl-2-propan-2-ylbenzene CAS NO.527-84-4 Application:1-methyl-2-propan-2-ylbenzene CAS NO.527-84-4
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inquiryBenzene,1-methyl-2-(1-methylethyl)- cas 527-84-4Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
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1-methyl-2-propan-2-ylbenzene CAS NO.527-84-4Appearance:please contact me Storage:Keep in dry and cool place Package:foil bags, drums or bottles Application:intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amou
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inquiry1-methyl-2-propan-2-ylbenzene CAS NO.527-84-4Appearance:please contact me Storage:Keep in dry and cool place Package:foil bags, drums or bottles Application:intermediates Transportation:By air - DHL, TNT,FEDEX,EMS...ETC. ...
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inquiryConditions | Yield |
---|---|
With potassium phosphate monohydrate; bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; C20H34O3P2 In toluene at 100℃; Suzuki-Miyaura Coupling; Inert atmosphere; | 99% |
2-methyl-1-(1-methylethyl)cyclohexa-2,5-diene-1-carboxylic acid
2-methylisopropylbenzene
Conditions | Yield |
---|---|
With chlorosulfonic acid In dichloromethane at 0℃; for 0.166667h; | 98% |
With chlorosulfonic acid In dichloromethane at 0℃; for 0.166667h; | 98% |
2-methyl-1-(1-methylethyl)cyclohexa-2,5-diene-1-carboxylic acid
A
2-methylisopropylbenzene
Conditions | Yield |
---|---|
With oxygen; 5,15,10,20-tetraphenylporphyrin In chloroform at -30℃; for 24h; Irradiation; | A 28% B 68% |
2-methylisopropylbenzene
Conditions | Yield |
---|---|
at 240 - 300℃; Leiten ueber Platin-Katalysatoren; |
Conditions | Yield |
---|---|
With nickel at 90℃; under 88260.9 Torr; Hydrogenation; | |
With nickel kieselguhr at 40℃; under 44130.5 Torr; Hydrogenation; | |
With ethanol; sodium |
Conditions | Yield |
---|---|
With copper oxide-chromium oxide at 100℃; under 88260.9 Torr; Hydrogenation; | |
Multi-step reaction with 2 steps 1: acid 2: hydrogen / 10percent palladium on charcoal / methanol View Scheme | |
Multi-step reaction with 2 steps 1: Destillation 2: Raney nickel / 90 °C / 88260.9 Torr / Hydrogenation View Scheme | |
Multi-step reaction with 2 steps 1: 350 °C / beim Leiten ueber ThO2 2: hydrogen; nickel substance / 200 - 220 °C View Scheme | |
Multi-step reaction with 2 steps 1: potassium pyrosulfate / durch Destillation 2: colloid/al palladium / Hydrogenation View Scheme |
toluene-4-sulfonic acid
isopropyl alcohol
A
2-methylisopropylbenzene
B
1-methyl-2,5-diisopropylbenzene
Conditions | Yield |
---|---|
at 40℃; folgende Wasserdampfdestillation bei 150-160grad; | |
With sulfuric acid at 40℃; anschliessend Destillation mit Wasserdampf bei 150-160grad; |
propene
trifluoroborane diethyl ether
toluene
benzene
2-methylisopropylbenzene
Conditions | Yield |
---|---|
at 5℃; und 65grad; | |
at 40℃; Kinetics; |
Conditions | Yield |
---|---|
With sodium |
Conditions | Yield |
---|---|
Multistep reaction; |
Isopropylbenzene
methyl cation
A
2-methylisopropylbenzene
B
m-cymene
C
4-methylisopropylbenzene
Conditions | Yield |
---|---|
Product distribution; Rate constant; with totally tritiated methyl cation, gas and liquid phases at r.t., solid phase at temp. of liquid N2; | A 11 % Chromat. B 39 % Chromat. C 50 % Chromat. |
propane
(2-methylphenyl)trimethylsilane
A
2-methylisopropylbenzene
B
m-cymene
C
4-methylisopropylbenzene
D
toluene
Conditions | Yield |
---|---|
With methanol; oxygen; triethylamine Product distribution; Mechanism; reaction of isomeric trimethylsilyltoluenes in gas phase; investigated by mass spectrometric and radiolytic techniques; |
1-methyl-2-(prop-1-en-2-yl)benzene
A
2-methylisopropylbenzene
B
o-1,4-menthadiene
C
o-3,6-menthadiene
D
o-1-menthene
Conditions | Yield |
---|---|
With hydrogen; calcium hexammine In hexane for 2h; Further byproducts given; | A 92.0 % Chromat. B 4.2 % Chromat. C 0.5 % Chromat. D 0.7 % Chromat. |
1-methyl-2-(prop-1-en-2-yl)benzene
A
2-methylisopropylbenzene
B
o-6-menthene
C
o-1-menthene
D
o-2-menthene
Conditions | Yield |
---|---|
With hydrogen; calcium hexammine for 24h; Further byproducts given; | A 79.0 % Chromat. B 5.3 % Chromat. C 9.1 % Chromat. D 4.8 % Chromat. |
With hydrogen; calcium hexammine for 24h; Further byproducts given; | A 79.0 % Chromat. B 5.3 % Chromat. C 9.1 % Chromat. D 4.2 % Chromat. |
1-methyl-2-(prop-1-en-2-yl)benzene
A
2-methylisopropylbenzene
B
o-1,4-menthadiene
C
o-3,6-menthadiene
D
toluene
Conditions | Yield |
---|---|
With hydrogen; calcium hexammine In hexane for 2h; Further byproducts given; | A 96 % Chromat. B 1.70 % Chromat. C 0.2 % Chromat. D 1.1 % Chromat. |
1-methyl-2-(prop-1-en-2-yl)benzene
A
2-methylisopropylbenzene
B
o-1,4-menthadiene
C
o-3,6-menthadiene
D
o-1-menthene
E
o-2-menthene
F
toluene
Conditions | Yield |
---|---|
With hydrogen; calcium hexammine In hexane for 2h; Product distribution; other mole ratio of hydrogen, other reaction time, other solvent; | A 96.0 % Chromat. B 1.7 % Chromat. C 0.2 % Chromat. D 0.2 % Chromat. E 0.1 % Chromat. F 1.1 % Chromat. |
o-1,4-menthadiene
2-methylisopropylbenzene
Conditions | Yield |
---|---|
With lithium 2-aminoethylamide at 100℃; for 1.5h; | 100 % Chromat. |
With calcium amide In hexane at 70℃; for 5h; Product distribution; var. react. time, Ca(NH2) to o-1,4-menthadiene 5:1; | 94 % Chromat. |
o-1,4-menthadiene
A
2-methylisopropylbenzene
B
o-6-menthene
C
o-1-menthene
D
o-2-menthene
cis-o-menthane
trans-o-menthane
Conditions | Yield |
---|---|
With zeolite NaX In octane at 120℃; for 12h; Product distribution; var. temperature, oth. zeolite; | A 77 % Chromat. B 2.7 % Chromat. C 10.5 % Chromat. D 3.4 % Chromat. E 2 % Chromat. F 0.5 % Chromat. |
o-1,4-menthadiene
A
2-methylisopropylbenzene
B
o-1,5-menthadieneo-1,5-menthadiene
C
o-1,3-menthadiene
D
1-isopropyl-5-ethylidenecyclopentane
Conditions | Yield |
---|---|
With potassium tert-butylate In dimethyl sulfoxide at 25℃; for 80h; Product distribution; var. react. time, oth. temperature; | A 24 % Chromat. B 34 % Chromat. C 25 % Chromat. D 17 % Chromat. |
o-1,4-menthadiene
A
2-methylisopropylbenzene
B
o-1,5-menthadiene
C
o-1,3-menthadiene
D
4-methyl-3-(1-methylethylidene)-1-cyclohexene
E
o-1(7),4-menthadiene
F
o-4,6-menthadiene
Conditions | Yield |
---|---|
With aluminosilicate diatomaceous earth In hexane at 270℃; for 0.00694444h; Product distribution; Mechanism; other time, other temperature; |
o-1,4-menthadiene
A
2-methylisopropylbenzene
B
1-isopropyl-5-ethylidenecyclopentane
Conditions | Yield |
---|---|
With silica gel In hexane at 350℃; for 0.014h; Product distribution; in a stream of nitrogen, oth. temperature; | A 52 % Chromat. B 39.5 % Chromat. |
2,5-dimethyl-4-isopropyl-3-isopropylidenehexa-1,4-diene
A
2-methylisopropylbenzene
B
para-xylene
Conditions | Yield |
---|---|
at 750℃; under 0.003 Torr; for 2.77778E-07h; Further byproducts given; |
(1α,6α)-6,9,9-Trimethyl-7,8-diazabicyclo<4.3.0>nona-2,5,7-trien
A
2-methylisopropylbenzene
B
1,7,7-Trimethyl-tropiliden
C
2,7,7-Trimethyl-cycloheptatrien
Conditions | Yield |
---|---|
In benzene at 28℃; other solvents C6D6 and CDCl3, other temperatures; also by photolysis; | A 3 % Chromat. B 3 % Chromat. C 94 % Chromat. |
In benzene-d6 at 39.2℃; Mechanism; Kinetics; Product distribution; energy data: ΔH(excit.), ΔS(excit.), ΔG(excit.); other solvents C6H6 or CDCl3, other temperatures; other educt (1α,6α)-6-Trideuteriomethyl-2,9,9-trimethyl-7,8-diazabicyclo<4.3.0>nona-2,4,7-trien; | A 3 % Chromat. B 3 % Chromat. C 94 % Chromat. |
3,3,3',3',5,5,5',5'-octamethyl-3,3',5,5'-tetrahydro-4,4'-bi(4H-pyrazolylidene)
A
2-methylisopropylbenzene
B
para-xylene
C
2,5-dimethyl-4-isopropyl-3-isopropylidenehexa-1,4-diene
D
1-isopropylidene-2,2,4,4,5,5-hexamethylspiropentane
E
2-(2,3-dimethylbut-1-en-3-yl)-1-isopropyl-3,3-dimethylcyclopropene
Conditions | Yield |
---|---|
at 400 - 800℃; for 2.77778E-07h; Product distribution; |
α-(o-tolyl)isobutyrophenone
A
1-methyl-2-(prop-1-en-2-yl)benzene
B
2-methylisopropylbenzene
C
benzaldehyde
Conditions | Yield |
---|---|
In benzene Quantum yield; Ambient temperature; Irradiation; |
trans-o-4-menthen-8-ol
A
2-methylisopropylbenzene
B
o-1,4-menthadiene
C
o-1-menthene
D
o-2(8),3-menthadiene
E
o-2(8),4-menthadiene
trans-o-4,8-menthadiene
Conditions | Yield |
---|---|
With potassium hydrogensulfate Product distribution; 1.)140 deg C, 1 h 2.)180 deg C, 15 min; |
trans-o-4-menthen-8-ol
A
2-methylisopropylbenzene
B
o-1,4-menthadiene
C
o-1-menthene
D
o-2(8),4-menthadiene
trans-o-4,8-menthadiene
Conditions | Yield |
---|---|
With acetic anhydride at 150℃; for 12h; Product distribution; sealed ampoule; |
methyl-3 dimethylcarbinol-4 cyclohexene trans
A
2-methylisopropylbenzene
B
o-1,4-menthadiene
C
o-2(8),5-menthadiene
D
o-1,5-menthadiene
trans-o-5,8-menthadiene
Conditions | Yield |
---|---|
With potassium hydrogensulfate Product distribution; 1.)140 deg C, 1 h 2.)180 deg C, 15 min; |
methyl-3 dimethylcarbinol-4 cyclohexene trans
A
2-methylisopropylbenzene
B
o-2(8),3-menthadiene
C
o-2(8),5-menthadiene
D
o-1,5-menthadiene
cis-o-5,8-menthadiene
trans-o-5,8-menthadiene
Conditions | Yield |
---|---|
With acetic anhydride at 150℃; for 12h; Product distribution; sealed ampoule; |
methyl-3 dimethylcarbinol-4 cyclohexene cis
A
2-methylisopropylbenzene
B
o-2(8),3-menthadiene
C
o-2(8),5-menthadiene
D
o-1,5-menthadiene
cis-o-5,8-menthadiene
trans-o-5,8-menthadiene
Conditions | Yield |
---|---|
With acetic anhydride at 150℃; for 12h; Product distribution; sealed ampoule; |
2-methylisopropylbenzene
A
2-isopropylbenzaldehyde
B
1-Isopropyl-2-nitromethyl-benzene
C
1-Isopropyl-2-nitrooxymethyl-benzene
Conditions | Yield |
---|---|
With ammonium cerium(IV) nitrate In acetonitrile at 17℃; for 0.666667h; Irradiation; | A 14% B 5% C 69% |
2-methylisopropylbenzene
1,1,1-trifluoroacetophenone
A
meso-1,1,1,4,4,4-Hexafluor-2,3-diphenylbutandiol(2,3)
B
C20H26
C
1,1,1-Trifluoro-3-(2-isopropyl-phenyl)-2-phenyl-propan-2-ol
Conditions | Yield |
---|---|
In acetonitrile at 30℃; | A 35% B 7% C 43% |
2-methylisopropylbenzene
A
meso-1,1,1,4,4,4-Hexafluor-2,3-diphenylbutandiol(2,3)
B
C20H26
C
1,1,1-Trifluoro-3-(2-isopropyl-phenyl)-2-phenyl-propan-2-ol
Conditions | Yield |
---|---|
With 2,2,2-Trifluoroacetophenone In acetonitrile at 30℃; | A 35% B 7% C 43% |
2-methylisopropylbenzene
A
2-isopropyl-5-nitrotoluene
B
2-isopropyl-3-nitrotoluene
C
2-isopropyl-4-nitrotoluene
D
2-isopropyl-6-nitrotoluene
Conditions | Yield |
---|---|
With nitric acid In sulfuric acid at 25℃; for 0.0833333h; Further byproducts given; | A 37.6% B 3.8% C 27.8% D 12.7% |
With nitric acid In sulfuric acid at 25℃; Further byproducts given; | A 35.3% B 3.8% C 27.1% D 12.8% |
With nitric acid In sulfuric acid at 25℃; Further byproducts given; | A 34.5% B 3.7% C 27.9% D 12.3% |
2-methylisopropylbenzene
A
1-methyl-2-nitrobenzene
B
2-isopropyl-5-nitrotoluene
C
2-isopropyl-3-nitrotoluene
D
2-isopropyl-4-nitrotoluene
Conditions | Yield |
---|---|
With nitric acid In sulfuric acid at 25℃; for 2h; Further byproducts given; | A 23% B 35.3% C 3.8% D 27.1% |
With nitric acid In sulfuric acid at 25℃; for 2h; Further byproducts given; | A 23% B 35.3% C 3.8% D 27.1% |
benzophenone
2-methylisopropylbenzene
A
tetraphenylethane-1,2-diol
B
2-Methyl-1,1-diphenyl-2-o-tolyl-propan-1-ol
C
2-(2-Isopropyl-phenyl)-1,1-diphenyl-ethanol
Conditions | Yield |
---|---|
In acetonitrile at 30℃; Irradiation; | A 35% B 4% C 13% |
2-methylisopropylbenzene
naphthalene-1,4-dicarbonitrile
A
4-(2-Isopropyl-benzyl)-naphthalene-1-carbonitrile
(1R,2R)-2-(2-Isopropyl-benzyl)-1,2-dihydro-naphthalene-1,4-dicarbonitrile
C22H20N2
Conditions | Yield |
---|---|
In acetonitrile at 17℃; for 20h; | A 15% B 23% C 27% |
Conditions | Yield |
---|---|
With 5% platinum on alumina at 300℃; | |
at 300℃; Leiten ueber Platin-Aluminiumoxyd-Kontakte; |
2-methylisopropylbenzene
A
pentabromotoluene
B
1,2,3-tribromo-5-isopropyl-4-methyl-benzene
Conditions | Yield |
---|---|
With sulfuric acid; bromine; iodine; iron at 0℃; Lichtausschluss; |
2-methylisopropylbenzene
1-isopropyl-2-methylcyclohexane
Conditions | Yield |
---|---|
With hydrogen; nickel at 170 - 180℃; |
Conditions | Yield |
---|---|
With chlorosulfonic acid; chloroform und anschliessend mit wss.NH3; |
2-methylisopropylbenzene
2-(o-tolyl)propyl-2-hydroperoxide
Conditions | Yield |
---|---|
With oxygen; lead acetate |
2-methylisopropylbenzene
4-bromo-1-isopropyl-2-methyl-benzene
Conditions | Yield |
---|---|
With bromine; iodine; iron at 0℃; Lichtausschluss; |
2-methylisopropylbenzene
1,2-dibromo-4-isopropyl-5-methyl-benzene
Conditions | Yield |
---|---|
With bromine; iodine; iron at 0℃; Lichtausschluss; |
2-methylisopropylbenzene
1,2,3,4-tetrabromo-5-isopropyl-6-methyl-benzene
Conditions | Yield |
---|---|
With bromine; iodine; iron at 0 - 50℃; Lichtausschluss; |
Conditions | Yield |
---|---|
at 410℃; Leiten ueber aktivierte Bleicherde; |
2,4,4-trimethyl-1-pentene
2-methylisopropylbenzene
6-Tert-Butyl-1,1,3,4-tetramethyl-3-neopentyl indan
Conditions | Yield |
---|---|
With sulfuric acid at 5℃; |
2-methylisopropylbenzene
o-1,4-menthadiene
Conditions | Yield |
---|---|
With calcium hexammine In hexane |
Conditions | Yield |
---|---|
With nitronium tetrafluoborate In sulfolane |
2-methylisopropylbenzene
o-6-menthene
Conditions | Yield |
---|---|
With calcium hexammine In hexane |
2-methylisopropylbenzene
o-3,6-menthadiene
Conditions | Yield |
---|---|
With calcium hexammine In hexane |
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