Quality assurance, stable process and affordable priceAppearance:detailed see specifications Storage:enquiry Package:according to the clients requirement Application:Pharmaceutical intermediates Transportation:Normal Port:chengdu
As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:603-76-9
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryItems Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------
Cas:603-76-9
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inquiryProduct description: Product name 1-Methylindole CAS number 603-76-9 Assay ≥99% Appearance Light yellow transparent liquid Capacity 200mt/year Application Pharmaceutical inte
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inquiry1-Methylindole Product Name: 1-Methylindole Molecular Weight: 131.17 CAS NO: 603-76-9 EC NO: 210-057-5 Molecular Formula: C9H9N
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&
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inquiryOur company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiryProduct Name: 1-Methylindole Synonyms: N-METHYLINDOLE;1-Methyl-1H-indole;Indole, 1-methyl-;1-METHYLINDOLE (N-);1-METHYLINDOLE;1-METHYLINDOL;1H-Indole, 1-methyl-;L-Methylindole CAS: 603
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inquiry1)quick response within 12 hours; 2)quality guarantee: all products are strictly tested by our qc, confirmed by qa and approved by third party lab in china, usa, canada, germany, uk, italy, france etc. 3) oem/odm available; 4) rea
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inquiryAdvantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best service is
1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
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inquiry1-Methylindole CAS:603-76-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediat
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inquiry1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
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inquiryCompany Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
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inquiryProduct name: 1-Methylindole CAS No.: 603-76-9 Molecule Formula:C9H9N Molecule Weight:131.17 Purity: 98.0% Package: 200kg/drum Description:Light yellow oil-like liquid Manufacture Standards:Enterprise Standard TEST
Cas:603-76-9
Min.Order:1 Kilogram
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inquiryWe product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:1-Methylindole CAS No:603-76-9 Synonym
1-Methylindole Chemical Properties Melting point 61.2°C (estimate) Boiling point 133 °C26 mm Hg(lit.) density 1.051 g/mL at 20 °C(lit.) refractive index n20/D 1.606(lit.) Fp >230 °F storage temp. Refrigerato
Cas:603-76-9
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inquiryWe Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O
Conditions | Yield |
---|---|
With sodium hydride In tetrahydrofuran at 0 - 20℃; for 0.5h; | 99% |
Stage #1: indole With sodium hydride In tetrahydrofuran Inert atmosphere; Stage #2: methyl iodide at 0 - 20℃; for 0.5h; Inert atmosphere; | 99% |
Stage #1: indole With sodium hydride In tetrahydrofuran at 0 - 20℃; for 1.25h; Stage #2: methyl iodide In tetrahydrofuran at 0 - 20℃; for 0.5h; | 99% |
Conditions | Yield |
---|---|
With H8O20P8Pt2(4-)*4C34H72N(1+) In methanol Inert atmosphere; Irradiation; | 99% |
With bis(1,5-cyclooctadiene)diiridium(I) dichloride In para-xylene at 130℃; for 20h; Catalytic behavior; Temperature; Solvent; Reagent/catalyst; Inert atmosphere; Sealed tube; | 99% |
With oxygen In N,N-dimethyl acetamide at 20℃; Schlenk technique; Irradiation; | 95% |
2,3-diiodo-1-methyl-1H-indole
1-methylindole
Conditions | Yield |
---|---|
Stage #1: 2,3-diiodo-1-methyl-1H-indole With tert.-butyl lithium In tetrahydrofuran; pentane at -78℃; for 0.333333h; Stage #2: With ammonium chloride In tetrahydrofuran; water; pentane at -78 - 20℃; | 99% |
Conditions | Yield |
---|---|
With potassium hydroxide In acetone | 99% |
Multi-step reaction with 3 steps 1.1: n-BuLi; CO2 / tetrahydrofuran / -78 °C 1.2: t-BuLi / tetrahydrofuran / -78 °C 1.3: 91 percent / ICH2CH2I 2.1: 100 percent / KOH / dimethylformamide 3.1: n-BuLi; ZnCl2 3.2: Pd(PPh3)2Cl2; 2-iodoindole View Scheme | |
Multi-step reaction with 4 steps 1.1: 90 percent 2.1: I2; KOH / dimethylformamide 3.1: n-Bu4NHSO4 / dimethylformamide 4.1: t-BuLi / tetrahydrofuran; pentane / 0.33 h / -78 °C 4.2: 99 percent / NH4Cl / H2O; tetrahydrofuran; pentane / -78 - 20 °C View Scheme |
Conditions | Yield |
---|---|
Stage #1: indole With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 0.5h; Inert atmosphere; Sealed tube; Stage #2: methyl halide In tetrahydrofuran; mineral oil at 0 - 20℃; Inert atmosphere; Sealed tube; | 99% |
Stage #1: indole With sodium hydroxide In dimethyl sulfoxide Stage #2: methyl halide In dimethyl sulfoxide at 10 - 15℃; for 3h; | |
Stage #1: indole With sodium hydride In N,N-dimethyl-formamide at 0 - 23℃; for 0.5h; Inert atmosphere; Stage #2: methyl halide In N,N-dimethyl-formamide at 0 - 23℃; Inert atmosphere; |
1-methylindole
Conditions | Yield |
---|---|
With tris(pentafluorophenyl)borate; water In chloroform at 80℃; for 24h; Sealed tube; | 99% |
Conditions | Yield |
---|---|
With cetyltrimethylammonium chloride at 150 - 170℃; under 12001.2 - 24002.4 Torr; Inert atmosphere; Sealed tube; Autoclave; | 98.8% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 50 - 130℃; for 9h; | 98% |
With tributyl-amine In N,N-dimethyl-formamide at 285℃; under 112511 Torr; for 0.05h; | 98% |
With 1,4-diaza-bicyclo[2.2.2]octane In N,N-dimethyl-formamide at 94 - 95℃; for 8h; | 97% |
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 20℃; | 97% |
Stage #1: indole With potassium hydroxide In N,N-dimethyl-formamide at 0℃; for 0.333333h; Stage #2: methyl bromide In N,N-dimethyl-formamide at 0 - 20℃; for 1h; | |
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 24h; | |
Stage #1: indole With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.5h; Stage #2: methyl bromide In N,N-dimethyl-formamide at 0℃; | |
With potassium hydroxide In N,N-dimethyl-formamide at 20℃; for 24h; Inert atmosphere; |
4-bromo-1-methyl-1H-indole
1-methylindole
Conditions | Yield |
---|---|
With potassium tert-butylate; benzyl alcohol In N,N-dimethyl-formamide at 130℃; for 2.5h; Reagent/catalyst; Schlenk technique; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 4h; Sealed tube; Glovebox; | 96% |
In acetonitrile at 20℃; | 96% |
5-chloro-1-methyl-1H-indole
1-methylindole
Conditions | Yield |
---|---|
With potassium tert-butylate; N,N-dimethyl-formamide In dimethyl sulfoxide at 35℃; for 24h; Schlenk technique; Inert atmosphere; Irradiation; | 96% |
Conditions | Yield |
---|---|
With potassium tert-butylate In acetone at 20℃; for 1h; | 94% |
With potassium hydroxide In acetone Methylation; | 93% |
With sodium amide; toluene | |
With potassium carbonate |
Conditions | Yield |
---|---|
With p-benzoquinone; lithium chloride; dichloro bis(acetonitrile) palladium(II) In tetrahydrofuran for 18h; Heating; | 94% |
N-methyl-3-formylindole
1-methylindole
Conditions | Yield |
---|---|
With palladium nanoparticles supported on fibrous silica In cyclohexane at 130℃; for 22h; Molecular sieve; | 94% |
Conditions | Yield |
---|---|
With dimethylethylsilane; 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; bis(pentafluorophenyl)borohydride In dichloromethane; toluene at 20℃; for 24h; Inert atmosphere; Sealed tube; chemoselective reaction; | 94% |
3-bromo-1-methyl-1H-indole
1-methylindole
Conditions | Yield |
---|---|
With sodium tetrahydroborate; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at 20℃; for 19h; Reagent/catalyst; Time; Inert atmosphere; | 93% |
With di-tert-butyl peroxide; caesium carbonate; isopropyl alcohol at 120℃; for 24h; Inert atmosphere; | 90 %Chromat. |
3-bromo-1-methyl-1H-indole
1-methylindole
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium tetrahydroborate; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at 25℃; for 19h; Inert atmosphere; | 93% |
1-methyl-5-iodoindole
1-methylindole
Conditions | Yield |
---|---|
With potassium tert-butylate; benzyl alcohol In N,N-dimethyl-formamide at 90℃; for 2h; Reagent/catalyst; Schlenk technique; Inert atmosphere; | 92% |
With potassium tert-butylate; benzaldehyde In N,N-dimethyl-formamide at 90℃; for 2h; Schlenk technique; Inert atmosphere; | 86% |
With 1,3-bis(2,6-diisopropylphenyl)-2,4-diphenylimidazole In N,N-dimethyl-formamide at 20℃; for 36h; Glovebox; | 85% |
With 2-(2-methoxyethoxy)ethyl alcohol; oxygen; sodium hydride In 1,4-dioxane at 20℃; for 24h; Schlenk technique; chemoselective reaction; | 76% |
5-bromo-1-methyl-H-indole
1-methylindole
Conditions | Yield |
---|---|
With 1,1,1,2,2,2-hexamethyldisilane; potassium methanolate; acetonitrile at 25℃; for 5h; Reagent/catalyst; Inert atmosphere; Glovebox; Sealed tube; | 92% |
With 2-H-1,3-di-tert-butyl-1,3,2-diazaphosphorinane; 2,2'-azobis(isobutyronitrile) In toluene at 90℃; for 12h; | 70% |
With tributyl-amine; tetrabutylammonium tetrafluoroborate In acetonitrile at 20℃; for 1.8h; Inert atmosphere; Electrolysis; | 64% |
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 4h; Solvent; Sealed tube; Glovebox; | 92% |
In acetonitrile at 20℃; Solvent; | 95 %Chromat. |
1-methyl-3-indolecarboxylic acid
1,1-Diphenylmethanol
A
3-(1,1-diphenylmethyl)-1-methyl-1H-indole
B
1-methylindole
Conditions | Yield |
---|---|
With sodium tetrachloroaurate(III) dihyrate; sodium 3-(diphenylphosphanyl)benzenesulfonate In water at 120℃; for 16h; Reagent/catalyst; Solvent; Sealed tube; | A 91% B 9% |
With sodium tetrachloroaurate(III) dihyrate; sodium 3-(diphenylphosphanyl)benzenesulfonate In water at 120℃; for 16h; Reagent/catalyst; Solvent; Sealed tube; | A 5% B 47% |
With sodium tetrachloroaurate(III) dihyrate; sodium 3-(diphenylphosphanyl)benzenesulfonate In water at 120℃; for 16h; Reagent/catalyst; Solvent; Sealed tube; | A 47% B 5% |
Conditions | Yield |
---|---|
Stage #1: indole With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h; Inert atmosphere; Stage #2: methy halide at 0 - 20℃; for 24h; | 90% |
Conditions | Yield |
---|---|
In toluene at 100℃; for 3h; | 90% |
2′-N,N-dimethylaminophenylacetylene
1-methylindole
Conditions | Yield |
---|---|
With ethanol at 120℃; for 4h; Microwave irradiation; Inert atmosphere; Green chemistry; | 89% |
Conditions | Yield |
---|---|
With potassium tert-butylate In N,N-dimethyl-formamide for 0.166667h; Heating; | 88% |
With potassium tert-butylate In N,N-dimethyl-formamide for 0.25h; Heating; | 88% |
Conditions | Yield |
---|---|
Stage #1: indole With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Stage #2: trifluoroacetic acid-methyl ester In N,N-dimethyl-formamide for 10h; | 88% |
2-bromo-1-methyl-1H-indole
1-methylindole
Conditions | Yield |
---|---|
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium tetrahydroborate; N,N,N,N,-tetramethylethylenediamine In tetrahydrofuran at 25℃; for 0.8h; Reagent/catalyst; Inert atmosphere; | 87% |
Conditions | Yield |
---|---|
With copper(II) choride dihydrate; oxygen In dimethyl sulfoxide at 20 - 120℃; for 0.166667h; | 87% |
Multi-step reaction with 2 steps 1: sodium hydride / tetrahydrofuran; mineral oil / 24 h / 20 °C 2: tris(pentafluorophenyl)borate / para-xylene / 22 h / 150 °C / Inert atmosphere; Sealed tube View Scheme | |
Multi-step reaction with 2 steps 1: triethylamine / dimethyl sulfoxide / 20 h / 150 °C / Sealed tube; Schlenk technique; Inert atmosphere 2: sodium carbonate / ethyl acetate / 24 h / 120 °C / Sealed tube; Green chemistry View Scheme | |
Multi-step reaction with 2 steps 1: acetic acid; sodium cyanoborohydride / water; methanol / 1 h / 20 °C 2: dichloro[1,3-bis(2-methylphenyl)-2-imidazolidinylidene](benzylidene) (tricyclohexylphosphine) ruthenium(II); oxygen / ethyl acetate / 46 h / 70 °C / 760.05 Torr / Sealed tube View Scheme |
Conditions | Yield |
---|---|
100% |
1-methylindole
orthoformic acid triethyl ester
tri(1-methyl-1H-indole-3-yl)methane
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In methanol at 70℃; for 0.166667h; | 100% |
With iodine In acetonitrile at 20℃; for 0.133333h; | 90% |
With acid-washed montmorillonite K10 clay at 20℃; | 87% |
With acid-washed montmorillonite K10 clay (acid-clay) at 20℃; |
1-methylindole
2,3-dicyano-5,6-dichloro-p-benzoquinone
4,5-Dichloro-3-hydroxy-1-(1-methyl-1H-indol-3-yl)-6-oxo-cyclohexa-2,4-diene-1,2-dicarbonitrile
Conditions | Yield |
---|---|
In 1,4-dioxane for 24h; Ambient temperature; | 100% |
1-methylindole
3-iodo-1-methyl-1H-indole
Conditions | Yield |
---|---|
With N-iodo-succinimide In N,N-dimethyl-formamide at 0℃; for 1.5h; Inert atmosphere; | 100% |
With potassium hydroxide; iodine In N,N-dimethyl-formamide Ambient temperature; | 98% |
With iodine; potassium hydroxide In N,N-dimethyl-formamide at 20℃; for 0.166667h; Inert atmosphere; Schlenk technique; Glovebox; | 97% |
1-methylindole
nitrostyrene
1-methyl-3-(2-nitro-1-phenylethyl)-1H-indole
Conditions | Yield |
---|---|
With Zn(2+)*2C6H6NO2S2(1-) In ethanol at 20℃; for 24h; | 100% |
With 1H-pyrrolo[2,3-b]pyridinium substituted-borate salt In toluene at 0 - 20℃; for 24h; | 99% |
Stage #1: nitrostyrene With (S)-10,10'-bis[(S)-4-isopropyl-4,5-dihydrooxazol-2-yl]-9,9'-biphenanthrene; zinc(II) trifluoroacetate In diethyl ether at 20℃; for 0.25h; Inert atmosphere; Stage #2: 1-methylindole In diethyl ether at 20℃; Friedel-Crafts alkylation; Inert atmosphere; | 99% |
1-methylindole
methyl vinyl ketone
4-(1-methyl-1H-indol-3-yl)-butan-2-one
Conditions | Yield |
---|---|
With trityl tetrafluoroborate In dichloromethane Inert atmosphere; | 100% |
With rac-9-phenyl-9H-cyclopenta[1,2-c:4,3-c']diphenanthren-9-ylium tetrakis(3,5-bis(tri-fluoromethyl)phenyl)borate In dichloromethane at 20℃; for 24h; Friedel-Crafts Alkylation; Glovebox; Inert atmosphere; | 100% |
hafnium tetrachloride In acetonitrile at 20℃; for 0.333333h; | 99% |
Conditions | Yield |
---|---|
With o-benzenedisulfonimide at 20℃; for 0.0833333h; Friedel Crafts alkylation; neat (no solvent); | 100% |
With cellulose sulfuric acid at 50℃; for 0.333333h; Neat (no solvent); Grinding; Combinatorial reaction / High throughput screening (HTS); chemoselective reaction; | 98% |
With N-Bromosuccinimide at 20℃; for 6h; | 96% |
1-methylindole
(E)-1,3-diphenyl-2-propen-1-ol
Conditions | Yield |
---|---|
With 5,11,17,23-tetrasulfonate-25,26,27,28-tetrakis(propoxy)calix[4]arene tetrasodium salt In water at 50℃; for 61h; Reagent/catalyst; Concentration; Time; Green chemistry; | 100% |
With magnetic Fe3O4-grafted calix[6]arene sulfonic acid In water at 50℃; for 24h; Catalytic behavior; Reagent/catalyst; | 99.9% |
With zinc dibromide In neat (no solvent) for 1.5h; Milling; Green chemistry; chemoselective reaction; | 92% |
Conditions | Yield |
---|---|
With 5,11,17,23-tetrasulfonate-25,26,27,28-tetrakis(propoxy)calix[4]arene tetrasodium salt In water at 50℃; for 24h; Reagent/catalyst; Concentration; Green chemistry; | 100% |
With magnetic Fe3O4-grafted calix[4]arene sulfonic acid In water at 50℃; for 25h; Catalytic behavior; Reagent/catalyst; | 99.9% |
With sodium tetrachloroaurate(III) dihydrate; sodium 3-(diphenylphosphanyl)benzenesulfonate In water at 80℃; for 16h; Sealed tube; | 95% |
With o-benzenedisulfonimide In neat (no solvent) at 20℃; for 0.25h; Friedel-Crafts Alkylation; | 94% |
With dodecylbenzene-sulphonic acid In water at 80℃; for 24h; Friedel-Crafts reaction; | 92% |
Conditions | Yield |
---|---|
With indium(III) bromide In dichloromethane at 20℃; for 2h; Michael addition; diastereoselective reaction; | 100% |
1-methylindole
A
3-(9-borabicyclo[3.3.1]nonan-9-yl)-1-methyl-1H-indole
Conditions | Yield |
---|---|
In dichloromethane at 50℃; for 2h; Sealed vessel; Inert atmosphere; | A 100% B n/a |
1-methylindole
4,4′,4″‑[(1,3,5‑triazine‑2,4,6‑triyl)tris(oxy)]tribenzaldehyde
C78H63N9O3
Conditions | Yield |
---|---|
With silica sulfuric acid In acetonitrile at 20℃; for 0.5h; Friedel-Crafts Alkylation; | 100% |
(E)‐1‐(1‐methyl‐1H‐imidazole‐2‐yl)‐but‐2‐en‐1‐one
1-methylindole
Conditions | Yield |
---|---|
With [ZnIIYIII(N,N'-bis(3-methoxysalicylidene)cyclohexane-1,2-diamine)(NO3)2(o-vanillin)2(MeOH)](MeOH) In ethyl acetate at 20℃; for 72h; Friedel-Crafts Alkylation; Inert atmosphere; | 100% |
With copper(II) nitrate trihydrate In aq. buffer at 20℃; for 72h; pH=6.5; Friedel-Crafts Alkylation; | 88% |
With copper(II) nitrate trihydrate In aq. buffer at 20℃; for 72h; pH=6.5; Reagent/catalyst; Friedel-Crafts Alkylation; enantioselective reaction; | 88% |
With 4,4'-dimethyl-2,2'-bipyridines; copper(II) nitrate trihydrate In acetonitrile at 20℃; for 72h; Catalytic behavior; Reagent/catalyst; Friedel-Crafts Alkylation; Inert atmosphere; | 80% |
With copper(II) nitrate trihydrate In acetonitrile at 20℃; for 16h; pH=7; Friedel-Crafts Alkylation; |
Conditions | Yield |
---|---|
With iron(III) chloride In 1,4-dioxane at 20℃; for 6h; | 100% |
1-methylindole
Conditions | Yield |
---|---|
With dimethylaluminum chloride In hexane; toluene at -30℃; for 18h; Temperature; | 100% |
Conditions | Yield |
---|---|
With norborn-2-ene; carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) In toluene at 150℃; for 16h; Inert atmosphere; | 100% |
2-phenylethynyl-quinoline-3-carbaldehyde
1-methylindole
Conditions | Yield |
---|---|
With silver trifluoromethanesulfonate In 1,2-dichloro-ethane for 1 - 24h; Inert atmosphere; Reflux; | 100% |
1-methylindole
7-chloro-2-(phenylethynyl)quinoline-3-carbaldehyde
Conditions | Yield |
---|---|
With silver trifluoromethanesulfonate In 1,2-dichloro-ethane for 1 - 24h; Inert atmosphere; Reflux; | 100% |
1-methylindole
1-methyl-3-propyl-1H-indole
Conditions | Yield |
---|---|
Stage #1: 1-methyl-3-propyl-1H-indole With 2,6-di-tert-butyl-pyridine; trifluoromethylsulfonic anhydride; dimethyl sulfoxide In dichloromethane; dimethyl sulfoxide at -78℃; for 0.25h; Inert atmosphere; Stage #2: 1-methylindole In dichloromethane; dimethyl sulfoxide for 0.25h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With C24H30N8; scandium tris(trifluoromethanesulfonate) In acetonitrile at 20℃; for 18h; Friedel-Crafts Alkylation; Inert atmosphere; Molecular sieve; chemoselective reaction; | 100% |
1-methylindole
trans-1-(4-fluorophenyl)-2-nitro-ethene
3-(1-(4-fluorophenyl)-2-nitroethyl)-1-methyl-1H-indole
Conditions | Yield |
---|---|
With Zn(2+)*2C6H6NO2S2(1-) In ethanol at 20℃; for 24h; | 100% |
With C22H35N4S(1+)*BF4(1-) In dichloromethane at 20℃; for 44h; Friedel-Crafts Alkylation; Inert atmosphere; | 92% |
With rose bengal In water at 60℃; Friedel-Crafts Alkylation; Irradiation; | 81% |
With 2C32H12BF24(1-)*C13H16N4S(2+) In chloroform-d1 at 20℃; Inert atmosphere; |
1-methylindole
Conditions | Yield |
---|---|
With trifluoroacetic acid In tetrahydrofuran; methanol at 20℃; diastereoselective reaction; | 100% |
Conditions | Yield |
---|---|
With trifluorormethanesulfonic acid; 1,1,1,3',3',3'-hexafluoro-propanol at 60℃; for 24h; Reagent/catalyst; | 100% |
1-methylindole
formaldehyd
dimethyl amine
3-(N,N-dimethylaminomethyl)-1-methylindole
Conditions | Yield |
---|---|
Stage #1: 1-methylindole; formaldehyd; dimethyl amine With acetic acid In water at 0 - 50℃; Mannich reaction; Stage #2: With sodium hydroxide In water | 99% |
With acetic acid at 0 - 50℃; for 14h; | 91% |
With zinc(II) chloride In ethanol at 20℃; for 2.5h; Mannich reaction; | 82% |
1-methylindole
1-methyl-1H-indole-2,3-dione
1-methyl-3,3-bis(1-methyl-1H-indol-3-yl)-2,3-dihydro-1H-indol-2-one
Conditions | Yield |
---|---|
With C19H22N4; scandium tris(trifluoromethanesulfonate) In acetonitrile at 20℃; for 18h; Friedel-Crafts Alkylation; Inert atmosphere; Molecular sieve; chemoselective reaction; | 99% |
In acetic acid at 35℃; for 24h; | 92% |
With H6P2W18O62 In water at 60℃; for 0.5h; | 90% |
Conditions | Yield |
---|---|
With tetrafluoroboric acid In diethyl ether; dichloromethane for 0.5h; | 99% |
1-methylindole
methyl 2-methoxy-2-(piperidin-1-yl)acetate
Conditions | Yield |
---|---|
With hafnium tetrakis(trifluoromethanesulfonate); chloro-trimethyl-silane In dichloromethane at 20℃; for 1h; | 99% |
With Methyltrichlorosilane In acetonitrile for 39h; Ambient temperature; | 88% |
1-methylindole
ammonium thiocyanate
N-methyl-3-thiocyanato-1H-indole
Conditions | Yield |
---|---|
With ammonium cerium(IV) nitrate In methanol Ambient temperature; | 99% |
In acetonitrile at 20℃; for 3h; Electrochemical reaction; Inert atmosphere; | 99% |
With oxygen In tetrahydrofuran at 25℃; under 750.075 Torr; for 10h; Irradiation; | 98% |
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