As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:616-44-4
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiry3-Methylthiophene Basic information Product Name: 3-Methylthiophene Synonyms: 3MT;3-METHYLTHIOPHENE;3-methyl-thiophen;3-Thiotolene;beta-methylthiophene;Methyl-3-thiophene;3-Methylthiophene,98%;3-Methylthi
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inquiryChemical Name: 3-Methylthiophene CAS No.: 616-44-4 Molecular Fomula: C5H6S Molecular weight: 98.17 Appearance: Colorless transparent or weak yellow liquid Assay:99% Appearance: Colorless Liquid Storage:RT. Package:drum Application: P
Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Lorcaserin(856681-05-5)is an orally administered agent and a selective 5-HT2C receptor agonist for the treatment of obesity. It had been approved for marketing in US by FDA on 27 June in 2012. In clinical studies, lorcaserin h
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inquirysuperior quality moderate price & quick delivery Appearance:clear colorless to light yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Applic
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:616-44-4
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inquiryProduct name: 3-Methylthiophene CAS No.:616-44-4 Molecule Formula:C5H6S Molecule Weight:98.17 Purity: 99.0% Package: 200kg/drum Description:Light yellow oil-like liquid Manufacture Standards:Enterprise Standard TES
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inquiryCAS:616-44-4 EINECS:210-482-6 MW:98.17 MF:C5H6S Melting point:−69 °C(lit.) Boiling point:114 °C738 mm Hg(lit.) Appearance:liquid Package:50kg/plastic drum Transportation:by sea Port:Shanghai
Name: Fmoc-N'- Acetyl-L-lysine. Synonyms:3-Methylthiophene,99+%;Thiophene,3-methyl-;3-Methylthiophene,98%;3-Methyl[b]thiophene;4-Methylthiophene;β-Methylthiophene;3-Methylthiophene,99+%50ML;3MT CAS No: 616-44-4. Molecular formula: C9
Cas:616-44-4
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inquiryAppearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea
3-MethylthiopheneAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Appearance:Liquid Storage:tightly from light Package:200kg/drum Transportation:SEA Port:Qingdao
Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:616-44-4
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inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
3-methlthiophene m.f.:C5H6S melting point:-69 C Density:1.016 boiling point: 115-117C Flash point: 11C refractive index:1.518-1.52 solubility:…Appearance:colorless or light yellow liquid Package:200kg drum Application:pharmaceutical intermediate
Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi
3-MethylthiopheneAppearance:liquid Storage:Flammables area Package:foil bags or bottles Application:A thiophene derivative used as an electropolymerization monomer in conducting polymer research. Transportation:By express (Door to door) such as FEDEX
2,5-Dichloro-3-methylthiophene
3-Methylthiophene
Conditions | Yield |
---|---|
With palladium 10% on activated carbon; hydrogen; potassium hydroxide In methanol at 80℃; under 60006 Torr; for 24h; | 95.33% |
Conditions | Yield |
---|---|
bis-triphenylphosphine-palladium(II) chloride In benzene at 80℃; for 24h; | 93% |
Conditions | Yield |
---|---|
Stage #1: 3-thienyl iodide; bis(iodozinc)methane With tris-(dibenzylideneacetone)dipalladium(0); tris<3,5-bis(trifluoromethyl)phenyl>phosphane In tetrahydrofuran at 40℃; for 0.5h; Stage #2: With hydrogenchloride In tetrahydrofuran; water chemoselective reaction; | 73% |
3-hydroxymethyl-thiophene
carbon monoxide
A
thiophen-3-yl-acetic acid
B
3-Methylthiophene
Conditions | Yield |
---|---|
With hydrogen iodide; tetrakis(triphenylphosphine) palladium(0) In acetone at 90℃; under 68400 Torr; for 42h; Carbonylation; reduction; | A 34% B 11% |
With tetrakis(triphenylphosphine) palladium(0); hydrogen iodide In acetone at 90℃; under 68400 Torr; for 42h; | A 34 % Spectr. B 11 % Spectr. |
thiophene
A
3-Methylthiophene
Conditions | Yield |
---|---|
A 32% B 33% C 6% |
bis-(1-propenyl) sulfide
A
thiophene
B
2-Methylthiophene
C
2-ethylthiophene
D
3-Methylthiophene
Conditions | Yield |
---|---|
at 500 - 520℃; pyrolysis at atmospheric pressure in a nitrogen stream; Further byproducts given; | A 32% B n/a C 25% D n/a |
Divinyl sulfone
A
thiophene
B
2-Methylthiophene
C
3-Methylthiophene
D
toluene
E
Benzo[b]thiophene
F
benzene
Conditions | Yield |
---|---|
With hydrogen sulfide at 580℃; thermal transformations of divinyl sulfone; further gaseous medium; | A 12% B 1.1% C 3% D 3.6% E 0.4% F 11% |
Conditions | Yield |
---|---|
With aluminium oxide-chromium oxide; sulfur dioxide |
Conditions | Yield |
---|---|
With aluminium oxide-chromium oxide; sulfur dioxide |
Conditions | Yield |
---|---|
With aluminium oxide-chromium oxide; sulfur dioxide |
Conditions | Yield |
---|---|
With aluminium oxide-chromium oxide; sulfur dioxide |
Conditions | Yield |
---|---|
With sulfur at 350℃; |
thiophene
dimethylfluoronium ion
A
2-Methylthiophene
B
3-Methylthiophene
Conditions | Yield |
---|---|
With oxygen; trimethylamine In gas Product distribution; gas-phase methylation of furan and thiophene, pressure dependence, effect of partial pressure of NMe3, competition experiments in the presence of benzene; mechanism of methylation; |
thiophene
dimethylchloronium
A
2-Methylthiophene
B
3-Methylthiophene
Conditions | Yield |
---|---|
With oxygen; trimethylamine In gas Product distribution; gas-phase methylation of furan and thiophene, pressure dependence, effect of partial pressure of NMe3, competition experiments in the presence of benzene; mechanism of methylation; |
2-Methylthiophene
A
2-ethylthiophene
B
2,4-dimethylthiophene
C
2,5-DIMETHYLTHIOPHENE
D
3-Methylthiophene
Conditions | Yield |
---|---|
1.) glow discharge, 2.) -196 deg C -> -80 deg C; Further byproducts given. Title compound not separated from byproducts; | A 11.7 % Chromat. B 0.6 % Chromat. C 4.9 % Chromat. D 9.2 % Chromat. |
2,3-dimethylthiophene
A
thiophene
B
2-ethylthiophene
C
2,5-DIMETHYLTHIOPHENE
D
3-Methylthiophene
Conditions | Yield |
---|---|
1.) glow discharge, 2.) -196 deg C -> -80 deg C; Further byproducts given. Title compound not separated from byproducts; | A 3.1 % Chromat. B 1.5 % Chromat. C 1.0 % Chromat. D 12.8 % Chromat. |
2,3-dimethylthiophene
A
2-Methylthiophene
B
3-Methylthiophene
C
toluene
D
benzene
Conditions | Yield |
---|---|
1.) glow discharge, 2.) -196 deg C -> -80 deg C; Further byproducts given. Title compound not separated from byproducts; | A 6.6 % Chromat. B 12.8 % Chromat. C 4.1 % Chromat. D 24.7 % Chromat. |
2,3-dimethylthiophene
A
3,4-dimethylthiophene
B
2-ethylthiophene
C
2,4-dimethylthiophene
D
3-Methylthiophene
Conditions | Yield |
---|---|
1.) glow discharge, 2.) -196 deg C -> -80 deg C; Further byproducts given. Title compound not separated from byproducts; | A 2.3 % Chromat. B 1.5 % Chromat. C 1.5 % Chromat. D 12.8 % Chromat. |
3,4-dimethylthiophene
A
2,3-dimethylthiophene
B
2,4-dimethylthiophene
C
2,5-DIMETHYLTHIOPHENE
D
3-Methylthiophene
Conditions | Yield |
---|---|
1.) glow discharge, 2.) -196 deg C -> -80 deg C; Further byproducts given. Title compound not separated from byproducts; | A 5.1 % Chromat. B 6.2 % Chromat. C 1.1 % Chromat. D 12.2 % Chromat. |
3,4-dimethylthiophene
A
2,4-dimethylthiophene
B
2,5-DIMETHYLTHIOPHENE
C
3-Methylthiophene
D
benzene
Conditions | Yield |
---|---|
1.) glow discharge, 2.) -196 deg C -> -80 deg C; Further byproducts given. Title compound not separated from byproducts; | A 6.2 % Chromat. B 1.1 % Chromat. C 12.2 % Chromat. D 17.6 % Chromat. |
Conditions | Yield |
---|---|
With n-butyllithium 1.) hexane, THF, -78 deg C, 1 h; 2.) -78 deg C to RT; Yield given. Multistep reaction; |
2,4-dimethylthiophene
A
2-Methylthiophene
B
3,4-dimethylthiophene
C
2,5-DIMETHYLTHIOPHENE
D
3-Methylthiophene
Conditions | Yield |
---|---|
1.) glow discharge, 2.) -196 deg C -> -80 deg C; Further byproducts given. Title compound not separated from byproducts; | A 6.6 % Chromat. B 2.9 % Chromat. C 3.5 % Chromat. D 9.5 % Chromat. |
2,5-DIMETHYLTHIOPHENE
A
thiophene
B
2-Methylthiophene
C
2,3-dimethylthiophene
D
3-Methylthiophene
Conditions | Yield |
---|---|
1.) glow discharge, 2.) -196 deg C -> -80 deg C; Further byproducts given. Title compound not separated from byproducts; | A 2.0 % Chromat. B 15.4 % Chromat. C 1.0 % Chromat. D 2.3 % Chromat. |
isopropyl vinyl sulfide
A
thiophene
B
2-Methylthiophene
C
3-Methylthiophene
D
toluene
E
benzene
Conditions | Yield |
---|---|
at 550℃; Product distribution; |
bis-(1-propenyl) sulfide
A
thiophene
B
2-Methylthiophene
C
2-ethylthiophene
D
3-Methylthiophene
E
Prop-1-en-1-thiol
F
benzene
Conditions | Yield |
---|---|
at 520℃; Product distribution; Mechanism; reaction in the presence of dimethyl selenide, 2-halothiophenes and acetylene, var. temp.; |
propyl vinyl sulfide
A
thiophene
B
2-Methylthiophene
C
3-Methylthiophene
D
toluene
E
benzene
Conditions | Yield |
---|---|
at 550℃; Product distribution; |
Conditions | Yield |
---|---|
With cerium(IV) oxide; aluminum oxide; chromium(III) oxide; lanthanum(III) oxide; praseodymium(III) oxide; Nd3O3; hydrogen sulfide; potassium oxide at 550℃; under 760 Torr; Yield given. Yields of byproduct given; | |
With hydrogen sulfide; cerium(IV) oxide; chromium(III) oxide; lanthanum(III) oxide; neodymium(III) oxide; praseodymium(III) oxide; potassium oxide at 550℃; Product distribution; Further Variations:; Catalysts; |
pentane
A
thiophene
B
2-Methylthiophene
C
3-Methylthiophene
D
2-methyl-but-2-ene
E
(Z)-pent-2-ene
F
(E)-pent-2-ene
Conditions | Yield |
---|---|
With hydrogen sulfide; ferrisilicate at 500℃; for 1h; Product distribution; other temperatures, other volume feed rates of n-pentane, other H2S/n-pentane molar ratios, other reaction times; | A 0.3 % Chromat. B 12.2 % Chromat. C 1.7 % Chromat. D n/a E n/a F n/a |
vinyl ethylsulfide
A
thiophene
B
2-Methylthiophene
C
3-Methylthiophene
D
toluene
E
benzene
Conditions | Yield |
---|---|
at 550℃; Product distribution; |
A
3-Methylthiophene
Conditions | Yield |
---|---|
at 430 - 600℃; |
3-Methylthiophene
4-heptanone
2-(4-hydroxy-4-heptyl)-4-methylthiophene
Conditions | Yield |
---|---|
Stage #1: 3-Methylthiophene With n-butyllithium In diethyl ether; hexane for 1h; Reflux; Stage #2: 4-heptanone In diethyl ether at 20℃; for 1h; | 100% |
3-Methylthiophene
2-bromo-3-methylthiophene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In tetrahydrofuran Inert atmosphere; | 99% |
With N-Bromosuccinimide | 99% |
With N-Bromosuccinimide In acetic acid for 0.416667h; | 97.9% |
3-Methylthiophene
2,5-dibromo-3-methylthiophene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In tetrahydrofuran Inert atmosphere; | 99% |
With benzyltrimethylazanium tribroman-2-uide; zinc(II) chloride In acetic acid for 15h; Ambient temperature; | 97% |
With potassium bromide In water; acetic acid at 30℃; for 0.25h; Temperature; | 94% |
3-Methylthiophene
[hydroxy(tosyloxy)iodo]benzene
(3-methyl-2-thienyl)(phenyl)iodonium tosylate
Conditions | Yield |
---|---|
In 2,2,2-trifluoroethanol at 20℃; for 3h; | 98% |
In 2,2,2-trifluoroethanol at 20℃; for 3h; | 98% |
In 2,2,2-trifluoroethanol at 0 - 20℃; | 98% |
In chloroform for 2h; Heating; | 78.1% |
3-Methylthiophene
[hydroxy(tosyloxy)iodo]benzene
(3-methyl-2-thienyl)(phenyl)iodonium tosylate
Conditions | Yield |
---|---|
In 2,2,2-trifluoroethanol at 20℃; for 2h; | 98% |
In 2,2,2-trifluoroethanol at 20℃; for 2h; | 84% |
3-Methylthiophene
3'-[4-(t-butyldimethylsilyloxy)-3-methylphenyl]pentan-3-ol
3'-[4-(hydroxy)-3-methylphenyl]-3'-[4-methylthiophen-2-yl]pentane
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate at -78 - 20℃; for 6.75h; | 95% |
With boron trifluoride diethyl etherate at -78 - 20℃; for 6.75h; Product distribution / selectivity; | 95% |
3-Methylthiophene
4-bromobenzenecarbonitrile
4-(4-methylthiophen-2-yl)benzonitrile
Conditions | Yield |
---|---|
Stage #1: 3-Methylthiophene With 2,2,6,6-tetramethyl-piperidine; tert.-butyl lithium In tetrahydrofuran; hexane at 0℃; for 1h; Inert atmosphere; Stage #2: With zinc(II) chloride In tetrahydrofuran; diethyl ether; hexane at 0℃; for 4h; Inert atmosphere; Stage #3: 4-bromobenzenecarbonitrile With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran; diethyl ether; hexane at 20 - 50℃; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
Stage #1: 3-Methylthiophene With 2,2,6,6-tetramethylpiperidin-4-yl heptanoate; isopropylmagnesium chloride In tetrahydrofuran at 66℃; for 23h; Stage #2: phthalic anhydride With hydrogenchloride In tetrahydrofuran; water at -20 - 20℃; | 94% |
Stage #1: 3-Methylthiophene With 2,2,6,6-tetramethyl-piperidine; isopropylmagnesium chloride In tetrahydrofuran at 66℃; for 23h; Inert atmosphere; Stage #2: phthalic anhydride In tetrahydrofuran at -25 - -20℃; for 1.08333h; Inert atmosphere; Stage #3: With hydrogenchloride In tetrahydrofuran; water at -20 - 20℃; pH=2; regioselective reaction; | 89.7% |
With aluminium trichloride; nitrobenzene |
3-Methylthiophene
2-iodo-3-methylthiophene
Conditions | Yield |
---|---|
With iodine; mercury(II) oxide | 94% |
With iodine; mercury(II) oxide In benzene for 0.5h; Ambient temperature; | 94% |
With iodine; mercury(II) oxide In benzene Iodination; | 79% |
3-Methylthiophene
2,3,5-triiodo-4-methyl-thiophene
Conditions | Yield |
---|---|
With N,N,N-trimethylbenzenemethanaminium dichloroiodate; zinc(II) chloride In acetic acid for 15h; Ambient temperature; | 94% |
With mercury(II) diacetate; iodine; acetic acid |
3-Methylthiophene
pentaamminetrifluoromethanesulfonato osmium(III) trifluoromethanesulfonate
Conditions | Yield |
---|---|
With Mg In N,N-dimethyl acetamide Kinetics; N2-atmosphere; | 93% |
With Z/Hg In methanol Kinetics; N2-atmosphere; | 93% |
In [D3]acetonitrile Kinetics; N2-atmosphere; -40°C; not isolated; detd. by (1)H NMR spectroscopy; |
Conditions | Yield |
---|---|
With tert-butylethylene; C25H40O2P2Ru In neat (no solvent) at 120℃; for 48h; Inert atmosphere; Schlenk technique; Glovebox; regioselective reaction; | 93% |
Stage #1: 1,1,1,3,5,5,5-heptamethyltrisiloxan With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; C25H35N3; cyclohexene In tetrahydrofuran Inert atmosphere; Glovebox; Stage #2: 3-Methylthiophene In tetrahydrofuran at 65℃; for 26h; Sealed tube; Inert atmosphere; regioselective reaction; | 89% |
3-Methylthiophene
3-methyl-2,5-diiodothiophene
Conditions | Yield |
---|---|
With N,N,N-trimethylbenzenemethanaminium dichloroiodate; zinc(II) chloride In acetic acid for 4h; Ambient temperature; | 92% |
With sulfuric acid; iodine; iodic acid In tetrachloromethane; water; acetic acid for 4h; Heating; | 64% |
3-Methylthiophene
N,N-dimethyl-formamide
4-methylthiophene-2-carbaldehyde
Conditions | Yield |
---|---|
Stage #1: 3-Methylthiophene With 2,2,6,6-tetramethyl-piperidine; tert.-butyl lithium In tetrahydrofuran; hexane at 0℃; for 1h; Inert atmosphere; Stage #2: N,N-dimethyl-formamide In tetrahydrofuran; hexane at 0 - 20℃; Inert atmosphere; | 92% |
Stage #1: 3-Methylthiophene With n-butyllithium In tetrahydrofuran at -65℃; for 0.5h; Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at -65℃; for 2h; | 90% |
With n-butyllithium In diethyl ether at 20℃; for 1.5h; | 84% |
3-Methylthiophene
Conditions | Yield |
---|---|
In acetonitrile addn. of solvent and thiophene to complex, degassed three times, sealed (vac.), heated at 60°C for 24 h in the dark; addn. of Et2O, pptn., filtered, addn. of Et2O to CH2Cl2 soln., filtered, dissolved in CH3CN, addn. of Et2O, recrystd. (CH2Cl2/Et2O); elem. anal.; | 92% |
3-Methylthiophene
diphenyltin(IV) dichloride
bis(4-methyl-2-thienyl)diphenyltin(IV)
Conditions | Yield |
---|---|
With n-C4H9Li In not given reflux 3 h; | 92% |
With PhLi In not given reflux 3 h; elem. anal.; | 79% |
3-Methylthiophene
Conditions | Yield |
---|---|
In 2,2,2-trifluoroethanol at 20℃; for 3h; | 92% |
Conditions | Yield |
---|---|
In 2,2,2-trifluoroethanol at 20℃; for 3h; | 92% |
Conditions | Yield |
---|---|
With 5%-palladium/activated carbon In ethanol at 60℃; for 22h; regioselective reaction; | 92% |
With palladium In tetrahydrofuran at 60℃; for 24h; | 71% |
Conditions | Yield |
---|---|
Stage #1: iodobenzene With peracetic acid; acetic acid In dichloromethane; 2,2,2-trifluoroethanol at 35℃; for 1h; Stage #2: 3-Methylthiophene; toluene-4-sulfonic acid In dichloromethane; 2,2,2-trifluoroethanol at 20℃; for 3h; | 91% |
3-Methylthiophene
3-Bromomethylthiophene
Conditions | Yield |
---|---|
With N-Bromosuccinimide; dihydrogen peroxide In tetrachloromethane | 90% |
With N-Bromosuccinimide; dibenzoyl peroxide In benzene for 0.5h; Heating; | 88% |
With N-Bromosuccinimide; dibenzoyl peroxide In tetrachloromethane for 2h; Reflux; | 87% |
Conditions | Yield |
---|---|
dirhodium tetraacetate In fluorobenzene for 15h; Ambient temperature; | 90% |
3-Methylthiophene
A
2-iodo-3-methylthiophene
B
3-methyl-2,5-diiodothiophene
Conditions | Yield |
---|---|
With ammonium iodide; dihydrogen peroxide In water; acetic acid for 20h; Green chemistry; regioselective reaction; | A 90% B 10% |
Conditions | Yield |
---|---|
Stage #1: 3-Methylthiophene With n-butyllithium In diethyl ether; hexane for 1h; Heating; Stage #2: With Trimethyl borate In diethyl ether; hexane at 20℃; for 1h; Stage #3: iodobenzene With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran; diethyl ether; hexane for 5h; Heating; | 89% |
3-Methylthiophene
(mesyloxyhydroxyiodo)benzene
Conditions | Yield |
---|---|
In 2,2,2-trifluoroethanol at 20℃; for 3h; | 89% |
3-Methylthiophene
(mesyloxyhydroxyiodo)benzene
(3-methyl-2-thienyl)(phenyl)iodonium methanesulfonate
Conditions | Yield |
---|---|
In 2,2,2-trifluoroethanol at 20℃; for 3h; | 89% |
Conditions | Yield |
---|---|
With dichloro bis(acetonitrile) palladium(II); lithium carbonate In 1,4-dioxane at 140℃; for 40h; Inert atmosphere; Schlenk technique; regioselective reaction; | 89% |
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; tetra-(n-butyl)ammonium iodide; copper(II) sulfate; sodium iodide In decane; dichloromethane at 70℃; for 8h; | 89% |
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