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Dayang Chem (Hangzhou) Co.,Ltd.

Index Name Specifications Appearance Colorless liquid Light component wt % 0.7834% n-pentane wt%

Pentane

Cas:109-66-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Test Result Content ≥95.0% 97.2120% Density of relativity 0.6253~0.6273

High purity Various Specifications n-Pentane CAS:109-66-0

Cas:109-66-0

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Manufacturers

inquiry

Hefei TNJ chemical industry co.,ltd

ISO9001 Good quality Competitive price On time delivery Appearance:colorless liquid Storage:kept in a light-proof,well-colsed,dry and cool place. Package:125kg/drum Application:For high density polyethylene solvent polymerization catalysts

Good quality Pentane//109-66-0

Cas:109-66-0

Min.Order:10 Metric Ton

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

The company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:White or off-white Solid Storage:Sealed, dr

Pentane

Cas:109-66-0

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Pentane

Cas:109-66-0

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Pentane

Cas:109-66-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

n-Pentane

Cas:109-66-0

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.

TIANFU-CHEM CAS NO.109-66-0 Pentane

Cas:109-66-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Product name Pentane CAS NO. 109-66-0 Other names PETANE;PENTANE;PENTANE-195;PENTANE FRACTION;PETROLEUM SPIRIT 30/40;N-PENTAN;N-

Pentane

Cas:109-66-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Lonwin Chemical Group Limited

n-Pentane CAS:109-66-0 Specification Alias: pentane B&J brand 4 L; Pentane,99.5%; Pentane mixed isomers; Pentane oil; pentane CAS No.: 109-66-0 EINECS No.: 203-692-4 Molecular formula: C5H12

Factory supply n-Pentane

Cas:109-66-0

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Pentane CAS NO.109-66-0

Cas:109-66-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediat

Pentane

Cas:109-66-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity Pentane

Cas:109-66-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

PentaneCAS NO.: 109-66-0

Cas:109-66-0

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Product Name:Pentane Synonym:n-Pentane Cas No:109-66-0 Molecular Formula:C5H12 Molecular Weight:72.15 Appearance and character: transparent colorless liquid Purity: 95%~99% Density: 0.626 Melting point: - 130℃ Boiling point: 36℃

Pentane manufacture

Cas:109-66-0

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

2-Butene-1,4-diol

Cas:109-66-0

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Nanjing Yuance Industry&Trade Co., Ltd.

Product name Pentane CAS 109-66-0 MF C5H12 MW 72.15 Product name PentaneCAS 109-66-0 MF C5H12 MW 72.15mp-130 °Cbp36 °Cd…

Pentane

Cas:109-66-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

n-Pentane

Cas:109-66-0

Min.Order:0

Negotiable

Type:Other

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 109-66-0 with competitive price

Cas:109-66-0

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Pentane

Cas:109-66-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

n-pentane

Cas:109-66-0

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Fandachem Co.,Ltd

Pentane cas 109-66-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Pentane cas 109-66-0

Cas:109-66-0

Min.Order:0

Negotiable

Type:Other

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

Pentane

Cas:109-66-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beantown Chemical

in stock Application:109-66-0

n-Pentane, Environmental, 98.0% min.

Cas:109-66-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HWRK Chem

in storeAppearance:Colorless liquid Package:500ml Application:Organic Chemicals

Pentane

Cas:109-66-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#109-66-0;CAT#A802071

Cas:109-66-0

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

1. ISO 9001 approved, GMP producing standard,Proffesional QA system, our quality is guaranteed. 2. Facotory direct sale, most comptive price ensured; 3. Audited Supplier on lookchem, No trick, No Scam! 4. Enough stock can make sure safe deliv

Buy 109-66-0 C5H12 Pentane

Cas:109-66-0

Min.Order:1 Kilogram

FOB Price: $750.0 / 850.0

Type:Trading Company

inquiry

Jilin Tiandicheng Biotech Co.,Ltd

Price, Service, Company and Transport Advantage: 1. Best service, high quality and reasonable price 2. It's customers' right to choose the package (EMS, DHL, FedEx, UPS); 3. It's customers' right to choose the packing w

High quality Pentane CAS NO.109-66-0

Cas:109-66-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Junyuan Petroleum Group

Junyuan Petroleum Group is China's leading manufacturer of n-Hexane, n-Pentane, Isopentane, Pentane Blends, Isohexane, n-Heptane and D solvents, founded in 1999. Junyuan Petroleum Group provides n-Hexane,99%, n-Pentane,99%, Isopentane, 99%, Pe

n-Pentane

Cas:109-66-0

Min.Order:15 Metric Ton

Negotiable

Type:Manufacturers

inquiry

shanghai Longyu biotechnology Co.,Ltd

We have strong R&D center which can support and provide custom synthesis accordingly such as fine chemicals,biotechnique , pharmaceuticals etc.We can provide free sample for our clients to test anf verify the quality of our goods.LongyuChem holds str

Pentane

Cas:109-66-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

1-penten
109-67-1

1-penten

pentane
109-66-0

pentane

Conditions
ConditionsYield
With H3Ni4(C5H5)4; hydrogen at 40℃; under 760 Torr; other olefins; var. times;100%
With hydrogen In N,N-dimethyl-formamide at 25℃; under 760.051 Torr; for 10h;87%
With C14H15NZr In toluene at 25℃; Reagent/catalyst;11%
2-Pentyne
627-21-4

2-Pentyne

A

(Z)-pent-2-ene
627-20-3

(Z)-pent-2-ene

B

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen; copper-palladium; silica gel In ethanol at 25℃; under 760 Torr; Kinetics;A 99.5%
B n/a
triethylsilane
617-86-7

triethylsilane

1-fluoropentane
592-50-7

1-fluoropentane

A

triethylsilyl fluoride
358-43-0

triethylsilyl fluoride

B

pentane
109-66-0

pentane

Conditions
ConditionsYield
With C21H16N3P(2+) In dichloromethane at 25℃; for 1.5h; Reagent/catalyst;A 97%
B n/a
With [(SIMes)PFMe2][B(C6F5)4]2 In dichloromethane-d2 for 1h; Catalytic behavior; Inert atmosphere;
2-Pentyne
627-21-4

2-Pentyne

A

(Z)-pent-2-ene
627-20-3

(Z)-pent-2-ene

B

(E)-pent-2-ene
646-04-8

(E)-pent-2-ene

C

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen; (3-ClMe2SiPr)P(Ph)CH2C4H7O2 on silicagel In propan-1-ol at 20℃; under 750.06 Torr; for 0.333333h; Product distribution; var. catalyst;A 96%
B 3%
C 1%
With hydrogen; palladium dichloride In N,N-dimethyl-formamide under 18751.5 Torr; for 0.216667h; Product distribution; Ambient temperature; various time;A 1.7%
B 82.7%
C 1.4%
With hydrogen In hexane at 24.84 - 59.84℃; Kinetics; Autoclave; Inert atmosphere;
1-fluoropentane
592-50-7

1-fluoropentane

pentane
109-66-0

pentane

Conditions
ConditionsYield
With triethylsilane; C24BF20(1-)*C30H32BF5P(1+) at 100℃; for 48h; Reagent/catalyst;95%
With triethylsilane; 2C24BF20(1-)*C18H17FNP(2+) at 25℃; for 1h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Schlenk technique; Glovebox;92%
With trityl tetrakis(pentafluorophenyl)borate In 1,2-dichloro-benzene at 22℃; for 24h; Product distribution; Further Variations:; Reagents; Solvents;
hexan-1-ol
111-27-3

hexan-1-ol

A

hexane
110-54-3

hexane

B

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen; aluminum oxide; nickel at 120℃;A 5%
B 94%
With hydrogen In n-heptane at 199.84℃; under 22502.3 Torr; Kinetics; Autoclave;
Cyclopentane
287-92-3

Cyclopentane

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen; osmium(VIII) oxide at 120℃; under 37503 Torr; for 15h; or 100 to 180 deg C, different Os-catalysts and -concentrations; Further byproducts given;90%
With hydrogen; osmium(VIII) oxide at 120℃; under 37503 Torr; for 15h; Product distribution; different Os-catalysts and concentration; reaction temperatures; other alkanes, cycloalkanes, benzene, toluene;90%
With platinum on activated charcoal at 300℃; Hydrogenation;
TETRAHYDROPYRANE
142-68-7

TETRAHYDROPYRANE

pentane
109-66-0

pentane

Conditions
ConditionsYield
With triethylsilane; tris(pentafluorophenyl)borate In dichloromethane at 20℃; for 20h; Reduction;88%
With triethylsilane; tris(pentafluorophenyl)borate In dichloromethane at 20℃; for 20h; Reduction;97 % Spectr.
hexahydro-2H-oxepin-2-one
502-44-3

hexahydro-2H-oxepin-2-one

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen; silica gel; palladium at 330℃;85%
1-penten
109-67-1

1-penten

A

pentane
109-66-0

pentane

B

2-pentene
109-68-2

2-pentene

Conditions
ConditionsYield
With hydrogen; 1-n-butyl-3-methylimidazolium hexafluoroantimonate; [Rh(I)(norbornadiene)(PPh3)2]PF6 In acetone at 30℃; under 750.06 Torr; for 2h;A 83%
B 13%
With hydrogen; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; [Rh(I)(norbornadiene)(PPh3)2]PF6 In acetone at 30℃; under 750.06 Torr;A 25%
B 74%
With C28H25ClNPTi In toluene at 25℃; Reagent/catalyst;A 7%
B 19%
With (iPr4antraphos)Ir(C2H4) at 180℃; for 130h; Inert atmosphere;A 45.5 %Chromat.
B 27.9 %Chromat.
hexanoic acid
142-62-1

hexanoic acid

A

decane
124-18-5

decane

B

1-penten
109-67-1

1-penten

C

pentane
109-66-0

pentane

D

2-pentene
109-68-2

2-pentene

Conditions
ConditionsYield
With potassium hydroxide In water pH=5.4 - 9.4; Concentration; pH-value; Kolbe Electrolysis; Electrochemical reaction;A 82%
B 44%
C 30%
D 26%
With potassium hydroxide In water pH=5.8 - 9; Kolbe Electrolysis; Electrochemical reaction;A 39%
B 14%
C 5%
D 7%
penta-1,3-diene
504-60-9

penta-1,3-diene

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen; nickel(II) oxide; aluminum oxide at 500℃;80.5%
With hydrogen; nickel(II) oxide; aluminum oxide at 500℃; other catalyst; other temp.;80.5%
With ethanol; nickel at 29 - 35℃; under 25742.8 Torr; Hydrogenation;
With dihydrogen hexachloroplatinate; ethanol; H2PtCl6-(C9H19)3N-(i-C4H9)2AlH-C2H5OH; hydrogen; diisobutylaluminium hydride In toluene at 20℃; under 300.02 Torr; further reagents;
n-butyllithium
109-72-8, 29786-93-4

n-butyllithium

1-methoxy-2,4,6-trinitrobenzene
606-35-9

1-methoxy-2,4,6-trinitrobenzene

A

lithium picrate
18390-55-1

lithium picrate

B

pentane
109-66-0

pentane

Conditions
ConditionsYield
In tetrahydrofuran Product distribution; Mechanism; formation of intermediate ς-complex, NMR spectrum of the ς-complex;A 80%
B n/a
1-Pentyne
627-19-0

1-Pentyne

A

(Z)-pent-2-ene
627-20-3

(Z)-pent-2-ene

B

(E)-pent-2-ene
646-04-8

(E)-pent-2-ene

C

1-penten
109-67-1

1-penten

D

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen; palladium dichloride In N,N-dimethyl-formamide under 18751.5 Torr; for 0.3h; Product distribution; Ambient temperature; various time;A n/a
B n/a
C 78.5%
D 2.4%
With [Ru4(μ-H)4(CO)12] In benzene at 25℃; for 23h; Irradiation;A 10%
B 13%
C 73%
D 4%
With [Ru4(μ-H)4(CO)12]; hydrogen In benzene at 25℃; under 517.1 Torr; for 24h; Irradiation;A 13%
B 10%
C 66%
D 11%
chloroform
67-66-3

chloroform

ethylmagnesium chloride
2386-64-3

ethylmagnesium chloride

A

propane
74-98-6

propane

B

3-ethylpentane
617-78-7

3-ethylpentane

C

pentane
109-66-0

pentane

Conditions
ConditionsYield
With C31H37ClN3NiO2(1-)*Li(1+) In tetrahydrofuran at 25℃; for 0.333333h; Inert atmosphere; Overall yield = 93.4 %;A 6%
B 9.4%
C 78%
With C31H37ClFeN3O2 In tetrahydrofuran at 25℃; for 0.0833333h; Inert atmosphere;
2-Pentyne
627-21-4

2-Pentyne

A

(Z)-pent-2-ene
627-20-3

(Z)-pent-2-ene

B

(E)-pent-2-ene
646-04-8

(E)-pent-2-ene

C

1-penten
109-67-1

1-penten

D

pentane
109-66-0

pentane

Conditions
ConditionsYield
With [Ru4(μ-H)4(CO)12] In benzene at 25℃; for 23h; Irradiation;A 75%
B 1%
C 24%
D n/a
With [Ru4(μ-H)4(CO)12]; hydrogen In benzene at 25℃; under 517.1 Torr; for 24h; Irradiation;A 19%
B 73%
C 2%
D 6%
With [Ru4(μ-H)4(CO)12]; hydrogen In benzene at 25℃; for 24h; Irradiation;A 19%
B 73%
C 2%
D 6%
With hydrogen; dodecacarbonyltetrarhodium(0) at 80℃; under 760 Torr; for 3h; Product distribution; other alkynes, other carbonyl-rhodium catalyst system;A 64 % Chromat.
B 17 % Chromat.
C 2 % Chromat.
D 12 % Chromat.
3,4,5,6-tetrahydro-2H-pyran-2-one
542-28-9

3,4,5,6-tetrahydro-2H-pyran-2-one

A

1 ,5-pentanediol
111-29-5

1 ,5-pentanediol

B

pentan-1-ol
71-41-0

pentan-1-ol

C

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen; (acetylacetonato)dicarbonylrhodium (l); molybdenum hexacarbonyl In 1,4-dioxane at 150℃; under 75007.5 Torr; for 3h;A 75%
B 19%
C 6%
pentan-1-ol
71-41-0

pentan-1-ol

A

methylbutane
78-78-4

methylbutane

B

pentane
109-66-0

pentane

Conditions
ConditionsYield
With aluminium trichloride; polyethoxysilane (silicone GKZh-94) In nitromethane Product distribution;A 72%
B 23%
(Z)-pent-2-ene
627-20-3

(Z)-pent-2-ene

A

(E)-pent-2-ene
646-04-8

(E)-pent-2-ene

B

pentane
109-66-0

pentane

Conditions
ConditionsYield
With lithium aluminium tetrahydride; water; uranium(IV) chloride 1.) diglyme, 2.) diglyme, 6 h;A 30%
B 70%
C13H21N3

C13H21N3

buta-1,3-diene
106-99-0

buta-1,3-diene

A

C12H15N3

C12H15N3

B

pentane
109-66-0

pentane

Conditions
ConditionsYield
With (2-(4-methoxyphenyl)ethene-1,1-diyl)bis(diphenylphosphane); bis(1,5-cyclooctadiene)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate In 1,4-dioxane; toluene at 160℃; for 72h; Molecular sieve; Glovebox; Sealed tube; regioselective reaction;A 70%
B n/a
1-penten
109-67-1

1-penten

A

(Z)-pent-2-ene
627-20-3

(Z)-pent-2-ene

B

(E)-pent-2-ene
646-04-8

(E)-pent-2-ene

C

pentane
109-66-0

pentane

Conditions
ConditionsYield
With H2Ru4(CO)12 In benzene at 25℃; for 7h; Product distribution; Quantum yield; Irradiation; further pentenes, other periods of time;A n/a
B n/a
C 69%
With hydrogen; palladium; platinum Mechanism; Product distribution; dependence of product distribution on kind of catalyst;
With hydrogen; (CO)12> In dichloromethane at 35℃; under 760 Torr; for 24h; Product distribution; other ruthenium catalysts, other temp., other pressure of H2, various partial pressure of CO, also in the presence of PPh3;
With hydrogen; bis(benzonitrile)palladium(II) dichloride In toluene at 25℃; Product distribution; Kinetics;
With iron pentacarbonyl; hydrogen Product distribution; Irradiation; var. times;
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

1-Bromopentane
110-53-2

1-Bromopentane

tetramethlyammonium chloride
75-57-0

tetramethlyammonium chloride

A

{(CH3)4N}(1+)*{B11H14}(1-)={(CH3)4N}{B11H14}

{(CH3)4N}(1+)*{B11H14}(1-)={(CH3)4N}{B11H14}

B

pentane
109-66-0

pentane

Conditions
ConditionsYield
In water; diethylene glycol byproducts: NaBr, H2; NaBH4 in diglyme heated to 105°C, n-amyl bromide added to stirred suspn. over 5 h, suspn. allowed to cool, filtered, solids washed with Et2O, combined solns. evapd. residue dissolved in water and Me4NCl added; ppt. filtered and recrystd. from acetone/water;A 67%
B n/a
1-methylbuta-1,3-diene
2004-70-8

1-methylbuta-1,3-diene

A

(Z)-pent-2-ene
627-20-3

(Z)-pent-2-ene

B

(E)-pent-2-ene
646-04-8

(E)-pent-2-ene

C

1-penten
109-67-1

1-penten

D

pentane
109-66-0

pentane

Conditions
ConditionsYield
With hydrogen; palladium dichloride In N,N-dimethyl-formamide under 18751.5 Torr; for 0.116667h; Product distribution; Ambient temperature; various time;A 11.7%
B 62.1%
C 15.3%
D 1.2%
With hydrogen; complex 1 under 684 Torr; for 6h; Product distribution; Variation of complex catalysts, time.;
With hydrogen; Pd-containing polymer In methanol at 20℃; Product distribution; catalytic properties of palladium fixed on poly(m- and p-)hydroxyphenylbenzoxazoleterephthalamides, hydrogenation and isomerization of olefins;
With hydrogen; <2> In dichloromethane for 5h; Product distribution; other alkene;
2-bromopentane
107-81-3

2-bromopentane

octylmagnesium bromide
17049-49-9

octylmagnesium bromide

A

4-methyldodecane
6117-97-1

4-methyldodecane

B

pentane
109-66-0

pentane

C

2-pentene
109-68-2

2-pentene

Conditions
ConditionsYield
With N,N,N,N,-tetramethylethylenediamine; cobalt(II) chloride; lithium iodide In tetrahydrofuran at 10℃; for 1h; Inert atmosphere; chemoselective reaction;A 62%
B n/a
C n/a
propane
74-98-6

propane

A

ethane
74-84-0

ethane

B

Isobutane
75-28-5

Isobutane

C

n-butane
106-97-8

n-butane

D

pentane
109-66-0

pentane

Conditions
ConditionsYield
silica/alumina-supp. -O-W[(C-tBu)(-CH2-tBu)2] at 150℃; under 600 Torr; for 120h; Product distribution; Further Variations:; Catalysts;A 61.7%
B 3.4%
C 25.7%
D 5.5%
tetrachloromethane
56-23-5

tetrachloromethane

ethylmagnesium chloride
2386-64-3

ethylmagnesium chloride

A

3-ethylpentane
617-78-7

3-ethylpentane

B

pentane
109-66-0

pentane

Conditions
ConditionsYield
With C31H37ClN3NiO2(1-)*Li(1+) In tetrahydrofuran at 25℃; for 0.333333h; Inert atmosphere; Overall yield = 100 %;A 42.8%
B 57.2%
dichloromethane
75-09-2

dichloromethane

ethylmagnesium chloride
2386-64-3

ethylmagnesium chloride

A

propene
187737-37-7

propene

B

n-butane
106-97-8

n-butane

C

pentane
109-66-0

pentane

Conditions
ConditionsYield
With C31H37ClN3NiO2(1-)*Li(1+) In tetrahydrofuran at 25℃; for 0.333333h; Inert atmosphere; Overall yield = 91 %;A 14%
B 20%
C 57%
pentane
109-66-0

pentane

decane
124-18-5

decane

Conditions
ConditionsYield
With di-tert-butyl peroxide; iodine100%
HOC6H3ClCH2N(CH3)C2H4N(CH3)CH2C6H2(C(CH3)3)2OH
1129682-90-1

HOC6H3ClCH2N(CH3)C2H4N(CH3)CH2C6H2(C(CH3)3)2OH

zirconium(IV) tert-butoxide

zirconium(IV) tert-butoxide

pentane
109-66-0

pentane

[(OC6H3ClCH2N(CH3)C2H4N(CH3)CH2C6H2(C(CH3)3)2O)Zr(OC(CH3)3)2]*0.5C5H12

[(OC6H3ClCH2N(CH3)C2H4N(CH3)CH2C6H2(C(CH3)3)2O)Zr(OC(CH3)3)2]*0.5C5H12

Conditions
ConditionsYield
In diethyl ether byproducts: (CH3)3COH; (N2); glovebox; soln. of ligand in ether was added to soln. of Zr complex in ether; stirred at room temp. for 2 h; solvent removed (vac.); washed (pentane); solvent removed (vac.); elem. anal.;100%
HOC6H2Cl2CH2N(CH3)C2H4N(CH3)CH2C6H2(C10H15)(CH3)OH
1129682-97-8

HOC6H2Cl2CH2N(CH3)C2H4N(CH3)CH2C6H2(C10H15)(CH3)OH

zirconium(IV) tert-butoxide

zirconium(IV) tert-butoxide

pentane
109-66-0

pentane

[(OC6H2Cl2CH2N(CH3)C2H4N(CH3)CH2C6H2(C10H15)(CH3)O)Zr(OC(CH3)3)2]*C5H12

[(OC6H2Cl2CH2N(CH3)C2H4N(CH3)CH2C6H2(C10H15)(CH3)O)Zr(OC(CH3)3)2]*C5H12

Conditions
ConditionsYield
In diethyl ether byproducts: (CH3)3COH; (N2); glovebox; soln. of ligand in ether was added to soln. of Zr complex in ether; stirred at room temp. for 2 h; solvent removed (vac.); washed (pentane); solvent removed (vac.); elem. anal.;100%
N,N-bis(3,4-dimethyl-2-hydroxybenzyl)-N',N'-dimethylethylenediamine
244005-01-4

N,N-bis(3,4-dimethyl-2-hydroxybenzyl)-N',N'-dimethylethylenediamine

C14H6(C4H9)4H2NC3H7O2Ti(OC3H7)2
359902-97-9

C14H6(C4H9)4H2NC3H7O2Ti(OC3H7)2

pentane
109-66-0

pentane

(C14H6(CH3)4H2NC2H4N(CH3)2O2)(C14H6(C4H9)4H2NC3H7O2)Ti*C5H12

(C14H6(CH3)4H2NC2H4N(CH3)2O2)(C14H6(C4H9)4H2NC3H7O2)Ti*C5H12

Conditions
ConditionsYield
In diethyl ether the mixt. in ether was stirred for 2 h at room temp. under N2; volatiles were removed under reduced pressure; elem. anal.;99%
HOC6H2Br2CH2N(CH3)C2H4N(CH3)CH2C6H2(C(CH3)3)2OH
1129682-92-3

HOC6H2Br2CH2N(CH3)C2H4N(CH3)CH2C6H2(C(CH3)3)2OH

zirconium(IV) tert-butoxide

zirconium(IV) tert-butoxide

pentane
109-66-0

pentane

[(OC6H2Br2CH2N(CH3)C2H4N(CH3)CH2C6H2(C(CH3)3)2O)Zr(OC(CH3)3)2]*C5H12

[(OC6H2Br2CH2N(CH3)C2H4N(CH3)CH2C6H2(C(CH3)3)2O)Zr(OC(CH3)3)2]*C5H12

Conditions
ConditionsYield
In diethyl ether byproducts: (CH3)3COH; (N2); glovebox; soln. of ligand in ether was added to soln. of Zr complex in ether; stirred at room temp. for 2 h; solvent removed (vac.); washed (pentane); solvent removed (vac.); elem. anal.;99%
HOC6H2I2CH2N(CH3)C2H4N(CH3)CH2C6H2(C10H15)(CH3)OH
1129683-02-8

HOC6H2I2CH2N(CH3)C2H4N(CH3)CH2C6H2(C10H15)(CH3)OH

zirconium(IV) tert-butoxide

zirconium(IV) tert-butoxide

pentane
109-66-0

pentane

[(OC6H2I2CH2N(CH3)C2H4N(CH3)CH2C6H2(C10H15)(CH3)O)Zr(OC(CH3)3)2]*C5H12

[(OC6H2I2CH2N(CH3)C2H4N(CH3)CH2C6H2(C10H15)(CH3)O)Zr(OC(CH3)3)2]*C5H12

Conditions
ConditionsYield
In diethyl ether byproducts: (CH3)3COH; (N2); glovebox; soln. of ligand in ether was added to soln. of Zr complex in ether; stirred at room temp. for 2 h; solvent removed (vac.); washed (pentane); solvent removed (vac.); elem. anal.;99%
[(dimethyl-bis(4-tert-butyl-2-pyridyl)borate)Pt(CH3)2]Na
1198747-49-7

[(dimethyl-bis(4-tert-butyl-2-pyridyl)borate)Pt(CH3)2]Na

water
7732-18-5

water

pentane
109-66-0

pentane

[(dimethyl-bis(4-tert-butyl-2-pyridyl)borate)PtH(1-pentene)]
1198747-51-1

[(dimethyl-bis(4-tert-butyl-2-pyridyl)borate)PtH(1-pentene)]

Conditions
ConditionsYield
In not given byproducts: NaOH; 3 equiv. H2O, room temp., 5 min;99%
4,4'-bis(P-((S,S)-[2,6-bis(4'-isopropyl-2'-oxazolinyl)phenyl]gold(I))(diphenylphosphino))biphenyl*(benzene)

4,4'-bis(P-((S,S)-[2,6-bis(4'-isopropyl-2'-oxazolinyl)phenyl]gold(I))(diphenylphosphino))biphenyl*(benzene)

niobium pentachloride
10026-12-7

niobium pentachloride

pentane
109-66-0

pentane

benzene
71-43-2

benzene

A

4,4'-bis[P-(chlorogold(I))diphenylphosphino]biphenyl
528522-58-9

4,4'-bis[P-(chlorogold(I))diphenylphosphino]biphenyl

B

(S,S)-[2,6-bis(4'-isopropyl-2'-oxazolinyl)phenyl]niobium(V) dichloride oxide dimer*(benzene)*(pentane)

(S,S)-[2,6-bis(4'-isopropyl-2'-oxazolinyl)phenyl]niobium(V) dichloride oxide dimer*(benzene)*(pentane)

Conditions
ConditionsYield
In tetrahydrofuran under N2; soln. of Au complex in THF added to solid NbCl5; stirred at room temp. overnight; volatiles removed in vac.; dissolved in benzene; centrifuged; decanted; concd. in vac.; crystd. from benzene-pentane; elem. anal.;A 99%
B 76%
N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

[[Li(THF)2][(CO)3CrGe9[Si(SiMe3)3)3]]2

[[Li(THF)2][(CO)3CrGe9[Si(SiMe3)3)3]]2

pentane
109-66-0

pentane

[(TMEDA)2Li][(CO)3CrGe9[Si(SiMe3)3)3]*0.5(pentane)

[(TMEDA)2Li][(CO)3CrGe9[Si(SiMe3)3)3]*0.5(pentane)

Conditions
ConditionsYield
In pentane (N2) to soln. Cr-Ge complex in pentane TMEDA was added at room temp., stored at 6°C overnight;99%
N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

[(THF)3Li][(CO)3CrGe9[Si(SiMe3)3)3]*pentane

[(THF)3Li][(CO)3CrGe9[Si(SiMe3)3)3]*pentane

pentane
109-66-0

pentane

[(TMEDA)2Li][(CO)3MoGe9[Si(SiMe3)3)3]*0.5(pentane)

[(TMEDA)2Li][(CO)3MoGe9[Si(SiMe3)3)3]*0.5(pentane)

Conditions
ConditionsYield
In pentane (N2) to soln. Mo-Ge complex in pentane TMEDA was added at room temp., stored at 6°C overnight;99%
(Rsi)-cyclohexyldimethoxy[(2S)-2-(methoxymethyl)-1-pyrrolidinyl]silane

(Rsi)-cyclohexyldimethoxy[(2S)-2-(methoxymethyl)-1-pyrrolidinyl]silane

tert.-butyl lithium
594-19-4

tert.-butyl lithium

pentane
109-66-0

pentane

C34H72Li2N2O4Si4*C5H12

C34H72Li2N2O4Si4*C5H12

Conditions
ConditionsYield
at -80 - -30℃; for 72h; Inert atmosphere; Schlenk technique;99%
2,2,2-trichloroethyl 2-(4-bromophenyl)-2-diazoacetate
1641528-26-8

2,2,2-trichloroethyl 2-(4-bromophenyl)-2-diazoacetate

pentane
109-66-0

pentane

2,2,2-trichloroethyl (2S,3R)-2-(4-bromophenyl)-3-methylhexanoate

2,2,2-trichloroethyl (2S,3R)-2-(4-bromophenyl)-3-methylhexanoate

Conditions
ConditionsYield
With Rh2[R-3,5-di(p-tBuC6H4)-triphenylcyclopropanecarboxylate]4 Reagent/catalyst; Reflux; stereoselective reaction;99%
perfluorophenyl azide
1423-15-0

perfluorophenyl azide

trityl tetrafluoroborate
341-02-6

trityl tetrafluoroborate

tris-(o-tolyl)phosphine
6163-58-2

tris-(o-tolyl)phosphine

pentane
109-66-0

pentane

C46H36F5N3P(1+)*C24BF20(1-)*0.5C5H12

C46H36F5N3P(1+)*C24BF20(1-)*0.5C5H12

Conditions
ConditionsYield
Stage #1: perfluorophenyl azide; trityl tetrafluoroborate; tris-(o-tolyl)phosphine In dichloromethane at 20℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;
Stage #2: pentane
99%
pentane
109-66-0

pentane

methylbutane
78-78-4

methylbutane

Conditions
ConditionsYield
With hydrogen under 15001.5 Torr; Catalytic behavior; Reagent/catalyst; Temperature; chemoselective reaction;98.5%
With hydrogen at 250℃; under 760.051 Torr; Reagent/catalyst; Temperature;73.2%
With hydrogen; Pd3(PW12O40)2 at 179.9℃;39.5%
15-crown-5
33100-27-5

15-crown-5

Na[U(N(SiMe3)2)(OC(=CH2)SiMe2NSiMe3)2(N3)]
1331740-29-4

Na[U(N(SiMe3)2)(OC(=CH2)SiMe2NSiMe3)2(N3)]

pentane
109-66-0

pentane

Na(C10H20O5)[U(N3)(NSi2C6H18)(COCH2Si(CH3)2N(Si(CH3)3))2]*0.5C5H12

Na(C10H20O5)[U(N3)(NSi2C6H18)(COCH2Si(CH3)2N(Si(CH3)3))2]*0.5C5H12

Conditions
ConditionsYield
In pentane Ar; U compd. and ligand (1:1 molar ratio), stirred for 12 at 20°C; filtered, evapd., elem. anal.;98%
bis[2-(trifluoromethyl)propyl]-2,2'-bipyridine-3,3'-dicarboxylate

bis[2-(trifluoromethyl)propyl]-2,2'-bipyridine-3,3'-dicarboxylate

C18H8Cl2F12N2O4Pd

C18H8Cl2F12N2O4Pd

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate
79060-88-1

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

pentane
109-66-0

pentane

C36H16F24N4O8Pd(2+)*2C32H12BF24(1-)*3C5H12

C36H16F24N4O8Pd(2+)*2C32H12BF24(1-)*3C5H12

Conditions
ConditionsYield
Stage #1: bis[2-(trifluoromethyl)propyl]-2,2'-bipyridine-3,3'-dicarboxylate; C18H8Cl2F12N2O4Pd; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In dichloromethane at 45℃; for 3h;
Stage #2: pentane
98%
tetrahydrofuran
109-99-9

tetrahydrofuran

[Ph(pyrazol-1-yl)B(μ-NH(Me))(μ-pyrazol-1-yl)B(pyrazol-1-yl)Ph]

[Ph(pyrazol-1-yl)B(μ-NH(Me))(μ-pyrazol-1-yl)B(pyrazol-1-yl)Ph]

methylmagnesium chloride
676-58-4

methylmagnesium chloride

pentane
109-66-0

pentane

A

MgCl(tetrahydrofuran)(x)[Ph(pyrazol-1-yl)B(μ-N(Me))(μ-pyrazol-1-yl)B(pyrazol-1-yl)Ph]

MgCl(tetrahydrofuran)(x)[Ph(pyrazol-1-yl)B(μ-N(Me))(μ-pyrazol-1-yl)B(pyrazol-1-yl)Ph]

Mg2(μ-Cl)2(tetrahydrofuran)[Ph(pyrazol-1-yl)B(μ-N(Me))(μ-pyrazol-1-yl)B(pyrazol-1-yl)Ph]2*pentane
1220508-55-3

Mg2(μ-Cl)2(tetrahydrofuran)[Ph(pyrazol-1-yl)B(μ-N(Me))(μ-pyrazol-1-yl)B(pyrazol-1-yl)Ph]2*pentane

Conditions
ConditionsYield
In tetrahydrofuran under N2 atm. using Schlenk techniques; stirred soln. of borate ligand in THF was treated at -78°C with soln. of MeMgCl in THF; mixt. allowed to warm to room temp.; stirred overnight; soln. concd. (vac.); layered with pentane; crystals are formed; mother liq. decanted; dried (vac.);A 97%
B n/a
(2-methylallyl)palladium-chloride dimer

(2-methylallyl)palladium-chloride dimer

1-diphenylphosphino-1'-(N-[(methoxycarbonyl)methyl]carbamoyl)ferrocene
1160484-10-5

1-diphenylphosphino-1'-(N-[(methoxycarbonyl)methyl]carbamoyl)ferrocene

pentane
109-66-0

pentane

[(η3-C3H4Me)PdCl((Ph2PC5H4)Fe(C5H4C(O)NHCH2CO2Me)-κP)2]ClO4*0.5C5H12

[(η3-C3H4Me)PdCl((Ph2PC5H4)Fe(C5H4C(O)NHCH2CO2Me)-κP)2]ClO4*0.5C5H12

Conditions
ConditionsYield
In chloroform byproducts: CH3CN; (Ar); exclusion of direct daylight; soln. of Fe complex (2 equiv.) in CHCl3 was added to Pd complex (1 equiv.); stirred at room temp. for 1 h; poured into pentane; kept at -18°C overnight; filtered; washed (pentane); dried (vac.); elem. anal.;97%
N,N'-bis(2-hydroxy-3,5-di tertiarybutylbenzyl)homopiperazine
527672-96-4

N,N'-bis(2-hydroxy-3,5-di tertiarybutylbenzyl)homopiperazine

pentane
109-66-0

pentane

C82H132Li4N4O7

C82H132Li4N4O7

Conditions
ConditionsYield
Stage #1: N,N'-bis(2-hydroxy-3,5-di tertiarybutylbenzyl)homopiperazine With n-butyllithium In tetrahydrofuran at 20℃; for 72h; Inert atmosphere; Schlenk technique;
Stage #2: pentane Inert atmosphere; Schlenk technique;
97%
1,4-bis(3-tert-butyl-5-methyl-2-hydroxybenzyl)-1,4-diazacycloheptane
503540-53-2

1,4-bis(3-tert-butyl-5-methyl-2-hydroxybenzyl)-1,4-diazacycloheptane

pentane
109-66-0

pentane

C70H108Li4N4O7

C70H108Li4N4O7

Conditions
ConditionsYield
Stage #1: 1,4-bis(3-tert-butyl-5-methyl-2-hydroxybenzyl)-1,4-diazacycloheptane With n-butyllithium In tetrahydrofuran at 20℃; for 72h; Inert atmosphere; Schlenk technique;
Stage #2: pentane Inert atmosphere; Schlenk technique;
97%
C84H84CeLi3O12

C84H84CeLi3O12

pentane
109-66-0

pentane

pentane

pentane

Conditions
ConditionsYield
Stage #1: C84H84CeLi3O12 With trityl chloride In tetrahydrofuran at 20℃; for 2h;
Stage #2: pentane
97%
2-(3-bromopropyl)isoindole-1,3-dione
5460-29-7

2-(3-bromopropyl)isoindole-1,3-dione

1-lithio-2-tert-butyldimethylsilyl-1,2-dicarba-closo-dodecaborane(12)
361544-93-6

1-lithio-2-tert-butyldimethylsilyl-1,2-dicarba-closo-dodecaborane(12)

pentane
109-66-0

pentane

2-(3'-tert-butyldimethylsiloxy-1'-oxo-1',3'-dihydroisoindol-3'-yl)-1,2'-propano-1,2-dicarba-closo-dodecaborane*0.5(pentane)

2-(3'-tert-butyldimethylsiloxy-1'-oxo-1',3'-dihydroisoindol-3'-yl)-1,2'-propano-1,2-dicarba-closo-dodecaborane*0.5(pentane)

Conditions
ConditionsYield
In diethyl ether; benzene cooled soln. (0°C) of B compd. in benzene-Et2O treated dropwise with benzene-Et2O soln. of C6H4(CO)2N(CH2)3Br (molar ratio 1:1.08); warmed to room temp.; gradually brought to reflux; refluxed for 2 d; solvent removed on rotary evaporator; treated with MeOH; cooled (-10°C) overnight; filtered; solid washed with chilled MeOH; dried in vac.; purified by slow evapn. of pentane-Et2O soln.; elem. anal.;95%
n-propylamino-N,N-bis(2-methylene-4,6-di-tert-butylphenol)
267428-18-2

n-propylamino-N,N-bis(2-methylene-4,6-di-tert-butylphenol)

[Ti(OCH(CH3)2)2N(CH3)2C2H4N(OC6H2(CH3)2CH2)2]
244005-02-5

[Ti(OCH(CH3)2)2N(CH3)2C2H4N(OC6H2(CH3)2CH2)2]

pentane
109-66-0

pentane

(C14H6(CH3)4H2NC2H4N(CH3)2O2)(C14H6(C4H9)4H2NC3H7O2)Ti*C5H12

(C14H6(CH3)4H2NC2H4N(CH3)2O2)(C14H6(C4H9)4H2NC3H7O2)Ti*C5H12

Conditions
ConditionsYield
In toluene 2 h at 110°C in toluene in a sealed tube;95%
chloroform
67-66-3

chloroform

trans-RuCl2(PPh3)(κ3-L(3))*(chloroform)*(diethyl ether)

trans-RuCl2(PPh3)(κ3-L(3))*(chloroform)*(diethyl ether)

pentane
109-66-0

pentane

trans-RuCl2(PPh3)(κ3-L(4))*(chloroform)*(pentane)

trans-RuCl2(PPh3)(κ3-L(4))*(chloroform)*(pentane)

Conditions
ConditionsYield
With H2O2 In chloroform under N2 or in vac.; a soln. of H2O2 (0.238 mmol) was added dropwise to a soln. of Ru-contg. compd. (0.198 mmol) in chloroform; the mixt. was stirred at room temp. for 12 h before it was filtered; the filtrate was evapd. to dryness in vac.; the residue was washed with diethyl ether and crystd. in a chloroform-pentane mixt.; elem. anal.; (31)P NMR spectra monitoring;95%
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