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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2,6-Dimethoxypyridine Manufacturer/High quality/Best price/In stock

Cas:6231-18-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

Manufacturer supply 2,6-Dimethoxypyridine CAS 6231-18-1 with best price Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Fe

Manufacturer supply 2,6-Dimethoxypyridine CAS 6231-18-1 with best price

Cas:6231-18-1

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Large Stock 99.0% 2,6-Dimethoxypyridine 6231-18-1 Producer

Cas:6231-18-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Tianfu Chemical, built in 2009, is a professional supplier for API materials in China. With 10 years development, we have bulit our own factory and lab to produce a certain of products. And we have established stable business relationship

TIANFU 6231-18-1 2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:1 Kilogram

FOB Price: $200.0

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 6231-18-1 with best quality

Cas:6231-18-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Pyridine,2,6-dimethoxy- 6231-18-1

Cas:6231-18-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

2,6-Dimethoxypyridine CAS:6231-18-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

2,6-Dimethoxypyridine CAS:6231-18-1

Cas:6231-18-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Pyridine,2,6-dimethoxy-

Cas:6231-18-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

TIANFU CHEM -- 2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:6231-18-1

Cas:6231-18-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Lab/Research institutions

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2£?6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

5-bromo-4-methylpyridine-3-carbonitrile

Cas:6231-18-1

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:1 Gram

Negotiable

Type:Other

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2£ 6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2£ 6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2£ 6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

TIANFU CHEM -- 2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

2,6-dimethoxypyridine

Cas:6231-18-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

TIANFU CHEM -- 2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2,6-Dimethoxypyridine cas no. 6231-18-1 98%

Cas:6231-18-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Greenutra Resource Inc

2,6-DimethoxypyridineAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

2,6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2£ 6-Dimethoxypyridine

Cas:6231-18-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2,6-Dibromopyridine
626-05-1

2,6-Dibromopyridine

methanol
67-56-1

methanol

2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

Conditions
ConditionsYield
With sodium hydroxide94%
With 5-(di(adamantan-1-yl)phosphino)-1′,3′,5′-triphenyl-1′H-1,4′-bipyrazole; palladium diacetate; caesium carbonate In toluene at 80℃; for 24h;77%
With 5-(di-tert-butylphosphino)-1′, 3′, 5′-triphenyl-1′H-[1,4′]bipyrazole; tris-(dibenzylideneacetone)dipalladium(0); potassium hydroxide at 0.1℃; for 3h; Inert atmosphere;
2,6-dichloropyridine
2402-78-0

2,6-dichloropyridine

methanol
67-56-1

methanol

2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

Conditions
ConditionsYield
With sodium hydroxide for 8h; Reflux;94%
2,6-Dibromopyridine
626-05-1

2,6-Dibromopyridine

sodium methylate
124-41-4

sodium methylate

2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 80℃;65%
2,6-Dibromopyridine
626-05-1

2,6-Dibromopyridine

2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

Conditions
ConditionsYield
With sodium methylate In N,N-dimethyl-formamide at 80℃; for 2h;65%
2,6-dichloropyridine
2402-78-0

2,6-dichloropyridine

sodium methylate
124-41-4

sodium methylate

A

6-chloro-2-methoxypyridine
17228-64-7

6-chloro-2-methoxypyridine

B

2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

Conditions
ConditionsYield
In methanol for 25h; Heating;A 80 % Spectr.
B 20 % Spectr.
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

methyl iodide
74-88-4

methyl iodide

N-methyl-6-methoxy-2-(1H)-pyridone
6231-16-9

N-methyl-6-methoxy-2-(1H)-pyridone

Conditions
ConditionsYield
at 40℃; under 4500450 Torr; for 24h; Hilbert-Johnson reaction;100%
at 80℃; for 24h;72%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

3-iodo-2,6-dimethoxypyridine
214360-56-2

3-iodo-2,6-dimethoxypyridine

Conditions
ConditionsYield
Stage #1: 2,6-dimethoxypyridine With 2,2,6,6-tetramethyl-piperidine; n-butyllithium; zinc dichloro(N,N,N′,N′-tetramethylethylenediamine) In tetrahydrofuran; hexane at 20℃; for 2h; Inert atmosphere;
Stage #2: With iodine In tetrahydrofuran; hexane at 20℃; Concentration; Time; Inert atmosphere; regioselective reaction;
98%
With iodine; silver(I) acetate In acetonitrile at 23℃; for 0.5h;80%
With iodine; sodium hydrogencarbonate at 20℃;41%
With dichloro(N,N,N’,N‘-tetramethylethylenediamine)zinc; 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran at 20℃; for 2h;
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

3-bromo-2,6-dimethoxypyridine
13445-16-4

3-bromo-2,6-dimethoxypyridine

Conditions
ConditionsYield
With N-Bromosuccinimide In acetonitrile at 80℃; for 18h;97%
With N-Bromosuccinimide In acetonitrile for 10h; Reflux;89%
With N-Bromosuccinimide In acetonitrile for 10h; Heating;85%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

1-Iodo-perfluorodecane
423-62-1

1-Iodo-perfluorodecane

C17H8F21NO2

C17H8F21NO2

Conditions
ConditionsYield
With (dppf)Ni(o-tol)Cl; caesium carbonate In neat (no solvent) at 130℃; for 16h; Inert atmosphere; Sealed tube;96%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

C13H20BNO4

C13H20BNO4

Conditions
ConditionsYield
With C25H36O2P2Ru In tetrahydrofuran at 120℃; for 12h; Inert atmosphere; Sealed tube;96%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

zinc dibromide

zinc dibromide

[Zn(2,6-dimethoxypyridine)4][Zn2Br6]
497233-01-9

[Zn(2,6-dimethoxypyridine)4][Zn2Br6]

Conditions
ConditionsYield
In dichloromethane under Ar atm. to suspn. ZnBr2 in CH2Cl2 2 equiv. 2,6-dimethoxypyridine was added and stirred at room temp. for 12 h; solvent was removed under vac. at 40°C; elem. anal.;95%
In diethyl ether under Ar atm. to soln. ZnBr2 in ether 2,6-dimethoxypyridine was added; ppt. was washed with ether; elem. anal.;
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

para-methylphenylmagnesium bromide
4294-57-9

para-methylphenylmagnesium bromide

2,6-di-p-tolylpyridine
14435-88-2

2,6-di-p-tolylpyridine

Conditions
ConditionsYield
With C68H72Cl2N6NiP2 In tetrahydrofuran at 25℃; for 24h; Inert atmosphere;95%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

phosphorous acid trimethyl ester
121-45-9

phosphorous acid trimethyl ester

dimethyl (2,6-dimethoxypyridin-3-yl)phosphonate

dimethyl (2,6-dimethoxypyridin-3-yl)phosphonate

Conditions
ConditionsYield
With ammonium peroxydisulfate; tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate In acetonitrile at 25℃; for 20h; Inert atmosphere; Irradiation;93%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

o-chlorobenzoyl chloride
609-65-4

o-chlorobenzoyl chloride

2-chlorophenyl(2,6-dimethoxypyridin-3-yl)ketone
1335212-81-1

2-chlorophenyl(2,6-dimethoxypyridin-3-yl)ketone

Conditions
ConditionsYield
Stage #1: 2,6-dimethoxypyridine With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; 2,2,6,6-tetramethylpiperidinyl-lithium; copper(l) chloride In tetrahydrofuran; hexanes at 20℃; for 2h; Inert atmosphere;
Stage #2: o-chlorobenzoyl chloride In tetrahydrofuran; hexanes at 0 - 20℃; for 16h; Inert atmosphere;
91%
Stage #1: 2,6-dimethoxypyridine With N,N,N,N,-tetramethylethylenediamine; 2,2,6,6-tetramethylpiperidinyl-lithium; copper(l) chloride In tetrahydrofuran at 20℃; for 2h; Schlenk technique; Inert atmosphere;
Stage #2: o-chlorobenzoyl chloride In tetrahydrofuran at 20℃; Schlenk technique; Inert atmosphere;
91%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

benzyl bromide
100-39-0

benzyl bromide

C14H16NO2(1+)*Br(1-)

C14H16NO2(1+)*Br(1-)

Conditions
ConditionsYield
In acetonitrile Reflux;90%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

aniline
62-53-3

aniline

6‐methoxy‐N‐phenylpyridin‐2‐amine
1282585-58-3

6‐methoxy‐N‐phenylpyridin‐2‐amine

Conditions
ConditionsYield
With potassium hexamethylsilazane In tetrahydrofuran at 100℃; for 16h; Inert atmosphere; Schlenk technique; Sealed tube; Green chemistry;86%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

triethyl phosphite
122-52-1

triethyl phosphite

diethyl (2,6-dimethoxypyridin-3-yl)phosphonate

diethyl (2,6-dimethoxypyridin-3-yl)phosphonate

Conditions
ConditionsYield
With ammonium peroxydisulfate; tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate In acetonitrile at 25℃; for 20h; Inert atmosphere; Irradiation;84%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

ethyl iodide
75-03-6

ethyl iodide

C8H11NO2

C8H11NO2

Conditions
ConditionsYield
at 100℃; under 6000600 Torr; for 48h; Hilbert-Johnson reaction;83%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

N-((4-chlorobenzyl)oxy)-N-methylacetamide
1352918-92-3

N-((4-chlorobenzyl)oxy)-N-methylacetamide

3-(4-chlorobenzyl)-2,6-dimethoxypyridine
1352918-69-4

3-(4-chlorobenzyl)-2,6-dimethoxypyridine

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 45℃; for 24h; Friedel Crafts alkylation; Inert atmosphere;83%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

3-chloro-2,6-dimethoxypyridine

3-chloro-2,6-dimethoxypyridine

Conditions
ConditionsYield
With N-chloro-succinimide; dimethyl sulfoxide In chloroform at 25℃; for 2h; Reagent/catalyst; Schlenk technique;83%
Multi-step reaction with 2 steps
1.1: N-Bromosuccinimide / acetonitrile / 10 h / Reflux
2.1: n-butyllithium; isopropylmagnesium chloride / tetrahydrofuran; hexane / 0.75 h / -2 - 0 °C / Inert atmosphere
2.2: 0 - 20 °C / Inert atmosphere
View Scheme
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

diethyl (bromodifluoromethyl)phosphonate
65094-22-6

diethyl (bromodifluoromethyl)phosphonate

diethyl ((2,6-dimethoxypyridin-3-yl)difluoromethyl)phosphonate

diethyl ((2,6-dimethoxypyridin-3-yl)difluoromethyl)phosphonate

Conditions
ConditionsYield
With potassium phosphate; fac-tris(2-phenylpyridinato-N,C2')iridium(III) In dichloromethane at 20℃; for 36h; Inert atmosphere; Irradiation;83%
1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

C21H19NO2

C21H19NO2

Conditions
ConditionsYield
With CoIII(dimethylglyoximate)2(4-NMe2-C5H4N)Cl; 3,6‐di‐tert‐butyl‐9‐mesityl‐10‐phenylacridin‐10‐ium tetrafluoroborate In 1,2-dichloro-ethane at 20℃; for 24h; Heck Reaction; Irradiation; Inert atmosphere; regioselective reaction;83%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

2,6-dimethoxypyridine-3-boronic acid
221006-70-8

2,6-dimethoxypyridine-3-boronic acid

Conditions
ConditionsYield
Stage #1: 2,6-dimethoxypyridine With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78℃; for 3h;
Stage #2: With Triisopropyl borate In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #3: With hydrogen bromide In water pH=6;
82%
With n-butyllithium; Triisopropyl borate; diisopropylamine In tetrahydrofuran at -78 - 20℃; Inert atmosphere;80%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

triisopropyl phosphite
116-17-6

triisopropyl phosphite

diisopropyl (2,6-dimethoxypyridin-3-yl)phosphonate

diisopropyl (2,6-dimethoxypyridin-3-yl)phosphonate

Conditions
ConditionsYield
With ammonium peroxydisulfate; tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate In acetonitrile at 25℃; for 20h; Inert atmosphere; Irradiation;82%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

N-(4-acetylphenyl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide

N-(4-acetylphenyl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]methanesulfonamide

2,6-dimethoxy-3-(trifluoromethyl)pyridine
1365122-59-3

2,6-dimethoxy-3-(trifluoromethyl)pyridine

Conditions
ConditionsYield
In acetonitrile Solvent; Irradiation;82%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

2,6-dimethoxy-3,5-dibromopyridine
16727-44-9

2,6-dimethoxy-3,5-dibromopyridine

Conditions
ConditionsYield
With bromine In chloroform at 20℃; for 4h;80%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

Triisopropyl borate
5419-55-6

Triisopropyl borate

2,6-dimethoxy-3-pyridinyl-boronic acid
1219744-53-2

2,6-dimethoxy-3-pyridinyl-boronic acid

Conditions
ConditionsYield
Stage #1: 2,6-dimethoxypyridine With n-butyllithium; diisopropylamine In tetrahydrofuran at -78℃; for 3h; Inert atmosphere;
Stage #2: Triisopropyl borate In tetrahydrofuran at -78 - 20℃; Inert atmosphere;
80%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

[tungsten(trispyrazoylborate)(NO)(trimethylphosphine)(η2-benzene)]

[tungsten(trispyrazoylborate)(NO)(trimethylphosphine)(η2-benzene)]

[TpW(NO)(PMe3)(3,4-η2-2,6-dimethoxypyridine)]

[TpW(NO)(PMe3)(3,4-η2-2,6-dimethoxypyridine)]

Conditions
ConditionsYield
In hexane stirring a suspn. of tungsten complex and ligand in hexanes for 26 h; obtained as a mixt. of diastereomers;79%
In pentane to a soln. of complex and pyridine-compound was added pentane, the mixt.was stirred for 26 h; the mixt. was added to pentane, ppt. was dried in vac.;79%
N-(trifluoromethyl)acyloxyphthalimide
5672-90-2

N-(trifluoromethyl)acyloxyphthalimide

2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

2,6-dimethoxy-3-(N-phthalimido)pyridine
848827-76-9

2,6-dimethoxy-3-(N-phthalimido)pyridine

Conditions
ConditionsYield
With tris[2-phenylpyridinato-C2,N]iridium(III) In acetonitrile at 20℃; for 24h; Sealed tube; Irradiation;79%
pyrrolidine
123-75-1

pyrrolidine

2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

2-(piperidin-1-yl)-6-(pyrrolidin-1-yl)pyridine

2-(piperidin-1-yl)-6-(pyrrolidin-1-yl)pyridine

Conditions
ConditionsYield
With sodium hydride; lithium iodide In tetrahydrofuran at 0 - 60℃; for 5h; Inert atmosphere; Sealed tube;79%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

((trispyrazol-1-yl)hydroborane)Mo(NO)(4-(dimethylamino)pyridine)(3,4-η2-α,α,α-trifluorotoluene)

((trispyrazol-1-yl)hydroborane)Mo(NO)(4-(dimethylamino)pyridine)(3,4-η2-α,α,α-trifluorotoluene)

Mo(tris(pyrazolyl)borate)(NO)(4-(dimethylamino)pyridine)(3,4-η2-2,6-dimethoxypyridine)

Mo(tris(pyrazolyl)borate)(NO)(4-(dimethylamino)pyridine)(3,4-η2-2,6-dimethoxypyridine)

Conditions
ConditionsYield
In tetrahydrofuran for 3.5h; Glovebox; Inert atmosphere;78.6%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

dibutylamine
111-92-2

dibutylamine

N,N-dibutyl-6-methoxypyridin-2-amine

N,N-dibutyl-6-methoxypyridin-2-amine

Conditions
ConditionsYield
Stage #1: dibutylamine With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 0.166667h; Inert atmosphere; Schlenk technique;
Stage #2: 2,6-dimethoxypyridine In tetrahydrofuran; hexane at 60℃; for 0.166667h; Inert atmosphere; Schlenk technique;
78%
2,6-dimethoxypyridine
6231-18-1

2,6-dimethoxypyridine

A

3-bromo-2,6-dimethoxypyridine
13445-16-4

3-bromo-2,6-dimethoxypyridine

B

2,6-dimethoxy-3,5-dibromopyridine
16727-44-9

2,6-dimethoxy-3,5-dibromopyridine

Conditions
ConditionsYield
With bromine In tetrachloromethane at -40 - -30℃;A 76%
B n/a
With pyridinium hydrobromide perbromide In tetrachloromethane Rt, overnight, then reflux, 2 h;A 30%
B 15%
With potassium bromide In water; dimethyl sulfoxide at 25℃; Irradiation; Overall yield = 69 percent;

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