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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Methyl sorbate Manufacturer/High quality/Best price/In stock

Cas:689-89-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. High quality and competitive price: 1) Standard: BP/USP/EP/ enterprise standard 2) All purity ≥99% 3) We are manufacturers and can provide high quality products at factory prices. 2. Fast and safe delivery 1) The package c

Methyl sorbate CAS: 689-89-4

Cas:689-89-4

Min.Order:1 Kilogram

FOB Price: $5.0 / 10.0

Type:Trading Company

inquiry

Leader Biochemical Group

About Product Details

China Biggest factory Supply High Quality Methyl sorbate 689-89-4

Cas:689-89-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

2,4-Hexadienoic acid,methyl ester, (2E,4E)-

Cas:689-89-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2,4-Hexadienoic acid,methyl ester, (2E,4E)-

Cas:689-89-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

(2E,4E)-Methyl hexa-2,4-dienoate

Cas:689-89-4

Min.Order:1 Gram

FOB Price: $41.0

Type:Trading Company

inquiry

Shanghai Hope Chem Co., Ltd

1. Product advantages: exquisite appearance and unique functions. 2. Product Advantages: Our products are the best,fast speed ,in large stock 3. High-quality products and thoughtful service are your greatest satisfaction. 4. The product

Methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl-sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Methyl sorbate

Cas:689-89-4

Min.Order:1 Kilogram

FOB Price: $30.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity Methyl sorbate

Cas:689-89-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

689-89-4 CAS NO.689-89-4

Cas:689-89-4

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

Methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Greenutra Resource Inc

methyl sorbateAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Other

inquiry

Antimex Chemical Limied

Methyl sorbateAppearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestu

Methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary a

Methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

689-89-4

Cas:689-89-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Methyl sorbate cas 689-89-4Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Methyl sorbate cas 689-89-4

Cas:689-89-4

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

Methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Terui OP New Material Technology Co., Ltd.

The factory supplies Application:manufacturing supplies

2,4-Hexadienoicacid,methylester,(2E,4E)-

Cas:689-89-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Application:Medical or chemical

689-89-4

Cas:689-89-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

METHYL SORBATE

Cas:689-89-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Methyl sorbate

Cas:689-89-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hubei Jusheng Technology Co., Ltd.,

1,Best Quality: Our products have exported to Germany, Spain, UK, USA, Australia, Middle East, and so on other countries, and we have got very good feedback from our customers.so you can trust us. 2, Payment method: for e

Methyl sorbate with high quality/best price

Cas:689-89-4

Min.Order:10 Gram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

Methyl sorbate CAS NO.689-89-4

Cas:689-89-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Eastar Chemical Corporation

A US privately owned family business established in 1986 Service driven Total Customer Satisfaction Philosophy Focus on reliable delivery of our products Guaranteed quality on all shipments backed by our Quality Assurance and Quality Control tea

methyl sorbate

Cas:689-89-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Kunshan Yalong Trading Co,.Ltd

Methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GZ HONESTCHEM CO., LTD

methyl sorbateAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air

methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the Methyl sorbate, CAS:689-89-4 with the most competitive price and the best quality. We

Methyl sorbate

Cas:689-89-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

methanol
67-56-1

methanol

sorbic Acid
110-44-1

sorbic Acid

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
With thionyl chloride at -10℃; for 2h; Reflux; Inert atmosphere;99%
With chloro-trimethyl-silane In dichloromethane for 16h;99%
Stage #1: sorbic Acid With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide at 0℃; for 1h; Inert atmosphere;
Stage #2: methanol In dichloromethane; N,N-dimethyl-formamide at 0 - 20℃;
95%
sorbic Acid
110-44-1

sorbic Acid

tert-butyl methyl ether
1634-04-4

tert-butyl methyl ether

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate at 90℃; Schlenk technique;86%
methyl 2-hexynoate
18937-79-6

methyl 2-hexynoate

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
With tributylphosphine; IrH5(P-(i-Pr)3)2 In toluene at 110℃; for 24h;85%
methanol
67-56-1

methanol

sorbinyl chloride
2614-88-2

sorbinyl chloride

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
85%
at 0℃;81%
methyl (E)-4-oxo-2-butenoate
5837-72-9

methyl (E)-4-oxo-2-butenoate

(triphenylphosphoranylidene)acetaldehyde
2136-75-6

(triphenylphosphoranylidene)acetaldehyde

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
In dichloromethane for 4h; Heating;82%
(E)-3-((4S,5S)-5-Methyl-2-oxo-[1,3]dioxolan-4-yl)-acrylic acid methyl ester

(E)-3-((4S,5S)-5-Methyl-2-oxo-[1,3]dioxolan-4-yl)-acrylic acid methyl ester

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
With copper(l) iodide; boron trifluoride diethyl etherate; methylmagnesium bromide In tetrahydrofuran at -78℃; for 0.333333h;82%
(1Z,3E)-1-(t-butyldimethylsilyloxy)-1-methoxyhexa-1,3-diene
287193-97-9

(1Z,3E)-1-(t-butyldimethylsilyloxy)-1-methoxyhexa-1,3-diene

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
With chloranil In dichloromethane for 0.00277778h; Elimination;72%
acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

4,4,5,5-tetramethyl-2-[(1E)-prop-1-en-1-yl]-1,3,2-dioxaborolane
83947-58-4

4,4,5,5-tetramethyl-2-[(1E)-prop-1-en-1-yl]-1,3,2-dioxaborolane

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
With silver hexafluoroantimonate; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; copper(II) acetate monohydrate In 1,2-dichloro-ethane at 80℃; for 12h; Inert atmosphere; Sealed tube; stereoselective reaction;70%
Epoxy-4,5 hexene-2 (E) oate de methyle
51830-12-7

Epoxy-4,5 hexene-2 (E) oate de methyle

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(+/-)-methyl-E-5-hydroxyhex-3-enoate
113351-26-1

(+/-)-methyl-E-5-hydroxyhex-3-enoate

Conditions
ConditionsYield
With maleic anhydride; carbon monoxide; N-ethyl-N,N-diisopropylamine; sodium bromide; Pd2(C4H7)2Cl2 In methanol under 22800 Torr; Ambient temperature;A 7%
B 67%
sorbic Acid
110-44-1

sorbic Acid

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
With copper(II) chloride monohydrate; dihydrogen peroxide; oxygen; potassium carbonate; calcium chloride at 80℃; for 15h; Sealed tube; Green chemistry;32%
tributyl-amine
102-82-9

tributyl-amine

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

triphenylphosphine
603-35-0

triphenylphosphine

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
palladium diacetate4%
sorbic Acid
110-44-1

sorbic Acid

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

hexa-2,4-dienoic acid
110-44-1

hexa-2,4-dienoic acid

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2Z,4Z)-hexadienoic acid methyl ester
53892-48-1

(2Z,4Z)-hexadienoic acid methyl ester

C

(2Z,4E)-hexadienoic acid methyl ester
6932-46-3

(2Z,4E)-hexadienoic acid methyl ester

D

(2E,4Z)-hexadienoic acid methyl ester
30361-31-0

(2E,4Z)-hexadienoic acid methyl ester

Conditions
ConditionsYield
1.) benzene, irradiation; 2.) MeOH; Yield given. Multistep reaction. Yields of byproduct given;
methanol
67-56-1

methanol

(E)-4-Benzenesulfonyl-2-diethylamino-hepta-2,6-dienenitrile
344890-72-8

(E)-4-Benzenesulfonyl-2-diethylamino-hepta-2,6-dienenitrile

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
With sulfuric acid; 1,8-diazabicyclo[5.4.0]undec-7-ene 2.) CH2Cl2; Multistep reaction;
2-methylthiophene-5-carboxylic acid
1918-79-2

2-methylthiophene-5-carboxylic acid

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

Methyl 2,5-Dihydro-5-methyl-2-thiophenecarboxylate
71624-92-5

Methyl 2,5-Dihydro-5-methyl-2-thiophenecarboxylate

C

methyl (E)-hex-3-enoate
13894-61-6

methyl (E)-hex-3-enoate

D

methyl (E)-hex-4-enoate
14017-81-3

methyl (E)-hex-4-enoate

E

methyl (Z)-hex-3-enoate
13894-62-7

methyl (Z)-hex-3-enoate

F

Methyl (Z)-5-Mercapto-3-hexenoate
86610-45-9

Methyl (Z)-5-Mercapto-3-hexenoate

Conditions
ConditionsYield
With methanol; sulfuric acid; ammonia; lithium Product distribution; Mechanism; 1) -78 degC, 60 min, 2) room temp., 24 h; other amount of Li: 10 eq.;A 2 % Spectr.
B 71 % Spectr.
C 8.5 % Spectr.
D n/a
E n/a
F 18 % Spectr.
trans-Crotonaldehyde
123-73-9

trans-Crotonaldehyde

Malonic acid monomethyl ester
16695-14-0

Malonic acid monomethyl ester

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2Z,4E)-hexadienoic acid methyl ester
6932-46-3

(2Z,4E)-hexadienoic acid methyl ester

C

methyl (E)-3,5-hexadienoate
32775-94-3

methyl (E)-3,5-hexadienoate

Conditions
ConditionsYield
dmap In pyridine at 60℃; for 24h; Yields of byproduct given. Title compound not separated from byproducts;
trans-Crotonaldehyde
123-73-9

trans-Crotonaldehyde

trimethyl phosphonoacetate
5927-18-4

trimethyl phosphonoacetate

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2Z,4E)-hexadienoic acid methyl ester
6932-46-3

(2Z,4E)-hexadienoic acid methyl ester

C

(E)-3-(6-Methyl-cyclohexa-1,3-dienyl)-acrylic acid methyl ester
95636-75-2

(E)-3-(6-Methyl-cyclohexa-1,3-dienyl)-acrylic acid methyl ester

D

(E)-3-(2,6-Dimethyl-5,6-dihydro-2H-pyran-3-yl)-acrylic acid methyl ester
95636-76-3

(E)-3-(2,6-Dimethyl-5,6-dihydro-2H-pyran-3-yl)-acrylic acid methyl ester

Conditions
ConditionsYield
With potassium tert-butylate DMF, rt; Yield given. Multistep reaction. Yields of byproduct given;
(2E)-5-Hydroxy-2-hexensaeuremethylester
19870-59-8

(2E)-5-Hydroxy-2-hexensaeuremethylester

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
With sulfuric acid In methanol Heating;
Methyl (cis,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate
127379-38-8

Methyl (cis,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2Z,4E)-hexadienoic acid methyl ester
6932-46-3

(2Z,4E)-hexadienoic acid methyl ester

C

(2E,4Z)-hexadienoic acid methyl ester
30361-31-0

(2E,4Z)-hexadienoic acid methyl ester

Conditions
ConditionsYield
In benzene-d6 at 189.6℃; Rate constant;
In acetonitrile at 144.4℃; Rate constant;
Methyl (cis,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate
127379-38-8

Methyl (cis,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2E,4Z)-hexadienoic acid methyl ester
30361-31-0

(2E,4Z)-hexadienoic acid methyl ester

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-00-9, 110434-36-1, 110434-37-2, 127281-01-0

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Methyl trans-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-01-0, 110434-36-1, 110434-37-2, 127281-00-9

Methyl trans-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Conditions
ConditionsYield
In benzene-d6 at 190℃; Yield given. Further byproducts given. Yields of byproduct given;
Methyl (trans,Z)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate
127379-37-7

Methyl (trans,Z)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2Z,4Z)-hexadienoic acid methyl ester
53892-48-1

(2Z,4Z)-hexadienoic acid methyl ester

C

(2Z,4E)-hexadienoic acid methyl ester
6932-46-3

(2Z,4E)-hexadienoic acid methyl ester

D

(2E,4Z)-hexadienoic acid methyl ester
30361-31-0

(2E,4Z)-hexadienoic acid methyl ester

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-00-9, 110434-36-1, 110434-37-2, 127281-01-0

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Methyl trans-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-01-0, 110434-36-1, 110434-37-2, 127281-00-9

Methyl trans-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Conditions
ConditionsYield
In benzene-d6 at 195℃; Thermodynamic data; Mechanism; Kinetics; product yield/distribution, ΔH(excit.)R, ΔS(excit.)R, ΔH(excit.)C, ΔS(excit.)C; other temperature, stereospecificity, stereoselectivity;
Methyl (trans,Z)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate
127379-37-7

Methyl (trans,Z)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2Z,4E)-hexadienoic acid methyl ester
6932-46-3

(2Z,4E)-hexadienoic acid methyl ester

C

(2E,4Z)-hexadienoic acid methyl ester
30361-31-0

(2E,4Z)-hexadienoic acid methyl ester

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-00-9, 110434-36-1, 110434-37-2, 127281-01-0

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Methyl trans-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-01-0, 110434-36-1, 110434-37-2, 127281-00-9

Methyl trans-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Conditions
ConditionsYield
In benzene-d6 at 170.2℃; Thermodynamic data; Mechanism; Kinetics; product yield/distribution, ΔH(excit.)R, ΔS(excit.)R, ΔH(excit.)C, ΔS(excit.)C; stereospecificity, stereoselectivity; other vinylcyclobutanes;
Methyl (trans,Z)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate
127379-37-7

Methyl (trans,Z)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2Z,4E)-hexadienoic acid methyl ester
6932-46-3

(2Z,4E)-hexadienoic acid methyl ester

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-00-9, 110434-36-1, 110434-37-2, 127281-01-0

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Methyl trans-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-01-0, 110434-36-1, 110434-37-2, 127281-00-9

Methyl trans-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Conditions
ConditionsYield
In benzene-d6 at 170℃; other temperatures; Yield given. Further byproducts given. Yields of byproduct given;
Methyl (trans,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate
127280-96-0

Methyl (trans,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2Z,4E)-hexadienoic acid methyl ester
6932-46-3

(2Z,4E)-hexadienoic acid methyl ester

C

(2E,4Z)-hexadienoic acid methyl ester
30361-31-0

(2E,4Z)-hexadienoic acid methyl ester

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-00-9, 110434-36-1, 110434-37-2, 127281-01-0

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Conditions
ConditionsYield
In benzene-d6 at 190℃; other temperatures; Yield given;A n/a
B n/a
C n/a
D 61 % Spectr.
In benzene-d6 at 179.8℃; Thermodynamic data; Kinetics; Mechanism; product yield/distribution; ΔH(excit.)R, ΔS(excit.)R, ΔH(excit.)C, ΔS(excit.)C; stereospecificity, stereoselectivity; other temperature;A n/a
B n/a
C n/a
D 65 % Spectr.
Methyl (trans,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate
127280-96-0

Methyl (trans,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2E,4Z)-hexadienoic acid methyl ester
30361-31-0

(2E,4Z)-hexadienoic acid methyl ester

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-00-9, 110434-36-1, 110434-37-2, 127281-01-0

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Conditions
ConditionsYield
In benzene-d6 at 170.8℃; Thermodynamic data; Kinetics; Mechanism; product yield/distribution; ΔH(excit.)R, ΔS(excit.)R, ΔH(excit.)C, ΔS(excit.)C; stereospecificity, stereoselectivity;A n/a
B n/a
C 70 % Spectr.
Methyl (trans,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate
127280-96-0

Methyl (trans,E)-3-(2-Methyl-5,8-dioxaspiro<3.4>oct-1-yl)-2-propenoate

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate
127281-00-9, 110434-36-1, 110434-37-2, 127281-01-0

Methyl cis-9-Methyl-1,4-dioxaspiro<4.5>dec-7-ene-6-carboxylate

Conditions
ConditionsYield
In benzene-d6 at 160.2℃; Thermodynamic data; Kinetics; Mechanism; product yield/distribution; ΔG(excit.), ΔH(excit.)R, ΔS(excit.)R, ΔH(excit.)C, ΔS(excit.)C; stereospecificity, stereoselectivity;A 25 % Spectr.
B 75 % Spectr.
(E)-4-(4-Chloro-benzenesulfinyl)-hex-2-enoic acid methyl ester

(E)-4-(4-Chloro-benzenesulfinyl)-hex-2-enoic acid methyl ester

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2E,4Z)-hexadienoic acid methyl ester
30361-31-0

(2E,4Z)-hexadienoic acid methyl ester

Conditions
ConditionsYield
In xylene for 2h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
(E)-(2S,3S)-2-Hydroxy-3-trimethylsilanyl-hex-4-enoic acid methyl ester
108965-77-1, 108965-78-2

(E)-(2S,3S)-2-Hydroxy-3-trimethylsilanyl-hex-4-enoic acid methyl ester

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2Z,4Z)-hexadienoic acid methyl ester
53892-48-1

(2Z,4Z)-hexadienoic acid methyl ester

C

(2Z,4E)-hexadienoic acid methyl ester
6932-46-3

(2Z,4E)-hexadienoic acid methyl ester

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at -20℃; Yield given. Yields of byproduct given;
(E)-(2S,3S)-2-Hydroxy-3-trimethylsilanyl-hex-4-enoic acid methyl ester
108965-77-1, 108965-78-2

(E)-(2S,3S)-2-Hydroxy-3-trimethylsilanyl-hex-4-enoic acid methyl ester

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2E,4Z)-hexadienoic acid methyl ester
30361-31-0

(2E,4Z)-hexadienoic acid methyl ester

Conditions
ConditionsYield
With potassium hydride In tetrahydrofuran at -78 - -40℃; Yield given. Yields of byproduct given;
5-methyl-2-carbomethoxy-2,5-dihydrothiophene-1,1-dioxide
88418-76-2

5-methyl-2-carbomethoxy-2,5-dihydrothiophene-1,1-dioxide

A

(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

B

(2E,4Z)-hexadienoic acid methyl ester
30361-31-0

(2E,4Z)-hexadienoic acid methyl ester

Conditions
ConditionsYield
In toluene for 3h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

methyl 3,4-hexadienoate
81981-05-7

methyl 3,4-hexadienoate

Conditions
ConditionsYield
With trifluoroacetic acid In dichloromethane for 36h; Irradiation;100%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

methyl (Z)-hex-3-enoate
13894-62-7

methyl (Z)-hex-3-enoate

Conditions
ConditionsYield
With hydrogen; tricarbonyl(η(6)-1,2,3-trimethoxybenzene)chromium In tetrahydrofuran at 80℃; under 45600 Torr; for 5h; different catalysts, different temperatures;100%
With hydrogen; tricarbonyl(η(6)-1,2,3-trimethoxybenzene)chromium In tetrahydrofuran at 100℃; under 45600 Torr; for 5h; various catalysts, other temperatures;100%
With hydrogen; methyl benzoate*Cr(CO)3 In acetone at 100℃; under 53200 Torr; for 16h;94%
With hydrogen; (η(6)-benzene)(η(2)-methylacrylate)dicarbonylchromium In tetrahydrofuran at 23℃; under 750.06 Torr; for 54h;87%
With hydrogen; chromium(0) hexacarbonyl
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

methyl (E)-3,5-hexadienoate
32775-94-3

methyl (E)-3,5-hexadienoate

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 1h;99%
With n-butyllithium; diisopropylamine In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at -78℃; for 1.5h;76.6%
With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; n-butyllithium; lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 1.25h; Inert atmosphere;70%
With lithium diisopropyl amide In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide
With n-butyllithium; diisopropylamine; Hexamethylphosphorous triamide In tetrahydrofuran; hexane at -78 - 0℃; for 1h; Schlenk technique;
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

1,4-trans-threo-disyndiotactic poly((E,E)-methyl sorbate), Mn = 5.4E4 Da, Mw/Mn = 1.4; monomer(s): methyl 2,4-hexadienoate

1,4-trans-threo-disyndiotactic poly((E,E)-methyl sorbate), Mn = 5.4E4 Da, Mw/Mn = 1.4; monomer(s): methyl 2,4-hexadienoate

Conditions
ConditionsYield
With tert.-butyl lithium; bis(2,6-di-tert-butyl-4-methylphenoxide)methylaluminum In toluene; pentane at -20℃; for 72h;98%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

methyl (E)-hex-2-enoate
13894-63-8

methyl (E)-hex-2-enoate

Conditions
ConditionsYield
With hydrogen; montmorillonit-bipyridinpalladium(II)-acetate In tetrahydrofuran Ambient temperature;97%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

(η6-7β-methyl-1,3,5-cycloheptatriene)tricarbonylchromium(0)

(η6-7β-methyl-1,3,5-cycloheptatriene)tricarbonylchromium(0)

10α,11β-dimethyl-7α-(methoxycarbonyl)-(1Hβ,6Hβ)-bicyclo[4.4.1]undeca-2,4,8-triene
129000-89-1

10α,11β-dimethyl-7α-(methoxycarbonyl)-(1Hβ,6Hβ)-bicyclo[4.4.1]undeca-2,4,8-triene

Conditions
ConditionsYield
In hexane for 3h; Irradiation;97%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

benzaldehyde
100-52-7

benzaldehyde

(2E,4E)-7-Hydroxy-7-phenyl-hepta-2,4-dienoic acid methyl ester

(2E,4E)-7-Hydroxy-7-phenyl-hepta-2,4-dienoic acid methyl ester

Conditions
ConditionsYield
Stage #1: (2E,4E)-methylhexa-2,4-dienoate; benzaldehyde With aluminium tris(2,6-diphenylphenoxide) In toluene at -78℃; for 0.333333h; Complexation;
Stage #2: With 2,2,6,6-tetramethylpiperidinyl-lithium In tetrahydrofuran; hexane; toluene at -78℃; for 0.5h; Crossed aldol condensation;
97%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

(E)-(1-methoxyprop-1-enyloxy)trimethylsilane
72658-09-4

(E)-(1-methoxyprop-1-enyloxy)trimethylsilane

methyl 5-methoxy-2-methyl-3-(1-propenyl)-5-trimethylsiloxy-4-pentenoate

methyl 5-methoxy-2-methyl-3-(1-propenyl)-5-trimethylsiloxy-4-pentenoate

Conditions
ConditionsYield
aluminum ion-exchanged montmorillonite In dichloromethane at -50℃; for 0.5h;96%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

(η6-1,3,5-cycloheptatriene)tricarbonylchromium(0)

(η6-1,3,5-cycloheptatriene)tricarbonylchromium(0)

7α-(methoxycarbonyl)-10α-methyl-(1Hβ,6Hβ)-bicyclo[4.4.1]undeca-2,4,8-triene
86067-63-2, 143428-66-4

7α-(methoxycarbonyl)-10α-methyl-(1Hβ,6Hβ)-bicyclo[4.4.1]undeca-2,4,8-triene

Conditions
ConditionsYield
In hexane for 0.5h; Irradiation;96%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

1,4-trans-threo-disyndiotactic poly((E,E)-methyl sorbate), Mn = 3.1E4 Da, Mw/Mn = 1.2; monomer(s): methyl 2,4-hexadienoate

1,4-trans-threo-disyndiotactic poly((E,E)-methyl sorbate), Mn = 3.1E4 Da, Mw/Mn = 1.2; monomer(s): methyl 2,4-hexadienoate

Conditions
ConditionsYield
With tert.-butyl lithium; bis(2,6-di-tert-butyl-4-methylphenoxide)methylaluminum; (-)-sparteine In toluene; pentane at -20℃; for 72h;96%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Sorbyl alcohol
17102-64-6

Sorbyl alcohol

Conditions
ConditionsYield
With 5%-palladium/activated carbon; hydrogen In methanol at 50℃; under 45004.5 Torr; for 12h; Temperature; Pressure; Autoclave; Green chemistry;94.95%
With strain of the zygomycete fungus S. racemosum MUT 770 In dimethyl sulfoxide for 72h; Enzymatic reaction;23%
With lithium aluminium tetrahydride
With diisobutylaluminium hydride In toluene at -40℃; for 2h; Inert atmosphere;
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

methyl (E)-4-oxo-2-butenoate
5837-72-9

methyl (E)-4-oxo-2-butenoate

Conditions
ConditionsYield
With ozone In methanol; dichloromethane at -30℃;90%
With dimethylsulfide; ozone In dichloromethane90%
With sodium perchlorate In water; acetonitrile (electrolysis);
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

(3E,7E)-5,6-Dimethyl-deca-3,7-dienedioic acid dimethyl ester
29653-35-8, 138823-73-1, 138823-74-2

(3E,7E)-5,6-Dimethyl-deca-3,7-dienedioic acid dimethyl ester

Conditions
ConditionsYield
With methanol; samarium diiodide In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide Ambient temperature;90%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

lithium (R)-N-3,4-dimethoxybenzyl-N-(α-methylbenzyl)amide

lithium (R)-N-3,4-dimethoxybenzyl-N-(α-methylbenzyl)amide

(E)-(S)-3-[(3,4-Dimethoxy-benzyl)-((R)-1-phenyl-ethyl)-amino]-hex-4-enoic acid methyl ester
213467-20-0

(E)-(S)-3-[(3,4-Dimethoxy-benzyl)-((R)-1-phenyl-ethyl)-amino]-hex-4-enoic acid methyl ester

Conditions
ConditionsYield
90%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

benzaldehyde
100-52-7

benzaldehyde

(Z)-methyl 2-[hydroxy(phenyl)methyl]hex-3-enoate

(Z)-methyl 2-[hydroxy(phenyl)methyl]hex-3-enoate

Conditions
ConditionsYield
With [Rh(OH)(cod)]2; triethyl borane In tetrahydrofuran at 20 - 50℃; Inert atmosphere; stereoselective reaction;90%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

N-p-Anisylmonothiomaleimide
167258-61-9

N-p-Anisylmonothiomaleimide

rel-(5S,7R,10S)-Methyl 7-methyl-1-p-methoxyphenyl-2-oxo-6-thia-1-azaspiro<4.5>deca-3,8-diene-10-carboxylate

rel-(5S,7R,10S)-Methyl 7-methyl-1-p-methoxyphenyl-2-oxo-6-thia-1-azaspiro<4.5>deca-3,8-diene-10-carboxylate

Conditions
ConditionsYield
In benzene for 15h; Ambient temperature;89%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

(E)-(4S,5S)-4,5-Dihydroxy-hex-2-enoic acid methyl ester
143289-07-0

(E)-(4S,5S)-4,5-Dihydroxy-hex-2-enoic acid methyl ester

Conditions
ConditionsYield
With AD-mix-α Sharpless reaction;88%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

1,4-trans-threo-disyndiotactic poly((E,E)-methyl sorbate), Mn = 4.2E4 Da, Mw/Mn = 1.6; monomer(s): methyl 2,4-hexadienoate

1,4-trans-threo-disyndiotactic poly((E,E)-methyl sorbate), Mn = 4.2E4 Da, Mw/Mn = 1.6; monomer(s): methyl 2,4-hexadienoate

Conditions
ConditionsYield
With tert.-butyl lithium; bis(2,6-di-tert-butyl-4-methylphenoxide)methylaluminum; (-)-sparteine In toluene; pentane at -50℃; for 72h;88%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

1,4-trans-threo-disyndiotactic poly((E,E)-methyl sorbate), Mn = 4.4E4 Da, Mw/Mn = 1.6; monomer(s): methyl 2,4-hexadienoate

1,4-trans-threo-disyndiotactic poly((E,E)-methyl sorbate), Mn = 4.4E4 Da, Mw/Mn = 1.6; monomer(s): methyl 2,4-hexadienoate

Conditions
ConditionsYield
With menthyl ethyl ether; tert.-butyl lithium; bis(2,6-di-tert-butyl-4-methylphenoxide)methylaluminum In toluene; pentane at -50℃; for 72h;88%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

1,4-trans-threo-disyndiotactic poly((E,E)-methyl sorbate), Mn = 3.3E4 Da, Mw/Mn = 1.4; monomer(s): methyl 2,4-hexadienoate

1,4-trans-threo-disyndiotactic poly((E,E)-methyl sorbate), Mn = 3.3E4 Da, Mw/Mn = 1.4; monomer(s): methyl 2,4-hexadienoate

Conditions
ConditionsYield
With tert.-butyl lithium; bis(2,6-di-tert-butyl-4-methylphenoxide)methylaluminum; (-)-sparteine In toluene; pentane at -60℃; for 168h;87%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

2-diazopropane
2684-60-8

2-diazopropane

5,5-Dimethyl-4-((E)-propenyl)-4,5-dihydro-1H-pyrazole-3-carboxylic acid methyl ester
96685-07-3

5,5-Dimethyl-4-((E)-propenyl)-4,5-dihydro-1H-pyrazole-3-carboxylic acid methyl ester

Conditions
ConditionsYield
In diethyl ether; ethylbenzene at -5℃;85%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane for 24h; Ambient temperature;85%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane Yield given;
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

<1-2H2>2,4-hexadien-1-ol

<1-2H2>2,4-hexadien-1-ol

Conditions
ConditionsYield
With lithium aluminium deuteride In diethyl ether at -78 - 20℃;85%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

7-exo-nethylcyclopentatriene complex

7-exo-nethylcyclopentatriene complex

10α,11β-dimethyl-7α-(methoxycarbonyl)-(1Hβ,6Hβ)-bicyclo[4.4.1]undeca-2,4,8-triene
129000-89-1

10α,11β-dimethyl-7α-(methoxycarbonyl)-(1Hβ,6Hβ)-bicyclo[4.4.1]undeca-2,4,8-triene

Conditions
ConditionsYield
Irradiation;83%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

A

Epoxy-4,5 hexene-2 (E) oate de methyle
51830-12-7

Epoxy-4,5 hexene-2 (E) oate de methyle

B

methyl (E)-4-oxo-2-butenoate
5837-72-9

methyl (E)-4-oxo-2-butenoate

C

methyl (E,E)-5-formyl-2,4-pentadienoate
40188-21-4

methyl (E,E)-5-formyl-2,4-pentadienoate

Conditions
ConditionsYield
With tert.-butylhydroperoxide; chloroperoxidase In phosphate buffer pH=6; Enzymatic reaction;A 4%
B 13%
C 83%
(2E,4E)-methylhexa-2,4-dienoate
689-89-4

(2E,4E)-methylhexa-2,4-dienoate

(R)-N-allyl (1-phenylethyl)amine
126275-19-2

(R)-N-allyl (1-phenylethyl)amine

methyl (3S,4E,αR)-3-[N-allyl-N-(α-methylbenzyl)amino]hex-4-enoate
1202039-13-1

methyl (3S,4E,αR)-3-[N-allyl-N-(α-methylbenzyl)amino]hex-4-enoate

Conditions
ConditionsYield
Stage #1: (R)-N-allyl (1-phenylethyl)amine With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: (2E,4E)-methylhexa-2,4-dienoate In tetrahydrofuran; hexane at -78℃; for 2h;
Stage #3: With ammonium chloride In tetrahydrofuran; hexane; water at -78 - 20℃; for 0.25h; optical yield given as %de; diastereoselective reaction;
83%

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