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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1,1,1-Tris(hydroxymethyl)ethane supplier in China

Cas:77-85-0

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

The company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:White or off-white Solid Storage:Sealed, dry, m

TriMethylolethane

Cas:77-85-0

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Ethylidynetrimethanol

Cas:77-85-0

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

1,1,1-Tris(hydroxymethyl)ethane Manufacturer Factory CAS 77-85-0 1,1,1-Tris(hydroxymethyl)ethane Manufacturer High quality Best price In stock factory CAS 77-85-0 1,1,1-Tris(hydroxymethyl)ethane COA TDS price MSDS Name 1,1,1-Tris(hydro

1,1,1-Tris(hydroxymethyl)ethane Manufacturer Factory CAS 77-85-0

Cas:77-85-0

Min.Order:5 Kiloliter

FOB Price: $3.5 / 5.0

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for t

High purity 1,1,1-Tris(hydroxymethyl)ethane 98% TOP1 supplier in China

Cas:77-85-0

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

1,1,1-Tris(hydroxymethyl)ethane Basic information Product Name: 1,1,1-Tris(hydroxymethyl)ethane Synonyms: 1,1,1-Tri(hydroxymethyl)ethane;1,1,1-tris(hydroxymethyl)-ethan;1,1,1-Tris(methyl

TIANFU-CHEM CAS:77-85-0 1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

GMP factory supply CAS 77-85-0 with competitive price

Cas:77-85-0

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,1,1-Tris(hydroxymethyl)ethane 77-85-0

Cas:77-85-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

1,1,1-Tris(hydroxymethyl)ethane CAS:77-85-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality orga

1,1,1-Tris(hydroxymethyl)ethane CAS:77-85-0

Cas:77-85-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Leader Biochemical Group

About Product Details

China Biggest Factory Manufacturer Supply 1,1,1-Tris(hydroxymethyl)ethane CAS 77-85-0

Cas:77-85-0

Min.Order:500 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:77-85-0

Cas:77-85-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

77-85-0 1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Trimethylolethane(TME)

Cas:77-85-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

1,1,1-TRIS(HYDROXYMETHYL)ETHANE

Cas:77-85-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

77-85-0 1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: 1,1,1-Tris(Hydroxymethyl)Ethane CAS No.:77-85-0 Molecule Formula:C5H12O3 Molecule Weight:120.14 Purity: 99% Package: 25kg/drum Description:White crystalline powder Manufacture Standards:Enterprise Standard TESTING I

High Quality 1,1,1-Tris(Hydroxymethyl)Ethane in stock

Cas:77-85-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

1,1,1-Tris(hydroxymethyl)ethane Basic information Product Name: 1,1,1-Tris(hydroxymethyl)ethane Synonyms: 2-METHYL-2-HYDROXYMETHYL-1,3-PROPANEDIOL;1,1,1-Tri(hydroxymethyl)ethane;1,1,1-tris(hydroxymethyl)-ethan;1,1,1-Tris(methylol)ethane;1,3-Pr

1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Trimethylolethane(TME)

Cas:77-85-0

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Hunan Kaimir Biotechnology Co., Ltd. is a professional technology company specializing in the research and production of raw materials and intermediates. In 2017, it was recognized as a high-tech enterprise and a small technological innovation giant

1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:1 Metric Ton

Negotiable

Type:Other

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

77-85-0 1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Trimethylolethane(TME)

Cas:77-85-0

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

1,1,1-Tris(hydroxymethyl)ethane

Cas:77-85-0

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Hangzhou Fandachem Co.,Ltd

Hangzhou Fandachem Co.,Ltd, a China-based chemical company, specialize in exporting cas no:77-85-0; 1,1,1-Tris(hydroxymethyl)ethane 98% Please contact us by email freely. We are leading exporter in China. If you really need this

cas no:77-85-0; 1,1,1-Tris(hydroxymethyl)ethane ;TME 98%

Cas:77-85-0

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Synthetic route

trimethyl-(2,2,5-trimethyl-[1,3]dioxan-5-ylmethoxy)-silane

trimethyl-(2,2,5-trimethyl-[1,3]dioxan-5-ylmethoxy)-silane

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In water at 30℃; for 24h;100%
copper-II acetate

copper-II acetate

propionaldehyde
123-38-6

propionaldehyde

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
With sodium hydroxide; formaldehyd; triethylamine; Ni-Cr-Al In acetone81.4%
1,1,1-Trimethylolethane dinitrate
84051-79-6

1,1,1-Trimethylolethane dinitrate

A

3-hydroxymethyl-3-methyloxethane
3143-02-0

3-hydroxymethyl-3-methyloxethane

B

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

C

ethyl nitrate
625-58-1

ethyl nitrate

D

1,1,1-Trimethylolethane mononitrate
84051-80-9

1,1,1-Trimethylolethane mononitrate

E

3-methyl-3-(nitroxymethyl)oxetane
84051-81-0

3-methyl-3-(nitroxymethyl)oxetane

F

NO2- (5.2percent), NO3-

NO2- (5.2percent), NO3-

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water at 55℃; for 3.10833h; Product distribution; Rate constant; var. NaOH conc.;A 13%
B 0.7%
C n/a
D 24%
E 66%
F n/a
trimethylolethane trinitrate
3032-55-1

trimethylolethane trinitrate

A

3-hydroxymethyl-3-methyloxethane
3143-02-0

3-hydroxymethyl-3-methyloxethane

B

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

C

1,1,1-Trimethylolethane mononitrate
84051-80-9

1,1,1-Trimethylolethane mononitrate

D

1,1,1-Trimethylolethane dinitrate
84051-79-6

1,1,1-Trimethylolethane dinitrate

E

3-methyl-3-(nitroxymethyl)oxetane
84051-81-0

3-methyl-3-(nitroxymethyl)oxetane

Conditions
ConditionsYield
With sodium hydroxide In methanol; water at 55℃; for 86.1667h; Product distribution; Rate constant; Thermodynamic data; var. NaOH conc., var. solv., solv. effect, ΔH(excit.), ΔF(excit.), ΔS(excit.);A 45.5%
B 2.3%
C 31.8%
D 1.5%
E 16.5%
formaldehyd
50-00-0

formaldehyd

benzophenone
119-61-9

benzophenone

diethyl ether
60-29-7

diethyl ether

A

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

B

2-methyl-1.3-propanediol
2163-42-0

2-methyl-1.3-propanediol

Conditions
ConditionsYield
Irradiation;
formaldehyd
50-00-0

formaldehyd

benzophenone
119-61-9

benzophenone

diethyl ether
60-29-7

diethyl ether

A

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

B

2-methyl-1.3-propanediol
2163-42-0

2-methyl-1.3-propanediol

C

hydroxy-2-propanone
116-09-6

hydroxy-2-propanone

Conditions
ConditionsYield
Sonnenlicht.Irradiation;
formaldehyd
50-00-0

formaldehyd

ethene
74-85-1

ethene

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
With sulfuric acid; acetic acid at 130 - 140℃; entsteht das Triacetat;
formaldehyd
50-00-0

formaldehyd

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
With benzophenone; diethyl ether bei wochenlangem Belichten mit Sonnenlicht;
1,3-Diiod-2-(iodmethyl)-2-methylpropan
85963-60-6

1,3-Diiod-2-(iodmethyl)-2-methylpropan

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
With hydrazine hydrate at 140℃;
3-hydroxy-2-(hydroxymethyl)-2-methylpropanal
18516-18-2

3-hydroxy-2-(hydroxymethyl)-2-methylpropanal

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
With aluminium amalgam
With potassium carbonate
Stage #1: 3-hydroxy-2-(hydroxymethyl)-2-methylpropanal With hydrogen In methanol at 60 - 110℃; under 15001.5 - 45004.5 Torr;
Stage #2: With hydrogen at 140 - 180℃; under 15001.5 - 45004.5 Torr; Temperature;
3-hydroxy-2-(hydroxymethyl)-2-methylpropanal
18516-18-2

3-hydroxy-2-(hydroxymethyl)-2-methylpropanal

A

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

B

2,2-bis(hydroxymethyl)propionic acid
4767-03-7

2,2-bis(hydroxymethyl)propionic acid

Conditions
ConditionsYield
With potassium hydroxide
formaldehyd
50-00-0

formaldehyd

propionaldehyde
123-38-6

propionaldehyde

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

1-bromo-3-chloro-2-chloromethyl-2-methyl-propane
89364-52-3

1-bromo-3-chloro-2-chloromethyl-2-methyl-propane

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
(hydrolysis);
formaldehyd
50-00-0

formaldehyd

propionaldehyde
123-38-6

propionaldehyde

quicklime

quicklime

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

formaldehyd
50-00-0

formaldehyd

propionaldehyde
123-38-6

propionaldehyde

alcoholic potash

alcoholic potash

A

formic acid
64-18-6

formic acid

B

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

C

2-hydroxymethyl-2-methyl-pentane-1,3-diol
100911-59-9

2-hydroxymethyl-2-methyl-pentane-1,3-diol

sodium acetate
127-09-3

sodium acetate

glycerol
56-81-5

glycerol

A

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

B

diglycerol
627-82-7

diglycerol

C

triglycerol

triglycerol

D

tetraglycerol

tetraglycerol

Conditions
ConditionsYield
weitere Produkte: Hexaglycerin; Heptaglycerin; 2.5(oder 2.6)-Bis-oxymethyl-dioxan-(1.4);
formaldehyd
50-00-0

formaldehyd

2-methyl-pent-2ξ-enal

2-methyl-pent-2ξ-enal

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
With calcium hydroxide; water
With water; sodium carbonate
With sodium hydroxide; water
1,3-Diiod-2-(iodmethyl)-2-methylpropan
85963-60-6

1,3-Diiod-2-(iodmethyl)-2-methylpropan

hydrazine hydrate
7803-57-8

hydrazine hydrate

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
at 140℃;
3-hydroxy-2-(hydroxymethyl)-2-methylpropanal
18516-18-2

3-hydroxy-2-(hydroxymethyl)-2-methylpropanal

amalgamated sheet aluminium

amalgamated sheet aluminium

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

3-hydroxy-2-(hydroxymethyl)-2-methylpropanal
18516-18-2

3-hydroxy-2-(hydroxymethyl)-2-methylpropanal

alcoholic potash

alcoholic potash

A

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

B

2,2-bis(hydroxymethyl)propionic acid
4767-03-7

2,2-bis(hydroxymethyl)propionic acid

5-hydroxymethyl-2,2,5-trimethyl-1,3-dioxane
3663-46-5

5-hydroxymethyl-2,2,5-trimethyl-1,3-dioxane

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 100 percent / Et3N / CH2Cl2 / 6 h / Heating
2: 100 percent / sodium tetrakis(3,5-trifluoromethylphenyl)borate dihydrate / H2O / 24 h / 30 °C
View Scheme
With C64H60Au2N12(2+)*2F6P(1-); water at 20℃; for 6h;
Dipentaerythritol
126-58-9

Dipentaerythritol

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: red phosphorus; acetic acid anhydride; HI / 140 °C
2: hydrazine hydrate / 140 °C
View Scheme
2-methyl-3-(4-methylbenzoyloxy)-2-((4-(trifluoromethyl)benzoyloxy)methyl)propyl 3,5-bis(trifluoromethyl)benzoate
1163693-67-1

2-methyl-3-(4-methylbenzoyloxy)-2-((4-(trifluoromethyl)benzoyloxy)methyl)propyl 3,5-bis(trifluoromethyl)benzoate

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
With methanol; samarium diiodide In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide Reflux;
3-hydroxymethyl-3-methyloxethane
3143-02-0

3-hydroxymethyl-3-methyloxethane

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
Stage #1: 3-hydroxymethyl-3-methyloxethane With hydrogenchloride; 4-Nitrobenzylpyridin; water In 1,4-dioxane
Stage #2: With triethylamine In 1,4-dioxane
(4-(5-(hydroxymethyl)-5-methyl-1,3,2-dioxaborinan-2-yl)phenyl)methanol

(4-(5-(hydroxymethyl)-5-methyl-1,3,2-dioxaborinan-2-yl)phenyl)methanol

A

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

B

(4-hydroxyphenyl)methanol
623-05-2

(4-hydroxyphenyl)methanol

Conditions
ConditionsYield
With water; dihydrogen peroxide In aq. phosphate buffer at 37℃; pH=7.4; Kinetics; Concentration; Reagent/catalyst; pH-value;
C5H9O3(3-)*Sb(3+)

C5H9O3(3-)*Sb(3+)

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Conditions
ConditionsYield
With water-d2 In dimethylsulfoxide-d6 Glovebox;
C10H18MnMo6O24(3-)*3Li(1+)

C10H18MnMo6O24(3-)*3Li(1+)

A

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

B

molybdenum(VI) ion

molybdenum(VI) ion

Conditions
ConditionsYield
With methanol Reagent/catalyst;
C10H18MnMo6O24(3-)*3Na(1+)

C10H18MnMo6O24(3-)*3Na(1+)

A

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

B

molybdenum(VI) ion

molybdenum(VI) ion

Conditions
ConditionsYield
With water Kinetics;
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

p-toluenesulfonyl chloride
98-59-9

p-toluenesulfonyl chloride

2-methyl-2-((tosyloxy)methyl)propane-1,3-diyl bis(4-methylbenzenesulfonate)
2387-43-1

2-methyl-2-((tosyloxy)methyl)propane-1,3-diyl bis(4-methylbenzenesulfonate)

Conditions
ConditionsYield
With pyridine at 20℃; for 16h; Inert atmosphere;100%
With pyridine at 0 - 20℃;90%
With pyridine In chloroform81%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

[2,2-bis(trifluoromethyl)-5-oxo-1,3-oxathiolan-4-yl]-acetyl chloride
170996-99-3

[2,2-bis(trifluoromethyl)-5-oxo-1,3-oxathiolan-4-yl]-acetyl chloride

1,1,1-tris(hydroxymethyl)ethane tris{2'-[2,2-bis(trifluoromethyl)-5-oxo-1,3-oxathiolan-4-yl]acetate}

1,1,1-tris(hydroxymethyl)ethane tris{2'-[2,2-bis(trifluoromethyl)-5-oxo-1,3-oxathiolan-4-yl]acetate}

Conditions
ConditionsYield
In toluene for 72h; Heating;100%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

phenyl isocyanate
103-71-9

phenyl isocyanate

1,1,1-tris[(N-phenylcarbamoyloxy)methyl]ethane
292157-64-3

1,1,1-tris[(N-phenylcarbamoyloxy)methyl]ethane

Conditions
ConditionsYield
With MoCl2O2(dmf)2 In dichloromethane for 1h; Inert atmosphere; Reflux;100%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

(2-chloro-4-{N-[5-cyclopropyl-2-(4-fluorophenyl)-3-(methylcarbamoyl)-1-benzofuran-6-yl]methanesulfonamido}phenyl)boronic acid
1423007-27-5

(2-chloro-4-{N-[5-cyclopropyl-2-(4-fluorophenyl)-3-(methylcarbamoyl)-1-benzofuran-6-yl]methanesulfonamido}phenyl)boronic acid

1-(2-chloro-4-(N-(5-cycloroyl-2-(4-fluorohenyl)-3-(methylcarbamoyl)benzofuran-6-yl)methylsulfonamido)henyl)-4-methyl-2,6,7-trioxa-1-borabicyclo[2.2.2]octan-1-uide potassium salt

1-(2-chloro-4-(N-(5-cycloroyl-2-(4-fluorohenyl)-3-(methylcarbamoyl)benzofuran-6-yl)methylsulfonamido)henyl)-4-methyl-2,6,7-trioxa-1-borabicyclo[2.2.2]octan-1-uide potassium salt

Conditions
ConditionsYield
Stage #1: 2-(hydroxymethyl)-2-methylpropane-1,3-diol; (2-chloro-4-{N-[5-cyclopropyl-2-(4-fluorophenyl)-3-(methylcarbamoyl)-1-benzofuran-6-yl]methanesulfonamido}phenyl)boronic acid In tetrahydrofuran for 4h; Molecular sieve; Reflux;
Stage #2: With potassium tert-butylate In tetrahydrofuran at 0 - 20℃;
100%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

(2-chloro-4-{N-[5-cyclopropyl-2-(4-fluorophenyl)-3-(methylcarbamoyl)-1-benzofuran-6-yl]methanesulfonamido}phenyl)boronic acid
1423007-27-5

(2-chloro-4-{N-[5-cyclopropyl-2-(4-fluorophenyl)-3-(methylcarbamoyl)-1-benzofuran-6-yl]methanesulfonamido}phenyl)boronic acid

1-(4-{N-[3-carbamoyl-5-cyclopropyl-2-(4-fluorophenyl)-1-benzofuran-6-yl]methanesulfonamido}-2-chlorophenyl)-4-methyl-2,6,7-trioxa-1-borabicyclo[2.2.2]octan-1-uide potassium salt

1-(4-{N-[3-carbamoyl-5-cyclopropyl-2-(4-fluorophenyl)-1-benzofuran-6-yl]methanesulfonamido}-2-chlorophenyl)-4-methyl-2,6,7-trioxa-1-borabicyclo[2.2.2]octan-1-uide potassium salt

Conditions
ConditionsYield
Stage #1: 2-(hydroxymethyl)-2-methylpropane-1,3-diol; (2-chloro-4-{N-[5-cyclopropyl-2-(4-fluorophenyl)-3-(methylcarbamoyl)-1-benzofuran-6-yl]methanesulfonamido}phenyl)boronic acid In tetrahydrofuran for 4h; Reflux;
Stage #2: With potassium tert-butylate In tetrahydrofuran at 0 - 20℃;
100%
Trimethyl orthoacetate
1445-45-0

Trimethyl orthoacetate

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

C7H16O3

C7H16O3

Conditions
ConditionsYield
With trifluoroacetic acid In dimethylsulfoxide-d6 at 20℃; for 1h;100%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

acrylonitrile
107-13-1

acrylonitrile

3,3'-((2-((2-cyanoethoxy)methyl)-2-methylpropane-1,3-diyl)bis(oxy))-dipropanenitrile
60758-55-6

3,3'-((2-((2-cyanoethoxy)methyl)-2-methylpropane-1,3-diyl)bis(oxy))-dipropanenitrile

Conditions
ConditionsYield
With sodium hydroxide Ambient temperature;99%
With potassium hydroxide In 1,4-dioxane at 25℃; for 20h;83%
With sodium hydroxide In water at 0 - 20℃; Michael Addition;75%
2-thienyl lithium
2786-07-4

2-thienyl lithium

2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

LiCH3C(CH2O)3B(2-thienyl)

LiCH3C(CH2O)3B(2-thienyl)

Conditions
ConditionsYield
Stage #1: 2-thienyl lithium With Triisopropyl borate In tetrahydrofuran; hexane at -78℃;
Stage #2: 2-(hydroxymethyl)-2-methylpropane-1,3-diol In tetrahydrofuran; hexane Further stages.;
99%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

4-fluoroboronic acid
1765-93-1

4-fluoroboronic acid

4-FC6H4B(OCH2)2C(CH3)CH2OH
1014716-67-6

4-FC6H4B(OCH2)2C(CH3)CH2OH

Conditions
ConditionsYield
In toluene99%
byproducts: H2O;99%
In toluene for 3h;
Stage #1: 2-(hydroxymethyl)-2-methylpropane-1,3-diol; 4-fluoroboronic acid In dichloromethane at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With magnesium sulfate In dichloromethane at 20℃; for 0.25h; Inert atmosphere;
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

4-trifluoromethylphenylboronic acid
128796-39-4

4-trifluoromethylphenylboronic acid

4-CF3C6H4B(OCH2)2C(CH3)CH2OH
1014716-70-1

4-CF3C6H4B(OCH2)2C(CH3)CH2OH

Conditions
ConditionsYield
In toluene99%
byproducts: H2O;99%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

3,4-(methylenedioxy)-benzeneboronic acid
94839-07-3

3,4-(methylenedioxy)-benzeneboronic acid

3,4-O2CH2C6H3B(OCH2)2C(CH3)CH2OH
1014716-56-3

3,4-O2CH2C6H3B(OCH2)2C(CH3)CH2OH

Conditions
ConditionsYield
In toluene99%
byproducts: H2O;99%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

2-thiopheneboronic acid pinacol ester
193978-23-3

2-thiopheneboronic acid pinacol ester

C4H3SB(OCH2)3CCH3(1-)*Na(1+)=NaC4H3SB(OCH2)3CCH3

C4H3SB(OCH2)3CCH3(1-)*Na(1+)=NaC4H3SB(OCH2)3CCH3

Conditions
ConditionsYield
With sodium hydroxide In 1,4-dioxane; water at 60℃; for 16h; Inert atmosphere;99%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

2-thiopheneboronic acid pinacol ester
193978-23-3

2-thiopheneboronic acid pinacol ester

sodium hydroxide
1310-73-2

sodium hydroxide

C4H3SB(OCH2)3CCH3(1-)*Na(1+)=NaC4H3SB(OCH2)3CCH3

C4H3SB(OCH2)3CCH3(1-)*Na(1+)=NaC4H3SB(OCH2)3CCH3

Conditions
ConditionsYield
In 1,4-dioxane 1.0 equiv. NaOH, 3 equiv. H2O, 60°C; stirred for 16 h; chromy.;99%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

acetone
67-64-1

acetone

5-hydroxymethyl-2,2,5-trimethyl-1,3-dioxane
3663-46-5

5-hydroxymethyl-2,2,5-trimethyl-1,3-dioxane

Conditions
ConditionsYield
With toluene-4-sulfonic acid at 20℃; for 48h; Inert atmosphere;98%
With toluene-4-sulfonic acid for 48h; Ambient temperature;96%
With toluene-4-sulfonic acid at 20℃; for 24h;92%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

hexadecanyl bromide
112-82-3

hexadecanyl bromide

2,2-Bis(hexadecyloxymethyl)propan-1-ol
166384-15-2

2,2-Bis(hexadecyloxymethyl)propan-1-ol

Conditions
ConditionsYield
Stage #1: 2-(hydroxymethyl)-2-methylpropane-1,3-diol With sodium hydride In N,N-dimethyl-formamide at 20℃; for 1h; Metallation;
Stage #2: hexadecanyl bromide In N,N-dimethyl-formamide at 50℃; for 44h; Etherification; Further stages.;
98%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

5-hydroxymethyl-2,2,5-trimethyl-1,3-dioxane
3663-46-5

5-hydroxymethyl-2,2,5-trimethyl-1,3-dioxane

Conditions
ConditionsYield
With toluene-4-sulfonic acid at 20℃; for 48h; Inert atmosphere;98%
With potassium carbonate; toluene-4-sulfonic acid In acetone
With p-toluenesulfonic acid monohydrate; sodium acetate In acetone; Petroleum ether
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

octadecyldimethyl[3-(trimethoxysilyl)propyl]ammonium chloride
27668-52-6

octadecyldimethyl[3-(trimethoxysilyl)propyl]ammonium chloride

C38H82NO9Si(1+)*Cl(1-)

C38H82NO9Si(1+)*Cl(1-)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 145℃;98%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

2,2-dimethoxy-propane
77-76-9

2,2-dimethoxy-propane

5-hydroxymethyl-2,2,5-trimethyl-1,3-dioxane
3663-46-5

5-hydroxymethyl-2,2,5-trimethyl-1,3-dioxane

Conditions
ConditionsYield
With toluene-4-sulfonic acid In tetrahydrofuran for 1h;97%
With 4 A molecular sieve; toluene-4-sulfonic acid In chloroform for 17h; Heating;96%
With toluene-4-sulfonic acid In chloroform for 17h; Heating;96%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

methyl 3-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
408492-29-5

methyl 3-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

Na(3-Cl-5-(MeO2C)-C6H3B(OCH2)3CCH3)

Na(3-Cl-5-(MeO2C)-C6H3B(OCH2)3CCH3)

Conditions
ConditionsYield
With sodium hydroxide In 1,4-dioxane; water at 30℃; for 16h; Inert atmosphere;97%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

sodium hydroxide
1310-73-2

sodium hydroxide

methyl 3-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
408492-29-5

methyl 3-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate

Na(3-Cl-5-(MeO2C)-C6H3B(OCH2)3CCH3)

Na(3-Cl-5-(MeO2C)-C6H3B(OCH2)3CCH3)

Conditions
ConditionsYield
In 1,4-dioxane 1.0 equiv. NaOH, 3 equiv. H2O, 30°C; stirred for 16 h; chromy.;97%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

methyllithium
917-54-4

methyllithium

lithium methyltriolborate

lithium methyltriolborate

Conditions
ConditionsYield
Stage #1: methyllithium With Triisopropyl borate In diethyl ether at -78 - 20℃; for 8.5h; Inert atmosphere;
Stage #2: 2-(hydroxymethyl)-2-methylpropane-1,3-diol In diethyl ether at 60℃; for 1h; Inert atmosphere;
97%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

2-bromodecanoic acid
2623-95-2

2-bromodecanoic acid

C35H66O9

C35H66O9

Conditions
ConditionsYield
Stage #1: 2-(hydroxymethyl)-2-methylpropane-1,3-diol With sodium hydride In tetrahydrofuran at 20℃; for 1h; Inert atmosphere;
Stage #2: 2-bromodecanoic acid In tetrahydrofuran at 65℃; for 24.5h; Cooling with ice; Inert atmosphere;
97%
Stage #1: 2-(hydroxymethyl)-2-methylpropane-1,3-diol With sodium hydride In tetrahydrofuran; mineral oil at 20℃; for 1h;
Stage #2: 2-bromodecanoic acid In tetrahydrofuran; mineral oil at 0 - 65℃;
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

triethyl phosphate
78-40-0

triethyl phosphate

Dipentaerythritol
126-58-9

Dipentaerythritol

triethyl phosphite
122-52-1

triethyl phosphite

C16H34O15P4

C16H34O15P4

Conditions
ConditionsYield
Stage #1: 2-(hydroxymethyl)-2-methylpropane-1,3-diol; Dipentaerythritol; triethyl phosphite at 85℃; for 5h; Inert atmosphere;
Stage #2: triethyl phosphate With Isobutyl bromide at 185℃; for 16h;
96.1%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

acetic anhydride
108-24-7

acetic anhydride

1,1,1-Tris(acetoxymethyl)ethane
13431-59-9

1,1,1-Tris(acetoxymethyl)ethane

Conditions
ConditionsYield
With In(OSO2CF3)3 In acetonitrile at 20℃; Acetylation;96%
With sodium acetate
With dmap; triethylamine
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

2-chloro-5,5-dimethyl-[1,3,2]dioxaphosphinane
2428-06-0

2-chloro-5,5-dimethyl-[1,3,2]dioxaphosphinane

C20H39O9P3

C20H39O9P3

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran for 15h; Ambient temperature;96%
With triethylamine at 20℃; for 1.5h;1.23 g
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

Octanoic acid
124-07-2

Octanoic acid

2-(hydroxymethyl)-2-methyl-1,3-propanediol trioctanoate
67874-06-0

2-(hydroxymethyl)-2-methyl-1,3-propanediol trioctanoate

Conditions
ConditionsYield
With pyridine; <(chlorosulfinyloxy)methylene>dimethylammonium chloride In dichloromethane at 20℃; for 6h;96%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

hexanoic acid
142-62-1

hexanoic acid

Trimethylolpropane tricaproate
74634-68-7

Trimethylolpropane tricaproate

Conditions
ConditionsYield
With pyridine; <(chlorosulfinyloxy)methylene>dimethylammonium chloride In dichloromethane at 20℃; for 6h;96%
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

4-MeC6H4B(OCH2)2C(CH3)CH2OH
1014716-63-2

4-MeC6H4B(OCH2)2C(CH3)CH2OH

Conditions
ConditionsYield
In toluene96%
byproducts: H2O;96%
In toluene for 4h; Reflux;
2-(hydroxymethyl)-2-methylpropane-1,3-diol
77-85-0

2-(hydroxymethyl)-2-methylpropane-1,3-diol

2-(3,4-dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
401797-02-2

2-(3,4-dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Na(3,4-(Cl2)-C6H3B(OCH2)3CCH3)

Na(3,4-(Cl2)-C6H3B(OCH2)3CCH3)

Conditions
ConditionsYield
With sodium hydroxide In 1,4-dioxane; water at 30℃; for 16h; Inert atmosphere;96%
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