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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

High purity Triphenylsilanol 98% TOP1 supplier in China

Cas:791-31-1

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Bottom price high purity Triphenylsilanol Cas 791-31-1 Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Food/Feed additives, Fin

Bottom price high purity Triphenylsilanol Cas 791-31-1

Cas:791-31-1

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Triphenylsilanol

Cas:791-31-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Triphenylsilanol Basic information Product Name: Triphenylsilanol Synonyms: TRIPHENYLSILANOL;hydroxytriphenyl-silan;Silane, (hydroxytriphenyl)-;Silanol,triphenyl-;Triphenylhydroxysilane;

TIANFU-CHEM CAS:791-31-1 Triphenylsilanol

Cas:791-31-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

China Gold SupplierCAS 791-31-1 with high-quality service

Cas:791-31-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Silanol,1,1,1-triphenyl- 791-31-1

Cas:791-31-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Triphenylsilanol; Triphenylhydroxysilane

Cas:791-31-1

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Qingdao Beluga Import and Export Co., LTD

Triphenylsilanol CAS:791-31-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

Triphenylsilanol CAS:791-31-1

Cas:791-31-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

High purity Triphenylsilanol

Cas:791-31-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:791-31-1

Cas:791-31-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Triphenylsilanol

Cas:791-31-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Triphenylsilanol

Cas:791-31-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Triphenylsilanol

Cas:791-31-1

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Triphenylsilanol

Cas:791-31-1

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Triphenylsilanol

Cas:791-31-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:White crystal Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Transportation:BY A

Triphenylsilanol

Cas:791-31-1

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Triphenylsilanol

Cas:791-31-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Triphenylsilanol

Cas:791-31-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Triphenylsilanol

Cas:791-31-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Triphenylsilanol

Cas:791-31-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Triphenylsilanol

Cas:791-31-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

triphenylsilanol cas no. 791-31-1 98%

Cas:791-31-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

triphenylsilanol

Cas:791-31-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kunshan Push Trading Co.,LTD

ADVANTAGE 1.Professional: More than 10 years chemical exporting experience. We have produced chemical more than fifteen years, 95% products are for export . More than 10 years chemical exporting experience. Good and stabilized factory price. 2.

TRIPHENYLSILANOL

Cas:791-31-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

Hangzhou Dingyan Chem is a leading manufacturer and supplier of chemicals in China.We develop,produce and distribute high quality pharmaceuticals, intermediates, special chemicals and other fine chemicals. We could give you: 1.Best quality in your re

Triphenylsilanol

Cas:791-31-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Triphenylsilanol 500g

Cas:791-31-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Triphenylsilanol

Cas:791-31-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

Silanol,1,1,1-triphenyl-

Cas:791-31-1

Min.Order:0

Negotiable

Type:Other

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Silanol,1,1,1-triphenyl-

Cas:791-31-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

Triphenylsilanol

Cas:791-31-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

HSiPh3
789-25-3

HSiPh3

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With water In acetone at 20℃; for 5h;99%
With 2,2,2-Trifluoroacetophenone; dihydrogen peroxide In acetonitrile; tert-butyl alcohol for 0.5h; Time; Green chemistry;99%
With water at 20℃; for 2.83333h;99%
tris(triphenylsiloxy)iron

tris(triphenylsiloxy)iron

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With H2O; HCl In water; acetone stirring (room temp., 5 min); evapn. in air, extn. (CCl4, 70°C), pptn. on evapn.; IR spectroscopy;99%
9H2O*6C4H12N(1+)*H(1+)*Sb5Mo18O66(7-)

9H2O*6C4H12N(1+)*H(1+)*Sb5Mo18O66(7-)

HSiPh3
789-25-3

HSiPh3

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With tert.-butylhydroperoxide In acetonitrile at 50℃; for 12h;98.3%
HSiPh3
789-25-3

HSiPh3

A

hydrogen
1333-74-0

hydrogen

B

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With water In acetone at 25℃; for 6h; Catalytic behavior; Mechanism;A n/a
B 98%
With water; silver nitrate at 24.84℃; for 0.5h;A 45%
B 49%
sodium triphenylsilanolate
16527-35-8

sodium triphenylsilanolate

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With CH3COOH In acetic acid97%
ethoxy(triphenylsilyl)keten

ethoxy(triphenylsilyl)keten

A

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

B

W(CO)6

W(CO)6

Conditions
ConditionsYield
With (CO)5WC(OEt)SiPh3 In diethyl ether at 80 - 100℃; for 1h; Product distribution;A 96%
B n/a
(CO)5WC(OEt)SiPh3

(CO)5WC(OEt)SiPh3

A

tungsten hexacarbonyl
14040-11-0

tungsten hexacarbonyl

B

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With carbon monoxide In diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A n/a
B 96%
With carbon monoxide In pentane High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A n/a
B 96%
(CO)5CrC(OEt)SiPh3

(CO)5CrC(OEt)SiPh3

A

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

B

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With carbon monoxide In diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A n/a
B 96%
With carbon monoxide In pentane High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A n/a
B 96%
(CO)5MoC(OEt)SiPh3

(CO)5MoC(OEt)SiPh3

A

molybdenum hexacarbonyl
13939-06-5, 199620-15-0

molybdenum hexacarbonyl

B

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With carbon monoxide In diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A n/a
B 96%
With carbon monoxide In pentane High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A n/a
B 96%
hexaphenyldisilane
1450-23-3

hexaphenyldisilane

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With 1% Au/TiO2; water In ethyl acetate at 55℃; for 5h;92%
(CO)5WC(OEt)SiPh3

(CO)5WC(OEt)SiPh3

benzylidene phenylamine
538-51-2

benzylidene phenylamine

A

tungsten hexacarbonyl
14040-11-0

tungsten hexacarbonyl

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

D

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With carbon monoxide In diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A n/a
B n/a
C n/a
D 90%
(CO)5CrC(OEt)SiPh3

(CO)5CrC(OEt)SiPh3

benzylidene phenylamine
538-51-2

benzylidene phenylamine

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

C

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

D

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With carbon monoxide In diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A 74%
B 16%
C n/a
D 90%
(CO)5MoC(OEt)SiPh3

(CO)5MoC(OEt)SiPh3

benzylidene phenylamine
538-51-2

benzylidene phenylamine

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(C6H5)

C

molybdenum hexacarbonyl
13939-06-5, 199620-15-0

molybdenum hexacarbonyl

D

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With carbon monoxide In diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A n/a
B n/a
C n/a
D 90%
(benzyloxy)triphenylsilane
18858-69-0

(benzyloxy)triphenylsilane

A

toluene
108-88-3

toluene

B

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With palladium on activated charcoal; hydrogen In tetrahydrofuran-d8 at 20℃; under 760.051 Torr; for 1.5h; Reagent/catalyst; Solvent;A n/a
B 90%
triphenylsilyl lithium

triphenylsilyl lithium

mercury dibromide

mercury dibromide

A

hexaphenyldisiloxanne
1829-40-9

hexaphenyldisiloxanne

B

hexaphenyldisilane
1450-23-3

hexaphenyldisilane

C

mercury

mercury

D

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
In tetrahydrofuran at -70°C; 2mol (C6H5)3SiLi;;A 11.2%
B 50.3%
C 77.5%
D 33.3%
In tetrahydrofuran at -70°C; 2mol (C6H5)3SiLi;;A 11.2%
B 50.3%
C 77.5%
D 33.3%
Acetyltriphenylsilane
4916-42-1

Acetyltriphenylsilane

1-phenyl-5-((3-phenylpropyl)sulfonyl)-1H-tetrazole

1-phenyl-5-((3-phenylpropyl)sulfonyl)-1H-tetrazole

A

5-phenyl-2-pentanone
2235-83-8

5-phenyl-2-pentanone

B

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
Stage #1: Acetyltriphenylsilane; 1-phenyl-5-((3-phenylpropyl)sulfonyl)-1H-tetrazole With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; Brook rearrangement;
Stage #2: With water In tetrahydrofuran
A 75%
B n/a
bis(triphenylsiloxy)cobalt

bis(triphenylsiloxy)cobalt

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With H2O In water; acetone stirring (room temp., 5 min); evapn. in air, extn. (CCl4, 70°C), pptn. on evapn.; IR spectroscopy;75%
(CO)5WC(OEt)SiPh3

(CO)5WC(OEt)SiPh3

N-Benzylidenemethylamine
622-29-7

N-Benzylidenemethylamine

A

tungsten hexacarbonyl
14040-11-0

tungsten hexacarbonyl

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

D

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With carbon monoxide In diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A n/a
B 74%
C 16%
D 5%
(CO)5CrC(OEt)SiPh3

(CO)5CrC(OEt)SiPh3

N-Benzylidenemethylamine
622-29-7

N-Benzylidenemethylamine

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

C

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

D

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With carbon monoxide In diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A 74%
B 16%
C n/a
D 5%
(CO)5MoC(OEt)SiPh3

(CO)5MoC(OEt)SiPh3

N-Benzylidenemethylamine
622-29-7

N-Benzylidenemethylamine

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

CH(C6H5)CSi(C6H5)3(C2H5O)CON(CH3)

C

molybdenum hexacarbonyl
13939-06-5, 199620-15-0

molybdenum hexacarbonyl

D

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With carbon monoxide In diethyl ether High Pressure; under dried N2; addn. of N-methylbenzimine at 25°C to a soln. of W-complex (CO-pressure: 50 atm); stirring for 2 d at room temp., then for 1-2 h at 80-100°C; vac.-evapn. until dryness; residue dissolved in petroleum ether/ether; chromy. (silica gel/petroleum ether/ether); recrystn. from petroleum ether; elem. anal.;A 74%
B 16%
C n/a
D 5%
allyltriphenylsilane
18752-21-1

allyltriphenylsilane

A

(E)-diphenyl-1-propenylsilanol

(E)-diphenyl-1-propenylsilanol

B

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With 18-crown-6 ether; potassium tert-butylate In tetrahydrofuran; dimethyl sulfoxide at -45 - 20℃;A 71%
B 19%
With 18-crown-6 ether; potassium tert-butylate; dimethyl sulfoxide In tetrahydrofuran at -45 - 20℃;A 71%
B 19%
With 18-crown-6 ether; potassium tert-butylate; dimethyl sulfoxide at 20℃; for 0.333333h;A 23%
B 70%
1-propenyl(triphenyl)silane
18752-22-2

1-propenyl(triphenyl)silane

A

(E)-diphenyl-1-propenylsilanol

(E)-diphenyl-1-propenylsilanol

B

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With 18-crown-6 ether; potassium tert-butylate; dimethyl sulfoxide at 20℃; for 0.333333h;A 68%
B 26%
dimethyl(phenyl)silyllithium
3839-31-4

dimethyl(phenyl)silyllithium

triphenylsilyl tris(trimethylsilyl)silanecarboxylate
81671-48-9

triphenylsilyl tris(trimethylsilyl)silanecarboxylate

A

Tris-(trimethylsilyl)-silancarbonsaeure
70096-33-2

Tris-(trimethylsilyl)-silancarbonsaeure

B

2,2-dimethyl-2-phenyltris(trimethylsilyl)disilane
197797-30-1

2,2-dimethyl-2-phenyltris(trimethylsilyl)disilane

C

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With water In tetrahydrofuran for 20h;A 10%
B 64%
C 61%
phenyllithium
591-51-5

phenyllithium

triphenylsilyl tris(trimethylsilyl)silanecarboxylate
81671-48-9

triphenylsilyl tris(trimethylsilyl)silanecarboxylate

A

2,2-dimethyl-2-phenyltris(trimethylsilyl)disilane
197797-30-1

2,2-dimethyl-2-phenyltris(trimethylsilyl)disilane

B

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With water In tetrahydrofuranA n/a
B 61%
p-chlorphenylisocyanate
104-12-1

p-chlorphenylisocyanate

3-Diethylamino-2-<1-(triphenylsiloxy)vinyl>-2-cyclobuten-1-on
79139-28-9

3-Diethylamino-2-<1-(triphenylsiloxy)vinyl>-2-cyclobuten-1-on

A

2-Acetyl-3-(diethylamino)-2-cyclobuten-1-on
73000-93-8

2-Acetyl-3-(diethylamino)-2-cyclobuten-1-on

B

4'-Chlor-3-<2-(diethylamino)-4-oxo-1-cyclobutenyl>-3-oxopropananilid
79139-27-8

4'-Chlor-3-<2-(diethylamino)-4-oxo-1-cyclobutenyl>-3-oxopropananilid

C

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
In acetonitrile for 144h; Ambient temperature;A 60%
B 30%
C 58%
3-Diethylamino-2-<1-(triphenylsiloxy)vinyl>-2-cyclobuten-1-on
79139-28-9

3-Diethylamino-2-<1-(triphenylsiloxy)vinyl>-2-cyclobuten-1-on

A

2-Acetyl-3-(diethylamino)-2-cyclobuten-1-on
73000-93-8

2-Acetyl-3-(diethylamino)-2-cyclobuten-1-on

B

4'-Chlor-3-<2-(diethylamino)-4-oxo-1-cyclobutenyl>-3-oxopropananilid
79139-27-8

4'-Chlor-3-<2-(diethylamino)-4-oxo-1-cyclobutenyl>-3-oxopropananilid

C

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With p-chlorphenylisocyanate In acetonitrile for 144h; Ambient temperature;A 60%
B 30%
C 58%
With p-chlorphenylisocyanate In acetonitrile for 144h; Ambient temperature; further reagent: m-chloroperbenzoic acid;A 60%
B 30%
C 58%
tris(trimethylsilyl)silyllithium
4110-02-5

tris(trimethylsilyl)silyllithium

triphenylsilyl tris(trimethylsilyl)silanecarboxylate
81671-48-9

triphenylsilyl tris(trimethylsilyl)silanecarboxylate

A

tetrakis(trimethylsilyl)silane
4098-98-0

tetrakis(trimethylsilyl)silane

B

Tris-(trimethylsilyl)-silancarbonsaeure
70096-33-2

Tris-(trimethylsilyl)-silancarbonsaeure

C

Si(SiMe3)3(SiPh3)

Si(SiMe3)3(SiPh3)

D

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With water In tetrahydrofuranA 19%
B 58%
C 46%
D 37%
C26H30Si
1277099-83-8

C26H30Si

A

C26H30O3Si
1277099-84-9

C26H30O3Si

B

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With oxygen; ozone In ethyl acetate at -78℃;A 9%
B 58%
1-fluorovinyl 2-benzyl-4-(tert-butyldiphenylsilyloxy)butanoate

1-fluorovinyl 2-benzyl-4-(tert-butyldiphenylsilyloxy)butanoate

4-methoxy-aniline
104-94-9

4-methoxy-aniline

A

triphenylsilyl fluoride
379-50-0

triphenylsilyl fluoride

B

4-methoxyacetanilide
51-66-1

4-methoxyacetanilide

C

3-benzyltetrahydrofuran-2-one
68975-07-5, 68975-13-3, 68975-14-4, 61129-28-0

3-benzyltetrahydrofuran-2-one

D

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran at 0 - 20℃; for 4h; Inert atmosphere;A 40%
B 57%
C 30%
D 46%
triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

triphenylsilyl fluoride
379-50-0

triphenylsilyl fluoride

Conditions
ConditionsYield
With hydrogen fluoride In methanol for 0.5h; Ambient temperature;100%
With hydrogen fluoride In methanol at 20℃; for 0.5h; Substitution;95%
With ethanol; hydrogen fluoride; water
With HF In hydrogen fluoride aq. HF; (C6H5)3SiOH and 48% aq. HF;;>99
With boron trifluoride diethyl etherate In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;
salicylic alcohol
90-01-7

salicylic alcohol

boric acid
11113-50-1

boric acid

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

2-triphenylsiloxy-4H-1,3,2-benzodioxaborin
82172-56-3

2-triphenylsiloxy-4H-1,3,2-benzodioxaborin

Conditions
ConditionsYield
In benzene byproducts: H2O; azeotropic removal of water; elem. anal.;100%
boric acid
11113-50-1

boric acid

benzene-1,2-diol
120-80-9

benzene-1,2-diol

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

2-triphenylsiloxy-1,3,2-benzodioxaborole
82172-55-2

2-triphenylsiloxy-1,3,2-benzodioxaborole

Conditions
ConditionsYield
In benzene byproducts: H2O; azeotropic removal of water; elem. anal.;100%
boric acid
11113-50-1

boric acid

ethylene glycol
107-21-1

ethylene glycol

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

2-triphenylsiloxy-1,3,2-dioxaborolane
82172-50-7

2-triphenylsiloxy-1,3,2-dioxaborolane

Conditions
ConditionsYield
In benzene byproducts: H2O; azeotropic removal of water; distd. in vac., elem. anal.;100%
trimethylaluminum
75-24-1

trimethylaluminum

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

C58H53AlO4Si3
143607-50-5

C58H53AlO4Si3

Conditions
ConditionsYield
With tetrahydrofuran In tetrahydrofuran; hexane byproducts: methane; (dry N2); dropwise addn. of AlMe3 hexane soln. to a stirred soln. of 3 equiv. of HOSiPh3 in THF at 0°C, stirring (12 h); removal of volatiles in vac.;99.9%
tetrabenzylzirconium(IV)
24356-01-2

tetrabenzylzirconium(IV)

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

tetrakis(triphenylsilanolato)zirconium

tetrakis(triphenylsilanolato)zirconium

Conditions
ConditionsYield
In benzene silanol reacted with Zr compd. (0.5 equiv.) in benzene;99%
[Re(neopentyl)2(neopentylidene)(neopentylydine)]
86823-35-0

[Re(neopentyl)2(neopentylidene)(neopentylydine)]

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

[Re(neopentyl)(OSiPh3)(neopentylidene)(neopentylidyne)]

[Re(neopentyl)(OSiPh3)(neopentylidene)(neopentylidyne)]

Conditions
ConditionsYield
In benzene byproducts: t-BuCH3; benzene, 1 equiv of silanol, room temp.;99%
In benzene-d6 byproducts: neopentane; (Ar); using Schlenk techniques; addn. of 1 equiv. of Ph3SiOH to soln. ofRe(C(t-Bu))(CH(t-Bu))(CH2(t-Bu))2 in C6D6 in NMR tube; holding at room temp. for 12 h; monitoring by NMR; evapn., as inseperable mixt. of syn and anti rotamersin 10/1 ratio; as oil;
(tetrahydrofuran)[trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamidato)cyclohexane-N,N'][bis(dimethylsilyl)amido]yttrium(III)

(tetrahydrofuran)[trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamidato)cyclohexane-N,N'][bis(dimethylsilyl)amido]yttrium(III)

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

Y(C4H8O)(OSi(C6H5)3)(C36H56N2O4S2)*C7H8

Y(C4H8O)(OSi(C6H5)3)(C36H56N2O4S2)*C7H8

Conditions
ConditionsYield
In toluene (argon); stirring (room temp., 12 h); removal of volatiles (vac.), recrystn. (hot toluene); elem. anal.;99%
diisopropoxidobis(2,4-pentanedionato)zirconium(IV)

diisopropoxidobis(2,4-pentanedionato)zirconium(IV)

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

zirconium (triphenylsilanolat)2-bis(acetylacetonate)

zirconium (triphenylsilanolat)2-bis(acetylacetonate)

Conditions
ConditionsYield
In benzene byproducts: (CH3)2CHOH; performed in a moisture free environment; benzene soln. of Zr(acac)2(OiPr)2 added to a benzene suspension of the organic ligand; refluxed for 4h; solvent removed under reduced pressure; purified by recrystallization from a mixture of dichloromethane and n-hexane; elem. anal.;99%
methoxy(diphenyl)pyrrolidinosilane
1384834-55-2

methoxy(diphenyl)pyrrolidinosilane

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

1-methoxy-1,1,3,3,3-pentaphenyldisiloxane
1384834-60-9

1-methoxy-1,1,3,3,3-pentaphenyldisiloxane

Conditions
ConditionsYield
In diethyl ether at 20℃; for 30h;99%
Zr(η5-cyclopentadienyl)3(η1-cyclopentadienyl)

Zr(η5-cyclopentadienyl)3(η1-cyclopentadienyl)

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

bis(η5-cyclopentadienyl)bis(triphenylsiloxy)zirconium(IV)

bis(η5-cyclopentadienyl)bis(triphenylsiloxy)zirconium(IV)

Conditions
ConditionsYield
In toluene byproducts: CpH; Ar-atmosphere; stirring Zr-complex with 2 equiv. of Si-compd. (room temp., 5 h); evapn. (after 15 h, reduced pressure, room temp.), addn. of heptane, filtration, washing (heptane), drying (vac.);98%
In toluene byproducts: CpH; Ar-atmosphere; stirring Zr-complex with 1 equiv. of Si-compd. (room temp., 5 h); evapn. (after 15 h, reduced pressure, room temp.), addn. of heptane, filtration, washing (heptane), drying (vac.);41%
[Li(C4H8O)2(AlH3(C(Si(CH3)3)3))]2

[Li(C4H8O)2(AlH3(C(Si(CH3)3)3))]2

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

[Al(OSiPh3)2(C(SiMe3)3)(thf)]
502188-76-3

[Al(OSiPh3)2(C(SiMe3)3)(thf)]

Conditions
ConditionsYield
In toluene under Ar; soln. of Ph3SiOH in toluene added to soln. of Al complex in toluene at 0°C under stirring, mixt. allowed to warm to room temp.,stirred for 18 h; filtered, filtrate evapd., residue recrystd. from heptane-toluene (1:1);elem. anal.;98%
(2,4-tert-butyl-6-([(2'-dimethylaminoethyl)methylamino]methyl)phenolate)ZnEt
613688-14-5

(2,4-tert-butyl-6-([(2'-dimethylaminoethyl)methylamino]methyl)phenolate)ZnEt

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

(2-tert-butyl-4-methoxy-6-{[(2'-dimethylaminoethyl)-methylamino]methyl}phenol-H)ZnSiOPh3
1570188-83-8

(2-tert-butyl-4-methoxy-6-{[(2'-dimethylaminoethyl)-methylamino]methyl}phenol-H)ZnSiOPh3

Conditions
ConditionsYield
In toluene at 24.84℃; for 16h; Inert atmosphere;98%
acridine orange
494-38-2

acridine orange

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

triphenylsilanol-acridine orange salt

triphenylsilanol-acridine orange salt

Conditions
ConditionsYield
In 1,4-dioxane at 20℃; for 0.25h;98%
tris(pentafluorophenyl)borate
1109-15-5

tris(pentafluorophenyl)borate

N,N-diethylaniline
91-66-7

N,N-diethylaniline

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

C36H15BF15OSi(1-)*C10H15N*H(1+)

C36H15BF15OSi(1-)*C10H15N*H(1+)

Conditions
ConditionsYield
In toluene at 20℃; for 2h;97%
[Me3SiFlSi]4O12[TiO(i)Pr]4
293329-43-8

[Me3SiFlSi]4O12[TiO(i)Pr]4

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

[Me3SiFlSi]4O12[TiOSiPh3]4

[Me3SiFlSi]4O12[TiOSiPh3]4

Conditions
ConditionsYield
In tetrahydrofuran under Ar atm. at 0°C HOSiPh3 was added dropwise to soln. (Me3SiFlSi)4O12(TiOiPr)4 in THF and stirred for 16 h; volatiles were removed in vacuo, recrystn. from hexane; elem. anal.;97%
ethyl trimethylsilyl ether
1825-62-3

ethyl trimethylsilyl ether

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

1,1,1-trimethyl-3,3,3-triphenyl-disiloxane
799-53-1

1,1,1-trimethyl-3,3,3-triphenyl-disiloxane

Conditions
ConditionsYield
96.5%
96.5%
96.5%
With hydrogenchloride
(((CH3)3C)2(O)C6H2CHNCH2)2Al(CH3)

(((CH3)3C)2(O)C6H2CHNCH2)2Al(CH3)

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

((((CH3)3C)2(O)C6H2CHNCH2)2)Al(OSi(C6H5)3)
190370-43-5

((((CH3)3C)2(O)C6H2CHNCH2)2)Al(OSi(C6H5)3)

Conditions
ConditionsYield
In toluene inert atmosphere; stirring (25°C, 2 h ); filtering,;96%
Cyclohexyl isocyanide
931-53-3

Cyclohexyl isocyanide

dimethyl acetylenedicarboxylate
762-42-5

dimethyl acetylenedicarboxylate

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

dimethyl 2-((cyclohexylimino)methylene)-3-(triphenylsilyloxy)succinate
1344030-61-0

dimethyl 2-((cyclohexylimino)methylene)-3-(triphenylsilyloxy)succinate

Conditions
ConditionsYield
In dichloromethane at 20℃; for 8h;96%
[C4H2N(2,5-CH2NMe2)2AlH2]
377726-64-2

[C4H2N(2,5-CH2NMe2)2AlH2]

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

[C4H2N(2,5-CH2NMe2)2Al(OSiPh3)2]
1341127-38-5

[C4H2N(2,5-CH2NMe2)2Al(OSiPh3)2]

Conditions
ConditionsYield
In dichloromethane N2; DCM soln. of ligand added dropwise to DCM soln. of Al compd. (2:1 molar ratio), mixt. stirred at room temp. for 12 h; evapd. (vac.), recrystd. (DCM);96%

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