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Antimex Chemical Limied

ProName: catechol 120-80-9 CasNo: 120-80-9 Molecular Formula: C6H6O2 Appearance: Light gray or light brown crystal Application: Pharmaceutical Intermediates DeliveryTime: prompt PackAge: 25kg/drum, 200kg/drum Port: Sh

1,2-Benzenediol (pyrocatechol)

Cas:120-80-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Pyrocatechol supplier in China

Cas:120-80-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

High purity Pyrocatechol 98% TOP1 supplier in China

Cas:120-80-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance White granules White granules Assay

High purity Pyrocatechol with high quality cas:120-80-9

Cas:120-80-9

Min.Order:1 Kilogram

FOB Price: $5.0 / 11.0

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product description: Product name Pyrocatechol CAS number 120-80-9 Assay ≥99% Appearance Off-white to light gray crystal Capacity 500mt/year Application Rubber hardener, elec

Pyrocatechol

Cas:120-80-9

Min.Order:100 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Hefei TNJ chemical industry co.,ltd

1,ISO Certificate 2,Factory price 3,Free sample and Fast delivery Appearance:White flakes Storage:Storage: All products should be stored at a dry and ventilated location away from fire and other dangerous goods, and should avoid direct sunlight. Pa

Pyrocatechol,CAS 120-80-9

Cas:120-80-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

The company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:White or off-white Solid Storage:Sealed, dr

Catechol

Cas:120-80-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Pyrocatechol

Cas:120-80-9

Min.Order:1

Negotiable

Type:Other

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shanghai Tauto Biotech Co., Ltd

17-year experience in Phytochemicals Each product has passed very strict tests (NMR\MS\HPLC) Agents in 13 countries Certified by ISO 9001:2008 quality management system Leader Supplier of Botanical Reference Materials in China

Catechol

Cas:120-80-9

Min.Order:10 Milligram

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

Pyrocatechol

Cas:120-80-9

Min.Order:1 Kilogram

FOB Price: $6.0 / 7.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Pyrocatechol

Cas:120-80-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

Pyrocatechol

Cas:120-80-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: Pyrocatechol Synonyms: 1,2-Benzenediol (pyrocatechol);1,2-benzenediol[qr];1,2-dihydroxybenzene[qr];2-Hydroxyphenol;2-hydroxyphenol[qr];ai3-03995[qr];Benzene, o-dihydroxy-;benzene,1,2-dihydroxy- CAS: 120-80-9 M

120-80-9 Pyrocatechol

Cas:120-80-9

Min.Order:1 Kilogram

FOB Price: $8900.0

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Appearance: Light gray to light brown crystal . Molecular Formula : C6H6O2 . Molecular weight :110.11. Solubility: Soluble in water, soluble in ethanol, ethyl ether. Application: 1,anti-microbial raw material. 2, Used

Catechol

Cas:120-80-9

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:off-white to similar to white powder Storage:Store in sealed

High purity Pyrocatechol or Catechol CAS NO. 120-80-9

Cas:120-80-9

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pyrocatechol

Cas:120-80-9

Min.Order:1 Kilogram

FOB Price: $1006.0

Type:Trading Company

inquiry

Triumph International Development Limilted

Appearance:white or yellowish white flaky crystal Storage:Keep the sun from direct sunlight ;prevention against high temperature Package:As customer request Application:Used for research and industrial manufacture. Transportatio

Catechol

Cas:120-80-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Pyrocatechol

Cas:120-80-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Pyrocatechol

Cas:120-80-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

PYROCATECHOL

Cas:120-80-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Pyrocatechol

Cas:120-80-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediates Tr

Pyrocatechol

Cas:120-80-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

High purity Pyrocatechol

Cas:120-80-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

PyrocatecholCAS NO.: 120-80-9

Cas:120-80-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

Catechol

Cas:120-80-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Catechol

Cas:120-80-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/Pyrocatechol

Cas:120-80-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beijing Greenchem Technology Co.,Ltd. ( Panjin Greenchem Technology Co.Ltd .)

Capability on chemical synthesis1. Beijing High-Tech Enterprises2. Strong R&D Team3. 8 years of experiences in R & D of high-tech Catalyst;4. 5000 production techniques, 69 items of national patents, and 360 kinds of products on sales;5. The producti

Pyrocatechol

Cas:120-80-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Catechol

Cas:120-80-9

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Pyrocatechol

Cas:120-80-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

phenol
108-95-2

phenol

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With dihydrogen peroxide; MgAlZr0.1-HT In Petroleum ether at 79.9℃; for 8h;100%
With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione In methanol; chloroform at -25℃; for 0.333333h;97%
With tert.-butylhydroperoxide In water; acetonitrile at 70℃; for 6h; Catalytic behavior; Temperature; Solvent;89%
1,3-benzodioxol-2-one
2171-74-6

1,3-benzodioxol-2-one

isopropyl alcohol
67-63-0

isopropyl alcohol

A

bis-2-propyl carbonate
6482-34-4

bis-2-propyl carbonate

B

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With sodium methylate In neat (no solvent) at 100℃; under 1500.15 Torr; for 5h; Inert atmosphere; Autoclave;A 67%
B 100%
With sodium methylate at 100℃; for 5h; Temperature; Autoclave; Inert atmosphere;A 90 %Chromat.
B n/a
Methylenedioxybenzene
274-09-9

Methylenedioxybenzene

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With 1,3-dimethyl-2-imidazolidinone; sodium hexamethyldisilazane In tetrahydrofuran at 185℃; for 12h; further reagent: LDA;99%
With sodium di(ethyl)amine In N,N,N,N,N,N-hexamethylphosphoric triamide; benzene for 12h; Heating;85%
With aluminium(III) iodide In carbon disulfide for 7h; Heating; Var. solvent, time and substrate reagent ratio;80%
2-methoxy-phenol
90-05-1

2-methoxy-phenol

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
Stage #1: 2-methoxy-phenol With pyridine; iodine; aluminium In acetonitrile for 18h; Reflux;
Stage #2: With hydrogenchloride In water; acetonitrile at 20℃;
99%
With hydrogenchloride In water at 250℃; under 37503.8 Torr; for 3h; Reagent/catalyst; Autoclave; Inert atmosphere; Green chemistry;97%
With aluminium(III) iodide; calcium oxide In acetonitrile at 80℃; for 18h; Reagent/catalyst;94%
2,2-dimethyl-1,3-benzodioxole
14005-14-2

2,2-dimethyl-1,3-benzodioxole

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 18h; Catalytic behavior; Reagent/catalyst; Solvent;99%
With indium(III) triflate In water; acetonitrile at 120℃; for 0.5h; Microwave irradiation;91%
With sodium di(ethyl)amine In N,N,N,N,N,N-hexamethylphosphoric triamide; benzene for 12h; Heating;88%
6H,11H-dibenzo<14>dioxocin
116915-91-4

6H,11H-dibenzo<14>dioxocin

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With hydrogen; palladium hydroxide - carbon In ethanol under 760 Torr;99%
1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With glycolic Acid; copper hydroxide; sodium hydroxide In water; dimethyl sulfoxide at 120℃; for 6h; Inert atmosphere; Schlenk technique;99%
With β-D-glucose; copper(II) acetate monohydrate; potassium hydroxide In water; dimethyl sulfoxide at 20 - 120℃; for 16h;83%
salicylaldehyde
90-02-8

salicylaldehyde

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With dihydrogen peroxide at 20℃; for 0.666667h; Time; Dakin Phenol Oxidation; Green chemistry;98%
With dihydrogen peroxide In water at 20℃; for 2h; Dakin Phenol Oxidation; Green chemistry;98%
With 7,8-difluoro-1,3-dimethyl-5-ethyl-4a-hydroperoxyalloxazine; dihydrogen peroxide; sodium hydrogencarbonate In methanol; water at 20℃; for 1h; Dakin oxidation;92%
1,2-bis(trimethylsilyloxy)benzene
5075-52-5

1,2-bis(trimethylsilyloxy)benzene

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With methanol; 1,3-disulfonic acid imidazolium hydrogen sulfate at 20℃; for 0.0666667h; Green chemistry;98%
2-ethoxyanisole
17600-72-5

2-ethoxyanisole

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With hydrogenchloride In water at 250℃; under 37503.8 Torr; for 3h; Autoclave; Inert atmosphere; Green chemistry;98%
With water; hydrogen bromide; Aliquat 336 at 105℃; for 9h; Catalytic behavior;72%
1,2-dimethoxybenzene
91-16-7

1,2-dimethoxybenzene

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With 1,3-dimethyl-2-imidazolidinone; lithium diisopropyl amide In tetrahydrofuran; n-heptane; ethylbenzene at 185℃; for 12h;97%
With hydrogen iodide at 25℃; for 24h; Inert atmosphere;96%
With aluminium(III) iodide In acetonitrile for 0.5h; Heating; Var. solvent, time and substrate reagent ratio;93%
1-(4-hydroxy-3-methoxyphenyl)propan-1-ol
6997-34-8

1-(4-hydroxy-3-methoxyphenyl)propan-1-ol

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With hydrogenchloride In water at 250℃; under 37503.8 Torr; for 3h; Sealed tube; Inert atmosphere;97%
2-Iodophenol
533-58-4

2-Iodophenol

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With copper(l) iodide; 8-quinolinol; potassium hydroxide In water; dimethyl sulfoxide; tert-butyl alcohol at 100℃; for 48h; Inert atmosphere;95%
Stage #1: 2-Iodophenol With copper(l) iodide; 1,10-Phenanthroline; potassium hydroxide In water; dimethyl sulfoxide at 20 - 100℃; Inert atmosphere;
Stage #2: With hydrogenchloride In water; dimethyl sulfoxide at 20℃; Inert atmosphere;
86%
With basolite C300; potassium hydroxide In water; dimethyl sulfoxide at 125℃; for 12h;84%
2-Ethoxyphenol
94-71-3

2-Ethoxyphenol

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With aluminium(III) iodide In dimethyl sulfoxide; acetonitrile at 80℃; for 18h;95%
With aluminium(III) iodide; dimethyl sulfoxide In acetonitrile at 80℃; for 18h;95%
With aluminium(III) iodide; N,N-dimethyl-formamide dimethyl acetal In acetonitrile at 80℃; for 18h;72%
With aluminium(III) iodide; N,N-dimethyl-formamide dimethyl acetal In acetonitrile at 80℃; for 18h;72%
With oxygen; copper(II) perchlorate; ascorbic acid In water; acetone at 60℃; for 20h;25%
2-allyloxyphenol
1126-20-1

2-allyloxyphenol

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With boron dimethyl-trifluoro sulphide In dichloromethane at 0℃; for 0.0833333h;95%
2-hydroxyphenyl boronic acid
89466-08-0

2-hydroxyphenyl boronic acid

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With ammonium bicarbonate In water at 20℃; for 2h; Schlenk technique;95%
2-(2-phenylethoxy)phenol
33130-24-4

2-(2-phenylethoxy)phenol

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With aluminium(III) iodide In dimethyl sulfoxide; acetonitrile at 80℃; for 18h;95%
With aluminium(III) iodide; dimethyl sulfoxide In acetonitrile at 80℃; for 18h;95%
With aluminium(III) iodide In dimethyl sulfoxide; acetonitrile at 80℃; for 18h;93%
N-(phenoxy)acetamide
5661-50-7

N-(phenoxy)acetamide

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; malonic acid In methanol at 25℃; for 12h; Catalytic behavior; Reagent/catalyst; Temperature; Solvent; Inert atmosphere;95%
2-Isopropoxyphenol
4812-20-8

2-Isopropoxyphenol

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With aluminium(III) iodide; diisopropyl-carbodiimide In acetonitrile at 80℃; for 18h;94%
With aluminium(III) iodide; diisopropyl-carbodiimide In acetonitrile at 80℃; for 18h;94%
With aluminium(III) iodide; calcium oxide In acetonitrile at 80℃; for 18h;94%
2-bromo-6-hydroxycyclohex-2-en-1-one

2-bromo-6-hydroxycyclohex-2-en-1-one

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene93%
O-benzylcatechol
6272-38-4

O-benzylcatechol

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With aluminium(III) iodide; dimethyl sulfoxide In acetonitrile at 80℃; for 18h;93%
With aluminium(III) iodide; N,N-dimethyl-formamide dimethyl acetal In acetonitrile at 80℃; for 18h;63%
With aluminium(III) iodide; N,N-dimethyl-formamide dimethyl acetal In acetonitrile at 80℃; for 18h;63%
3,4-Dihydroxybenzoic acid
99-50-3

3,4-Dihydroxybenzoic acid

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With Na-X zeolite In water at 200℃; for 1h; Autoclave;91%
With Cocos nucifera juice at 20℃; for 48h; Inert atmosphere;88%
With cucumber juice at 30 - 35℃; for 48h; Inert atmosphere; Green chemistry;85%
4-tert-Butylcatechol
98-29-3

4-tert-Butylcatechol

A

4-tert-butyltoluene
98-51-1

4-tert-butyltoluene

B

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With Nafion-H; toluene for 2h; Heating;A 97 % Chromat.
B 91%
4-tert-Butylcatechol
98-29-3

4-tert-Butylcatechol

toluene
108-88-3

toluene

A

4-tert-butyltoluene
98-51-1

4-tert-butyltoluene

B

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With Nafion-H for 2h; Heating;A 97 % Chromat.
B 91%
4-oxo-cyclohexyl 2,2-dimethylpropanoate
165105-99-7

4-oxo-cyclohexyl 2,2-dimethylpropanoate

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With iodine; oxygen; dimethyl sulfoxide at 80℃; for 12h;91%
ortoquinone
583-63-1

ortoquinone

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With aluminium(III) iodide In acetonitrile for 1h; Heating;90%
With sulphurous acid
Rate constant; pH 7.00; reaction with substrate reduced glucose oxidase;
o-hydroxyacetophenone
118-93-4

o-hydroxyacetophenone

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With sodium percarbonate In tetrahydrofuran; water; N,N-dimethyl-formamide for 8h; ultrasonication;90%
With sulfuric acid; dihydrogen peroxide; boric acid In tetrahydrofuran; water at 20℃; for 36h; Oxidation;90%
1-acetoxy-6-oxocyclohexa-2,4-dienyl propanoate
75724-54-8

1-acetoxy-6-oxocyclohexa-2,4-dienyl propanoate

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether for 1h; Heating;90%
3,4-dihydro-2H-benzo[b][1,4]dioxepine
7216-18-4

3,4-dihydro-2H-benzo[b][1,4]dioxepine

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Conditions
ConditionsYield
With aluminum (III) chloride In benzene for 4h; Solvent; Time; Temperature; Reflux;90%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

Phenazin
92-82-0

Phenazin

Conditions
ConditionsYield
In water at 210℃; for 0.25h; Microwave irradiation;100%
at 200℃;
at 200 - 210℃; in geschlossenen Rohr;
With potassium dichromate; acetic acid for 24h; Reflux;
benzene-1,2-diol
120-80-9

benzene-1,2-diol

phenylboronic acid
98-80-6

phenylboronic acid

2-phenyl-1,3,2-benzodioxaborole
5747-23-9

2-phenyl-1,3,2-benzodioxaborole

Conditions
ConditionsYield
at 80℃; for 1h;100%
for 0.166667h; Schlenk technique;96%
In dichloromethane; ethyl acetate at 20℃;81%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

1-bromo-3,4-dihydroxybenzene
17345-77-6

1-bromo-3,4-dihydroxybenzene

Conditions
ConditionsYield
With benzyltriphenylphosphonium peroxodisulfate; potassium bromide In acetonitrile for 3.5h; Heating;100%
With tetrafluoroboric acid diethyl ether; N-Bromosuccinimide In acetonitrile at -30 - 20℃;100%
With N-Bromosuccinimide; tetrafluoroboric acid In diethyl ether; acetonitrile regioselective reaction;100%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

ortoquinone
583-63-1

ortoquinone

Conditions
ConditionsYield
With 2,2'-bipyridylchromium peroxide In benzene for 0.5h; Product distribution; Heating; effect of various chromium(VI) based oxidants;100%
With barium ferrate(VI) In benzene for 0.7h; Product distribution; Heating;100%
With 2,2'-bipyridylchromium peroxide In benzene for 0.5h; Heating;100%
dichloromethylenedimethyliminium chloride
33842-02-3, 529510-96-1

dichloromethylenedimethyliminium chloride

benzene-1,2-diol
120-80-9

benzene-1,2-diol

Benzo[1,3]dioxol-2-ylidene-dimethyl-ammonium; chloride
36156-21-5

Benzo[1,3]dioxol-2-ylidene-dimethyl-ammonium; chloride

Conditions
ConditionsYield
at -20℃; for 1h; ball mill;100%
In dichloromethane for 1h; Heating;
benzene-1,2-diol
120-80-9

benzene-1,2-diol

1-dodecylbromide
143-15-7

1-dodecylbromide

1,2-bisdodecyloxybenzene
42244-53-1

1,2-bisdodecyloxybenzene

Conditions
ConditionsYield
With potassium carbonate In acetone for 48h; Williamson ether synthesis; Reflux;100%
With potassium carbonate In acetone for 48h; Heating;95%
With potassium carbonate; potassium iodide In acetone for 48h; Reflux;95%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

ethyl bromoacetate
105-36-2

ethyl bromoacetate

ethyl 2-<2-<(ethoxycarbonyl)methoxy>phenoxy>acetate
52376-09-7

ethyl 2-<2-<(ethoxycarbonyl)methoxy>phenoxy>acetate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 60℃; for 120h;100%
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In acetonitrile for 8h; Heating;95%
With potassium carbonate In N,N-dimethyl-formamide at 75 - 80℃; for 1.5h;90%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

1-(benzenesulfonyl)-3-methylimidazolium triflate
142841-88-1

1-(benzenesulfonyl)-3-methylimidazolium triflate

1,2-bis<(benzenesulfonyl)oxy>benzene
3905-43-9

1,2-bis<(benzenesulfonyl)oxy>benzene

Conditions
ConditionsYield
With 1-methyl-1H-imidazole In tetrahydrofuran 1) 0 deg C, 30 min, 2) RT, 6 h;100%
(3-methyl-2-butenyl)trimethoxysilane
72142-16-6

(3-methyl-2-butenyl)trimethoxysilane

benzene-1,2-diol
120-80-9

benzene-1,2-diol

triethylamine
121-44-8

triethylamine

triethylammonium bis(catecholato)(3-methyl-2-butenyl)siliconate
114571-77-6

triethylammonium bis(catecholato)(3-methyl-2-butenyl)siliconate

Conditions
ConditionsYield
at 45℃; for 5h;100%
allyltrimethoxysilane
2551-83-9

allyltrimethoxysilane

benzene-1,2-diol
120-80-9

benzene-1,2-diol

triethylamine
121-44-8

triethylamine

triethylammonium bis(pyrocatecholato)allylsilicate
114612-18-9

triethylammonium bis(pyrocatecholato)allylsilicate

Conditions
ConditionsYield
for 5h; room temperature to 40 deg C;100%
at 40℃; for 4h; Inert atmosphere; Sealed tube;55%
(2-methyl-2-propenyl)trimethoxysilane
125715-25-5

(2-methyl-2-propenyl)trimethoxysilane

benzene-1,2-diol
120-80-9

benzene-1,2-diol

triethylamine
121-44-8

triethylamine

triethylammonium bis(catecholato)(2-methyl-2-propenyl)siliconate
125715-30-2

triethylammonium bis(catecholato)(2-methyl-2-propenyl)siliconate

Conditions
ConditionsYield
at 45℃; for 5h;100%
2-Butenyltrimethoxysilane
13436-83-4

2-Butenyltrimethoxysilane

benzene-1,2-diol
120-80-9

benzene-1,2-diol

triethylamine
121-44-8

triethylamine

triethylammonium bis(catecholato)-2-butenylsiliconate

triethylammonium bis(catecholato)-2-butenylsiliconate

Conditions
ConditionsYield
at 45℃; for 5h;100%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

1,1-dichloro-5-aza-2,8-dioxa-1-phosphaV-dibenzo<9,9',11,11'-tetra-tert-butyl>-bicyclo<3.3.0>octadiene
161868-74-2

1,1-dichloro-5-aza-2,8-dioxa-1-phosphaV-dibenzo<9,9',11,11'-tetra-tert-butyl>-bicyclo<3.3.0>octadiene

C34H44NO4P

C34H44NO4P

Conditions
ConditionsYield
In benzene for 24h; Ambient temperature;100%
3,4-Difluorobenzonitrile
64248-62-0

3,4-Difluorobenzonitrile

benzene-1,2-diol
120-80-9

benzene-1,2-diol

2-cyanodibenzo[1,4]dioxine
234113-44-1

2-cyanodibenzo[1,4]dioxine

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide; toluene at 125 - 130℃;100%
With potassium carbonate In N,N-dimethyl-formamide; toluene at 130 - 135℃; Etherification; cyclization;98%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

C6-C4 carboxylic acids; C6-C4 aldehydes; C6-C4 ketones; mixture of

C6-C4 carboxylic acids; C6-C4 aldehydes; C6-C4 ketones; mixture of

Conditions
ConditionsYield
With ozone In water at 20℃; for 0.1h; pH=2; Oxidation; Formation of xenobiotics;100%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

triphenyl(1,2-phenylenedioxy)phosphorane
62785-50-6

triphenyl(1,2-phenylenedioxy)phosphorane

Conditions
ConditionsYield
at 70 - 80℃; for 2h;100%
(E)-(2-(phenyldiazenyl)phenyl)boronic acid
866252-03-1

(E)-(2-(phenyldiazenyl)phenyl)boronic acid

benzene-1,2-diol
120-80-9

benzene-1,2-diol

2-[2-(phenylazo)phenyl]-1,3,2-benzodioxaborole

2-[2-(phenylazo)phenyl]-1,3,2-benzodioxaborole

Conditions
ConditionsYield
In toluene for 4h; Heating;100%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

tetraethylene glycol monoacrylate
19812-60-3

tetraethylene glycol monoacrylate

CH2CHC(O)(OCH2CH2)4OB(O2C6H4)

CH2CHC(O)(OCH2CH2)4OB(O2C6H4)

Conditions
ConditionsYield
Stage #1: benzene-1,2-diol With Trimethyl borate In acetonitrile at 60℃; for 1h;
Stage #2: tetraethylene glycol monoacrylate In acetonitrile for 2h; Further stages.;
100%
diethylzinc
557-20-0

diethylzinc

benzene-1,2-diol
120-80-9

benzene-1,2-diol

A

ethane
74-84-0

ethane

B

zinc pyrocatecholate
10586-34-2

zinc pyrocatecholate

Conditions
ConditionsYield
react. of the educts in a molar ratio of 1:1;A 100%
B n/a
boric acid
11113-50-1

boric acid

benzene-1,2-diol
120-80-9

benzene-1,2-diol

triphenylhydroxysilane
791-31-1

triphenylhydroxysilane

2-triphenylsiloxy-1,3,2-benzodioxaborole
82172-55-2

2-triphenylsiloxy-1,3,2-benzodioxaborole

Conditions
ConditionsYield
In benzene byproducts: H2O; azeotropic removal of water; elem. anal.;100%
Trimethyl borate
121-43-7

Trimethyl borate

benzene-1,2-diol
120-80-9

benzene-1,2-diol

tetraethylene glycol monoacrylate
19812-60-3

tetraethylene glycol monoacrylate

CH2CHC(O)(OCH2CH2)4OB(O2C6H4)

CH2CHC(O)(OCH2CH2)4OB(O2C6H4)

Conditions
ConditionsYield
In acetonitrile stirring of catechol and B(OMe)3 at 60 °C for 1h, addn of tetraethylene glycol monoacrylate, 2 h stirring; cooling, vac. evapn. at 40 °C for 24 h;100%
(E)-dihydroxy(2-{[4-(trifluoromethyl)phenyl]azo}phenyl)borane
1048382-97-3

(E)-dihydroxy(2-{[4-(trifluoromethyl)phenyl]azo}phenyl)borane

benzene-1,2-diol
120-80-9

benzene-1,2-diol

(E)-2-(2-{[4-(trifluoromethyl)phenyl]azo}phenyl)-1,3,2-benzodioxaborole

(E)-2-(2-{[4-(trifluoromethyl)phenyl]azo}phenyl)-1,3,2-benzodioxaborole

Conditions
ConditionsYield
In toluene for 16h; Heating;100%
benzene-1,2-diol
120-80-9

benzene-1,2-diol

N-cyclohexyl-cyclohexanamine
101-83-7

N-cyclohexyl-cyclohexanamine

N-(trimethoxysilylmethyl)hexahydroazepin-2-one
76128-65-9

N-(trimethoxysilylmethyl)hexahydroazepin-2-one

dicyclohexylammonium bis(1,2-catecholato-O,O')-[(2-oxohexahydroazepin-1-yl)methyl-C,O]silicate

dicyclohexylammonium bis(1,2-catecholato-O,O')-[(2-oxohexahydroazepin-1-yl)methyl-C,O]silicate

Conditions
ConditionsYield
In o-xylene at 130 - 140℃;100%
triethylene glucol monomethyl ether
112-35-6

triethylene glucol monomethyl ether

lithium tetramethanolatoborate
6867-35-2

lithium tetramethanolatoborate

benzene-1,2-diol
120-80-9

benzene-1,2-diol

C20H34BO10(1-)*Li(1+)

C20H34BO10(1-)*Li(1+)

Conditions
ConditionsYield
Stage #1: triethylene glucol monomethyl ether; lithium tetramethanolatoborate for 24h; Reflux; Inert atmosphere;
Stage #2: benzene-1,2-diol for 24h; Reflux; Inert atmosphere;
100%
9,9-didodecylfluorene-2,7-diboronic acid
480424-86-0

9,9-didodecylfluorene-2,7-diboronic acid

benzene-1,2-diol
120-80-9

benzene-1,2-diol

C49H64B2O4
1446012-94-7

C49H64B2O4

Conditions
ConditionsYield
In toluene Reflux; Inert atmosphere;100%
boric acid
11113-50-1

boric acid

benzene-1,2-diol
120-80-9

benzene-1,2-diol

tris(catecholato)diboron
37737-62-5

tris(catecholato)diboron

Conditions
ConditionsYield
In toluene Dean-Stark; Reflux;100%
2,2'-dihydroxy-1,1'-binaphthyl-3,3'-diboronic acid

2,2'-dihydroxy-1,1'-binaphthyl-3,3'-diboronic acid

benzene-1,2-diol
120-80-9

benzene-1,2-diol

C32H20B2O6

C32H20B2O6

Conditions
ConditionsYield
With sodium sulfate In toluene at 50℃; Reflux;100%
Trimethyl orthoacetate
1445-45-0

Trimethyl orthoacetate

benzene-1,2-diol
120-80-9

benzene-1,2-diol

o-(1-methoxyethoxy)-phenol
51487-87-7

o-(1-methoxyethoxy)-phenol

Conditions
ConditionsYield
With trifluoroacetic acid In dimethylsulfoxide-d6 at 20℃; for 1h;100%
Triisopropyl borate
5419-55-6

Triisopropyl borate

benzene-1,2-diol
120-80-9

benzene-1,2-diol

C23H22BNO3

C23H22BNO3

Conditions
ConditionsYield
In toluene at 80℃; for 1h; Inert atmosphere;100%
Stage #1: Triisopropyl borate; benzene-1,2-diol In toluene Inert atmosphere; Reflux;
Stage #2: (S)-diphenylprolinol In toluene at 80℃; for 1h; Inert atmosphere; Reflux;
100%
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