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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 3,3-Dimethylacrylic acid methyl( 924-50-5)

Cas:924-50-5

Min.Order:100 Metric Ton

Negotiable

Type:Other

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Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and

Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:1 Gram

Negotiable

Type:Other

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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Methyl 3-methyl-2-butenoate Manufacturer/High quality/Best price/In stock

Cas:924-50-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methyl 3-Methyl-2-Butenoate supplier in China

Cas:924-50-5

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:1

Negotiable

Type:Other

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EAST CHEMSOURCES LIMITED

Organic synthesis, Intermediate of pesticides Appearance:Colorless liquid Storage:Stored in the ventilated, low temperature and dry room away from direct sunlight. Package:200kg/drum Application:Organic synthesis, Intermediate of pesticides Port:QIN

Methyl 3,3-dimethylacrylate

Cas:924-50-5

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Senecioic acid methyl ester

Cas:924-50-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scient

TIANFU-CHEM Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:1 Gram

FOB Price: $120.0 / 150.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 924-50-5 with competitive price

Cas:924-50-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name Methyl 3-methyl-2-butenoate Synonyms Methyl 3-methyl-2-butenoate;Crotonic acid CAS: 924-50-5 MF: - MW: - EINECS:

Methyl 3,3-dimethylacrylate CAS:924-50-5

Cas:924-50-5

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Methyl 3-methyl-2-butenoate 924-50-5

Cas:924-50-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Methylene-bis(4-cyclohexylisocyanate) 99%

Cas:924-50-5

Min.Order:1 Kilogram

FOB Price: $90.0 / 95.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Methyl 3-methyl-2-butenoate CAS:924-50-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organi

Methyl 3-methyl-2-butenoate CAS:924-50-5

Cas:924-50-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:924-50-5

Cas:924-50-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methyl 3-Methyl-2-Butenoate

Cas:924-50-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3,3-Dimethyl Acrylic Acid Methyl Ester

Cas:924-50-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

METHYL-3.3 3-DIMETHYL ACRYLATE

Cas:924-50-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Methyl 3-methyl-2-butenoate/High quality/Best price

Cas:924-50-5

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Methyl 3-methyl-2-butenoate CAS NO.924-50-5

Cas:924-50-5

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

Methyl 3-methyl-2-butenoateAppearance:Pls see the Details Storage:Keep away of light, hot, water, Store in dry, dark and ventilated place Package:according to customers' requirements Application:Steroids, Cosmetics Ingredients, APIs, Intermediates, O

Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Methyl3-methyl-2-butenoate

Cas:924-50-5

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api, intermediat

Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:1 Kilogram

FOB Price: $777.0 / 888.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: Methyl 3,3-Dimethylacrylate CAS No.: 924-50-5 Molecule Formula:C6H10O2 Molecule Weight:114.14 Purity: 98.5% Package: 25kg/drum Description: Colorless to yellow liquid Manufacture Standards:Enterprise Standard

High Quality Methyl 3,3-Dimethylacrylate

Cas:924-50-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:Methyl 3-methyl-2-butenoate CAS No:924

Methyl 3-methyl-2-butenoate

Cas:924-50-5

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Synthetic route

methanol
67-56-1

methanol

3-Methylbutenoic acid
541-47-9

3-Methylbutenoic acid

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Conditions
ConditionsYield
With [1-(3-sulfonic acid)]propyl-3-methylimidazolium hydrogen sulfate for 3h; Reflux; Green chemistry;97.8%
With sulfuric acid95%
With sulfuric acid for 16h; Heating;92%
tert-butyl(1-methoxyvinyl)dimethylsilane
105245-42-9

tert-butyl(1-methoxyvinyl)dimethylsilane

acetone
67-64-1

acetone

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Conditions
ConditionsYield
Stage #1: tert-butyl(1-methoxyvinyl)dimethylsilane; acetone With C40H61Al3O3 In acetonitrile at 0 - 5℃; for 72h; Mukaiyama Aldol Addition;
Stage #2: With hydrogenchloride In water; acetonitrile at 20℃; for 3h; Mukaiyama Aldol Addition;
90%
methanol
67-56-1

methanol

C9H18ClNO3
135765-56-9

C9H18ClNO3

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

β-(N-methoxy-N-isopropoxyamino)-isovaleric acid methyl ester
82004-48-6

β-(N-methoxy-N-isopropoxyamino)-isovaleric acid methyl ester

Conditions
ConditionsYield
With triethylamine 1.) -20 deg C, 6 h, 2.) 20 deg C, 1 h;A 14%
B 86%
(E)-4-bromo-3-methyl-2-butenoic acid methyl ester
27652-13-7, 50465-52-6, 19041-17-9

(E)-4-bromo-3-methyl-2-butenoic acid methyl ester

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

(E)-5-Isopropenyl-3-methyl-hex-2-enedioic acid dimethyl ester
91664-11-8

(E)-5-Isopropenyl-3-methyl-hex-2-enedioic acid dimethyl ester

Conditions
ConditionsYield
With zinc In dimethyl sulfoxide for 4h;A 10%
B 68%
(Z)-methyl-β-bromomethyl-β-methylacrylate
27652-13-7

(Z)-methyl-β-bromomethyl-β-methylacrylate

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

(Z)-5-Isopropenyl-3-methyl-hex-2-enedioic acid dimethyl ester
91664-12-9

(Z)-5-Isopropenyl-3-methyl-hex-2-enedioic acid dimethyl ester

Conditions
ConditionsYield
With zinc In dimethyl sulfoxide for 4h;A 10%
B 67%
β-(N-chloro-N-methoxyamino)-isovaleric acid methyl ester
70569-70-9

β-(N-chloro-N-methoxyamino)-isovaleric acid methyl ester

isobutene
115-11-7

isobutene

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

β-isovaleric acid methyl ester
135765-48-9

β-isovaleric acid methyl ester

Conditions
ConditionsYield
With sulfur dioxide 1.) 7 deg C, 24 h, 2.) 20 deg C, 2 h;A 13%
B 67%
2,2,3,3-tetracyano-4,4-dimethylcyclopentanone dimethyl acetal
76430-13-2

2,2,3,3-tetracyano-4,4-dimethylcyclopentanone dimethyl acetal

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

methyl 3,3-dimethyl-4,5,5-tricyano-4-pentenoate
76430-21-2

methyl 3,3-dimethyl-4,5,5-tricyano-4-pentenoate

C

methyl 3,3-dimethyl-4,4,5,5-tetracyanopentanoate
76430-18-7

methyl 3,3-dimethyl-4,4,5,5-tetracyanopentanoate

Conditions
ConditionsYield
With water In acetonitrile at 80℃; for 12h;A n/a
B n/a
C 63%
(2-Trifluoromethanesulfonyl-pentane-2-sulfonyl)-acetic acid methyl ester
101146-22-9

(2-Trifluoromethanesulfonyl-pentane-2-sulfonyl)-acetic acid methyl ester

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane; water62%
β-(N,N-dimethoxyamino)-isovaleric acid methyl ester
70569-71-0

β-(N,N-dimethoxyamino)-isovaleric acid methyl ester

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

3-(2-Methoxycarbonyl-1,1-dimethyl-ethyl-NNO-azoxy)-3-methyl-butyric acid methyl ester
80552-91-6

3-(2-Methoxycarbonyl-1,1-dimethyl-ethyl-NNO-azoxy)-3-methyl-butyric acid methyl ester

Conditions
ConditionsYield
With triethylamine hydrochloride In chloroform for 126h; Product distribution; Heating; various acyclic N,N-dialkoxyamines;A 15%
B 51.9%
methyl 2-diazo-3-methylbutanoate
63282-42-8

methyl 2-diazo-3-methylbutanoate

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Conditions
ConditionsYield
at 400℃; under 0.001 - 0.1 Torr;47%
methanol
67-56-1

methanol

4,4-dimethyl-2-(2-propylidene)-3-thietanone
74966-50-0

4,4-dimethyl-2-(2-propylidene)-3-thietanone

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

4-Isopropylidene-5-methoxy-2,2-dimethyl-[1,3]oxathiolane
74966-53-3

4-Isopropylidene-5-methoxy-2,2-dimethyl-[1,3]oxathiolane

Conditions
ConditionsYield
In methanol for 3h; Irradiation;A 28%
B 22%
3-diazo-2,2,5,5-tetramethylthiolan-4-one
74966-46-4

3-diazo-2,2,5,5-tetramethylthiolan-4-one

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

2,2,4,4-Tetramethyl-thietane-3-carboxylic acid methyl ester
74966-52-2

2,2,4,4-Tetramethyl-thietane-3-carboxylic acid methyl ester

C

4-Isopropylidene-5-methoxy-2,2-dimethyl-[1,3]oxathiolane
74966-53-3

4-Isopropylidene-5-methoxy-2,2-dimethyl-[1,3]oxathiolane

Conditions
ConditionsYield
In methanol Irradiation;A 19%
B 28%
C 14%
4,4-dimethyl-2-(2-propylidene)-3-thietanone
74966-50-0

4,4-dimethyl-2-(2-propylidene)-3-thietanone

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

4-Isopropylidene-5-methoxy-2,2-dimethyl-[1,3]oxathiolane
74966-53-3

4-Isopropylidene-5-methoxy-2,2-dimethyl-[1,3]oxathiolane

Conditions
ConditionsYield
In methanol Irradiation;A 28%
B 22%
methanol
67-56-1

methanol

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

2,2,4,4-Tetramethyl-thietane-3-carboxylic acid methyl ester
74966-52-2

2,2,4,4-Tetramethyl-thietane-3-carboxylic acid methyl ester

C

4-Isopropylidene-5-methoxy-2,2-dimethyl-[1,3]oxathiolane
74966-53-3

4-Isopropylidene-5-methoxy-2,2-dimethyl-[1,3]oxathiolane

Conditions
ConditionsYield
Irradiation;A 19%
B 27.8%
C 14%
β-(N-chloro-N-methoxyamino)-isovaleric acid methyl ester
70569-70-9

β-(N-chloro-N-methoxyamino)-isovaleric acid methyl ester

acetonitrile
75-05-8

acetonitrile

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

methyl β-(Nacetylamino)isovalerate
43135-04-2

methyl β-(Nacetylamino)isovalerate

Conditions
ConditionsYield
With silver fluoride at -78℃; for 15h;A n/a
B 27.8%
methyl 2-bromo-3-methylbutanoic ester
69367-52-8, 70332-52-4, 114528-93-7, 26330-51-8

methyl 2-bromo-3-methylbutanoic ester

A

2-pyrrolidinon
616-45-5

2-pyrrolidinon

B

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

C

trimethylsilyl bromide
2857-97-8

trimethylsilyl bromide

Conditions
ConditionsYield
With N-trimethylsilyl-pyrrolidin-2-one at 165 - 195℃; for 3h; Yields of byproduct given;A n/a
B 27%
C n/a
methyl (2,2-dimethyl-3-oxocyclobutyl)acetate
27830-36-0

methyl (2,2-dimethyl-3-oxocyclobutyl)acetate

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

methyl 2-(2,2-dimethyl-5-oxotetrahydrofuran-3-yl)acetate
38306-10-4

methyl 2-(2,2-dimethyl-5-oxotetrahydrofuran-3-yl)acetate

C

Methyl 2,2-dimethyl-4,5-dihydro-3-furanacetate
121757-31-1

Methyl 2,2-dimethyl-4,5-dihydro-3-furanacetate

D

Methyl 2,2-dimethyl-5-(2,2-dimethyltetrahydro-3-(methoxycarbonyl)furan-5-ylidene)tetrahydro-3-furanacetate
121757-32-2

Methyl 2,2-dimethyl-5-(2,2-dimethyltetrahydro-3-(methoxycarbonyl)furan-5-ylidene)tetrahydro-3-furanacetate

Conditions
ConditionsYield
With 4 A molecular sieve In dichloromethane for 72h; Irradiation; Further byproducts given;A 16%
B n/a
C 12%
D 22%
methanol
67-56-1

methanol

Bromoform
75-25-2

Bromoform

acetone
67-64-1

acetone

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In benzonitrile; acetonitrile at 20℃; for 5h;22%
3,3-dimethyl-4-oxo-oxetane-2-carboxylic acid methyl ester

3,3-dimethyl-4-oxo-oxetane-2-carboxylic acid methyl ester

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

methylammonium carbonate
15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

Conditions
ConditionsYield
bei der Destillation im Vakuum ueber eine rotgluehende Platinspirale;
diethyl ether
60-29-7

diethyl ether

3,4-Dibromo-3-methyl-butan-2-one
85526-21-2

3,4-Dibromo-3-methyl-butan-2-one

sodium methylate
124-41-4

sodium methylate

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

β-methoxy-isovaleric acid methyl ester
56830-25-2

β-methoxy-isovaleric acid methyl ester

methyl 3-methyl-3-butenoate
25859-52-3

methyl 3-methyl-3-butenoate

sodium methylate
124-41-4

sodium methylate

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

β-methoxy-isovaleric acid methyl ester
56830-25-2

β-methoxy-isovaleric acid methyl ester

Conditions
ConditionsYield
With diethyl ether
3,4-Dibromo-3-methyl-butan-2-one
85526-21-2

3,4-Dibromo-3-methyl-butan-2-one

sodium methylate
124-41-4

sodium methylate

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

β-methoxy-isovaleric acid methyl ester
56830-25-2

β-methoxy-isovaleric acid methyl ester

Conditions
ConditionsYield
With diethyl ether anfangs unter Kuehlung;
With diethyl ether
methyl 2-bromo-3-methylbutanoic ester
69367-52-8, 70332-52-4, 114528-93-7, 26330-51-8

methyl 2-bromo-3-methylbutanoic ester

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Conditions
ConditionsYield
With N,N-diethylaniline
methanol
67-56-1

methanol

ethyl 2-acetyl-3-methylbut-2-enoate
35044-52-1

ethyl 2-acetyl-3-methylbut-2-enoate

methyl iodide
74-88-4

methyl iodide

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Conditions
ConditionsYield
With sodium methylate
methanol
67-56-1

methanol

isopropylideneketene
63364-70-5

isopropylideneketene

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Conditions
ConditionsYield
at -196.1℃;
methanol
67-56-1

methanol

methyl (2,2-dimethyl-3-oxocyclobutyl)acetate
27830-36-0

methyl (2,2-dimethyl-3-oxocyclobutyl)acetate

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

(2,2-Dimethyl-cyclopropyl)-essigsaeuremethylester
20602-89-5

(2,2-Dimethyl-cyclopropyl)-essigsaeuremethylester

Methyl (3R*,5S*)-5-methoxy-2,2-dimethyltetrahydro-3-furanacetate
113371-55-4, 113371-56-5

Methyl (3R*,5S*)-5-methoxy-2,2-dimethyltetrahydro-3-furanacetate

Methyl (3R*,5R*)-5-methoxy-2,2-dimethyltetrahydro-3-furanacetate
113371-55-4, 113371-56-5

Methyl (3R*,5R*)-5-methoxy-2,2-dimethyltetrahydro-3-furanacetate

Conditions
ConditionsYield
for 16h; Irradiation; Yield given. Yields of byproduct given;
3-methyl-but-2-enal dimethyl acetal
31525-65-2

3-methyl-but-2-enal dimethyl acetal

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

3,3-dimethyl acrylaldehyde
107-86-8

3,3-dimethyl acrylaldehyde

C

3-Dimethoxymethyl-2,2-dimethyl-oxirane
87128-47-0

3-Dimethoxymethyl-2,2-dimethyl-oxirane

Conditions
ConditionsYield
With potassium fluoride; sodium fluoride; 3-chloro-benzenecarboperoxoic acid In dichloromethane 1.) 15 h, RT; 2.) 1 h, RT;
β,β-Di(3>methyl)acrylsaeure-methylester
100342-98-1

β,β-Di(3>methyl)acrylsaeure-methylester

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Conditions
ConditionsYield
With potassium hydroxide In methanol
methyl tert-butyl(pivaloyl)acetate
144864-97-1

methyl tert-butyl(pivaloyl)acetate

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

methyl 3,3-dimethylbutyrate
10250-48-3

methyl 3,3-dimethylbutyrate

Conditions
ConditionsYield
at 900℃; under 8E-05 Torr; Product distribution;
methyl tert-butyl(pivaloyl)acetate
144864-97-1

methyl tert-butyl(pivaloyl)acetate

A

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

B

methyl 3,3-dimethylbutyrate
10250-48-3

methyl 3,3-dimethylbutyrate

C

Methyl 4,4-dimethyl-3-oxopentanoate
55107-14-7

Methyl 4,4-dimethyl-3-oxopentanoate

D

isobutene
115-11-7

isobutene

E

malonic acid dimethyl ester
108-59-8

malonic acid dimethyl ester

Conditions
ConditionsYield
at 600℃; under 8E-05 Torr; Product distribution; other temperatures;
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

nonylmagnesium bromide
39691-62-8

nonylmagnesium bromide

methyl 3,3-dimethyldodecanoate

methyl 3,3-dimethyldodecanoate

Conditions
ConditionsYield
With copper(l) iodide; chloro-trimethyl-silane In tetrahydrofuran; diethyl ether at -15 - 20℃;100%
With chloro-trimethyl-silane; copper(l) iodide In tetrahydrofuran at -15 - 20℃;
With copper(l) iodide; chloro-trimethyl-silane In tetrahydrofuran at -15 - 20℃;
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

5,5-dimethylpyrazolidin-3-one
42953-82-2

5,5-dimethylpyrazolidin-3-one

Conditions
ConditionsYield
With hydrazine hydrate In ethanol at 20℃; for 5h; Reflux;99%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Methyl 3-mercaptopropionate
2935-90-2

Methyl 3-mercaptopropionate

3-(2-methoxycarbonyl-ethylsulfanyl)-3-methylbutyric acid methyl ester

3-(2-methoxycarbonyl-ethylsulfanyl)-3-methylbutyric acid methyl ester

Conditions
ConditionsYield
Stage #1: Methyl 3,3-dimethylacrylate With piperidine; N-benzyl-trimethylammonium hydroxide In methanol at 0℃; Inert atmosphere;
Stage #2: Methyl 3-mercaptopropionate at 60℃; for 24h; Inert atmosphere;
97.23%
With piperidine; N-benzyl-trimethylammonium hydroxide In methanol at 0 - 60℃; for 24h; Inert atmosphere;97%
With piperidine; N-benzyl-trimethylammonium hydroxide In methanol at 60℃; for 24h; Michael addition;75%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

3,5-Dimethylphenol
108-68-9

3,5-Dimethylphenol

4,4,5,7-tetramethyl-3,4-dihydrocoumarin
40662-14-4

4,4,5,7-tetramethyl-3,4-dihydrocoumarin

Conditions
ConditionsYield
With methanesulfonic acid at 70℃; for 6h;96%
With sulfuric acid Michael Addition; Reflux;93%
With methanesulfonic acid at 20 - 70℃; for 17h;92%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

tert-butylhydrazine
32064-67-8

tert-butylhydrazine

3-(N'-tert-Butyl-hydrazino)-3-methyl-butyric acid methyl ester

3-(N'-tert-Butyl-hydrazino)-3-methyl-butyric acid methyl ester

Conditions
ConditionsYield
In Dimethyl ether for 168h;96%
methanol
67-56-1

methanol

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

methyl 2-iodo-3-methoxy-3-methylbutanoate

methyl 2-iodo-3-methoxy-3-methylbutanoate

Conditions
ConditionsYield
With ammonium cerium (IV) nitrate; iodine at 50℃; for 15h;96%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

3,5-Dimethylphenol
108-68-9

3,5-Dimethylphenol

3,3,5,7-tetramethylchroman-2-one

3,3,5,7-tetramethylchroman-2-one

Conditions
ConditionsYield
With methanesulfonic acid at 70℃;96%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

n-decyl magnesium bromide
17049-50-2

n-decyl magnesium bromide

methyl 3,3-dimethyltridecanoate

methyl 3,3-dimethyltridecanoate

Conditions
ConditionsYield
With copper(l) iodide; chloro-trimethyl-silane In tetrahydrofuran; 2-methyltetrahydrofuran at -15 - 20℃; Inert atmosphere;96%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

isononanoyl chloride
36727-29-4

isononanoyl chloride

3,7,9,9-tetramethyl-2-decen-5-onic acid methyl ester

3,7,9,9-tetramethyl-2-decen-5-onic acid methyl ester

Conditions
ConditionsYield
With aluminum (III) chloride; tin(IV) chloride at 40℃; for 5h; Time; Cooling with ice; Reflux;95.4%
Stage #1: isononanoyl chloride With aluminum (III) chloride In dichloromethane at 30℃; for 0.666667h;
Stage #2: Methyl 3,3-dimethylacrylate In dichloromethane at 38℃; for 1h; Temperature;
Stage #1: isononanoyl chloride With aluminum (III) chloride In dichloromethane for 5h;
Stage #2: Methyl 3,3-dimethylacrylate In dichloromethane at 40℃; for 10h; Time;
Stage #1: isononanoyl chloride With anhydrous aluminum chloride, anhydrous lanthanum chloride, anhydrous lithium perchlorate on silica gel catalyst In dichloromethane at 0℃; for 1h;
Stage #2: Methyl 3,3-dimethylacrylate In dichloromethane at 25 - 40℃; for 11h; Temperature;
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

(+/-)-lavandulol
58461-27-1

(+/-)-lavandulol

A

2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate
23960-07-8

2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate

B

2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-3-butenoate

2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-3-butenoate

Conditions
ConditionsYield
With titanium(IV) isopropylate In toluene at 100℃; Temperature; Reagent/catalyst;A 94.9%
B n/a
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

2,3-dibromo-3-metyl-butenoate
63881-44-7

2,3-dibromo-3-metyl-butenoate

Conditions
ConditionsYield
With bromine In dichloromethane at 0℃; for 0.25h; Inert atmosphere; Schlenk technique;94%
With bromine In dichloromethane at 0℃; for 10h;73%
With tetrachloromethane; bromine
With bromine
With bromine In neat (no solvent) for 48h; from -50 deg C to -70 deg C;
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

2,4-Xylenol
105-67-9

2,4-Xylenol

4,4,6,8-tetramethyldihydrocoumarin
249629-60-5

4,4,6,8-tetramethyldihydrocoumarin

Conditions
ConditionsYield
With methanesulfonic acid at 70℃; Condensation; cyclization;93%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

allyl bromide
106-95-6

allyl bromide

2-(prop-1-en-2-yl)pent-4-en-1-ol
99799-91-4

2-(prop-1-en-2-yl)pent-4-en-1-ol

Conditions
ConditionsYield
Stage #1: Methyl 3,3-dimethylacrylate With n-butyllithium; diisopropylamine In tetrahydrofuran at -78 - 0℃; for 1.83333h; Inert atmosphere; Cooling with acetone-dry ice;
Stage #2: allyl bromide In tetrahydrofuran at -78 - 0℃; for 15h; Inert atmosphere; Cooling with acetone-dry ice;
Stage #3: With lithium aluminium tetrahydride In tetrahydrofuran for 3h; Inert atmosphere;
93%
Stage #1: Methyl 3,3-dimethylacrylate; allyl bromide With lithium diisopropyl amide Inert atmosphere;
Stage #2: With lithium aluminium tetrahydride Inert atmosphere;
93%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

methyl 3-hydroxy-3-methyl-2-iodobutanoate

methyl 3-hydroxy-3-methyl-2-iodobutanoate

Conditions
ConditionsYield
With ammonium cerium (IV) nitrate; water; iodine In acetonitrile at 50℃; for 9h; Reagent/catalyst;93%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

methyl 3-methylbutanoate
556-24-1

methyl 3-methylbutanoate

Conditions
ConditionsYield
With zinc copper In methanol for 24h; Heating;88%
With magnesium In methanol at 10℃; for 2.5h;78%
With platinum(IV) oxide Hydrogenation;
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

methyllithium
917-54-4

methyllithium

2,4-dimethyl-3-penten-2-ol
56763-70-3

2,4-dimethyl-3-penten-2-ol

Conditions
ConditionsYield
In diethyl ether at 0℃; for 1h;88%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

Trimethylhydroquinone
700-13-0

Trimethylhydroquinone

6-hydroxy-4,4,5,7,8-pentamethyl-3,4-dihydrocoumarin
40662-76-8

6-hydroxy-4,4,5,7,8-pentamethyl-3,4-dihydrocoumarin

Conditions
ConditionsYield
With methanesulfonic acid87%
With methanesulfonic acid at 70℃; for 3h;81.2%
With methanesulfonic acid at 70℃; for 2h;80%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

tert-butyl-(1-methoxy-3-methyl-buta-1,3-dienyloxy)-dimethyl-silane

tert-butyl-(1-methoxy-3-methyl-buta-1,3-dienyloxy)-dimethyl-silane

Conditions
ConditionsYield
With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; n-butyllithium; diisopropylamine In tetrahydrofuran at -78 - 20℃; for 1.5h;87%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

methyl 3-amino-3-methyl-butanoate
29637-56-7

methyl 3-amino-3-methyl-butanoate

Conditions
ConditionsYield
With ammonia In methanol at 120℃; for 4h; Inert atmosphere; Microwave irradiation;87%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

<(phenylsuilfonyl)methylene>dilithium
59807-81-7

<(phenylsuilfonyl)methylene>dilithium

1-benzenesulfonyl-4-methylpent-3-en-2-one
107006-44-0

1-benzenesulfonyl-4-methylpent-3-en-2-one

Conditions
ConditionsYield
86%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

3-Chloro-2-methylpropene
563-47-3

3-Chloro-2-methylpropene

2,6-dimethyl-4-(2'-methyl-2'-propenyl)-1,5-heptadien-4-ol

2,6-dimethyl-4-(2'-methyl-2'-propenyl)-1,5-heptadien-4-ol

Conditions
ConditionsYield
With magnesium In tetrahydrofuran Heating;86%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

[1,1-(2)H2]-3-methyl-2-buten-1-ol

[1,1-(2)H2]-3-methyl-2-buten-1-ol

Conditions
ConditionsYield
With lithium aluminium deuteride at 20℃; for 2h;86%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

[1,1-2H2]-3-methyl-2-butenol
6158-92-5

[1,1-2H2]-3-methyl-2-butenol

Conditions
ConditionsYield
With lithium aluminium deuteride86%
With lithium aluminium deuteride In diethyl ether at 0℃; for 1h; Inert atmosphere; Reflux;76%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

(R)-1-methyl-4-(1-(phenylsulfonyl)propan-2-yl)benzene

(R)-1-methyl-4-(1-(phenylsulfonyl)propan-2-yl)benzene

(6R)-2-methyl-5-(phenylsulfonyl)-6-p-tolylhept-2-en-4-one

(6R)-2-methyl-5-(phenylsulfonyl)-6-p-tolylhept-2-en-4-one

Conditions
ConditionsYield
Stage #1: (R)-1-methyl-4-(1-(phenylsulfonyl)propan-2-yl)benzene With n-butyllithium In tetrahydrofuran at -78 - -50℃; Inert atmosphere; Glovebox; Schlenk technique;
Stage #2: With magnesium bromide ethyl etherate In tetrahydrofuran at -78 - 20℃; for 0h; Inert atmosphere; Glovebox; Schlenk technique;
Stage #3: Methyl 3,3-dimethylacrylate In tetrahydrofuran at -78 - 20℃; Inert atmosphere; Glovebox; Schlenk technique;
85%
Stage #1: (R)-1-methyl-4-(1-(phenylsulfonyl)propan-2-yl)benzene With n-butyllithium In tetrahydrofuran; hexane at -50℃; Inert atmosphere;
Stage #2: With magnesium bromide ethyl etherate In tetrahydrofuran; diethyl ether; hexane at -78 - 0℃; for 0.166667h; Inert atmosphere;
Stage #3: Methyl 3,3-dimethylacrylate In tetrahydrofuran; diethyl ether; hexane at -78 - 20℃; Inert atmosphere; enantioselective reaction;
77%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

7-methyl-3-methylene-7-octen-1-ol
73945-79-6

7-methyl-3-methylene-7-octen-1-ol

7-methyl-3-methylene-7-octenyl senecioate

7-methyl-3-methylene-7-octenyl senecioate

Conditions
ConditionsYield
With titanium(IV) isopropylate Inert atmosphere; Heating;84.7%
Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

(4-(tert-butyldimethylsilyloxy)butyl)magnesium chloride

(4-(tert-butyldimethylsilyloxy)butyl)magnesium chloride

C15H30O2Si

C15H30O2Si

Conditions
ConditionsYield
Stage #1: (4-(tert-butyldimethylsilyloxy)butyl)magnesium chloride With zirconocene dichloride In tetrahydrofuran; toluene at 0℃; for 3h;
Stage #2: Methyl 3,3-dimethylacrylate In tetrahydrofuran; toluene at 0 - 20℃;
84%
piperazine
110-85-0

piperazine

Methyl 3,3-dimethylacrylate
924-50-5

Methyl 3,3-dimethylacrylate

dimethyl 3,3'-(piperazine-1,4-diyl)bis-(3-methylbutanoate)
1260115-90-9

dimethyl 3,3'-(piperazine-1,4-diyl)bis-(3-methylbutanoate)

Conditions
ConditionsYield
In tetrahydrofuran; methanol at 20℃; for 24h; Aza-Michael addition; hyperbaric;84%

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