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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price Deuterated reagents ETHANOL-D 925-93-9 Manufacturer

Cas:925-93-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

ETHANOL-D

Cas:925-93-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 925-93-9 with competitive price

Cas:925-93-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph

Ethyl alcohol-D anhydrous

Cas:925-93-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Ethanol-d (9CI)

Cas:925-93-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Ethanol-d (9CI)

Cas:925-93-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:925-93-9

Cas:925-93-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application: Labelled Ethy

Ethanol-d (9CI)

Cas:925-93-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS925-93-9 ETHANOL-D

Cas:925-93-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

ETHANOL-D1

Cas:925-93-9

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Ethanol-d (9CI)

Cas:925-93-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

925-93-9 CAS NO.925-93-9

Cas:925-93-9

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

925-93-9

Cas:925-93-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Ethanol-OD 50g

Cas:925-93-9

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Ethanol-d (9CI)

Cas:925-93-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Ethanol-d, 99.5 atoM%D, for NMR

Cas:925-93-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Circle Star Chem-medical Technology co.,Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:25kg,50kg,180kg,200kg,250kg,1000kg,customization Application:Pharma;Industry;Agricultural;chemical reaserch Tran

Ethanol-OD

Cas:925-93-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

925-93-9

Cas:925-93-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Ethanol-d (9CI)Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Ethanol-d (9CI)

Cas:925-93-9

Min.Order:0

Negotiable

Type:Other

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

ETHANOL-D

Cas:925-93-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Yurui(Shanghai)Chemical Co.,Ltd

How May We Serve You We can Supply HPLC\HMMR\MS report for you ,pls feel free to contact us! Capability on chemical synthesis ● Shanghai High-Tech Enterprises ● Strong R&D Team from USA, Japan, Korea ● 65000M2+ Factory, 300+ reac

UIV CHEM best selling Ethanol-dEthyl alcohol-d C2H5DO CAS 925-93-9

Cas:925-93-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

925-93-9 CAS NO.925-93-9

Cas:925-93-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Ruishun Trade Co.,Ltd

Superiority 1.We have more than 10 years experience in this area. 2.We could offer you competitive prices with satisfied quality. 3.Our company provides after-sale service and technical assistance as the customers requirements. 4.As first c

MONODEUTERO ETHANOL

Cas:925-93-9

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Trading Company

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

Cerametek Materials (CMT) is your industrial and R&D supplier: 1. Semiconductor materials: Compounds of II, III, IV, V, VI groups such as Metal Sulfides, Selenides, Tellurides, Arsenide, Antimonide, Phosphide... 2. Advanced ceramic and crys

Ethanol-OD

Cas:925-93-9

Min.Order:0

Negotiable

Type:Other

inquiry

Jiangxi shengwei chemical technology co. LTD

Jiangxi Shengwei Chemical Technology Co., Ltd.supplies scientific research products as below:1.High-purity organic chemical reagents;2.Analytical reagents; 3.Biochemical reagents;4.Chemical raw materials;5.Experimental instruments;6.Experimental cons

Ethan(ol-d) 98 atom % D

Cas:925-93-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the ETHANOL-D, CAS:925-93-9 with the most competitive price and the best quality. We can

ETHANOL-D

Cas:925-93-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Clearsynth Labs Limited

Ethanol-d (9CI)

Cas:925-93-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Medical Isotopes, Inc.

ETHANOL-D

ETHANOL-D

Cas:925-93-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Cambridge Isotope Laboratories, Inc.

more information,please contact us

ETHANOL-D

Cas:925-93-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

C/D/N Isotopes Inc.

more information,please contact us

ETHANOL-D

Cas:925-93-9

Min.Order:0

Negotiable

Type:

inquiry

Synthetic route

ethoxy(diphenyl)-λ6-sulfanenitrile
127022-76-8

ethoxy(diphenyl)-λ6-sulfanenitrile

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

S,S-diphenylsulphoximine
22731-83-5

S,S-diphenylsulphoximine

Conditions
ConditionsYield
With [D3]acetonitrile; water-d2 In phosphate buffer at 20℃; for 0.75h; pH=6.1; Kinetics; Thermodynamic data; Product distribution; Further Variations:; pH-values; Reagents; Solvents; Temperatures; Hydrolysis;A 86%
B 99%
(C5(CH3)5)IrP(C6H5)3(D)(OCH2CH3)

(C5(CH3)5)IrP(C6H5)3(D)(OCH2CH3)

A

(C5(CH3)5)Ir(P(C6H5)3)2

(C5(CH3)5)Ir(P(C6H5)3)2

B

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Conditions
ConditionsYield
With triphenyl phosphine In benzene-d6; (2)H8-toluene (N2); dissolved Ir-compound with 1 drop toluene-d-8; placed in NMR tube; added triphenyl phosphine; (2)H NMR;A n/a
B 64%
diethyl sulphide
352-93-2

diethyl sulphide

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Conditions
ConditionsYield
With sulfuric acid; water-d2
ethanol
64-17-5

ethanol

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Conditions
ConditionsYield
With (CD3COCD3)D(1+) In gas at 57.9℃; Rate constant; Mechanism; Thermodynamic data; experiment conditions: NBS pulsed ion cyclotron resonance; probability of a reactive H/D exchange encounter for the deuteronated ion as a function of the Gibbs free-energy change of the (endoergic) deuteron transfer reaction;
With (C2D5)2OD(1+) In gas at 57.9℃; Rate constant; Mechanism; experiment conditions: NBS pulsed ion cyclotron resonance; probability of a reactive H/D exchange encounter for the deuteronated ion as a function of the Gibbs free-energy change of the (endoergic) deuteron transfer reaction;
With water-d2 In water at 34.9℃; Equilibrium constant;
orthocarbonic acid tetraethyl ester
78-09-1

orthocarbonic acid tetraethyl ester

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Conditions
ConditionsYield
With sulfuric acid; water-d2
sodium ethanolate
141-52-6

sodium ethanolate

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Conditions
ConditionsYield
With water-d2; decalin
With diethyl ether; water-d2
With water-d2
aluminum ethoxide
555-75-9

aluminum ethoxide

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Conditions
ConditionsYield
With decane; water-d2
With water-d2 at 80℃;
tetraethoxy orthosilicate
78-10-4

tetraethoxy orthosilicate

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Conditions
ConditionsYield
With thionyl chloride; water-d2 1.) 0 deg C, 1 h, 2.) ambient temp., 2 h, 3) reflux, 4 weeks;175 g
methylene chloride
74-87-3

methylene chloride

diazomethane-d2
14621-84-2

diazomethane-d2

A

ethanol
64-17-5

ethanol

B

chloromethane-d2
4960-87-6

chloromethane-d2

C

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

D

D3-chloromethane
1111-89-3

D3-chloromethane

Conditions
ConditionsYield
at -78℃; Product distribution; Irradiation; various alkylhalides;
chloroform-d1
865-49-6

chloroform-d1

diethoxyltriphenylphosphorane
86852-11-1, 18509-25-6

diethoxyltriphenylphosphorane

A

chloroethane
75-00-3

chloroethane

B

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

C

ethyl deuterioformate
35976-76-2

ethyl deuterioformate

D

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

Conditions
ConditionsYield
at 70℃; for 72h;
at 70℃; for 72h; Product distribution;
ethanol
64-17-5

ethanol

deuteromethanol
1455-13-6

deuteromethanol

A

methanol
67-56-1

methanol

B

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Conditions
ConditionsYield
Equilibrium constant;
ethane
74-84-0

ethane

A

ethylene glycol-d2
2219-52-5

ethylene glycol-d2

B

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

C

deuteroacetic acid
758-12-3

deuteroacetic acid

D

(O-2H2)-glycolic acid
81278-02-6

(O-2H2)-glycolic acid

Conditions
ConditionsYield
With potassium tetrachloroplatinate; water-d2; oxygen; platinum at 108℃; under 25857.4 Torr; for 19h; Product distribution; Mechanism; var. temperatures and reaction time;A 0.002 mmol
B 0.004 mmol
C 0.002 mmol
D 0.0017 mmol
carbon monoxide
201230-82-2

carbon monoxide

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

A

diethyl ether
60-29-7

diethyl ether

B

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

C

C3H6(2)H2O

C3H6(2)H2O

D

[2H]-diethoxymethane

[2H]-diethoxymethane

E

ethyl ethoxymonodeuteroacetate

ethyl ethoxymonodeuteroacetate

F

di-deuteromethylcarbonate

di-deuteromethylcarbonate

Conditions
ConditionsYield
With deuterium; Λ(+)-tris(pentane-2,5-dionato)ruthenium; methyl iodide Product distribution; 1.) 150 deg C, 4 h, 14 MPa, CO/D2=2.5; 2.) 170 deg C, 4 h, 10 MPa, CO/D2=2.5; 3.) 200 deg C, 6 h, 8 MPa, CO/D2=1.0; product distribution after successive steps;A n/a
B n/a
C 7.0 % Chromat.
D 3.0 % Chromat.
E 1.0 % Chromat.
F 0.3 % Chromat.
C6H14(2)HO5P

C6H14(2)HO5P

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

dimethyl acetylphosphonate
17674-28-1

dimethyl acetylphosphonate

Conditions
ConditionsYield
at 18℃; Kinetics; Equilibrium constant;
d(4)-methanol
811-98-3

d(4)-methanol

acetyl propionyl peroxide
13043-82-8

acetyl propionyl peroxide

A

methane
34557-54-5

methane

B

Monodeuteromethan
676-49-3

Monodeuteromethan

C

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

D

C4H4(2)H4O3

C4H4(2)H4O3

Conditions
ConditionsYield
at 39.85℃; for 0.666667h; Product distribution; Further Variations:; Temperatures; reaction times;
acetyl propionyl peroxide
13043-82-8

acetyl propionyl peroxide

A

methane
34557-54-5

methane

B

Monodeuteromethan
676-49-3

Monodeuteromethan

C

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

D

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
With d(4)-methanol at -60.15℃; for 2h; Product distribution; Further Variations:; Temperatures; reaction times;
acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

d(4)-methanol
811-98-3

d(4)-methanol

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

tert-butyl alcohol-d
3972-25-6

tert-butyl alcohol-d

Conditions
ConditionsYield
With sodium methylate; lanthanum(lll) triflate at 25℃; pH=8; Kinetics;
d(4)-methanol
811-98-3

d(4)-methanol

ethyl acetate
141-78-6

ethyl acetate

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

methyl acetate-d3
24704-57-2

methyl acetate-d3

Conditions
ConditionsYield
With sodium methylate; lanthanum(lll) triflate at 25℃; pH=8.5; Kinetics; Further Variations:; Reagents;
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics; Solvolysis;
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics;
ammonium 3,5-dicyano-4-ethyl-4-methyl-6-oxo-1,4,5,6-tetrahydro-pyridin-2-olate
956541-46-1

ammonium 3,5-dicyano-4-ethyl-4-methyl-6-oxo-1,4,5,6-tetrahydro-pyridin-2-olate

A

ethane
74-84-0

ethane

B

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

C

2,6-dihydroxy-4-methyl-pyridine-3,5-dicarbonitril; ammonium salt
18519-97-6

2,6-dihydroxy-4-methyl-pyridine-3,5-dicarbonitril; ammonium salt

Conditions
ConditionsYield
With borax; diclazuril In water-d2 at 20℃; pH=8;
C2H5(2)HO2Se

C2H5(2)HO2Se

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Conditions
ConditionsYield
With sodium periodate In water-d2; [D3]acetonitrile at 100℃; for 14h;
d(4)-methanol
811-98-3

d(4)-methanol

C8H15NO3
912359-83-2

C8H15NO3

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

C7H10(2)H3NO3

C7H10(2)H3NO3

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics; Solvolysis;
d(4)-methanol
811-98-3

d(4)-methanol

ethyl N-isobutyryl-N-methylglycinate
1235407-80-3

ethyl N-isobutyryl-N-methylglycinate

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

C8H12(2)H3NO3

C8H12(2)H3NO3

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics; Solvolysis;
d(4)-methanol
811-98-3

d(4)-methanol

C10H19NO3
1235407-81-4

C10H19NO3

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

C9H14(2)H3NO3

C9H14(2)H3NO3

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics; Solvolysis;
d(4)-methanol
811-98-3

d(4)-methanol

C9H17NO3
1235407-82-5

C9H17NO3

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

C8H12(2)H3NO3

C8H12(2)H3NO3

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics; Solvolysis;
d(4)-methanol
811-98-3

d(4)-methanol

C10H19NO3
1235407-83-6

C10H19NO3

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

C9H14(2)H3NO3

C9H14(2)H3NO3

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics; Solvolysis;
d(4)-methanol
811-98-3

d(4)-methanol

C11H21NO3
1235407-84-7

C11H21NO3

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

C10H16(2)H3NO3

C10H16(2)H3NO3

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics; Solvolysis;
d(4)-methanol
811-98-3

d(4)-methanol

C12H23NO3
1235407-85-8

C12H23NO3

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

C11H18(2)H3NO3

C11H18(2)H3NO3

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics; Solvolysis;
d(4)-methanol
811-98-3

d(4)-methanol

C13H25NO3
1235407-86-9

C13H25NO3

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

C12H20(2)H3NO3

C12H20(2)H3NO3

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics; Solvolysis;
d(4)-methanol
811-98-3

d(4)-methanol

C8H13NO3
3154-55-0

C8H13NO3

A

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

B

C7H8(2)H3NO3

C7H8(2)H3NO3

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine at 21.5℃; Kinetics; Solvolysis;
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

2-(2,5-difluorophenyl)-2,2-d2-acetic acid

2-(2,5-difluorophenyl)-2,2-d2-acetic acid

ethyl 2-(2,5-difluorophenyl)acetate-d2

ethyl 2-(2,5-difluorophenyl)acetate-d2

Conditions
ConditionsYield
With sulfuric acid at 20℃;100%
(η5-C5H4Me)(carbonyl)2manganese(η1-vinylideneiron(η5-C5Me5)(carbonyl)2)

(η5-C5H4Me)(carbonyl)2manganese(η1-vinylideneiron(η5-C5Me5)(carbonyl)2)

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

(η5-C5H4Me)(carbonyl)2manganese(η1-CCD-iron(η5-C5Me5)(carbonyl)2)

(η5-C5H4Me)(carbonyl)2manganese(η1-CCD-iron(η5-C5Me5)(carbonyl)2)

Conditions
ConditionsYield
With n-C4H9Li In tetrahydrofuran (Ar, Schlenk tube technique); n-BuLi is added to a THF soln. of the complex cooled to -78°C, the mixture is stirred for 70 min, EtOD is added, the mixture is warmed up to room temp.; the volatiles are removed under reduced pressure, the products are extd. with ether and filtered through an alumina pad, product is detected by (1)H-NMR;99%
With NaOC2H5 In tetrahydrofuran byproducts: (Fe(C5Me5)(CO)2)2; Irradiation (UV/VIS); (Ar, Schlenk tube technique); EtONa-EtOD is added to a THF soln. of the complex, the mixture is stirred for 2 h at ambient temp.; the volatiles are removed under reduced pressure, the products are extd. with ether and filtered through an alumina pad, product is detected by (1)H-NMR;99%
hydrogen cation In ethyl [2]alcohol
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

phenylacetonitrile-α,α-d2
935-66-0

phenylacetonitrile-α,α-d2

phenyldideuterioacetamidic acid ethyl ester hydrochloride

phenyldideuterioacetamidic acid ethyl ester hydrochloride

Conditions
ConditionsYield
With hydrogenchloride at 0℃;95%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

(C5(CH3)5)Rh(P(CH3)3)((13)CHCH2CH2)I
104267-65-4

(C5(CH3)5)Rh(P(CH3)3)((13)CHCH2CH2)I

(C5(CH3)5)Rh(P(CH3)3)((13)CHCH2CH2)(H)
104373-38-8

(C5(CH3)5)Rh(P(CH3)3)((13)CHCH2CH2)(H)

Conditions
ConditionsYield
With tert.-butyl lithium In not given (N2); -78°C; deuteration with C2H5OD at -60°C; 55% 13C-enriched according to NMR;93%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

5-Azidocarbonyloxy-7-phenyl-2,2-dimethyl-3-heptyne
308274-37-5

5-Azidocarbonyloxy-7-phenyl-2,2-dimethyl-3-heptyne

C18H24(2)HNO3
308274-40-0

C18H24(2)HNO3

Conditions
ConditionsYield
With chloro-trimethyl-silane; iron(II) chloride at 20℃; Cyclization; Intramolecular amination;91%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

bromoacetic-2,2-d2 acid bromoanhydride
40897-88-9

bromoacetic-2,2-d2 acid bromoanhydride

ethyl bromo-<2,2-2H2>acetate
14341-47-0

ethyl bromo-<2,2-2H2>acetate

Conditions
ConditionsYield
Ambient temperature;90%
(Z)-3-(ferrocenyl)acrylonitrile

(Z)-3-(ferrocenyl)acrylonitrile

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

cis-β-ferrocenyl-α-deuterio-acrylonitrile

cis-β-ferrocenyl-α-deuterio-acrylonitrile

Conditions
ConditionsYield
With potassium In tetrahydrofuran byproducts: CH3CH2OH; mixture of ferrocenyl-compd. and EtOD in THF or pure EtOD, in which metallic K was dissolved, was stirred in absence of O2 and moisture at 50°C during 4 h, stored for 12 h at 25°C; removing of the solvent in vacuum, extn. of the residue with abs. ether, filtn. and evapn., chromatographed on a thin layer of silica gel;90%
(E)-3-(ferrocenyl)acrylonitrile

(E)-3-(ferrocenyl)acrylonitrile

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

trans-β-ferrocenyl-α-deuterio-acrylonitrile

trans-β-ferrocenyl-α-deuterio-acrylonitrile

Conditions
ConditionsYield
With potassium In tetrahydrofuran byproducts: CH3CH2OH; mixture of EtOD and ferrocenyl-compd. in THF or pure EtOD, in which metallic K was dissolved, was stirred in absence of O2 and moisture at 50°C during 4 h, stored for 12 h at 25°C; removing of the solvent in vacuum, extn. of the residue with abs. ether, filtn. and evapn., chromatographed on a thin layer of silica gel;90%
pentamethylcyclopentadienyliridium(III) PMe3 dihydride
80146-01-6

pentamethylcyclopentadienyliridium(III) PMe3 dihydride

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

(η5-methylcyclopentadienyl)(trimethylphosphine)iridium dideuteride

(η5-methylcyclopentadienyl)(trimethylphosphine)iridium dideuteride

Conditions
ConditionsYield
With silica gel In ethyl [2]alcohol N2-atmosphere; degassed EtOD; stirring (16 h, room temp.); evapn. (vac.); EtOD addn.; stirring (16 h, room temp.); evapn. (vac.); suspended in pentane; filtration (Celite); evapn. (vac.);isotopic purity detd. by (1)H NMR spectroscopy;90%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

2-bromoacetic-d2 acid-d
14341-48-1

2-bromoacetic-d2 acid-d

ethyl bromo-<2,2-2H2>acetate
14341-47-0

ethyl bromo-<2,2-2H2>acetate

Conditions
ConditionsYield
With sulfuric acid In benzene for 4.5h; Heating;89%
(η5-C5H4Me)(carbonyl)2manganese(η1-vinylideneiron(η5-C5Me5)(carbonyl)2)

(η5-C5H4Me)(carbonyl)2manganese(η1-vinylideneiron(η5-C5Me5)(carbonyl)2)

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

trifluoroacetic acid
76-05-1

trifluoroacetic acid

(η5-C5H4Me)(carbonyl)2manganese(η1-CCD-iron(η5-C5Me5)(carbonyl)2)

(η5-C5H4Me)(carbonyl)2manganese(η1-CCD-iron(η5-C5Me5)(carbonyl)2)

Conditions
ConditionsYield
In dichloromethane (Ar, Schlenk tube technique); EtOD and CF3COOH are added to a CH2Cl2 soln. of the complex, the mixture is stirred for 30 min at room temp.; the volatiles are evapd., the products are extd. with ether and filtered through an alumina pad, solvent is removed;89%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

dodecamethylcyclohexasilane

dodecamethylcyclohexasilane

dimethylethoxysilane-Si-d1

dimethylethoxysilane-Si-d1

Conditions
ConditionsYield
In diethyl ether at 5℃; for 1.5h; Irradiation;84%
3,5-dichloro-pyrazine-2-carboxylic acid methyl ester
330786-09-9

3,5-dichloro-pyrazine-2-carboxylic acid methyl ester

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

ethyl 3,5-d2-pyrazine-2-carboxylate

ethyl 3,5-d2-pyrazine-2-carboxylate

Conditions
ConditionsYield
With 5%-palladium/activated carbon; potassium carbonate; deuterium at 20℃; under 6000.6 Torr; for 1h; Sealed tube;83%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

4‐(5‐amino‐1‐methyl‐1H‐benzo[d]imidazol‐2‐yl‐4,6‐d2)butanoic‐2,2,4,4‐d4 acid hydrochloride

4‐(5‐amino‐1‐methyl‐1H‐benzo[d]imidazol‐2‐yl‐4,6‐d2)butanoic‐2,2,4,4‐d4 acid hydrochloride

ethyl 4‐(5‐amino‐1‐methyl‐1H‐benzo[d]imidazol‐2‐yl‐4,6‐d2)butanoate‐2,2,4,4‐d4

ethyl 4‐(5‐amino‐1‐methyl‐1H‐benzo[d]imidazol‐2‐yl‐4,6‐d2)butanoate‐2,2,4,4‐d4

Conditions
ConditionsYield
With thionyl chloride at 0 - 50℃; for 4.5h;81.3%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

6-chloro-pyrazine-2-carboxylic acid methyl ester
23611-75-8

6-chloro-pyrazine-2-carboxylic acid methyl ester

ethyl 6-d-pyrazine-2-carboxylate

ethyl 6-d-pyrazine-2-carboxylate

Conditions
ConditionsYield
With 5%-palladium/activated carbon; potassium carbonate; deuterium at 20℃; under 6000.6 Torr; for 1h; Sealed tube;79%
2,5-dichloroisonicotinic acid methyl ester
623585-74-0

2,5-dichloroisonicotinic acid methyl ester

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

ethyl 2,5-d2-isonicotinate

ethyl 2,5-d2-isonicotinate

Conditions
ConditionsYield
With 5%-palladium/activated carbon; potassium carbonate; deuterium at 20℃; under 6000.6 Torr; for 4h; Sealed tube;72%
With palladium on activated charcoal; potassium carbonate; deuterium
(CH3)3Ge(B(C4H9)2)CCH(OC2H5)
115880-58-5

(CH3)3Ge(B(C4H9)2)CCH(OC2H5)

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

(CH3)3Ge((2)H)CC(H)OC2H5
115880-67-6

(CH3)3Ge((2)H)CC(H)OC2H5

Conditions
ConditionsYield
In tetrahydrofuran under Ar; dropwise addn. of soln. of alcohol to the ether; fractionated; elem. anal.;70%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

C11H7F3O3S
1013936-27-0

C11H7F3O3S

C12H10(2)H2O

C12H10(2)H2O

Conditions
ConditionsYield
[Cp*RuCl(η2-SMe)]2 at 20℃; for 4h;67%
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

(+/-)-dicyano{2,2,3,3,7,7,8,8,12,12,13,13,17,17,18,18-hexadecamethyl-2,3,7,8,12,13,17,18-octahydro-1H,21H-10,20-diaza-porphinato}cobalt(III)

(+/-)-dicyano{2,2,3,3,7,7,8,8,12,12,13,13,17,17,18,18-hexadecamethyl-2,3,7,8,12,13,17,18-octahydro-1H,21H-10,20-diaza-porphinato}cobalt(III)

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Co(C34H50(2)HN6)
95762-90-6

Co(C34H50(2)HN6)

Conditions
ConditionsYield
In ethyl [2]alcohol 48 h at r.t.; filtered, washed (EtOH/H2O 1:1 then H2O), dried (80°C, 72 h, 0.01 Torr);66%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

methyl 5-chloropyrazine-2-carboxylate
33332-25-1

methyl 5-chloropyrazine-2-carboxylate

ethyl 5-d-pyrazine-2-carboxylate

ethyl 5-d-pyrazine-2-carboxylate

Conditions
ConditionsYield
With 5%-palladium/activated carbon; potassium carbonate; deuterium at 20℃; under 6000.6 Torr; for 1h; Sealed tube;65%
lithium aluminium deuteride

lithium aluminium deuteride

bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]

bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

[(η5-C5Me5)Ru(μ-D)4Ru(η5-C5Me5)]

[(η5-C5Me5)Ru(μ-D)4Ru(η5-C5Me5)]

Conditions
ConditionsYield
In diethyl ether under argon, addn. of Al-compound to a stirred suspn. of Ru-complex at -78°C, slow warming to room temperature, stirring for 5 h, cooling again to -78°C, addn. of EtOD, warming to room temperature, stirring for 12 h; removing solvent (reduced pressure), extn. of residue (toluene), filtn., concg. filtrate, chromy. (alumina);63%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

3-Bromo-2-cyclopropyl-2-ethylsulfanylcarbonyl-propionic acid ethyl ester

3-Bromo-2-cyclopropyl-2-ethylsulfanylcarbonyl-propionic acid ethyl ester

C11H17(2)HO4

C11H17(2)HO4

Conditions
ConditionsYield
With cyanocobalamin60%
bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]

bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

(C5(CH3)5)Ru(H)2(2)H2Ru(C5(CH3)5)

(C5(CH3)5)Ru(H)2(2)H2Ru(C5(CH3)5)

Conditions
ConditionsYield
With LiAlH4 In diethyl ether under argon, addn. of Al-compound to a stirred suspn. of Ru-complex at -78°C, slow warming to room temperature, stirring for 5 h, cooling again to -78°C, addn. of EtOD, warming to room temperature, stirring for 12 h; removing solvent (reduced pressure), extn. of residue (toluene), filtn., concg. filtrate, chromy. (alumina);60%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

4-methyliminomethyl-2,2,5,5-tetramethyl-3-imidazoline-1-oxyl
89148-76-5

4-methyliminomethyl-2,2,5,5-tetramethyl-3-imidazoline-1-oxyl

copper dichloride

copper dichloride

[(C3N2)(CH3)4(O)(CH(OCH2CH3)N(2)H(CH3))]CuCl2
89140-56-7

[(C3N2)(CH3)4(O)(CH(OCH2CH3)N(2)H(CH3))]CuCl2

Conditions
ConditionsYield
In ethyl [2]alcohol for 1-24 h; ppt. filtered off, washed (ethanol-d); elem. anal.;60%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

3,6-dibromopyrazine-2-carboxylic acid methyl ester
13301-04-7

3,6-dibromopyrazine-2-carboxylic acid methyl ester

ethyl 3,6-d2-pyrazine-2-carboxylate

ethyl 3,6-d2-pyrazine-2-carboxylate

Conditions
ConditionsYield
With 5%-palladium/activated carbon; water-d2; sodium carbonate; deuterium at 20℃; under 6000.6 Torr; for 1h; Sealed tube;60%
ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

1-phenylbut-3-yn-2-one
31739-46-5

1-phenylbut-3-yn-2-one

C12H10(2)H2O

C12H10(2)H2O

Conditions
ConditionsYield
[Cp*RuCl(η2-SMe)2RuCp*(OH2)]OSO2CF3 at 60℃; for 2h;56%
sodium borodeuteride

sodium borodeuteride

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

tris(2-diphenylphosphinoethyl)phosphine
23582-03-8

tris(2-diphenylphosphinoethyl)phosphine

iron(II) chloride

iron(II) chloride

{(P(CH2CH2P(C6H5)2)3)Fe(H)2}
128973-37-5

{(P(CH2CH2P(C6H5)2)3)Fe(H)2}

{(P(CH2CH2P(C6H5)2)3)Fe((2)H)(H)}

{(P(CH2CH2P(C6H5)2)3)Fe((2)H)(H)}

{(P(CH2CH2P(C6H5)2)3)Fe((2)H)2}

{(P(CH2CH2P(C6H5)2)3)Fe((2)H)2}

Conditions
ConditionsYield
In tetrahydrofuran (N2) or (Ar) excess of NaBD4; addn. of C2H5OD, NMR;A 20%
B 25%
C 55%
sodium borodeuteride

sodium borodeuteride

(+/-)-dicyano{2,2,3,3,7,7,8,8,12,12,13,13,17,17,18,18-hexadecamethyl-2,3,7,8,12,13,17,18-octahydro-1H,21H-10,20-diaza-porphinato}cobalt(III)

(+/-)-dicyano{2,2,3,3,7,7,8,8,12,12,13,13,17,17,18,18-hexadecamethyl-2,3,7,8,12,13,17,18-octahydro-1H,21H-10,20-diaza-porphinato}cobalt(III)

ethyl [2]alcohol
925-93-9

ethyl [2]alcohol

Co(C34H50(2)HN6)
95762-90-6

Co(C34H50(2)HN6)

Conditions
ConditionsYield
In ethyl [2]alcohol 48 h at r.t.; filtered, washed (EtOH/H2O 1:1 then H2O), dried (80°C, 72 h, 0.01 Torr);53%

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