img _fcksavedurl="/UserAppearance:detailed see specifications Storage:Store in dry, dark and ventilated place. Package:according to the clients requirement Application:95-51-2 Transportation:by air or by sea Port:Shanghai
Cas:95-51-2
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
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inquiry2-Chloroaniline CAS No.:95-51-2 Name: 2-Chloroaniline Synonyms: 2-Chlorobenzenamine; 1-Amino-2-chlorobenzene; Fast yellow GC base Molecular Structure Molecular Formula: C6H6ClN
Cas:95-51-2
Min.Order:1 Kilogram
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inquiryhigh quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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2-Chloroaniline Basic information Product Name: 2-Chloroaniline Synonyms: ORTHO-CHLOROANILINE;O-CHLOROANILINE;OCA;1,2-aminochlorobenzene;2-chloro-benzenamin;Aniline, o-chloro-;Azoic diaz
Cas:95-51-2
Min.Order:1 Gram
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inquiryName: 2-Chloroaniline CAS No.: 95-51-2 Formula: C6H6ClN Molecular Weight: 127.57 Synonyms: Aniline,o-chloro- (8CI);1-Amino-2-chlorobenzene;2-Amino-1-chlorobenzene;2-Chlorobenzenamine;2-Chlorophenylamine;Fast Yellow GC Base;
Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:95-51-2
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2-ChloroanilineAppearance:Colorless transparent liquid Storage:Sealed dry preservation Package:according to customers' requirements Application:Pesticide intermediates: herbicides intermediates: sulfonylurea herbicides Transportation:By air(EMS or EU
CHENGDU YANXI is a comprehensive manufacturer and an international distribution of products throughout the world. Specialized in Scrap metal, Chemical raw materials, Paper products and color industry. We aim to become leading position in global dis
Cas:95-51-2
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inquiryLocated in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h
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Superior quality, moderate price & quick delivery. Appearance:light yellow liquid Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Inter
high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
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Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
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Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:95-51-2
Min.Order:1 Kilogram
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Type:Trading Company
inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
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Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:Transparent amber liquid St
Cas:95-51-2
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inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China
Conditions | Yield |
---|---|
With hydrazine hydrate In ethanol; water at 80℃; for 1h; chemoselective reaction; | 100% |
With [1-butyl-2,3-dimethylimidazolium][tppm] stabilized rhodium nanoarticles at 50℃; under 22502.3 Torr; for 5h; Ionic liquid; Autoclave; chemoselective reaction; | 100% |
With hydrogen at 50℃; under 22502.3 Torr; for 5h; Autoclave; Sealed tube; Ionic liquid; chemoselective reaction; | 100% |
Conditions | Yield |
---|---|
With 2-((dicyclohexylphosphino)methyl)-1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium iodide; ammonia; palladium diacetate; sodium t-butanolate In 1,4-dioxane at 120℃; under 7500.75 Torr; for 24h; Autoclave; Inert atmosphere; chemoselective reaction; | 96% |
With tris(dibenzylideneacetone)dipalladium (0); lithium hexamethyldisilazane; CyJohnPhos; 1,1,1-triphenylsilylamine In toluene at 100℃; for 19h; | 92% |
With copper(l) iodide; ammonia; sodium phosphate In water at 100℃; for 24h; | 81% |
With ammonium hydroxide; copper(ll) sulfate pentahydrate; potassium carbonate; sodium L-ascorbate In dimethyl sulfoxide; glycerol at 100℃; for 8h; | 50% |
With 2-(di-tert-butylphosphino)-1-mesityl-4,5-diphenyl-1H-imidazole; ammonia; palladium diacetate; sodium t-butanolate In 1,4-dioxane at 120℃; under 7500.75 Torr; for 24h; Autoclave; Inert atmosphere; | 68 %Chromat. |
Conditions | Yield |
---|---|
With copper(l) iodide; 2-carboxyquinoline N-oxide; potassium carbonate; ammonium hydroxide In dimethyl sulfoxide at 50℃; for 23h; Inert atmosphere; | 87% |
With acetamidine hydrochloride; caesium carbonate In N,N-dimethyl-formamide at 130℃; for 20h; Inert atmosphere; Green chemistry; | 74% |
With copper(l) iodide; tetra(n-butyl)ammonium hydroxide; ammonia In water at 45℃; for 48h; Inert atmosphere; Sealed tube; chemoselective reaction; | 73% |
With ammonium hydroxide; copper(ll) sulfate pentahydrate; potassium carbonate; sodium L-ascorbate In dimethyl sulfoxide; glycerol at 80℃; for 2h; | 54% |
With ammonium hydroxide; copper(l) iodide; N,N'-bis(3,5-dimethoxyphenyl)cyclopentane-1,1-dicarboxamide; caesium carbonate In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere; Sealed tube; | 38% |
Conditions | Yield |
---|---|
With potassium carbonate; ammonium hydroxide In methanol at 60℃; for 16h; | 91% |
With copper(I) oxide; ammonium hydroxide In water for 0.0833333h; Microwave irradiation; |
Conditions | Yield |
---|---|
With platinum on activated charcoal; hydrogen In neat (no solvent) at 90℃; for 1.5h; Temperature; Supercritical conditions; Autoclave; chemoselective reaction; | A 5.8% B 93.4% |
With bis(acetylacetonato)palladium(II); phosphorus; hydrogen In N,N-dimethyl-formamide; benzene at 30℃; under 1520.1 Torr; for 5.41667h; Catalytic behavior; Time; Reagent/catalyst; chemoselective reaction; | A 9% B 90.6% |
With isopropyl alcohol; sodium hydroxide for 12h; Inert atmosphere; Reflux; chemoselective reaction; | A n/a B 83% |
2-chlorophenylhydroxamic acid
2-Chloroaniline
Conditions | Yield |
---|---|
Stage #1: 2-chlorophenylhydroxamic acid With acetic anhydride; potassium carbonate In dimethyl sulfoxide at 50℃; for 2h; Lossen Rearrangement; Stage #2: With hydrogenchloride In water; dimethyl sulfoxide at 0℃; | 99% |
With sodium hydroxide In dimethyl sulfoxide at 80℃; for 1.5h; Lossen rearrangement; |
Conditions | Yield |
---|---|
With butyltriphenylphosphonium tetrahydroborate In dichloromethane at 20℃; for 0.0833333h; | 99% |
With aluminum oxide; sodium formate; potassium hydroxide In neat (no solvent) for 1.5h; Milling; | 95% |
With iron In water at 20℃; Inert atmosphere; | 91% |
Conditions | Yield |
---|---|
With Imidazole hydrochloride In neat (no solvent) at 150℃; for 12h; Schlenk technique; | 40% |
Conditions | Yield |
---|---|
With methanesulfonic acid; trimethylsilylazide In tetrachloromethane at 80℃; for 4h; | 65% |
2-Chloronitrobenzene
A
o-Chloronitrosobenzene
B
2-Chloroaniline
C
2,2'-dichloroazobenzene
D
1,2-bis(2-chlorophenyl)hydrazine
E
2,2'-azoxychlorobenzene
Conditions | Yield |
---|---|
With hydrogen In ethanol at 35℃; under 30003 Torr; for 0.833333h; | |
With platinum on carbon; hydrogen In ethanol at 35℃; under 30003 Torr; for 0.0833333h; Reagent/catalyst; Time; Pressure; Solvent; Autoclave; |
2-(2-Chlorophenoxy)propionamide
2-Chloroaniline
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 140℃; for 4h; Green chemistry; | 52% |
Conditions | Yield |
---|---|
With 2-((dicyclohexylphosphino)methyl)-1,3-bis(2,6-diisopropylphenyl)-4,5-dimethyl-1H-imidazol-3-ium iodide; ammonia; palladium diacetate; sodium t-butanolate In 1,4-dioxane at 120℃; under 7500.75 Torr; for 24h; Autoclave; Inert atmosphere; | 75% |
With ethanol; ammonia; copper; copper(l) chloride at 150 - 250℃; Darst.; | |
With ethanol; copper-compound; ammonia; copper at 150 - 250℃; Darst.; | |
With 2-(di-tert-butylphosphino)-1-mesityl-4,5-diphenyl-1H-imidazole; ammonia; palladium diacetate; sodium t-butanolate In 1,4-dioxane at 120℃; under 7500.75 Torr; for 24h; Autoclave; Inert atmosphere; | 89 %Chromat. |
2-Chloronitrobenzene
A
o-Chloronitrosobenzene
B
nitrobenzene
C
aniline
D
2-Chloroaniline
E
2,2'-dichloroazobenzene
F
1,2-bis(2-chlorophenyl)hydrazine
G
2,2'-azoxychlorobenzene
Conditions | Yield |
---|---|
With 5%-palladium/activated carbon; hydrogen In ethanol; water at 35℃; under 30003 Torr; for 0.416667h; Reagent/catalyst; Time; Solvent; Autoclave; |
Conditions | Yield |
---|---|
With chlorine; natural kaolinitic clay In tetrachloromethane for 2h; Heating; | A 20% B 77% |
With iron(III) chloride; N-chloro-succinimide; 1-butyl-3-methylimidazolium trifluoromethanesulfonimide In tetrahydrofuran at 40℃; for 24h; Inert atmosphere; regioselective reaction; | A 53% B 30% |
With 1,3-di(adamantan-1-yl)-1H-imidazol-3-ium tetrafluoroborate; N-chloro-succinimide; camphor-10-sulfonic acid In 1,4-dioxane at 25℃; for 24h; | A 40% B 20% |
Conditions | Yield |
---|---|
With {Ru(H)(BH4)(CO)(3-(di-tert-butylphosphino)-N-((1-methyl-1H-imidazol-2-yl)methyl)propylamine)}; hydrogen In isopropyl alcohol at 120℃; under 22502.3 Torr; for 18h; Autoclave; | A 98 %Chromat. B 97 %Chromat. |
With C16H25MnN3O3P(1+)*Br(1-); potassium tert-butylate; hydrogen In cyclohexane at 100℃; under 22502.3 Torr; for 16h; Inert atmosphere; Autoclave; | A 80 %Chromat. B 84 %Chromat. |
Conditions | Yield |
---|---|
With [bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); formic acid; bis(trifluoromethanesulfonyl)amide; triethylamine; [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] In dibutyl ether at 130℃; for 24h; | A n/a B 73% |
With C18H32ClIrO2P2; tris(pentafluorophenyl)borate; hydrogen; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In toluene at 120℃; under 38002.6 Torr; for 24h; Overall yield = 82 %; Overall yield = 85 %Chromat.; chemoselective reaction; |
(2-chlorophenyl)-carbamic acid 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1,1-dimethylundecyl ester
2-Chloroaniline
Conditions | Yield |
---|---|
With trifluoroacetic acid In dichloromethane at 20℃; | 92% |
2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1-chlorobenzene
2-Chloroaniline
Conditions | Yield |
---|---|
With O-Methylhydroxylamin; n-butyllithium In tetrahydrofuran; hexane at -78 - 60℃; for 24h; Inert atmosphere; Cooling with acetone-dry ice; stereospecific reaction; | 29% |
2-Chloronitrobenzene
A
2-chloro-N-hydroxybenzenamine
B
aniline
C
2-Chloroaniline
D
2,2'-dichloroazobenzene
E
2,2'-azoxychlorobenzene
Conditions | Yield |
---|---|
With bis(acetylacetonato)palladium(II); phosphorus; hydrogen In N,N-dimethyl-formamide; benzene at 30℃; under 1520.1 Torr; for 4.1h; Catalytic behavior; Time; Reagent/catalyst; chemoselective reaction; | A n/a B 14.6% C 73.1% D n/a E n/a |
2-Chloronitrobenzene
A
2-chloro-N-hydroxybenzenamine
B
2-Chloroaniline
C
2,2'-dichloroazobenzene
D
2,2'-azoxychlorobenzene
Conditions | Yield |
---|---|
With bis(acetylacetonato)palladium(II); phosphorus; hydrogen In N,N-dimethyl-formamide; benzene at 30℃; under 1520.1 Torr; for 1.6h; Catalytic behavior; Time; Reagent/catalyst; chemoselective reaction; | A n/a B 64.3% C n/a D n/a |
Conditions | Yield |
---|---|
With 1-n-butyl-3-methylimidazolium azide; sulfuric acid; acetic acid at 54℃; for 4h; Schmidt Reaction; | 97% |
Stage #1: ortho-chlorobenzoic acid With trifluorormethanesulfonic acid; trimethylsilylazide In chloroform at 90℃; for 0.0633333h; Schmidt Reaction; Flow reactor; Stage #2: With water In methanol; chloroform at 20℃; Schmidt Reaction; Flow reactor; | 79% |
With thionyl chloride; hydroxylamine-O-sulfonic acid 1) 1h, reflux, 2) toluene, 1h, reflux; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With copper(I) oxide; tetramethlyammonium chloride; L-proline In ethanol at 110℃; for 36h; Inert atmosphere; | 97% |
Multi-step reaction with 5 steps 1: d(4)-methanol 2: zinc; deuteriated sodium hydroxide / water-d2 / 72 h / Reflux 3: pyridine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere 4: N-chloro-succinimide; oxygen; copper dichloride / acetonitrile / 1 h / 100 °C / 760.05 Torr 5: magnesium / methanol / 20 °C / Sonication View Scheme |
Conditions | Yield |
---|---|
With calcium hypochlorite In water; acetic acid; acetone at 0℃; for 0.0833333h; | 30% |
Multi-step reaction with 3 steps 1: pyridine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere 2: N-chloro-succinimide; oxygen; copper dichloride / acetonitrile / 0.75 h / 100 °C / 760.05 Torr / Inert atmosphere 3: magnesium / methanol / 20 °C / Sonication View Scheme | |
Multi-step reaction with 3 steps 1: pyridine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere 2: N-chloro-succinimide; oxygen; copper dichloride / acetonitrile / 24 h / 130 °C / 760.05 Torr 3: magnesium / methanol / 20 °C / Sonication View Scheme | |
Multi-step reaction with 3 steps 1: pyridine / tetrahydrofuran / 0 - 20 °C / Inert atmosphere 2: N-chloro-succinimide; oxygen; copper dichloride / acetonitrile / 4 h / 100 °C / 760.05 Torr 3: magnesium / methanol / 20 °C / Sonication View Scheme | |
With D-glucose; Escherichia coli flavin reductase; Bacillus megaterium glucose dehydrogenase; Lechevalieria aerocolonigenes tryptophan-7-halogenase; flavin adenine dinucleotide; NADH; sodium chloride In aq. phosphate buffer; isopropyl alcohol pH=7.4; Enzymatic reaction; |
Conditions | Yield |
---|---|
With sodium ethanolate | |
With water; sodium hydroxide for 5.5h; Electrochemical reaction; |
2-[(2-chlorophenylamino)-methylene]-malonic acid diethyl ester
2-Chloroaniline
Conditions | Yield |
---|---|
With ethylenediamine In ethanol at 20℃; for 2.15h; | 90% |
2-chloro-4-iodoaniline
2-Chloroaniline
Conditions | Yield |
---|---|
With formic acid; tributyl-amine; fac-tris[2-phenylpyridinato-C2,N]iridium(III) In acetonitrile at 25 - 30℃; for 32h; Inert atmosphere; Irradiation; | 94% |
2-Chloroaniline
Conditions | Yield |
---|---|
With magnesium In methanol at 20℃; Sonication; | 85% |
2,2'-dichloroazobenzene
2-Chloroaniline
Conditions | Yield |
---|---|
With hydrazine hydrate In ethanol Heating; | 92% |
With hydrazine hydrate; aluminium In ethanol Heating; | 92% |
With perchloric acid In isopropyl alcohol; acetonitrile at 25℃; for 0.733333h; pH=2; Inert atmosphere; Irradiation; | 84% |
controlled potential electrolysis; pH=6.5-9.2; -0.25 V; |
Conditions | Yield |
---|---|
With palladium on activated charcoal; hydrogen In ethanol at 50℃; under 750.075 Torr; Catalytic behavior; |
formic acid
2-Chloronitrobenzene
A
2-chloro-N-phenylformamide
B
2-Chloroaniline
Conditions | Yield |
---|---|
With cobalt nanoparticles anchoring on nitrogen doped carbon, pyrolysis at 700 °C In acetonitrile at 110℃; under 750.075 Torr; for 5h; Inert atmosphere; chemoselective reaction; | A 20.4% B n/a |
Conditions | Yield |
---|---|
In diethyl ether Ring cleavage; Substitution; | 100% |
In benzene at 25℃; for 1h; | 92% |
In diethyl ether at 20℃; | 88% |
Conditions | Yield |
---|---|
for 0.5h; Heating; | 100% |
In dichloromethane at 20℃; Inert atmosphere; | 100% |
With cadmium(II) oxide at 80℃; for 0.166667h; Neat (no solvent); Microwave irradiation; | 98% |
N-methylacetonitrilium trifluoromethanesulphonate
2-Chloroaniline
Conditions | Yield |
---|---|
In benzene at 20℃; for 0.5h; | 100% |
2-Chloroaniline
3-benzoyloxy-4-methoxybenzoyl chloride
3-(benzoyloxy)-N-(2-chlorophenyl)-4-methoxybenzamide
Conditions | Yield |
---|---|
With triethylamine In dichloromethane for 5h; Ambient temperature; | 100% |
2-Chloroaniline
Conditions | Yield |
---|---|
Stage #1: trifluoromethyl dihydro-1,4-dioxin-3-carbonyl chloride With pyridine; polystyrene-bound 4-hydroxy-3-nitrobenzophenone In dichloromethane at 20℃; for 24h; Acylation; Stage #2: o-chloroaniline With triethylamine In acetonitrile for 24h; Acylation; Heating; | 100% |
1-bromo-4-methoxy-benzene
2-Chloroaniline
2-chloro-N-(4-methoxyphenyl)aniline
Conditions | Yield |
---|---|
With tri-tert-butyl phosphine; sodium t-butanolate; palladium diacetate In toluene for 22h; Heating; | 100% |
With sodium t-butanolate; palladium diacetate; (2,2-dimethylpropane-1,3-diyl)bis(diphenylphosphane) In 1,4-dioxane at 80℃; for 72h; Heating / reflux; | 73% |
With C22H26Cl2NPPd; sodium t-butanolate In toluene at 110℃; for 22h; Inert atmosphere; |
tert-Butyl 2,2,2-trichloroacetimidate
2-Chloroaniline
tert-butyl-(2-chloro-phenyl)-amine
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In cyclohexane at 20℃; | 100% |
2-Chloroaniline
Conditions | Yield |
---|---|
In tetrachloromethane for 1h; Heating; | 100% |
2-Chloroaniline
Conditions | Yield |
---|---|
In tetrachloromethane for 1h; Heating; | 100% |
Conditions | Yield |
---|---|
In tetrachloromethane for 1h; Heating; | 100% |
Conditions | Yield |
---|---|
Stage #1: o-chloroaniline With hydrogenchloride; sodium nitrite In water at 0℃; for 0.333333h; Stage #2: p-toluidine With sodium acetate In water at 0 - 5℃; | 100% |
Conditions | Yield |
---|---|
With hydrogenchloride In water at 80℃; for 12h; | 100% |
Stage #1: o-chloroaniline With hydrogenchloride In water Reflux; Stage #2: ammonium thiocyanate In water Reflux; |
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0 - 20℃; | 100% |
cinnamoyl chloride
2-Chloroaniline
N-(2-chlorophenyl)-3-phenylacrylamide
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 20℃; Inert atmosphere; | 100% |
2-Chloroaniline
3-(1-methyl-1H-indol-3-yl)-3-oxopropanenitrile
Conditions | Yield |
---|---|
Stage #1: o-chloroaniline With hydrogenchloride In water; acetonitrile at 0 - 20℃; for 0.5h; Stage #2: With sodium nitrite In water; acetonitrile at 0℃; for 0.0833333h; Stage #3: 3-(1-methyl-1H-indol-3-yl)-3-oxopropanenitrile With sodium acetate In ethanol; water; N,N-dimethyl-formamide; acetonitrile | 100% |
2-Chloroaniline
dicyclohexyl-carbodiimide
N-o-chlorophenyl-N', N"-dicyclohexylguanidine
Conditions | Yield |
---|---|
With Sm[N(TMS)2]2(THF)3 at 20℃; for 0.25h; Inert atmosphere; | 99.3% |
Stage #1: o-chloroaniline With C76H124N6Nd2O6Si4 In neat (no solvent) for 0.166667h; Schlenk technique; Inert atmosphere; Stage #2: dicyclohexyl-carbodiimide In neat (no solvent) at 60℃; for 0.25h; Schlenk technique; Inert atmosphere; | 98% |
With C114H132N6O6Yb3*2C7H8 at 60℃; for 0.25h; Schlenk technique; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 24h; | 99% |
With 1-methyl-1H-imidazole; N,N,N,N,-tetramethylethylenediamine; potassium carbonate In acetonitrile at 0 - 5℃; for 1h; | 99% |
With N,N-dimethyl-aniline at 100℃; for 0.75h; | 96% |
phenyl isothiocyanate
2-Chloroaniline
1-(2-chloro-phenyl)-3-phenyl-thiourea
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide Heating; | 99% |
for 0.00833333h; Microwave irradiation; Neat (no solvent); | 98% |
With [κ2-{(Ph2P-(=Se))}2NCH2(C5H4N)ZnCl2] In toluene at 25℃; Schlenk technique; Inert atmosphere; | 84% |
methanesulfonyl chloride
2-Chloroaniline
N‐(2‐chlorophenyl)methanesulfonamide
Conditions | Yield |
---|---|
With pyridine In dichloromethane | 99% |
In water at 20℃; for 0.583333h; | 85% |
With pyridine In dichloromethane Ambient temperature; | 82% |
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 1h; | 99% |
With dmap In dichloromethane for 2h; Inert atmosphere; | 99% |
With acetic acid at 20℃; for 1.5h; Cooling with ice; | 98% |
2-nitrophenyl bromide
2-Chloroaniline
N-(2-chlorophenyl)-N-(2-nitrophenyl)amine
Conditions | Yield |
---|---|
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; tris(dibenzylideneacetone)dipalladium (0) In toluene at 110℃; | 99% |
With sodium acetate; nitrobenzene | |
With copper; potassium carbonate at 160℃; |
2-Chloroaniline
diethyl 2-ethoxymethylenemalonate
2-[(2-chlorophenylamino)-methylene]-malonic acid diethyl ester
Conditions | Yield |
---|---|
In ethanol at 28℃; for 5h; | 99% |
In neat (no solvent) at 120℃; for 0.75h; | 98% |
In toluene for 1h; Heating; | 85% |
2-Thiophenecarbonyl chloride
2-Chloroaniline
N-(2-chlorophenyl)thiophene-2-carboxamide
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 24h; | 99% |
In toluene |
pivaloyl chloride
2-Chloroaniline
N-(2-chlorophenyl)-2,2,2-trimethylacetamide
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran at 0℃; for 3h; Inert atmosphere; | 99% |
With sodium hydroxide In tert-butyl methyl ether; water at 0 - 20℃; for 6h; | 98.2% |
With sodium hydroxide In tert-butyl methyl ether; water at 20℃; | 97% |
Conditions | Yield |
---|---|
With potassium carbonate In water; acetone at 20℃; | 99% |
Stage #1: o-chloroaniline With potassium carbonate In water; acetone at 0℃; for 0.0833333h; Stage #2: acryloyl chloride In water; acetone at 0 - 20℃; | 87% |
With pyridine Yield given; | |
With N-ethyl-N,N-diisopropylamine In dichloromethane at 0℃; |
Conditions | Yield |
---|---|
With Sm[N(TMS)2]2(THF)3 at 20℃; for 0.0333333h; Inert atmosphere; | 99% |
With (1,4-bis(4-imino-2-pentanone)(-1H))[Yb(2,6-tBu2-4-MeC6H2O)2(THF)]2 In neat (no solvent) at 60℃; for 0.5h; Schlenk technique; Inert atmosphere; | 99% |
Stage #1: o-chloroaniline With C76H124N6Nd2O6Si4 In neat (no solvent) for 0.166667h; Schlenk technique; Inert atmosphere; Stage #2: diisopropyl-carbodiimide In neat (no solvent) at 60℃; for 0.25h; Schlenk technique; Inert atmosphere; | 98% |
di-tert-butyl dicarbonate
2-Chloroaniline
o-chlorobenzenecarbamic acid tert-butyl ester
Conditions | Yield |
---|---|
In neat (no solvent) at 80℃; for 0.166667h; Green chemistry; chemoselective reaction; | 99% |
aminosulfonic acid In water at 25 - 28℃; for 0.25h; ultrasound; | 90% |
With iron(III) chloride In dichloromethane at 20℃; for 24h; | 20% |
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