1-Naphthoyl chloride supplier

Name
1-Naphthoyl chloride
EINECS 212-903-9
CAS No. 879-18-5
Article Data16
CAS DataBase
Density 1.271 g/cm³
Solubility Reacts with water.
Melting Point 16-19 °C(lit.)
Formula C₁₁H₇ClO
Boiling Point 297.5 °C at 760 mmHg
Molecular Weight 190.629
Flash Point 141.2 °C
Transport Information UN 3261 8/PG 2
Appearance Low melting solid/liquid
Safety 26-36/37/39-45-28A-60-30-20-8
Risk Codes 34-37-14
Molecular Structure
Hazard Symbols
Synonyms 1-Naphthoic acid chloride;1-(Chlorocarbonyl)naphthalene;.alpha.-Naphthoyl chloride;alpha-Naphthoyl chloride;naphthalene-1-carbonyl chloride;1-Naphthalenecarbonyl chloride;1-Naphthylcarbonyl chloride;1-Naphthaleneformyl chloride;
PSA 17.07000
LogP 3.21880

Synthetic route

: 86-55-5
1-naphthalenecarboxylic acid

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
With thionyl chloride In toluene for 2h; Reflux;	100%
With thionyl chloride for 2h; Heating / reflux;	98%
With thionyl chloride for 2h; Heating;	98%

: 201230-82-2
carbon monoxide

: 90-14-2
1-Iodonaphthalene

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
With bis(tri-t-butylphosphine)palladium(0); benzyltriphenylphosphonium chloride In toluene at 110℃; under 38002.6 Torr; for 24h; Glovebox; Autoclave; Inert atmosphere;	98%

: 90-14-2
1-Iodonaphthalene

: 122-04-3
4-nitro-benzoyl chloride

A: 636-98-6
p-nitrobenzene iodide

B: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
With (Xantphos)Pd(4-C6H4NO2)(I) In benzene at 90℃; for 20h; Sealed tube; Inert atmosphere;	A n/a B 71%

...Expand

: 79-37-8
oxalyl dichloride

: 91-20-3
naphthalene

A: 879-18-5
naphthalene-1-carbonic acid chloride

B β-naphthoic acid chloride: β-naphthoic acid chloride

Conditions

Conditions	Yield
With carbon disulfide; aluminium trichloride

...Expand

: 56-23-5
tetrachloromethane

: 91-20-3
naphthalene

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
at 190℃;

...Expand

: 56-23-5
tetrachloromethane

: 91-20-3
naphthalene

copper-powder: copper-powder

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
at 190℃;

...Expand

: 56-23-5
tetrachloromethane

: 91-20-3
naphthalene

FeBr2: FeBr2

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
at 190℃;

...Expand

: 56-23-5
tetrachloromethane

: 91-20-3
naphthalene

FeCl2: FeCl2

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
at 190℃;

...Expand

: 110-86-1
pyridine

: 91-20-3
naphthalene

: 76-03-9
trichloroacetic acid

CuCl2: CuCl2

A: 75-44-5
phosgene

B: 67-66-3
chloroform

C: 879-18-5
naphthalene-1-carbonic acid chloride

D HCl and CO and CO2: HCl and CO and CO2

Conditions

Conditions	Yield
at 190℃;

...Expand

: 79-37-8
oxalyl dichloride

: 86-55-5
1-naphthalenecarboxylic acid

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
In dichloromethane

...Expand

: 3416-93-1
2-(4,5-Dihydro-1,3-oxazol-2-yl)aniline

: 86-55-5
1-naphthalenecarboxylic acid

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
With oxalyl dichloride In dichloromethane; N,N-dimethyl-formamide

: 201230-82-2
carbon monoxide

: 90-11-9
1-Bromonaphthalene

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
With bis(tri-t-butylphosphine)palladium(0); benzyltriphenylphosphonium chloride In toluene at 110℃; under 15201 Torr; for 24h; Autoclave; Glovebox;

A

B

Conditions

Conditions	Yield
With (Xantphos)Pd(4-C6H4NO2)(I) In benzene at 110℃; for 20h; Sealed tube; Inert atmosphere;	A n/a B 63 %Spectr.

...Expand

aroyl chloride: aroyl chloride

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 125℃; for 12h;

: 79-37-8
oxalyl dichloride

: 86-55-5
1-naphthalenecarboxylic acid

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
With N,N-dimethyl-formamide In dichloromethane at 0 - 20℃; for 2h; Inert atmosphere;

: 90-14-2
1-Iodonaphthalene

: 141-75-3
butyryl chloride

: 879-18-5
naphthalene-1-carbonic acid chloride

Conditions

Conditions	Yield
With 1,4-diaza-bicyclo[2.2.2]octane; tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 100℃; for 16h; Sealed tube; Inert atmosphere;

1-Naphthoyl chloride Chemical Properties

IUPAC Name: Naphthalene-1-carbonyl chloride
Following is the structure of 1-Naphthoyl chloride (CAS NO.879-18-5):

Empirical Formula: C₁₁H₇ClO
Molecular Weight: 190.6257
EINECS: 212-903-9
Index of Refraction: 1.644
Molar Refractivity: 54.33 cm³
Molar Volume: 149.9 cm³
Density: 1.271 g/cm³
Flash Point: 141.2 °C
Melting point: 16-19 °C(lit.)
Sensitive: Moisture Sensitive
Surface Tension: 48.1 dyne/cm
Enthalpy of Vaporization: 53.74 kJ/mol
Boiling Point: 297.5 °C at 760 mmHg
Vapour Pressure: 0.00134 mmHg at 25 °C
Appearance of 1-Naphthoyl chloride (CAS NO.879-18-5): Low melting solid/Liquid
Stability of 1-Naphthoyl chloride (CAS NO.879-18-5): Stable. Incompatible with water, moisture, strong oxidizing agents, bases.
Product Categories of 1-Naphthoyl chloride (CAS NO.879-18-5): Miscellaneous; Acid Halides; Carbonyl Compounds; Organic Building Blocks
Canonical SMILES: C1=CC=C2C(=C1)C=CC=C2C(=O)Cl
InChI: InChI=1S/C11H7ClO/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7H
InChIKey: NSNPSJGHTQIXDO-UHFFFAOYSA-N

1-Naphthoyl chloride Toxicity Data With Reference

1-Naphthoyl chloride (CAS NO.879-18-5) hasn't been listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.

1-Naphthoyl chloride Safety Profile

Hazard Codes: Corrosive C
Risk Statements: 34-37-14
R34:Causes burns.
R37:Irritating to respiratory system
R14 :Reacts violently with water.
Safety Statements: 26-36/37/39-45-28-60-30-20-8
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S28:After contact with skin, wash immediately with plenty of soap-suds.
S60:This material and its container must be disposed of as hazardous waste.
S20:When using, do not eat or drink.
S30:Never add water to this product.
S8:Keep container dry.
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
F: 21
Hazard Note: Corrosive
HazardClass: 8
PackingGroup: II

1-Naphthoyl chloride Specification

1-Naphthoyl chloride , its cas register number 879-18-5. It also can be called 1-Naphthalenecarbonyl chloride ; 1-(Chlorocarbonyl)naphthalene ;1-Naphthoic acid chloride ; and alpha-Naphthoyl chloride . Its extinguishing agents is foam ,carbon dioxide, and sand.
1-Naphthoyl chloride (CAS NO.879-18-5) could be stable under normal temperatures and pressures. It should avoid the condition like exposure to moist air or water. It is not compatible with strong oxidizing agents, strong bases. And also prevent it to broken down into hazardous decomposition products: Hydrogen chloride, carbon monoxide, carbon dioxide. However, its hazardous polymerization has not been reported.

Product Name

1-Naphthoyl chloride

Synthetic route

1-Naphthoyl chloride Chemical Properties

1-Naphthoyl chloride Toxicity Data With Reference

1-Naphthoyl chloride Safety Profile

1-Naphthoyl chloride Specification

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