Conditions | Yield |
---|---|
With zirconocene dichloride; tert-butylmagnesium chloride; water Product distribution; multistep reaction; other hydrozirconation agents; other substrates; | 100% |
With hydrogen In ethanol at 20℃; under 760.051 Torr; for 2.5h; | 95% |
With 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine cobalt(II) dichloride; diethoxymethylane; sodium triethylborohydride In neat (no solvent) at -78 - 40℃; for 1h; | 95% |
(S)-2-octyl chloroformate
A
trans-2-Octene
B
oct-1-ene
C
(R)-2-chlorooctane
Conditions | Yield |
---|---|
With hexabutylguanidinium chloride In neat (no solvent) for 10h; | A n/a B n/a C 100% |
Conditions | Yield |
---|---|
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In ethyl acetate at 0℃; for 3h; | 97% |
With aluminum oxide at 350℃; | |
With fired clay fragments at 450 - 500℃; |
Conditions | Yield |
---|---|
With potassium hydroxide; triisopropylsilanol In N,N-dimethyl-formamide Ambient temperature; | 97% |
With 3-(tert-Butylamino)-1,1,1,5,5,5-hexakis(dimethylamino)-3-<amino>-1λ5,3λ5,5λ5-1,4-triphosphazadiene In tetrahydrofuran; xylene for 6h; Ambient temperature; | 96% |
With lithium diisopropylamide at 0℃; Kinetics; | 87% |
Conditions | Yield |
---|---|
With hydrogen In hexane at 40℃; under 760.051 Torr; for 6h; | A 3% B 97% |
With triisobutylaluminum; zirconocene dichloride In benzene for 0.333333h; | A 44% B 51% |
With hydrogen In cyclohexane at 150℃; under 75007.5 Torr; for 48h; Autoclave; Glovebox; | A 43% B 47% |
Conditions | Yield |
---|---|
With hexabutylguanidinium chloride at 100℃; for 5h; Yields of byproduct given; | A n/a B n/a C 97% |
Conditions | Yield |
---|---|
With nickel(II) iodide; 1,1,3,3-Tetramethyldisiloxane; copper(II) bis(trifluoromethanesulfonate); triphenylphosphine In neat (no solvent) at 190℃; for 16h; Reagent/catalyst; Sealed tube; Schlenk technique; Inert atmosphere; | 94% |
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel (0); 2,2-dimethylpropanoic anhydride; potassium iodide at 180 - 190℃; for 2h; Inert atmosphere; Glovebox; | 78% |
With sodium persulfate; sulfuric acid; silver nitrate; copper(II) sulfate 1.) water, reflux, 2.) 5 min, reflux; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
cobalt(II) naphthenate In nonane Product distribution / selectivity; | 93.1% |
Conditions | Yield |
---|---|
With potassium hydroxide; Aliquat 336 at 20℃; for 20h; | A 92% B 7% |
1-bromo-octane
potassium ethoxide
A
ethyl octyl ether
B
oct-1-ene
Conditions | Yield |
---|---|
With Aliquat 336 at 20℃; for 20h; | A 92% B 5% |
2-(phenylsulfonyl)-1-(trimethylsilyl)octane
oct-1-ene
Conditions | Yield |
---|---|
With tetrabutyl ammonium fluoride In tetrahydrofuran for 0.666667h; Heating; | 92% |
Conditions | Yield |
---|---|
With trifluoroacetic anhydride | 91% |
Conditions | Yield |
---|---|
With CrCl2(tetrahydrofuran)2; N,N'-bis(diphenylphosphino)-N,N'-dimethylpropane-1,3-diamine In methyl cyclohexane at 80℃; under 30003 Torr; for 0.5h; Inert atmosphere; | A 9% B 91% |
bis(2-(decylthio)ethyl)amine; chromium chloride In toluene at 90℃; under 33753.4 Torr; for 0.502778 - 0.527778h; Product distribution / selectivity; | A 90.85% B 0.5% |
chromium(III)2-ethylhexanoate; trimethylaluminum; N-[bis(2-methoxyphenyl)phosphino]-P,P-bis(2-methoxyphenyl)-N-methylphosphinous amide In methyl cyclohexane; toluene at 60℃; under 36003.6 - 37503.8 Torr; for 0.175h; Product distribution / selectivity; | A 89.7% B 8.5% |
Conditions | Yield |
---|---|
With formic acid at 20 - 240℃; Inert atmosphere; | 91% |
With methyltrioxorhenium(VII); sodium sulfite at 150℃; for 20h; sealed tube; | 60 %Chromat. |
With 15-crown-5; tetrabutylammonium perrhenate; sodium sulfite In benzene at 150 - 160℃; for 100h; regiospecific reaction; | 68 %Chromat. |
Conditions | Yield |
---|---|
at 375℃; under 760.051 Torr; for 0.7h; Reagent/catalyst; | A 5.9% B 90.1% |
With copper(II) sulfate In neat (no solvent) at 180℃; under 660 Torr; for 5h; Yield given; |
Conditions | Yield |
---|---|
With lithium diisopropylamide In tetrahydrofuran; hexane at -78℃; | 89% |
Multi-step reaction with 2 steps 1: 1.) sodium hydride / 1.) DMF, 20 deg C, 1 h, 2.) 80 deg C, 18 h 2: 1.) NaH / 1.) DMF, 1 h, 2.) 70 deg C, 6 h View Scheme | |
Multi-step reaction with 2 steps 1: sodium hydride, trifluoroacetamide / dimethylformamide / 18 h / 80 °C 2: 1.) NaH / 1.) DMF, 1 h, 2.) 70 deg C, 6 h View Scheme | |
Multi-step reaction with 2 steps 1: potassium iodide / methanol / Irradiation 2: methanol / Irradiation View Scheme |
Conditions | Yield |
---|---|
In diethyl ether for 15h; from 0 degC to 20 degC; | 88% |
Conditions | Yield |
---|---|
With tetrabutylammomium bromide; cesium fluoride for 1h; Heating; | A 88% B 9.4 % Chromat. |
With C12H35N7P2*FH In tetramethylurea; 1,3,5-trimethyl-benzene at 120℃; for 0.416667h; Inert atmosphere; | A 72% B 14% |
With 1,1,1-trifluoro-2-(2,2,2-trifluoroethoxy)ethane; 2,2-Dimethylpropyltrimethylammonium fluoride at 25℃; | A 71% B 29% |
Conditions | Yield |
---|---|
With lithium diisopropylamide In tetrahydrofuran; hexane at -78℃; | 88% |
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; for 14h; | 87% |
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride at 0 - 20℃; Inert atmosphere; | 87% |
Conditions | Yield |
---|---|
With sodium hydride In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; for 13h; | 88% |
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride at 0 - 20℃; Inert atmosphere; | 88% |
Conditions | Yield |
---|---|
aluminum oxide; tetramethylstannane; rhenium(VII) oxide In chlorobenzene at 25℃; for 3h; Yields of byproduct given; | A n/a B 87.8% |
Conditions | Yield |
---|---|
With Aliquat 336 at 20℃; for 20h; | A 87% B 13% |
1-bromo-octane
sodium ethanolate
A
ethyl octyl ether
B
oct-1-ene
Conditions | Yield |
---|---|
With potassium hydroxide; Aliquat 336 at 20℃; for 20h; | A 86% B 10% |
di-2-octyl phenylphosphonate
A
2-octene
B
oct-1-ene
C
phenylphosphonate
Conditions | Yield |
---|---|
With Amberlite 200C In dichloromethane at 40℃; for 72h; Product distribution; | A n/a B n/a C 85% |
(E) 2-iodo-1-chloroethylene
n-octyne
A
oct-1-ene
B
(1E,3E)-1-chloro-1,3-decadiene
Conditions | Yield |
---|---|
Stage #1: n-octyne With diisobutylaluminium hydride In n-heptane at 50℃; for 4h; Stage #2: With indium(III) chloride In tetrahydrofuran; n-heptane at 0℃; for 0.5h; Stage #3: (E) 2-iodo-1-chloroethylene With trifuran-2-yl-phosphane; Cl2Pd[bis(2-diphenylphosphinophenyl)ether]; diisobutylaluminium hydride In tetrahydrofuran; hexane; n-heptane at 0℃; for 4h; | A 4 % Spectr. B 85% |
Conditions | Yield |
---|---|
With tetra(n-butyl)ammonium hydrogensulfate; triphenyltinfluoride In acetonitrile at 85℃; for 10h; | A 83% B 12% |
Conditions | Yield |
---|---|
With 2C24BF20(1-)*C21H16N3P(2+) In dichloromethane at 55℃; for 24h; Reagent/catalyst; Inert atmosphere; | 83% |
(R)-2-octanol trimethylsilyl ether
A
cis-2-octene
B
trans-2-Octene
C
oct-1-ene
Conditions | Yield |
---|---|
With diethylamino-sulfur trifluoride In dichloromethane at -78 - -20℃; for 10h; | A n/a B n/a C n/a D 82% |
(E)-1-bromo-2-iodoethylene
n-octyne
A
oct-1-ene
B
(7E,9E)-hexadeca-7,9-diene
C
(1E,3E)-1-bromo-1,3-decadiene
Conditions | Yield |
---|---|
Stage #1: n-octyne With diisobutylaluminium hydride In n-heptane at 50℃; for 4h; Stage #2: With indium(III) chloride In tetrahydrofuran; n-heptane at 0℃; for 0.5h; Stage #3: (E)-1-bromo-2-iodoethylene With trifuran-2-yl-phosphane; Cl2Pd[bis(2-diphenylphosphinophenyl)ether]; diisobutylaluminium hydride In tetrahydrofuran; hexane; n-heptane at 0℃; for 4h; | A 7% B 2% C 82% |
Conditions | Yield |
---|---|
at 80-100 °C;; | 100% |
at 80-100 °C;; | 100% |
In neat (no solvent) other Radiation; under Ar; (60)Co-irradiation; 1.5:1 molar ratio (olefine:Sn-compound) ;25°C; GLC; | 74% |
Conditions | Yield |
---|---|
With hydrogen; In dichloromethane at 65℃; for 15h; same yield with a similar catalyst; Pressure (range begins): 120 ; | 100% |
With {(η6-C6H6)Ru(NCCH3)3}{BF4}2; water; hydrogen In benzene at 90℃; under 30400 Torr; for 4h; | 100% |
With hydrogen; In dichloromethane at 65℃; for 15h; Product distribution; other catalyst, other substrates; Pressure (range begins): 120 ; | 100% |
Conditions | Yield |
---|---|
With poly{[CuBa(pyridine-2,5-dicarboxylate)2(H2O)5]*H2O}; dihydrogen peroxide In acetonitrile at 60℃; for 6h; Catalytic behavior; Reagent/catalyst; | 100% |
With dmap; osmium(VIII) oxide; 4-methylmorpholine N-oxide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate In water; tert-butyl alcohol at 20℃; for 16h; | 99% |
With 4-methylmorpholine N-oxide; dendritic osmium catalyst In hexane; acetonitrile; tert-butyl alcohol at 20℃; for 36h; | 98% |
oct-1-ene
1,2-dichlorooctane
Conditions | Yield |
---|---|
With tetraethylammonium trichloride In dichloromethane | 100% |
With chlorine In chloroform at 20℃; for 1.5h; | 97% |
With oxone||potassium monopersulfate triple salt; potassium chloride; N-(n-butyl)-2-methylbenzamide In dichloromethane; water at 20℃; for 0.25h; | 91% |
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid; iron(III) perchlorate In acetonitrile at -10℃; for 0.0833333h; | 100% |
With 3-chloro-benzenecarboperoxoic acid; (Cl8TPP)FeIII(ClO4) In acetonitrile at -10℃; for 0.0833333h; Product distribution; invetigation of the iron(III) perchlorate-catalyzed epoxidation of olefins and oxidative cleavage of diols by m-chloroperbenzoic acid and pentafluoroiodobenzene; | 100% |
With oxygen; isobutyraldehyde In acetonitrile at 60℃; for 18h; | 99% |
Conditions | Yield |
---|---|
at 90℃; for 5h; Inert atmosphere; | 100% |
at 90℃; for 5h; Inert atmosphere; | 100% |
With graphene nanoplates-supported platinum nanoparticles In neat (no solvent) at 80℃; for 2h; Catalytic behavior; | 99% |
Conditions | Yield |
---|---|
With triethyl borane; oxygen In cyclohexane at 20℃; | 100% |
at 30℃; for 17h; (γ-irradiation); |
Conditions | Yield |
---|---|
With 2-pyridylpropylimine rhodium(I)chlorocarbonyl; hydrogen In toluene at 95℃; Catalytic behavior; Reagent/catalyst; Pressure; Temperature; Autoclave; chemoselective reaction; | 100% |
With hydrogen In dichloromethane at 45℃; under 51716.2 Torr; for 16h; Autoclave; Inert atmosphere; Green chemistry; regioselective reaction; | 100% |
With hydrogen In cyclohexane at 120℃; under 37503.8 Torr; for 4h; Autoclave; | 99% |
oct-1-ene
thexylchloroborane * dimethylsulfide
A
octanol
B
rac-octan-2-ol
C
2,3-dimethylbutan-2-ol
Conditions | Yield |
---|---|
With methanol; dihydrogen peroxide Product distribution; different solvents; other olefins; | A 99.2% B 0.8% C 100% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; 6-molybdo-6-tungstophosphoric acid/Al/C In tert-butyl alcohol at 60℃; for 4h; | 100% |
With [Me(n-Oct)3N]3{PO4[WO(O2)2]4}; dihydrogen peroxide In water; 1,2-dichloro-ethane at 95℃; for 5h; Catalytic behavior; Reagent/catalyst; Temperature; Concentration; Reflux; Green chemistry; | 97% |
With jones reagent; osmium(VIII) oxide In water; acetone for 20h; Ambient temperature; | 85% |
Conditions | Yield |
---|---|
With zinc In diethyl ether at 15 - 20℃; for 1.5h; sonication; | 100% |
With zinc/copper couple; trichlorophosphate In diethyl ether Reflux; | |
With zinc-copper couple; trichlorophosphate In diethyl ether Reflux; Inert atmosphere; | |
With zinc/copper couple; trichlorophosphate In diethyl ether at 0℃; Inert atmosphere; Reflux; |
oct-1-ene
1,1,1,3,5,5,5-heptamethyltrisiloxan
3-n-octyl-1,1,1,3,5,5,5-heptamethyltrisiloxane
Conditions | Yield |
---|---|
With tetradecyl(tributyl)phosphonium bis(trifluoromethylsulfonyl)amide; C24H20Cl2P2Pt at 100℃; for 1h; Reagent/catalyst; | 100% |
With tetradecyl(tributyl)phosphonium bis(trifluoromethylsulfonyl)amide; bis(cyclooctadiene (μ-silyloxytrimethyl) rhodium(I)) at 110℃; for 1h; Catalytic behavior; Reagent/catalyst; Time; | 100% |
With nickel 2-ethylhexanoate; 1,4-bis(2,6-diisopropylphenyl)-2,3-dimethyl-1,4-diazabuta-1,3-diene In neat (no solvent) at 23℃; for 6h; regioselective reaction; | 99% |
oct-1-ene
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
4,4,5,5-tetramethyl-2-octyl-[1,3,2]dioxaborolane
Conditions | Yield |
---|---|
With sodium triethylborohydride at 23℃; for 3h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; | 100% |
Wilkinson's catalyst In dichloromethane 25°C, 10 min; | 99% |
With chlorocarbonylbis(triphenylphosphine)rhodium(I) In dichloromethane at 0 - 20℃; for 1.83333h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
With hypophosphorous acid; palladium; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In water; N,N-dimethyl-formamide at 110℃; for 24h; | 100% |
With tris-(dibenzylideneacetone)dipalladium(0); hypophosphorous acid; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; oxygen In N,N-dimethyl-formamide at 110℃; for 20h; | |
Multi-step reaction with 2 steps 1: tris-(dibenzylideneacetone)dipalladium(0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene / tetrahydrofuran / 9 h / 70 °C 2: sodium hydroxide; potassium permanganate / water / 5 h / 15 °C / Cooling with ice View Scheme |
Conditions | Yield |
---|---|
With diisobutylaluminium hydride 75-80°C;; | 100% |
With (iso-C4H9)2AlH 75-80°C;; | 100% |
With diisobutylaluminium hydride 75-80°C;; | 100% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 4h; Inert atmosphere; | 100% |
oct-1-ene
(2S)-2-hexyloxirane
Conditions | Yield |
---|---|
With titanium(IV) isopropylate; Pentafluorobenzoic acid; C32H22F10N2O2; dihydrogen peroxide In water; 1,2-dichloro-ethane at 20℃; for 45h; Inert atmosphere; enantioselective reaction; | 100% |
With titanium(IV) isopropylate; C46H40N2O2; dihydrogen peroxide In dichloromethane; water; 1,2-dichloro-ethane at 20℃; for 100h; Reagent/catalyst; Inert atmosphere; | 82% |
With oxygen; isobutyraldehyde In acetonitrile at 25℃; for 8h; Catalytic behavior; Green chemistry; enantioselective reaction; | 70 %Chromat. |
Conditions | Yield |
---|---|
In Petroleum ether at -10 - 0℃; for 1h; Inert atmosphere; | 100% |
at 0 - 20℃; for 3h; Inert atmosphere; Further stages; | |
In tetrahydrofuran at 20℃; for 1h; Cooling with ice; | |
In diethyl ether Inert atmosphere; Reflux; |
Conditions | Yield |
---|---|
With MesPDI; cobalt(II) stearate In tetrahydrofuran at 60℃; for 5h; Reagent/catalyst; | 100% |
With C22H31Cl2CoN2P In neat (no solvent) at 60℃; for 24h; Reagent/catalyst; Temperature; Sealed tube; Inert atmosphere; regioselective reaction; | 92% |
With 2,6-bis[1-(2,4,6-trimethylimino)ethyl]pyridine; C10H14CoO5 In toluene at 60℃; for 24h; Reagent/catalyst; Temperature; regioselective reaction; | 91% |
With 2,6-bis[1-(2,4,6-trimethylimino)ethyl]pyridine; cobalt(II) tetrafluoroborate hexahydrate In tetrahydrofuran at 20℃; for 4h; Catalytic behavior; Reagent/catalyst; regioselective reaction; | 72 %Spectr. |
Conditions | Yield |
---|---|
at 110℃; Inert atmosphere; Schlenk technique; | 100% |
oct-1-ene
Conditions | Yield |
---|---|
With selenium dibromide In tetrachloromethane at -20 - 20℃; for 18h; regioselective reaction; | 100% |
With selenium dibromide In chloroform at 20 - 25℃; for 18h; regioselective reaction; | 95% |
Stage #1: oct-1-ene With selenium(IV) oxide; hydrogen bromide In diethyl ether; water at 0 - 25℃; for 0.5h; Stage #2: With sodium metabisulfite In benzene at 5 - 25℃; for 2h; | 84% |
oct-1-ene
Conditions | Yield |
---|---|
With tellurium tetrachloride In chloroform at 20 - 25℃; for 20h; regioselective reaction; | 100% |
Conditions | Yield |
---|---|
With tellurium tetrachloride In chloroform at 20 - 25℃; for 20h; regioselective reaction; | 100% |
Conditions | Yield |
---|---|
With tellurium(IV) tetrabromide at 55 - 60℃; for 6h; regioselective reaction; | 100% |
oct-1-ene
Conditions | Yield |
---|---|
With selenium(II) chloride In chloroform at -60 - 20℃; for 18h; regioselective reaction; | 100% |
Stage #1: oct-1-ene With hydrogenchloride; selenium(IV) oxide In diethyl ether; water at 0 - 25℃; for 7h; Stage #2: With sodium metabisulfite In benzene at 5 - 25℃; for 2h; | 80% |
Conditions | Yield |
---|---|
Stage #1: oct-1-ene With tellurium tetrachloride In chloroform at 0 - 20℃; for 14h; Stage #2: ethanol In chloroform for 5h; Reflux; | 100% |
Conditions | Yield |
---|---|
for 2h; UV-irradiation; cooling; | 99.6% |
Conditions | Yield |
---|---|
With Wilkinson's catalyst at 80℃; for 6h; Reagent/catalyst; | 99.3% |
With graphite oxide-supported Karstedt catalyst at 60℃; for 1h; | |
With rhodium(III) chloride trihydrate; diphenyl(3-triethylsilylphenyl)phosphine at 90℃; for 5h; Inert atmosphere; Schlenk technique; |
The 1-Octene, with the CAS registry number 111-66-0, is also known as 1-Caprylene. It belongs to the product categories of 1-Olefins (GC Standard); Analytical Chemistry; Standard Materials for GC; N-OAnalytical Standards; Alpha Sort; Alphabetic; Volatiles/Semivolatiles; Acyclic; Alkenes; Organic Building Blocks; Hydrocarbons; NeatsAnalytical Standards; OGasoline, Diesel & Petroleum; Olefins; Substance classes. Its EINECS number is 203-893-7. This chemical's molecular formula is C8H16 and molecular weight is 112.21. What's more, its IUPAC name is oct-1-ene. It should be sealed and stored in a cool, ventilated and dry place. What's more, it should be protected from oxides, acids, heat and fire. It is used in the area of organic synthesis. It can be used to prepare plasticizer and surface active agent. 1-Octene is a higher olefin, or alkene. It is one of the important linear alpha olefins in industry. The primary use of it is as a comonomer in production of polyethylene. Another significant use of it is for production of linear aldehyde via OXO Synthesis (hydroformylation) for later production of the short-chain fatty acid nonanoic acid, a carboxylic acid, by oxidation of an intermediate aldehyde or linear alcohols for plasticizer application by hydrogenation of the aldehyde.
Physical properties of 1-Octene are: (1)ACD/LogP: 4.50; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 4.5; (4)ACD/BCF (pH 5.5): 1538.72; (5)ACD/KOC (pH 5.5): 6652.22; (6)#Freely Rotating Bonds: 5; (7)Index of Refraction: 1.413; (8)Molar Refractivity: 38.83 cm3; (9)Molar Volume: 155.6 cm3; (10)Surface Tension: 22.5 dyne/cm; (11)Density: 0.72 g/cm3; (12)Flash Point: 21.1 °C; (13)Enthalpy of Vaporization: 34.07 kJ/mol; (14)Boiling Point: 120.9 °C at 760 mmHg; (15)Vapour Pressure: 17.9 mmHg at 25°C.
Preparation: this chemical can be prepared by 1-bromo-octane at the ambient temperature. This reaction will need reagent KOH, triisopropylsilanol and solvent dimethylformamide. The yield is about 97%.
Uses of 1-Octene: it can be used to produce 1-chloro-octan-2-ol by heatibng. It will need reagent chloramine T, H2SO4 and solvent acetone, H2O. The yield is about 75%.
When you are using this chemical, please be cautious about it as the following:
It is highly flammable, so you should keep it away from sources of ignition - No smoking. It is toxic to aquatic organisms as it may cause long-term adverse effects in the aquatic environment. It is harmful as it may cause lung damage if swallowed. This material and its container must be disposed of as hazardous waste. It should be avoided releasing to the environment just refering to special instructions/safety data sheet.
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CCCCCCC=C
(2)InChI: InChI=1S/C8H16/c1-3-5-7-8-6-4-2/h3H,1,4-8H2,2H3
(3)InChIKey: KWKAKUADMBZCLK-UHFFFAOYSA-N
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