2-(tert-Butylamino)ethyl methacrylate supplier

Name
2-(TERT-BUTYLAMINO)ETHYL METHACRYLATE
EINECS 223-228-4
CAS No. 3775-90-4
Density 0.914 g/mL at 25 °C(lit.)
Solubility 10 % water in ester
Melting Point 100～105℃/12 mm
Formula C10H19 N O2
Boiling Point 248 °C at 760 mmHg
Molecular Weight 185.266
Flash Point 103.8 °C
Transport Information
Appearance clear, colourless up to yellowish liquid
Safety Poison by intraperitoneal route. See also ESTERS and AMINES. Combustible when exposed to heat or flame. To fight fire, use alcohol foam, water spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of NO_x.
Risk Codes 36/38-43
Molecular Structure
Hazard Symbols Xi
Synonyms Methacrylicacid, 2-(tert-butylamino)ethyl ester (6CI,7CI,8CI); Ethanol, 2-(tert-butylamino)-,methacrylate (ester) (8CI); 2-(tert-Butylamino)ethyl methacrylate; Ageflex FM4; Mhoromer BM 615; N-tert-Butylaminoethyl methacrylate; t-Butylaminoethylmethacrylate; tert-Butylaminoethyl methacrylate
PSA 38.33000
LogP 1.88470

Synthetic route

: 4620-70-6
2-[(1,1-dimethylethyl)amino]-ethanol

: 80-62-6
methacrylic acid methyl ester

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 24801-88-5
3-(triethoxypropyl) isocyanate

: 10-(tert-butyl)-4,4-diethoxy-9-oxo-3-oxa-8,10-diaza-4-siladodecan-11-yl methacrylate

Conditions

Conditions	Yield
at 45℃;	100%

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 829-85-6
diphenylphosphane

: C22H30NO2P

Conditions

Conditions	Yield
In 2-methyltetrahydrofuran at 90℃; for 4h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction;	89%

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 38565-53-6
(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyl)oxirane

: 2-methyl-acrylic acid 2-[tert-butyl-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-2-hydroxy-undecyl)-amino]-ethyl ester

Conditions

Conditions	Yield
With hydroquinone at 150℃; for 17h;	84%

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 814-68-6
acryloyl chloride

: 1604699-42-4
C13H21NO3

Conditions

Conditions	Yield
With triethylamine In dichloromethane at -10 - 20℃; for 2h; Inert atmosphere;	80%

: 75-44-5
phosgene

: 6278-73-5
2-(4-aminophenyl)benzothiazole

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: C24H27N3O3S

Conditions

Conditions	Yield
Stage #1: phosgene; 2-(4-aminophenyl)benzothiazole In chloroform; toluene Reflux; Stage #2: 2-tert-butylaminoethyl methacrylate In dichloromethane for 0.0166667h;	52%

...Expand

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 506-77-4
cyanogen chloride

: 86239-80-7
1-(tert-butyl-cyano-amino)-2-methacryloyloxy-ethane

Conditions

Conditions	Yield
With potassium carbonate

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 80-62-6
methacrylic acid methyl ester

copolymer; monomer(s): methyl methacrylate; (tert-butylamino)ethyl methacrylate: copolymer; monomer(s): methyl methacrylate; (tert-butylamino)ethyl methacrylate

Conditions

Conditions	Yield
With N-propyl 2-pyridinylmethanimine; copper(I) bromide In toluene at 90℃;

: 79-41-4
poly(methacrylic acid)

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 97-63-2
methyl methacrylate

: 79-39-0
Methacrylamide

: 79-10-7
acrylic acid

poly(acrylic acid-co-N-tert-butylaminoethyl methacrylate-co-ethyl methacrylate-co-methacrylamide-co-methacrylic acid): poly(acrylic acid-co-N-tert-butylaminoethyl methacrylate-co-ethyl methacrylate-co-methacrylamide-co-methacrylic acid)

Conditions

Conditions	Yield
Stage #1: poly(methacrylic acid); 2-tert-butylaminoethyl methacrylate; methyl methacrylate; Methacrylamide; acrylic acid In ethanol; water at 65 - 70℃; for 9h; Stage #2: With tert-butyl peroxypivalate In ethanol; water at 70 - 80℃; for 2.5h; Stage #3: With N-methyl-3-hydroxypropylamine In ethanol; water for 0.166667h;

...Expand

: 79-41-4
poly(methacrylic acid)

: 1663-39-4
tert-Butyl acrylate

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 79-10-7
acrylic acid

poly(acrylic acid-co-methacrylic acid-co-N-(tert-butyl)-aminoethyl methacrylate-co-tert-butyl acrylate): poly(acrylic acid-co-methacrylic acid-co-N-(tert-butyl)-aminoethyl methacrylate-co-tert-butyl acrylate)

Conditions

Conditions	Yield
Stage #1: poly(methacrylic acid); tert-Butyl acrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With 2-Amino-2-methyl-1-propanol In ethanol; water for 0.166667h; Product distribution / selectivity;
Stage #1: poly(methacrylic acid); tert-Butyl acrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With 2-Amino-2-methyl-1-propanol In ethanol; water for 0.166667h; Product distribution / selectivity;

...Expand

: 88-12-0
1-ethenyl-2-pyrrolidinone

: 1663-39-4
tert-Butyl acrylate

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 79-10-7
acrylic acid

poly(acrylic acid-co-N-(tert-butyl) aminomethyl methacrylate-co-tert-butyl acrylate-co-vinylpyrrolidone): poly(acrylic acid-co-N-(tert-butyl) aminomethyl methacrylate-co-tert-butyl acrylate-co-vinylpyrrolidone)

Conditions

Conditions	Yield
Stage #1: 1-ethenyl-2-pyrrolidinone; tert-Butyl acrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With 2-(N,N-dimethylamino)ethanol; α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 63 - 65℃; for 7h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 65 - 80℃; for 2.5h; Stage #3: With 2-(N,N-dimethylamino)ethanol In ethanol; water at 40℃; pH=8.0; Product distribution / selectivity;
Stage #1: 1-ethenyl-2-pyrrolidinone; tert-Butyl acrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With 2-(N,N-dimethylamino)ethanol; α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 63 - 65℃; for 7h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 65 - 80℃; for 2.5h; Stage #3: With 2-(N,N-dimethylamino)ethanol In ethanol; water at 40℃; pH=8.0; Product distribution / selectivity;

Yield

Stage #1: 1-ethenyl-2-pyrrolidinone; tert-Butyl acrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With 2-(N,N-dimethylamino)ethanol; α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 63 - 65℃; for 7h;
Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 65 - 80℃; for 2.5h;
Stage #3: With 2-(N,N-dimethylamino)ethanol In ethanol; water at 40℃; pH=8.0; Product distribution / selectivity;

...Expand

: 88-12-0
1-ethenyl-2-pyrrolidinone

: 1663-39-4
tert-Butyl acrylate

: 107-58-4
N-tert-Butylacrylamide

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 79-10-7
acrylic acid

poly(acrylic acid-co-N-tert-butylarylamide-co-N-(tert-butyl) aminomethyl methacrylate-co-tert-butyl acrylate-co-vinylpyrrolidone): poly(acrylic acid-co-N-tert-butylarylamide-co-N-(tert-butyl) aminomethyl methacrylate-co-tert-butyl acrylate-co-vinylpyrrolidone)

Conditions

Conditions	Yield
Stage #1: 1-ethenyl-2-pyrrolidinone; tert-Butyl acrylate; N-tert-Butylacrylamide; 2-tert-butylaminoethyl methacrylate; acrylic acid With 2-(N,N-dimethylamino)ethanol; α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 63 - 65℃; for 7h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 65 - 80℃; for 2.5h; Stage #3: With 2-(N,N-dimethylamino)ethanol In ethanol; water at 40℃; pH=8.0; Product distribution / selectivity;

Yield

Stage #1: 1-ethenyl-2-pyrrolidinone; tert-Butyl acrylate; N-tert-Butylacrylamide; 2-tert-butylaminoethyl methacrylate; acrylic acid With 2-(N,N-dimethylamino)ethanol; α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 63 - 65℃; for 7h;
Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 65 - 80℃; for 2.5h;
Stage #3: With 2-(N,N-dimethylamino)ethanol In ethanol; water at 40℃; pH=8.0; Product distribution / selectivity;

...Expand

: 1663-39-4
tert-Butyl acrylate

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 79-10-7
acrylic acid

poly(acrylic acid-co-N-(tert-butyl)-aminoethyl methacrylate-co-tert-butyl acrylate): poly(acrylic acid-co-N-(tert-butyl)-aminoethyl methacrylate-co-tert-butyl acrylate)

Conditions

Conditions	Yield
Stage #1: tert-Butyl acrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With 2-Amino-2-methyl-1-propanol In ethanol; water for 0.166667h; Product distribution / selectivity;
Stage #1: tert-Butyl acrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With 2-Amino-2-methyl-1-propanol In ethanol; water for 0.166667h; Product distribution / selectivity;

...Expand

: 1663-39-4
tert-Butyl acrylate

: 585-07-9
tert-Butyl methacrylate

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 79-10-7
acrylic acid

poly(acrylic acid-co-N-(tert-butyl) aminoethyl methacrylate-co-tert-butyl acrylate-tert-butyl methacrylate): poly(acrylic acid-co-N-(tert-butyl) aminoethyl methacrylate-co-tert-butyl acrylate-tert-butyl methacrylate)

Conditions

Conditions	Yield
Stage #1: tert-Butyl acrylate; tert-Butyl methacrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With 2-Amino-2-methyl-1-propanol In ethanol; water for 0.166667h; Product distribution / selectivity;

...Expand

: 1663-39-4
tert-Butyl acrylate

: 107-58-4
N-tert-Butylacrylamide

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 79-10-7
acrylic acid

poly(acrylic acid-co-N-tert-butylacrylamide-co-N-(tert-butyl) aminoethyl methacrylate-co-tert-butyl acrylate): poly(acrylic acid-co-N-tert-butylacrylamide-co-N-(tert-butyl) aminoethyl methacrylate-co-tert-butyl acrylate)

Conditions

Conditions	Yield
Stage #1: tert-Butyl acrylate; N-tert-Butylacrylamide; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With 2-Amino-2-methyl-1-propanol In ethanol; water for 0.166667h; Product distribution / selectivity;
Stage #1: tert-Butyl acrylate; N-tert-Butylacrylamide; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With 2-Amino-2-methyl-1-propanol In ethanol; water for 0.166667h; Product distribution / selectivity;
Stage #1: tert-Butyl acrylate; N-tert-Butylacrylamide; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With 2-Amino-2-methyl-1-propanol In ethanol; water for 0.166667h; Product distribution / selectivity;

...Expand

: N-tert-octylacrylamide

: 1663-39-4
tert-Butyl acrylate

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 79-10-7
acrylic acid

poly(acrylic acid-co-N-(tert-butyl) aminoethyl methacrylate-co-N-tert-octylacrylamide-co-tert-butyl acrylate): poly(acrylic acid-co-N-(tert-butyl) aminoethyl methacrylate-co-N-tert-octylacrylamide-co-tert-butyl acrylate)

Conditions

Conditions	Yield
Stage #1: N-tert-octylacrylamide; tert-Butyl acrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With triethanolamine In ethanol; water for 0.166667h; Product distribution / selectivity;

...Expand

: 3775-90-4
2-tert-butylaminoethyl methacrylate

poly(2-(tert-butylamino)ethyl methacrylate): poly(2-(tert-butylamino)ethyl methacrylate)

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In propan-1-ol; butanone at 60℃; for 5h;

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 97-88-1
2-methyl-butyl acrylate

poly(2-(tert-butylamino)ethyl methacrylate-co-n-butyl methacrylate): poly(2-(tert-butylamino)ethyl methacrylate-co-n-butyl methacrylate)

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile) In propan-1-ol; butanone at 60℃; for 5h;

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 4098-71-9
isophorone diisocyanate

: C22H37N3O4

Conditions

Conditions	Yield
at 30℃;

: 15875-49-7
5-furfurylidene-2,2-dimethyl-[1,3]dioxane-4,6-dione

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: 2-(tert-butyl ((1E,3Z)-5-(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)-4-hydroxypenta-1,3-dien-1-yl)amino)ethyl methacrylate

Conditions

Conditions	Yield
In tetrahydrofuran at 25℃; for 1h;	1.67 g

: 3775-90-4
2-tert-butylaminoethyl methacrylate

: C70H116N4O23

: C90H154N6O27

Conditions

Conditions	Yield
With hydroquinone In dichloromethane at 5 - 20℃; for 14h;	215 g

2-(tert-Butylamino)ethyl methacrylate Chemical Properties

Product Name: 2-(TERT-BUTYLAMINO)ETHYL METHACRYLATE
Synonyms: 2-(tert-butylamino)-ethanomethacrylate(ester);2-Methyl-2-propenoicacid,2-[(1,1-dimethylethyl)amino]ethylester;2-(tert-Butylamino)ethyl 2-methylacrylate;;2-[(1,1-Dimethylethyl)amino]ethyl2-methyl-2-propenoate;2-Propenoic acid, 2-methyl-, 2-[(1,1-dimethylethyl)amino]ethyl ester;2-propenoicacid,2-methyl-,2-((1,1-dimethylethyl)amino)ethylester;2-[(1,1-Dimethylethyl)amino ]ethyl 2-methyl-2-propenoate
Molecular formula: C₁₀H₁₉NO₂
Molar mass: 185.26
Boiling point: 82 °C10 mm Hg(lit.)
density : 0.914 g/mL at 25 °C(lit.)
refractive index : n20/D 1.442(lit.)
Fp : 160 °F

2-(tert-Butylamino)ethyl methacrylate Toxicity Data With Reference

ipr-mus LD50:174 mg/kg

JDREAF Journal of Dental Research. 51 (1972),526.

2-(tert-Butylamino)ethyl methacrylate Consensus Reports

Reported in EPA TSCA Inventory.

2-(tert-Butylamino)ethyl methacrylate Safety Profile

Poison by intraperitoneal route. See also ESTERS and AMINES. Combustible when exposed to heat or flame. To fight fire, use alcohol foam, water spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of NO_x.

Risk Statements :36/38: Irritating to eyes and skin ;43: May cause sensitization by skin contact
Safety Statements : 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Hazard Codes : Xi
RIDADR : 1760
WGK Germany : 1

Product Name

2-(TERT-BUTYLAMINO)ETHYL METHACRYLATE

Synthetic route

2-(tert-Butylamino)ethyl methacrylate Chemical Properties

2-(tert-Butylamino)ethyl methacrylate Toxicity Data With Reference

2-(tert-Butylamino)ethyl methacrylate Consensus Reports

2-(tert-Butylamino)ethyl methacrylate Safety Profile

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