3,3',4,4'-Diphenylsulfonetetracarboxylic dianhydride supplier

Name
3,3',4,4'-DIPHENYLSULFONETETRACARBOXYLIC DIANHYDRIDE
EINECS
CAS No. 2540-99-0
Article Data5
CAS DataBase
Density 1.756 g/cm³
Solubility
Melting Point 283 °C
Formula C₁₆H₆O₈S
Boiling Point 718.549 °C at 760 mmHg
Molecular Weight 358.285
Flash Point 388.364 °C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Phthalicanhydride, 4,4'-sulfonyldi- (7CI,8CI);3,3',4,4'-Diphenyl sulfonetetracarboxylic anhydride;3,3',4,4'-Diphenyl sulfone tetracarboxylicdianhydride;3,3',4,4'-Diphenylsulfoxide tetracarboxylic acid;3,3',4,4'-Tetracarboxydiphenyl sulfone dianhydride;3,4,3',4'-Diphenylsulfonete tracarboxylic acid dianhydride;4,4'-Diphthalic anhydride sulfone;4,4'-Sulfonylbis(phthalic anhydride);4,4'-Sulfonyldiphthalic acid dianhydride;4,4'-Sulfonyldiphthalic anhydride;Bis(3,4-dicarboxyphenyl)sulfone dianhydride;NSC 689416;Rikacid DSDA;3,3',4,4'-Diphenylsulfonetetracarboxylic dianhydride;
PSA 129.26000
LogP 2.22140

Synthetic route

: 10595-31-0
3,3’,4,4’-diphenylsulfonetetracarboxylic acid

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

Conditions

Conditions	Yield
With 2,6-bis[(2,2,6,6-tetramethylpiperidin-1-yl)methyl]phenylboronic acid In propyl cyanide for 12h; Reflux;	92%

: 25884-43-9
3,3′,4,4′-diphenylsulfidetetracarboxylic dianhydride

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

Conditions

Conditions	Yield
With dipotassium peroxodisulfate; ammonium cerium (IV) nitrate; tetra-(n-butyl)ammonium iodide In water; acetonitrile at 60℃; Temperature; Solvent; Reagent/catalyst;

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 107-11-9
1-amino-2-propene

: C22H16N2O6S

Conditions

Conditions	Yield
With acetic acid at 20℃; for 9h; Inert atmosphere; Reflux;	92%

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 328-39-2
LEUCINE

: C28H28N2O10S

Conditions

Conditions	Yield
With acetic acid at 120℃;	90%

: aluminum(III) nitrate nonahydrate

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: [Al2(OH)2(DPSTC)(H2O)2]·0.5H2O

Conditions

Conditions	Yield
With sodium hydroxide In water at 170℃; for 5h; Microwave irradiation;	85%

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 328-38-1
(R)-leucine

: C28H28N2O10S

Conditions

Conditions	Yield
With acetic acid at 120℃; for 0.166667h; Microwave irradiation;	79%

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: gallium(III) nitrate heptahydrate

: 7732-18-5
water

: Ga-CAU-11-COOH

Conditions

Conditions	Yield
With acetic acid; sodium hydroxide at 180℃; for 24h; Autoclave;	77%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 61-90-5
L-leucine

: C28H28N2O10S

Conditions

Conditions	Yield
With acetic acid at 120℃; for 0.166667h; Microwave irradiation;	72%

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 108-46-3
recorcinol

: 2-(3,6,9-trihydroxyxanthen-9-yl)-5-(3,4-dicarboxyphenylsulfonyl)benzoic acid lactone

Conditions

Conditions	Yield
at 180℃; for 6h;	66.5%

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 10595-31-0
3,3’,4,4’-diphenylsulfonetetracarboxylic acid

Conditions

Conditions	Yield
With water Hydrolysis; Heating;	65%

: 553-26-4
4,4'-bipyridine

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 7732-18-5
water

: silver nitrate

: [Ag(4,4'-bipyridine)]2*3,3',4,4'-tetracarboxydiphenylsulfone(2-)*2water

Conditions

Conditions	Yield
In water High Pressure; heating a mixt. of silver salt, ligand and bipyridine in water in autoclave at 120°C for 4 d, cooling to room temp. during 8 h; elem. anal.;	65%

...Expand

: 66-71-7
1,10-Phenanthroline

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: copper(II) nitrate trihydrate

: 7732-18-5
water

: [Cu4(3,3',4,4'-diphenylsulfonetetracarboxylic acid-2H)4(1,10-phenanthroline)4]*12H2O

Conditions

Conditions	Yield
In water High Pressure; mixt. of Cu(NO3)2*3H2O (0.10 mmol), 3,3',4,4'-diphenylsulfonetetracarboxylic dianhydride (0.05 mmol), phenenthroline (0.05 mmol) and H2O stirred(20 min) in air; heated in autoclave (160°C, 72 h); cooled to room temp. (5°C/h); elem. anal.;	65%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 7732-18-5
water

: 6147-53-1
cobalt(II) diacetate tetrahydrate

: 1135-32-6
trans-1,2-bis(4-pyridyl)ethylene

: {[Co2(dstc)(bpe)2(H2O)2]·2H2O}n

Conditions

Conditions	Yield
In water at 150℃; for 72h; Autoclave;	65%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: silver nitrate

: 1135-32-6
trans-1,2-bis(4-pyridyl)ethylene

: [Ag(bpe)2]·H3dstc

Conditions

Conditions	Yield
In water at 120℃; for 72h; Autoclave;	55%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 89-00-9
Pyridine-2,3-dicarboxylic acid

: 12125-02-9
ammonium chloride

: copper dichloride

: C58H24Cu2N22O2S

Conditions

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	54%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 4916-57-8
1,2-bis(4'-pyridyl)ethane

: 7732-18-5
water

: 6147-53-1
cobalt(II) diacetate tetrahydrate

: {[Co2(dstc)(bpe)2(H2O)2]·2H2O}n

Conditions

Conditions	Yield
In water at 150℃; for 72h; Autoclave;	52%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 56-40-6
glycine

: C20H12N2O10S

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 100℃;	52%

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 89-00-9
Pyridine-2,3-dicarboxylic acid

: 12125-02-9
ammonium chloride

: nickel dichloride

: C58H24N22Ni2O2S

Conditions

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	51%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 17252-51-6
1,3-di(4-pyridyl)propane

: 7732-18-5
water

: silver nitrate

: [Ag(bpe)2]·H3dstc

Conditions

Conditions	Yield
In water at 130℃; for 72h; Autoclave;	50%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: aluminium(III) chloride hexahydrate

: ([Al(OH)(H2DPSTC)]·0.5H2O)

Conditions

Conditions	Yield
With sodium hydroxide In water at 170℃; for 5h; Microwave irradiation;	50%

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: C13H15Cl2N3

: C42H32Cl4N6O6S

Conditions

Conditions	Yield
In toluene for 13h; Reflux;	46%

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 89-00-9
Pyridine-2,3-dicarboxylic acid

: 12125-02-9
ammonium chloride

: iron(II) chloride

: C58H24Fe2N22O2S

Conditions

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	44%

...Expand

: 553-26-4
4,4'-bipyridine

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 7732-18-5
water

: 5743-04-4
cadmium(II) acetate dihydrate

: 1310-73-2
sodium hydroxide

: ([Cd5(3,3',4,4'-diphenylsulfonetetracarboxylic acid-4H)2(4,4'-bipyridine)2(μ3-OH)2(H2O)4]*4H2O)n

Conditions

Conditions	Yield
In water High Pressure; mixt. of Cd(CH3COO)2*2H2O (0.1 mmol), 3,3',4,4'-diphenylsulfonetetracarboxylic dianhydride (0.05 mmol), 4,4'-bipyridine (0.05 mmol), NaOH (0.2 mmol) and H2O stirred (20 min) in air; heated in autoclave (160°C,72 h); cooled to room temp. (5°C/h); elem. anal.;	43%

...Expand

: 553-26-4
4,4'-bipyridine

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: copper(II) nitrate trihydrate

: 7732-18-5
water

: 1310-73-2
sodium hydroxide

: [Cu3(3,3',4,4'-diphenylsulfonetetracarboxylic acid-4H)(4,4'-bipyridine)(μ2-OH)2(H2O)2]n

Conditions

Conditions	Yield
In water High Pressure; mixt. of Cu(NO3)2*3H2O (0.10 mmol), 3,3',4,4'-diphenylsulfonetetracarboxylic dianhydride (0.05 mmol), 4,4'-bipyridine (0.05 mmol), NaOH (0.2 mmol) and H2O stirred (20 min) in air; heated in autoclave (160°C, 72 h); cooled to room temp. (5°C/h); elem. anal.;	40%

...Expand

: 66-71-7
1,10-Phenanthroline

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: cadmium(II) acetate trihydrate

: 7803-57-8
hydrazine hydrate

: C16H8N4O6S(2-)*C12H8N2*2H2O*Cd(2+)

Conditions

Conditions	Yield
In water at 170℃; for 96h; pH=8;	40%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: copper(II) nitrate trihydrate

: 7732-18-5
water

: 1135-32-6
trans-1,2-bis(4-pyridyl)ethylene

: ([Cu2(3,3',4,4'-diphenylsulfonetetracarboxylic acid-4H)(1,2-bis(4-pyridyl)ethene)(H2O)2]*4H2O)n

Conditions

Conditions	Yield
With NaOH In water High Pressure; mixt. of Cu(NO3)2*3H2O (0.10 mmol), 3,3',4,4'-diphenylsulfonetetracarboxylic dianhydride (0.05 mmol), 1,2-bis(4-pyridyl)ethene (0.05 mmol), NaOH(0.2 mmol) and H2O stirred (20 min) in air; heated in autoclave (160.de gree.C, 72 h); cooled to room temp. (5°C/h); elem. anal.;	36%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 89-00-9
Pyridine-2,3-dicarboxylic acid

: 12125-02-9
ammonium chloride

: 7646-79-9
cobalt(II) chloride

: C58H24Co2N22O2S

Conditions

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	25%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 89-00-9
Pyridine-2,3-dicarboxylic acid

: 12125-02-9
ammonium chloride

: manganese(ll) chloride

: C58H24Mn2N22O2S

Conditions

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	25%

...Expand

: 31951-46-9
N,N'-dipiperidylpropane

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 7732-18-5
water

: 5970-45-6
zinc(II) acetate dihydrate

: [H2(1,3-bis(piperidyl)propane)]2[Zn2(4,4′-sulfonediphthalate)2]*H2O

Conditions

Conditions	Yield
With triethylamine In methanol at 140℃; for 72h; pH=7; High pressure;	20%

...Expand

: 2540-99-0
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

: 89-00-9
Pyridine-2,3-dicarboxylic acid

: 12125-02-9
ammonium chloride

: 7646-85-7
zinc(II) chloride

: C58H24N22O2SZn2

Conditions

Conditions	Yield
With ammonium dimolybdate; urea for 10h; Heating; Reflux;	11%

...Expand

3,3',4,4'-Diphenylsulfonetetracarboxylic dianhydride Specification

The 3,3',4,4'-Diphenylsulfonetetracarboxylic dianhydride, with the CAS registry number 2540-99-0, is also known as 4,4'-Diphthalic anhydride sulfone. It belongs to the product categories of Aromatic Tetracarboxylic Dianhydrides (for High-Performance Polymer Research); Diphenyl Sulfones (for High-Performance Polymer Research); Functional Materials; Reagent for High-Performance Polymer Research. This chemical's molecular formula is C₁₆H₆O₈S and molecular weight is 358.28. What's more, its systematic name is 5,5'-Sulfonylbis(2-benzofuran-1,3-dione).

Physical properties of 3,3',4,4'-Diphenylsulfonetetracarboxylic dianhydride are: (1)ACD/LogP: 0.324; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.32; (4)ACD/LogD (pH 7.4): 0.32; (5)ACD/BCF (pH 5.5): 1.04; (6)ACD/BCF (pH 7.4): 1.04; (7)ACD/KOC (pH 5.5): 35.73; (8)ACD/KOC (pH 7.4): 35.73; (9)#H bond acceptors: 8; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 129.26 Å²; (13)Index of Refraction: 1.697; (14)Molar Refractivity: 78.642 cm³; (15)Molar Volume: 204.054 cm³; (16)Polarizability: 31.176×10^-24cm³; (17)Surface Tension: 81.2 dyne/cm; (18)Density: 1.756 g/cm³; (19)Flash Point: 388.364 °C; (20)Enthalpy of Vaporization: 104.992 kJ/mol; (21)Boiling Point: 718.549 °C at 760 mmHg; (22)Vapour Pressure: 0 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C4OC(=O)c1c4cc(cc1)S(=O)(=O)c2ccc3C(=O)OC(=O)c3c2
(2)Std. InChI: InChI=1S/C16H6O8S/c17-13-9-3-1-7(5-11(9)15(19)23-13)25(21,22)8-2-4-10-12(6-8)16(20)24-14(10)18/h1-6H
(3)Std. InChIKey: ZHBXLZQQVCDGPA-UHFFFAOYSA-N

Product Name

3,3',4,4'-DIPHENYLSULFONETETRACARBOXYLIC DIANHYDRIDE

Synthetic route

3,3',4,4'-Diphenylsulfonetetracarboxylic dianhydride Specification

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