Conditions | Yield |
---|---|
(10)B2O3 was dissolved in H2O, evaporation to dryness at room temp.;; |
Conditions | Yield |
---|---|
at 25℃; Activation energy; |
Conditions | Yield |
---|---|
In neat (no solvent) Reflux; Inert atmosphere; | 96% |
Inert atmosphere; Reflux; | 95% |
In toluene byproducts: H2O; (Schlesinger, H. I., et al.; J. Am. Chem. Soc., 1953, v. 75, pp. 216-215); to anhyd. H3(10)BO3 b-BuOH and toluene added; mixt. heated to 130°C over 5 h; distilled at 226-228°C under 1 atm; | 87% |
With sulfuric acid In toluene at 130℃; for 3.5h; | 73.58% |
[10B]boric acid
2-methoxy-N,N-bis(2-methoxyphenyl)-aniline
2,2',2''-nitrilotriphenyl borate
Conditions | Yield |
---|---|
In toluene byproducts: H2O; heating a mixture of 0.61 g (10-B) boric acid and 3 g 2,2',2''-nitrilotriphenol in 50 ml toluene under reflux, evaporation and sublimation at 300°C, 0.05 Torr;; elem. anal.;; | 90% |
Conditions | Yield |
---|---|
room temperature; trap to trap condensation in vacuum, determination of purity by IR; | 75% |
Conditions | Yield |
---|---|
chlorinated at 560°C; | 75% |
Conditions | Yield |
---|---|
With calcium hydride at 90℃; Inert atmosphere; Schlenk technique; | 54% |
With calcium hydride In neat (no solvent) at 90℃; for 16h; Inert atmosphere; |
Conditions | Yield |
---|---|
Stage #1: 2,3-dimethyl-2,3-butane diol; [10B]boric acid In benzene at 100℃; for 10h; Stage #2: With sodium tetrahydroborate In benzene | 35% |
Conditions | Yield |
---|---|
In neat (no solvent) sol-gel method; accordingly to K. S. Chou, J. Non Cryst. Solids 110 (1989) 122, A. Adamczyk, PhD Thesis, University of Mining and Metallurgy, Krakow, 1999 and A. Adamczyk et al., XXII EUCMOS, Balatonfuered, Hungary, 1996; |
Conditions | Yield |
---|---|
In neat (no solvent) sol-gel method; accordingly to K. S. Chou, J. Non Cryst. Solids 110 (1989) 122, A. Adamczyk, PhD Thesis, University of Mining and Metallurgy, Krakow, 1999 and A. Adamczyk et al., XXII EUCMOS, Balatonfuered, Hungary, 1996; |
Conditions | Yield |
---|---|
In neat (no solvent) sol-gel method; accordingly to K. S. Chou, J. Non Cryst. Solids 110 (1989) 122, A. Adamczyk, PhD Thesis, University of Mining and Metallurgy, Krakow, 1999 and A. Adamczyk et al., XXII EUCMOS, Balatonfuered, Hungary, 1996; |
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) well ground, mixed under petroleum ether, heated in a covered platinum crucible up to 850°C for 1 d, reground and heated by steps of 50°C up to a maximum of 1100°C; observed by IR spectroscopy and X-ray diffraction; |
Conditions | Yield |
---|---|
In neat (no solvent, solid phase) well ground, mixed under petroleum ether, heated in a covered platinum crucible up to 850°C for 1 d, reground and heated by steps of 50°C up to a maximum of 1100°C; observed by IR spectroscopy and X-ray diffraction; |
Conditions | Yield |
---|---|
In not given |
Conditions | Yield |
---|---|
In neat (no solvent) powder ground, gradually heated in a Pt crucible, evolution of gases, sintered (24 h, 800°C); starting material: boric acid with 92.4% (10)B isotopic purity; |
Conditions | Yield |
---|---|
In neat (no solvent) powder ground, gradually heated in a Pt crucible, evolution of gases, sintered (24 h, 800°C); starting material: boric acid with 92.4% (10)B isotopic purity; |
[10B]boric acid
trihydroxy boroxine
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: H2O; 95-100°C, 24h;; | |
In toluene byproducts: H2O; dehydration in boiling toluene by azeotropic distn.;; | |
In toluene byproducts: H2O; dehydration in boiling toluene by azeotropic distn.;; | |
In neat (no solvent) byproducts: H2O; 95-100°C, 24h;; |
Conditions | Yield |
---|---|
In melt melting, casting, annealing (500°C); |
Conditions | Yield |
---|---|
In melt melting, casting, annealing (500°C); |
ammonium dihydrogen phosphate
[10B]boric acid
Conditions | Yield |
---|---|
In neat (no solvent) mixing, pressing into pellets, heating (Pt crucible, 400°C, 4 h),grinding, pelletizing, calcination (1350+/-10°C, 72 h), cooling (room temp.); |
Conditions | Yield |
---|---|
In neat (no solvent) sol-gel method; accordingly to K. S Chou, J. Non Cryst. Solids 110 (1989) 122, A. Adamczyk, PhD Thesis, University of Mining and Metallurgy, Krakow, 1999 and A. Adamczyk et al., XXIII EUCMOS, Balatonfuered, Hungary, 1996; |
Conditions | Yield |
---|---|
In neat (no solvent) fusing, standing (1 h), quenching by removing the platinum crucible fromthe furnace, cooling (dry N2 atm.); |
Conditions | Yield |
---|---|
In neat (no solvent) fusing, standing (1 h), quenching by removing the platinum crucible fromthe furnace, cooling (dry N2 atm.); |
Conditions | Yield |
---|---|
In neat (no solvent) fusing, standing (1 h), quenching by removing the platinum crucible fromthe furnace, cooling (dry N2 atm.); |
Conditions | Yield |
---|---|
In neat (no solvent) fusing, standing (1 h), quenching by removing the platinum crucible fromthe furnace, cooling (dry N2 atm.); |
Conditions | Yield |
---|---|
In neat (no solvent) fusing, standing (1 h), quenching by removing the platinum crucible fromthe furnace, cooling (dry N2 atm.); |
Conditions | Yield |
---|---|
In neat (no solvent) fusing, standing (1 h), quenching by removing the platinum crucible fromthe furnace, cooling (dry N2 atm.); |
Conditions | Yield |
---|---|
In neat (no solvent) fusing, standing (1 h), quenching by removing the platinum crucible fromthe furnace, cooling (dry N2 atm.); |
Conditions | Yield |
---|---|
In not given reacting, removing solvent, sintering slightly below m. p.; |
Conditions | Yield |
---|---|
In not given reacting, removing solvent, sintering slightly below m. p.; |
Conditions | Yield |
---|---|
In not given HF, H3(10)BO3, Na2CO3 reacted according to H. S. Booth, K. S. Wilson, Inorg. Syn. 1 (1939) 21; |
The Boric-10B acid, with the CAS registry number 13813-79-1, is also known as (10B)Orthoboric acid. It belongs to the product categories of Alphabetical Listings; B; Stable Isotopes. Its EINECS registry number is 237-478-7. This chemical's molecular formula is H310BO3 and molecular weight is 61.83. Its IUPAC name is called boric acid. This chemical's classification code is TSCA Flag P [A commenced PMN (Premanufacture Notice) substance].
Physical properties of Boric-10B acid: (1)ACD/BCF (pH 5.5): 1; (2)ACD/BCF (pH 7.4): 1; (3)ACD/KOC (pH 7.4): ; (4)#H bond acceptors: 3; (5)#H bond donors: 3; (6)#Freely Rotating Bonds: 3; (7)Index of Refraction: 1.385; (8)Molar Refractivity: 10.083 cm3; (9)Molar Volume: 43.003 cm3; (10)Surface Tension: 59.198 dyne/cm; (11)Density: 1.438 g/cm3.
When you are using this chemical, please be cautious about it as the following:
This chemical may cause damage to health. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: B(O)(O)O
(2)InChI: InChI=1S/BH3O3/c2-1(3)4/h2-4H
(3)InChIKey: KGBXLFKZBHKPEV-UHFFFAOYSA-N
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