Cyclododecene supplier | CasNO.1501-82-2

Name
CYCLODODECENE
EINECS 216-117-7
CAS No. 1501-82-2
Article Data51
CAS DataBase
Density 0.806 g/cm³
Solubility Insoluble in water. Soluble in alcohol.
Melting Point 9°C
Formula C₁₂H₂₂
Boiling Point 238.1 °C at 760 mmHg
Molecular Weight 166.307
Flash Point 93.9 °C
Transport Information
Appearance colourless liquid
Safety 37 23-24/25
Risk Codes 38
Molecular Structure
Hazard Symbols Xi
Synonyms 1-Cyclododecene;Cyclododecene (c,t);Cyclododecene,c&t;CYCLODODECENE;CYCLODECENE;Cyclododecene (cis- and trans- mixture);Cyclododecene (cis+trans);Cyclododecene, ca 70% trans isomer
PSA 0.00000
LogP 4.45720

Synthetic route

: 4904-61-4
cyclododeca-1,5,9-triene

A: 294-62-2
cyclododecane

B: 1501-82-2
cyclododecene

C: 1502-04-1, 67881-13-4
cyclododeca-1,5-diene

Conditions

Conditions	Yield
With hydrogen at 80 - 160℃; under 760.051 Torr; Reagent/catalyst; Flow reactor;	A 100% B n/a C n/a
With hydrogen; Ru4Sn6/Davison 923 mesoporous silica at 119.84℃; under 22502.3 Torr; for 12h; Product distribution; Further Variations:; reaction times;

...Expand

: 51371-31-4
meso-1,2-dibromocyclododecane

: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With triethyl borane; tri-n-butyl-tin hydride In hexane; toluene at -78℃; for 0.5h;	96%

: 87563-19-7
2-(cyclododecyloxy)tropone

A: 533-75-5
2-hydroxy-2,4,6-cycloheptatrien-1-one

B: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
In dimethylsulfoxide-d6 at 180℃; for 2h;	A n/a B 95%

: 97-94-9
triethyl borane

: 4373-12-0
O-cyclododecyl-S-methyl dithiocarbonate

A: 10596-55-1
S-Ethyl S'-methyl dithiocarbonate

B: 294-62-2
cyclododecane

C: 1501-82-2
cyclododecene

D: 88011-88-5
1,1'-bicyclododecane

E: 830-13-7
cyclododecanone

Conditions

Conditions	Yield
With air In hexane Product distribution; Mechanism; Ambient temperature; variation of temperature; other thiocarbonyl derivatives;	A 91% B 62% C 12% D 9% E 4%

...Expand

: 1724-39-6
cyclododecanol

: 1821-12-1
4-Phenylbutyric acid

A: 1501-82-2
cyclododecene

B: cyclododecyl 4-phenylbutyrate

Conditions

Conditions	Yield
CHF3O3S*C14H13N In n-heptane at 115℃; for 6 - 9h; Product distribution / selectivity;	A 10% B 90%
diphenylammonium trifluoromethanesulfonate In n-heptane at 115℃; for 6 - 10h; Product distribution / selectivity;	A 20% B 71%
With sulfonated polypyrene In n-heptane at 80℃; for 24h;	A 35% B 45%

...Expand

: 6773-29-1
dimethyl diazomalonate

: 286-99-7
1,2-epoxycyclododecane

A: 3298-40-6
mesoxalate de methyle

B: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With dirhodium tetraacetate In benzene for 0.75h; Heating;	A n/a B 85%

...Expand

: 1-(triethoxysilyl)-cyclododecene

: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With silver fluoride In tetrahydrofuran; methanol; water	84%

: 884-36-6
cyclododecanecarboxylic acid

: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With 2,2-dimethylpropanoic anhydride; bis[2-(diphenylphosphino)phenyl] ether; palladium dichloride In various solvent(s) at 110℃; for 16h;	81%

: 706-31-0
(1E,5E,9Z)-cyclododeca-1,5,9-triene

A: 294-62-2
cyclododecane

B: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With hydrogen at 240℃; under 760.051 Torr; Reagent/catalyst; Flow reactor;	A 71% B 26%

: 888021-89-4
2-cyclododecyloxysulfonyl-benzoic acid 2-(2-methoxy-ethoxy)-ethyl ester

A: 34039-83-3
chlorocyclododecane

B: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With titanium tetrachloride In dichloromethane at -78℃;	A 66% B 21%

: Dodecahydro-1,3-dioxa-2-thia-cyclopentacyclododecene 2,2-dioxide

: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With iodine; triphenylphosphine In N,N-dimethyl-formamide Heating;	65%

: 4904-61-4
cyclododeca-1,5,9-triene

A: 1501-82-2
cyclododecene

B: 1502-04-1, 67881-13-4
cyclododeca-1,5-diene

Conditions

Conditions	Yield
With hydrogen at 240℃; under 760.051 Torr; for 0.000638889h;	A 65% B 25%
Stage #1: cyclododeca-1,5,9-triene With hydrogen; 0.5% palladium on alumina at 120℃; under 825.083 Torr; Industry scale; Gas phase; Stage #2: 0.5% palladium on alumina Product distribution / selectivity;	A n/a B 0.2%
Stage #1: cyclododeca-1,5,9-triene With carbon monoxide; hydrogen; 0.5% palladium on alumina at 120℃; under 825.083 Torr; Industry scale; Gas phase; Stage #2: 0.5% palladium on alumina Product distribution / selectivity;	A n/a B 0.2%
With hydrogen; Ru4Sn6/Davison 923 mesoporous silica at 99.84℃; under 22502.3 Torr; for 8h; Product distribution; Further Variations:; Catalysts; Temperatures;

: 286-99-7
1,2-epoxycyclododecane

: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With bis(cyclopentadienyl)titanium dichloride; manganese In tetrahydrofuran at 20℃; Inert atmosphere;	60%
With niobium pentachloride; zinc In tetrahydrofuran; benzene at 23℃; for 24h; Inert atmosphere;	45%
With triethylsilane; [NiNPtBu3]4 In toluene at 90℃; for 12h; Inert atmosphere; Sealed tube;

: 5037-22-9
formyl cyclododecane

A: 1892-12-2
hydroxymethylcyclododecane

B: 294-62-2
cyclododecane

C: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With [(η4-Ph4C4C-OH)(1,3-bis-(2,6-diisopropylphenyl)imidazol-2-ylidene)IrH2] In 1,3,5-trimethyl-benzene at 160℃; for 20h; Temperature; Concentration; Solvent;	A 14 %Chromat. B n/a C 55%

...Expand

: 61682-10-8
cyclododecyl iodide

: 100-52-7
benzaldehyde

A: 294-62-2
cyclododecane

B: 1501-82-2
cyclododecene

C: 108229-11-4
1-cyclododecyl-1-phenylmethanol

Conditions

Conditions	Yield
With chromium dichloride; cobalt(II) phthalocyanine In N,N-dimethyl-formamide at 30℃; for 20h;	A 21% B 54% C 2%

...Expand

: 7795-35-9
cyclododecyl bromide

A: 294-62-2
cyclododecane

B: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With zinc; cob(I)alamin In water; acetic acid at 0℃; for 1h;	A 17 % Chromat. B 76.7 % Chromat.

: 4904-61-4
cyclododeca-1,5,9-triene

: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With hydrogen; nickel(II) In methanol at 150℃; under 36752.9 Torr; var. solvents, var. catalysts Co and Ni complexes; other object of study- activity of catalysts;
With ruthenium trichloride; formaldehyd; hydrogen; acetic acid; triphenylphosphine In ethanol; water at 25 - 160℃; under 7500.75 - 15001.5 Torr; for 6.66667h;
With ruthenium trichloride; formaldehyd; hydrogen; acetic acid; triphenylphosphine In ethanol; water at 25 - 160℃; under 7500.75 - 15001.5 Torr; for 6.66667h;
With ruthenium trichloride; formaldehyd; hydrogen; acetic acid; triphenylphosphine In ethanol at 160℃; under 15001.5 Torr; Temperature; Pressure;

: 1724-39-6
cyclododecanol

: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With silica gel; copper(II) sulfate In 1,1,2,2-tetrachloroethylene for 1h; Heating; pentadecane (internal standard in g.l.c. analysis);	98 % Chromat.
With silica gel; copper(II) sulfate In 1,1,2,2-tetrachloroethylene for 0.416667h; Product distribution; Thermodynamic data; Mechanism; Heating; other solvents, catalysts, adsorbents, different time;	98 % Chromat.

: 27092-44-0
Cyclododecyl p-toluenesulphonate

A: 1501-82-2
cyclododecene

B: 1724-39-6
cyclododecanol

Conditions

Conditions	Yield
In water at 100℃; for 15h; Yield given. Yields of byproduct given;

: 51306-71-9, 51371-31-4, 66768-00-1
trans-1,2-dibromocyclododecane

: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With tetrahydrofuran; chromium chloride; lithium aluminium tetrahydride In N,N-dimethyl-formamide at 90℃; Yield given;

: 97567-72-1
Cyclododecyl phenyl telluride

A: 1501-82-2
cyclododecene

B: 1724-39-6
cyclododecanol

C: 6221-92-7
cyclododecyl acetate

D: 830-13-7
cyclododecanone

Conditions

Conditions	Yield
With sodium periodate; acetic acid at 25℃; for 24h;	A 37 % Chromat. B 10 % Chromat. C 11 % Chromat. D 20 % Chromat.

...Expand

: diisobutylaluminum benzenetellurolate

: 103763-35-5
cyclododecyl methanesulfonate

A: 1501-82-2
cyclododecene

B: 97567-72-1
Cyclododecyl phenyl telluride

Conditions

Conditions	Yield
In dichloromethane at -40℃; for 5.5h;	A 43 % Chromat. B 46 % Chromat.

...Expand

: 97567-72-1
Cyclododecyl phenyl telluride

: 64-19-7
acetic acid

A: 1501-82-2
cyclododecene

B: 1724-39-6
cyclododecanol

C: 6221-92-7
cyclododecyl acetate

D: 830-13-7
cyclododecanone

Conditions

Conditions	Yield
With sodium periodate In water at 25℃; for 24h;	A 37 % Chromat. B 10 % Chromat. C 11 % Chromat. D 20 % Chromat.

...Expand

: C30H38OP(1+)*BF4(1-)

A: 1501-82-2
cyclododecene

B: 61682-09-5
1-fluorocyclododecane

Conditions

Conditions	Yield
In tetrahydrofuran for 0.666667h; Heating; Yield given. Yields of byproduct given;

: 294-62-2
cyclododecane

: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
IrH2[anthracene(P-t-Bu2)-1,8] at 230℃; Product distribution; Further Variations:; Temperatures; Catalysts;
With C28H54BIrN2P2 at 230℃; for 20h; Catalytic behavior; Temperature; Glovebox;

: 7795-35-9
cyclododecyl bromide

: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With silver tetrafluoroborate In nitromethane; N,N-dimethyl-formamide at 20℃; for 12h;

: 1724-39-6
cyclododecanol

A: 34039-83-3
chlorocyclododecane

B: 1501-82-2
cyclododecene

Conditions

Conditions	Yield
With trichloroacetamide; triphenylphosphine In dichloromethane at 30℃; for 0.25h;

: 1132-79-2
1-bromocyclododec-1-ene

: 98-80-6
phenylboronic acid

A: 16250-58-1
(Z)-1-bromocyclododec-1-ene

B: 1501-82-2
cyclododecene

C: (E)-1-phenylcyclododecene

Conditions

Conditions	Yield
tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane; water Suzuki coupling; Heating;

...Expand

: 1501-82-2
cyclododecene

: 286-99-7
1,2-epoxycyclododecane

Conditions

Conditions	Yield
With tert.-butylhydroperoxide In toluene at 79.84℃; for 4.83333h; Temperature; Concentration;	100%
With phosphoric acid; sodium tungstate; sulfuric acid; dihydrogen peroxide; aliquat 336 In water at 90℃; for 4h; pH=3;	99.6%
With copper 1,3,5-benzenetricarboxylate; oxygen; pivalaldehyde In acetonitrile at 40℃; under 760.051 Torr; for 6h;	99%

: 1501-82-2
cyclododecene

: 294-62-2
cyclododecane

Conditions

Conditions	Yield
With aluminum oxide; sodium tetrahydroborate; nickel dichloride In hexane at 40℃; Catalytic hydrogenation;	100%
With ethanol; lithium; nickel dichloride; 4,4'-di-tert-butylbiphenyl In tetrahydrofuran at 20℃; for 1h;	99%
With hydrogen; NiCl2-Li-[poly(2-vinyl-naphthalene)-co-(divinylbenzene)] In tetrahydrofuran at 20℃; under 760.051 Torr; for 1h;	99%

: 1501-82-2
cyclododecene

: 71-43-2
benzene

: 15971-88-7
phenylcyclododecane

Conditions

Conditions	Yield
With Et3NH[Al2Cl7] at 40℃; for 6h; Temperature; Inert atmosphere;	98%
ethylaluminum dichloride

: 75-11-6
diiodomethane

: 1501-82-2
cyclododecene

: 3105-35-9
bicyclo<10.1.0>tridecane

Conditions

Conditions	Yield
With tetradecafluorohexane; triethylaluminum In hexane at 20℃; for 36h; Darkness;	98%

: 67-56-1
methanol

: 1501-82-2
cyclododecene

: 84201-78-5
12,12-dimethoxydodecanal

Conditions

Conditions	Yield
Stage #1: cyclododecene With ozone In methanol; dichloromethane at -40℃; Stage #2: With toluene-4-sulfonic acid In methanol at 20℃; for 1.5h; Stage #3: methanol With dimethylsulfide; sodium hydrogencarbonate at 20℃;	92%

: 1070-70-8
1,4-Butanediol diacrylate

: 1501-82-2
cyclododecene

polymer; monomer(s): 1,4-butanediol diacrylate; cyclododecene: polymer; monomer(s): 1,4-butanediol diacrylate; cyclododecene

Conditions

Conditions	Yield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane Heating;	91%

: 1501-82-2
cyclododecene

: 61682-10-8
cyclododecyl iodide

Conditions

Conditions	Yield
With titanium(IV) iodide In dichloromethane at 20℃; for 12h;	91%

: 1501-82-2
cyclododecene

: 52913-14-1
O-tosylhydroxylamine

: 286-98-6
13-aza-bicyclo[10.1.0]tridecane

Conditions

Conditions	Yield
In dichloromethane	90%

: 1501-82-2
cyclododecene

: 410096-79-6
1-fluoro-2-iodocyclododecane

Conditions

Conditions	Yield
With N,N,N,N,N,N-hexamethylphosphoric triamide; N-iodo-succinimide; perfluoropropylene; diethylamine In water; toluene for 24h; Ambient temperature;	88%
With triethylamine pentahydrogen fluoride salt; triethylammonium iodide In dichloromethane at 20℃; Electrochemical reaction;	84%
With iodine pentafluoride-pyridine-hydrogen fluoride; potassium iodide In dichloromethane at 0 - 20℃; for 17.5h; Reagent/catalyst;	78%
With iodine pentafluoride-pyridine-hydrogen fluoride; potassium iodide In dichloromethane at 0 - 20℃; for 17.5h;	78%

: 1501-82-2
cyclododecene

: 100-61-8
N-methylaniline

: N-(cyclododecylmethyl)aniline

Conditions

Conditions	Yield
With chlorotris(dimethylamido)(κ2-N,O-3-phenyl-2-pyridonato)tantalum(V) In (2)H8-toluene at 145℃; for 44h; Glovebox; Inert atmosphere;	88%

: 1501-82-2
cyclododecene

: 830-13-7
cyclododecanone

Conditions

Conditions	Yield
With dihydrogen peroxide In water; acetonitrile at 55℃; for 12h; Wacker Oxidation;	87%
With tert.-butylhydroperoxide; silver hexafluoroantimonate; [Pd(Quinox)Cl2] In dichloromethane; water at 20℃; Wacker Oxidation; regioselective reaction;	76%
With dinitrogen monoxide for 1h; Flow reactor;	52%
With dinitrogen monoxide In cyclohexane at 300 - 350℃; under 75007.5 Torr; for 6h; Temperature; Flow reactor;

: 1501-82-2
cyclododecene

: 405-31-2
bis(4-fluorophenyl)disulfide

: 2-(4-fluorophenylthio)cyclododecan-1-one

Conditions

Conditions	Yield
Stage #1: bis(4-fluorophenyl)disulfide In dichloromethane at -78℃; Electrolysis; Stage #2: cyclododecene In dichloromethane; dimethyl sulfoxide at -78℃; for 0.0833333h; Schlenk technique; Stage #3: With triethylamine In dichloromethane; dimethyl sulfoxide at -78 - 25℃; for 1.08333h; Schlenk technique;	87%

: 1501-82-2
cyclododecene

: 97797-70-1
perdeuterated cyclododecene

Conditions

Conditions	Yield
With water-d2; palladium on activated charcoal at 250℃; for 12h;	85%
With water-d2; palladium on activated charcoal at 250℃; for 4h;	84%

: 1501-82-2
cyclododecene

: 693-23-2
1,12-dodecanedioic acid

Conditions

Conditions	Yield
With Oxone; 2-iodo-3,4,5,6-tetramethylbenzoic acid In water; acetonitrile for 24h;	85%
With tetrafluoroboric acid; iodomesitylene; 3-chloro-benzenecarboperoxoic acid In dichloromethane; water; acetonitrile at 50℃; for 10h; Inert atmosphere;	77 %Spectr.
With potassium peroxymonosulfate; iodobenzene In water; acetonitrile at 60℃; for 8h;	82 %Spectr.

: 75-25-2
Bromoform

: 1501-82-2
cyclododecene

: 17301-57-4
13,13-dibromobicyclo<10.1.0>tridecane

Conditions

Conditions	Yield
With potassium hydroxide; benzyltrimethylammonium chloride In ethanol; water for 12h;	84%
With potassium tert-butylate In hexane at 10℃; for 4h; Inert atmosphere;
With N-benzyl-N,N,N-triethylammonium chloride; potassium hydroxide In ethanol; water at 0 - 20℃; for 16h;

: 1501-82-2
cyclododecene

: N-(benzenesulfonyl)-N-[(trifluoromethyl)sulfanyl]benzenesulfonamide

: 2-(trifluoromethylthio)cyclododecanol

Conditions

Conditions	Yield
With dimethyl sulfoxide at 20℃; for 2h; Schlenk technique; Inert atmosphere;	84%

: 1501-82-2
cyclododecene

: 82936-35-4
1,2-dichlorocyclododecane

Conditions

Conditions	Yield
With chloro-trimethyl-silane; nitro acetate In dichloromethane at -10℃;	83%
With chlorine In dichloromethane at -10℃;

: 1501-82-2
cyclododecene

: 14337-43-0
ethyl 2-chloro-2-(hydroxyimino)acetate

: Propionic acid 3a,4,5,6,7,8,9,10,11,12,13,13a-dodecahydro-1-oxa-2-aza-cyclopentacyclododecen-3-yl ester

Conditions

Conditions	Yield
In toluene for 80h; Ambient temperature;	81%

: 689-12-3
isopropyl acrylate

: 1501-82-2
cyclododecene

: diisopropyl (2E,14E)-hexadec-2,14-dienoate

Conditions

Conditions	Yield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In dichloromethane for 16h; Inert atmosphere; Reflux;	81%

: 1501-82-2
cyclododecene

A: C48H88O12

B: 74515-85-8
C48H88O16

Conditions

Conditions	Yield
With ozone-containing oxygen In diethyl ether at -70℃; for 1h;	A n/a B 80%

: 1501-82-2
cyclododecene

A: 4575-77-3, 4806-74-0, 6667-06-7
α-Chlorcyclododecanonoxim

B: 121779-61-1
C24H44Cl2N2O2

Conditions

Conditions	Yield
With chloro-trimethyl-silane; isopentyl nitrite at -10℃; Neat (no solvent);	A 10% B 80%

Cyclododecene Chemical Properties

IUPAC Name: Cyclododecene
CAS: 1501-82-2
Formula: C₁₂H₂₂
Molecular Weight: 166.3
Molecular Structure of Cyclododecene (CAS NO.1501-82-2):

Density: 0.806 g/cm³
Flash Point: 93.9 °C
Melting Point: 9°C
Boiling Point: 238.1 °C at 760 mmHg
Index of Refraction: 1.445
Molar Refractivity: 54.94 cm³
Molar Volume: 206.1 cm³
Polarizability: 21.78 ×10^-24cm³
Surface Tension: 27.4 dyne/cm
Enthalpy of Vaporization: 45.57 kJ/mol
Vapour Pressure: 0.0665 mmHg at 25°C
Water Solubility: 0.1677(mg/L) at 25°C
Appearance: colourless liquid
Product Categories: alkenes;cyclic;organic building blocks.

Cyclododecene Safety Profile

Safety Information about Cyclododecene (CAS NO.1501-82-2):
Safety Statements about Cyclododecene (CAS NO.1501-82-2):
S23: Do not breathe dust.
S24/25: Avoid contact with skin and eyes.
WGK Germany: 1

Cyclododecene Specification

The chemical synonyms of Cyclododecene (CAS NO.1501-82-2) are 1-Cyclododecene ; Cyclododecene (c,t) ; Cyclododecene,c&t ; Cyclododecene ; Cyclodecene ; Cyclododecene (cis- and trans- mixture) ; Cyclododecene (cis+trans) ; Cyclododecene, ca 70% trans isomer .It non-irritating to the eyes.Causes skin irritation.May be harmful if absorbed through the skin.May cause irritation of the digestive tract.May be harmful if swallowed.May cause respiratory tract irritation.May be harmful if inhaled.It shoud avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container.As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire.Use water spray, dry chemical, carbon dioxide, or chemical foam.

Product Name

CYCLODODECENE

Synthetic route

Cyclododecene Chemical Properties

Cyclododecene Safety Profile

Cyclododecene Specification

Related Products

Hot Products