D-Allose supplier | CasNO.2595-97-3

Name
D-(+)-ALLOSE
EINECS 219-994-4
CAS No. 2595-97-3
Article Data110
CAS DataBase
Density 1.732 g/cm³
Solubility almost transparency
Melting Point 148-150 °C(lit.)
Formula C₆H₁₂O₆
Boiling Point 410.797 °C at 760 mmHg
Molecular Weight 180.158
Flash Point 202.243 °C
Transport Information
Appearance white crystalline powder
Safety 24/25
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Allose, D-(8CI);beta-D-Allose;D-allopyranose;
PSA 110.38000
LogP -3.22140

Synthetic route

: 504-29-0
2-aminopyridine

: 551-68-8
D-psicose

A: 1990-29-0
D-altrose

B: 2595-97-3
D-Allose

Conditions

Conditions	Yield
Stage #1: D-psicose With 2-aminopyridine; acetic acid at 90℃; Lobry de Bruyn-van Ekenstein transformation; Sealed tube; Stage #2: 2-aminopyridine With acetic acid at 90℃; Sealed tube; Stage #3: With trifluoroacetic acid at 65℃; for 1h;	A 11% B 32%

...Expand

: 1990-29-0
D-altrose

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With molybdic acid In water for 0.05h; Bilik reaction; microwave irradiation;	24%

: 551-68-8
D-psicose

A: 1990-29-0
D-altrose

B: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With potassium hydroxide In water at 25℃; for 336h; Product distribution; Kinetics;

: 1990-29-0
D-altrose

A: 551-68-8
D-psicose

B: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With potassium hydroxide In water at 25℃; for 336h; Product distribution; Kinetics;

: 120019-25-2
1-Deoxy-1-nitro-D-allitol

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With sulfuric acid	0.12 g

: 127324-55-4
Cardiomanol

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With trifluoroacetic acid at 100℃; for 1h;	25 mg

: 52387-26-5, 52387-28-7, 52387-29-8, 70849-32-0, 70849-33-1, 70849-34-2, 70849-35-3, 70849-36-4, 108887-14-5, 108887-15-6, 131320-56-4, 131320-57-5, 131320-58-6, 131320-59-7, 131320-64-4
D-ribose cyanohydrin

A: 1990-29-0
D-altrose

B: 2595-97-3
D-Allose

: 79974-65-5
N-{1-[(3aR,4R,6R,6aR)-6-((R)-1,2-Dihydroxy-ethyl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl]-2-oxo-1,2-dihydro-pyrimidin-4-yl}-acetamide

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With Dowex 50 resin (H+) In water at 100℃; for 1.5h;

: chrysoeriol 7-(2''-O-β-D-allopyranosyl)-β-D-glucopyranoside

A: 50-99-7
D-glucose

B: 2595-97-3
D-Allose

C: 491-71-4
chrysoeriol

Conditions

Conditions	Yield
With hydrogenchloride In ethanol at 100℃; for 1h;

...Expand

: p-hydroxyphenyl β-D-alloside

A: 2595-97-3
D-Allose

B: 123-31-9
hydroquinone

Conditions

Conditions	Yield
With hydrogenchloride for 2h; Heating;	A n/a B 13 mg

: 29474-78-0
D-allono-1,4-lactone

sodium amalgam: sodium amalgam

: 2595-97-3
D-Allose

: 57-48-7
D-Fructose

: 7732-18-5
water

potassium-salt of/the/ (E)-propene-1,2,3-tricarboxylic acid: potassium-salt of/the/ (E)-propene-1,2,3-tricarboxylic acid

: 57-48-7, 87-79-6, 87-81-0, 551-68-8, 3615-39-2, 3615-56-3, 6035-50-3, 7776-48-9, 16354-64-6, 17598-81-1, 17598-82-2, 23140-52-5, 30237-26-4, 65732-90-3, 73952-10-0, 73952-11-1, 139686-85-4
sorbose

B: 2595-97-3
D-Allose

C D-sorbose: D-sorbose

D DL(?)-allose: DL(?)-allose

Conditions

Conditions	Yield
Produkt: DL-Psicose und D-Glucuronsaeure;

...Expand

D-allonic acid-4-lactone: D-allonic acid-4-lactone

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With sodium amalgam; water; oxalic acid Reagens 4: Natriumoxalat;

d-allonic acid lactone: d-allonic acid lactone

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With sodium amalgam

: 21675-42-3
D-gluconic acid

sodium amalgam: sodium amalgam

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
das Lacton reagiert;

: (2R,3R,4R)-2,3,4-Tris-benzyloxy-4-[(R)-2-(4-methoxy-phenyl)-[1,3]dioxolan-4-yl]-butyraldehyde

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With hydrogen; palladium dihydroxide In tetrahydrofuran; water

: 57-48-7
D-Fructose

A: 3458-28-4
D-Mannose

B: 50-99-7
D-glucose

C: 1990-29-0
D-altrose

D: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide at 110℃; Product distribution;

...Expand

: 50-99-7
D-glucose

A: 3458-28-4
D-Mannose

B: 59-23-4
D-Galactose

C: 1990-29-0
D-altrose

D: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With 4-methylmorpholine N-oxide at 110℃; Product distribution;

...Expand

: (23E)-5β,19-epoxycucurbita-6,23,25-trien-3β-ol 3-O-β-D-allopyranoside

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With hydrogenchloride In methanol for 1h; Heating;

: (23S)-5β,19-epoxy-23-methoxycucurbita-6,24-dien-3β-ol 3-O-β-D-allopyranoside

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With hydrogenchloride In methanol for 1h; Heating;

: (19R,23R)-5β,19-epoxy-19,23-dimethoxycucurbita-6,24-dien-3β-ol 3-O-β-D-allopyranoside

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With hydrogenchloride In methanol for 1h; Heating;

: 50-69-1
D-ribose

bromine water: bromine water

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 0.2 g / Na / methanol / 1.5 h 2: 0.12 g / 2N H2SO4 View Scheme

: 63064-67-5
4-N-acetyl-1-(2,3-O-isopropylidene-β-D-ribo-pentodialdo-1,5-furanosyl)cytosine

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 38 percent / tetrahydrofuran / 2 h / 60 °C 2: 28 percent / boron trifluoride-ether / tetrahydrofuran / 0.08 h / Ambient temperature 3: Dowex 50 resin (H+) / H2O / 1.5 h / 100 °C View Scheme

: 79974-63-3, 79974-64-4
N-[1-((3aR,4R,6R,6aR)-2,2-Dimethyl-6-oxiranyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-2-oxo-1,2-dihydro-pyrimidin-4-yl]-acetamide

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 28 percent / boron trifluoride-ether / tetrahydrofuran / 0.08 h / Ambient temperature 2: Dowex 50 resin (H+) / H2O / 1.5 h / 100 °C View Scheme

: 79974-62-2
4-N-acetyl-1-<5-deoxy-2,3-O-isopropylidene-5,5-(N,N'-diphenylethylenediamino)-β-D-ribofuranosyl>cytosine

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: Dowex 50 resin (H+) / trifluoroacetic acid; H2O / 1 h / Ambient temperature 2: 38 percent / tetrahydrofuran / 2 h / 60 °C 3: 28 percent / boron trifluoride-ether / tetrahydrofuran / 0.08 h / Ambient temperature 4: Dowex 50 resin (H+) / H2O / 1.5 h / 100 °C View Scheme

: 16667-80-4
2',3'-O-isopropylidene-N4-acetylcytidine

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
Multi-step reaction with 5 steps 1: 1.) dicyclohexylcarbodi-imide, pyridine, trifluoroacetic acid, 2.) AcOH / 1.) DMSO, H2O, RT, 30 min, 2.) MeOH, 1 h 2: Dowex 50 resin (H+) / trifluoroacetic acid; H2O / 1 h / Ambient temperature 3: 38 percent / tetrahydrofuran / 2 h / 60 °C 4: 28 percent / boron trifluoride-ether / tetrahydrofuran / 0.08 h / Ambient temperature 5: Dowex 50 resin (H+) / H2O / 1.5 h / 100 °C View Scheme

Yield

Multi-step reaction with 5 steps
1: 1.) dicyclohexylcarbodi-imide, pyridine, trifluoroacetic acid, 2.) AcOH / 1.) DMSO, H2O, RT, 30 min, 2.) MeOH, 1 h
2: Dowex 50 resin (H+) / trifluoroacetic acid; H2O / 1 h / Ambient temperature
3: 38 percent / tetrahydrofuran / 2 h / 60 °C
4: 28 percent / boron trifluoride-ether / tetrahydrofuran / 0.08 h / Ambient temperature
5: Dowex 50 resin (H+) / H2O / 1.5 h / 100 °C
View Scheme

: 1310536-12-9
25-hydroxy-7β-methoxycucurbita-5,23(E)-dien-19-al 3-O-β-D-allopyranoside

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With hydrogenchloride; water In 1,4-dioxane at 80℃; for 3h;

: 1310536-13-0
(23R)-7β,23-dihydroxycucurbita-5,24-dien-19-al 3-O-β-D-allopyranoside

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With hydrogenchloride; water In 1,4-dioxane at 80℃; for 3h;

: 1310536-14-1
(1R,4S,5S,8R,9R,12S,13S,16S)-8-[(2R,4E)-6-methoxy-6-methylhept-4-en-2-yl]-5,9,17,17-tetramethyl-18-oxapentacyclo[10.5.2.01,13.04,12.05,9]nonadec-2-en-19-one 16-O-β-D-allopyranoside

: 2595-97-3
D-Allose

Conditions

Conditions	Yield
With hydrogenchloride; water In 1,4-dioxane at 80℃; for 3h;

: 2595-97-3
D-Allose

: 1904-60-5
3-amino-2-phenylquinazolin-4(3H)-one

: 2-phenyl-3-{(1Z)-(2,3,4,5,6-pentahydroxyhexylidene)amino}quinazolin-4(3H)-one

Conditions

Conditions	Yield
With NaY zeolite catalyst for 0.316667h; Microwave irradiation; Neat (no solvent);	85%

: 120-72-9
indole

: 2595-97-3
D-Allose

: 108-24-7
acetic anhydride

: Acetic acid (1S,2S,3R,4R)-2,3,4,5-tetraacetoxy-1-[bis-(1H-indol-2-yl)-methyl]-pentyl ester

Conditions

Conditions	Yield
Stage #1: indole; D-Allose; scandium tris(trifluoromethanesulfonate) In ethanol; water at 50℃; for 48h; Stage #2: acetic anhydride With pyridine; dmap at 20℃;	82%

...Expand

: 2595-97-3
D-Allose

: 77-76-9
2,2-dimethoxy-propane

: 27108-13-0
2,3:5,6-Di-O-isopropylidene-α-D-allofuranose

Conditions

Conditions	Yield
With calcium sulfate; toluene-4-sulfonic acid In 1,2-dimethoxyethane at 20℃; for 24h; Condensation;	71%

: 2595-97-3
D-Allose

: D-allose (Z)-oxime

Conditions

Conditions	Yield
Stage #1: With hydroxylamine hydrochloride; sodium methylate In ethanol at 20℃; Stage #2: D-Allose In ethanol at 70℃;	68%

: 2595-97-3
D-Allose

: 13437-75-7
N-Phenyl-N'-thiobenzoyl-hydrazin

: (1R,2R,3R,4R)-1-<(2S)-(3,5-diphenyl-2,3-dihydro-<1,3,4>thiadiazol-2-yl)>-pentane-1,2,3,4,5-pentaol

Conditions

Conditions	Yield
With hydrogenchloride In ethanol at 20℃; for 20h;	66%

: 2595-97-3
D-Allose

: D-allonitrile

Conditions

Conditions	Yield
With phenoxyamine hydrochloride In aq. phosphate buffer; water-d2 at 20℃; for 48h;	63%

: 2033-24-1
cycl-isopropylidene malonate

: 2595-97-3
D-Allose

A: 315202-37-0
3,6-anhydro-2-deoxy-D-glycero-D-altro-octono-1,4-lactone

B: 315202-38-1
3,6-anhydro-2-deoxy-D-glycero-D-gluco-octono-1,4-lactone

Conditions

Conditions	Yield
With triethylamine In N,N-dimethyl-formamide at 48 - 49℃; for 240h; Substitution; cyclization;	A 20% B 61%
With tert-butylamine In N,N-dimethyl-formamide at 40℃; for 120h; Substitution; cyclization;	A 31% B 51%

...Expand

: 2595-97-3
D-Allose

: S,S'-((4-(2-aminoethoxy)-1,2-phenylene)bis(methylene)) bis(2-methylpropanethioate) hydrochloride

: S,S'-((4-(2-(bis((2S,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexyl)amino)ethoxy)-1,2-phenylene)bis(methylene)) bis(2-methylpropanethioate) hydrochloride

Conditions

Conditions	Yield
Stage #1: D-Allose; S,S'-((4-(2-aminoethoxy)-1,2-phenylene)bis(methylene)) bis(2-methylpropanethioate) hydrochloride With sodium cyanoborohydride; acetic acid In methanol at 55℃; for 7h; Stage #2: With hydrogenchloride In water pH=3;	56%

: 2595-97-3
D-Allose

: 67-47-0
5-hydroxymethyl-2-furfuraldehyde

Conditions

Conditions	Yield
With chromium dichloride at 120℃; for 3h; Reagent/catalyst; Inert atmosphere; Ionic liquid;	44%

: 2595-97-3
D-Allose

: 1990-29-0
D-altrose

Conditions

Conditions	Yield
With molybdic acid In water for 0.05h; Bilik reaction; microwave irradiation;	42%

: 75-52-5
nitromethane

: 2595-97-3
D-Allose

A: 130930-34-6
1-deoxy-1-nitro-D-glycero-D-galacto-heptitol

B: 130930-33-5
1-Deoxy-1-nitro-D-glycero-D-alloheptitol

Conditions

Conditions	Yield
With sodium methylate In methanol; dimethyl sulfoxide for 24h;	A 30% B 21%

...Expand

: 2595-97-3
D-Allose

: 1101863-07-3
(3S)-O-(N-methoxyglycyl)betulinic acid

: 1101863-11-9
(3S)-O-(N-methoxy-N-β-D-allosylglycyl)betulinic acid

Conditions

Conditions	Yield
In methanol; dichloromethane at 40℃; for 48h;	23%

: 2595-97-3
D-Allose

A: 22430-69-9
D-altronic acid

B: 21675-42-3
D-gluconic acid

Conditions

Conditions	Yield
With sodium anthraquinone-2-sulfonate; calcium chloride In sodium hydroxide at 50℃;	A 4% B 13%

: 2595-97-3
D-Allose

: 2161-86-6
2,4-diacetylphloroglucinol

: 1044237-24-2
C16H20O10

Conditions

Conditions	Yield
With scandium tris(trifluoromethanesulfonate) In ethanol; water for 66h; Heating;	6.25%

: 7635-11-2
beta-L-allose

: 2595-97-3
D-Allose

: 50-99-7, 59-23-4, 921-60-8, 1949-88-8, 1990-29-0, 2152-76-3, 2595-97-3, 2595-98-4, 3458-28-4, 4205-23-6, 5934-56-5, 5978-95-0, 5987-68-8, 6027-89-0, 6038-51-3, 7635-11-2, 10030-80-5, 15572-79-9, 19163-87-2, 23567-25-1, 26566-61-0, 30077-17-9, 31103-86-3, 39665-52-6, 40866-07-7, 58367-01-4, 58407-05-9, 58407-06-0, 83198-69-0, 83198-70-3, 83198-71-4, 93780-23-5, 145920-48-5
DL-allo-2,3,4,5,6-Pentahydroxy-hexanal

Conditions

Conditions	Yield
With ethanol

: 2595-97-3
D-Allose

: 143-33-9
sodium cyanide

A: 89-67-8, 3257-66-7, 5329-44-2, 10030-65-6, 15397-07-6, 15397-08-7, 15397-09-8, 22404-04-2, 60046-25-5, 92007-82-4
D-glycero-D-altro-heptonic acid-4-lactone

B: 89-67-8, 3257-66-7, 5329-44-2, 10030-65-6, 15397-07-6, 15397-08-7, 15397-09-8, 22404-04-2, 60046-25-5, 92007-82-4
D-glycero-D-allo-heptonic acid-4-lactone

Conditions

Conditions	Yield
With water anschliessend Erhitzen der Reaktionsloesung unter vermindertem Druck;

...Expand

: 2595-97-3
D-Allose

: 488-44-8
allitol

Conditions

Conditions	Yield
With Ni-doped silica; ethanol at 100 - 140℃; under 66195.7 - 88260.9 Torr; Hydrogenation;
With sodium tetrahydroborate at 4℃; for 2h;
With sodium tetrahydroborate
With sodium tetrahydroborate In water for 1h;

: 2595-97-3
D-Allose

: 551-68-8
D-psicose

Conditions

Conditions	Yield
With pyridine

: 2595-97-3
D-Allose

: 14059-68-8
1,6-anhydro-β-D-glucopyranoside

Conditions

Conditions	Yield
With hydrogenchloride

: 2595-97-3
D-Allose

: 108-24-7
acetic anhydride

: 4257-94-7
β-D-allose pentaacetate

Conditions

Conditions	Yield
With sodium acetate

: 2595-97-3
D-Allose

: 100-63-0
phenylhydrazine

: 23275-67-4
lyxo-[2]Hexosulose-bis-phenylhydrazon

Conditions

Conditions	Yield
With acetic acid phenyl-d-altrosazone;

: 1990-29-0
D-altrose

: 2595-97-3
D-Allose

: 534-97-4, 3154-35-6, 3322-00-7, 3879-35-4, 4746-10-5, 5934-57-6, 5978-96-1, 6032-23-1, 6035-51-4, 6164-71-2, 23275-67-4, 71075-64-4, 81872-41-5
D-ribo-hexulose phenylosazone

: 2595-97-3
D-Allose

: 685-27-8
2,2,2-trifluoro-N-methyl-N-(2,2,2-trifluoroacetyl)acetamide

: 622-33-3
N-benzyloxyamine

A: 128613-60-5
trifluoroacetylated allose anti-O-benzyloxime

B: 128613-78-5
trifluoroacetylated allose syn-O-benzyloxime

Conditions

Conditions	Yield
1.) NMP, 75 deg C, 30 min, 2.) NMP, RT, 5-10 min; Multistep reaction;

...Expand

: 2595-97-3
D-Allose

A: 551-68-8
D-psicose

B: 1990-29-0
D-altrose

Conditions

Conditions	Yield
With potassium hydroxide In water at 25℃; for 336h; Product distribution; Kinetics;

: 2595-97-3
D-Allose

: 21675-42-3
D-gluconic acid

Conditions

Conditions	Yield
With potassium hydroxide; platinum on activated charcoal In water at 25℃; under 760 Torr; for 3h; Rate constant; Mechanism; relative, initial rate;

: 2595-97-3
D-Allose

: 126-25-0, 26001-54-7, 52050-05-2
D-psicose 1-phosphate

Conditions

Conditions	Yield
With ATP 1) L-rhamnose isomerase, tris buffer pH 8.0, mercaptoethanol, MgCl2, ATP (cat.), 2) L-rhamnulose kinase, PEP/pyruvate kinase; Yield given. Multistep reaction;

D-Allose Specification

The CAS register number of D-Allose is 2595-97-3. It also can be called as beta-D-Allose and the IUPAC about this chemical is (2R,3R,4R,5R)-2,3,4,5,6-pentahydroxyhexanal. The molecular formula about this chemical is C₆H₁₂O₆and the molecular weight is 180.16. It belongs to the following product categories which include Allose; Basic Sugars (Mono & Oligosaccharides); Biochemistry; Sugars and so on. This chemical can be used in Biochemistry. When you are using it, please avoid contact with skin and eyes.

Physical properties about D-Allose are: (1)ACD/LogP: -1.88; (2)# of Rule of 5 Violations: 1; (3)#H bond acceptors: 6; (4)#H bond donors: 5; (5)#Freely Rotating Bonds: 6; (6)Polar Surface Area: 55.38Å²; (7)Index of Refraction: 1.635; (8)Molar Refractivity: 37.25 cm³; (9)Molar Volume: 104 cm³; (10)Polarizability: 14.76x10^-24cm³; (11)Surface Tension: 81.7 dyne/cm; (12)Flash Point: 202.2 °C; (13)Enthalpy of Vaporization: 76.63 kJ/mol; (14)Boiling Point: 410.8 °C at 760 mmHg; (15)Vapour Pressure: 1.83E-08 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O[C@@H]1[C@H](O)[C@H](O[C@@H](O)[C@@H]1O)CO
(2)InChI: InChI=1/C6H12O6/c7-1-2-3(8)4(9)5(10)6(11)12-2/h2-11H,1H2/t2-,3-,4-,5-,6-/m1/s1
(3)InChIKey: WQZGKKKJIJFFOK-QZABAPFNBC
(4)Std. InChI: InChI=1S/C6H12O6/c7-1-2-3(8)4(9)5(10)6(11)12-2/h2-11H,1H2/t2-,3-,4-,5-,6-/m1/s1
(5)Std. InChIKey: WQZGKKKJIJFFOK-QZABAPFNSA-N

Product Name

D-(+)-ALLOSE

Synthetic route

D-Allose Specification

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