Product Name

  • Name

    Methyl 2-chloro-2-propenoate

  • EINECS
  • CAS No. 80-63-7
  • Article Data43
  • CAS DataBase
  • Density 1.189
  • Solubility
  • Melting Point
  • Formula C4H5 Cl O2
  • Boiling Point 52 °C (50 mmHg)
  • Molecular Weight 120.535
  • Flash Point 33 °C
  • Transport Information
  • Appearance
  • Safety Moderately toxic by inhalation. Human systemic effects by inhalation: conjunctiva irritation. A severe skin irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl−. See also ESTERS.
  • Risk Codes R34; R26; R24/25; R10
  • Molecular Structure Molecular Structure of 80-63-7 (Methyl 2-chloro-2-propenoate)
  • Hazard Symbols T+
  • Synonyms Acrylicacid, 2-chloro-, methyl ester (6CI,7CI,8CI); 2-Chloroacrylic acid methyl ester;Methyl 2-chloro-2-propenoate; Methyl 2-chloroacrylate; Methyl2-chloropropenoate; Methyl a-chloroacrylate; NSC 32608
  • PSA 26.30000
  • LogP 0.91190

Synthetic route

endo-5-Carbomethoxy-6-chloro-1,6-diazabicyclo<3.1.0>hexane
89019-24-9, 108392-47-8, 108392-49-0, 113085-27-1, 113158-29-5

endo-5-Carbomethoxy-6-chloro-1,6-diazabicyclo<3.1.0>hexane

A

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
In chloroform-d1 at 80℃; for 10h; Product distribution;A 95%
B n/a
exo-6-chloro-5-methoxycarbonyl-1,6-diazabicyclo<3.1.0>hexane
89019-24-9, 108392-47-8, 108392-49-0, 113085-27-1, 113158-29-5

exo-6-chloro-5-methoxycarbonyl-1,6-diazabicyclo<3.1.0>hexane

A

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

B

ethene
74-85-1

ethene

C

N2

N2

Conditions
ConditionsYield
In dichloromethane at 80℃; for 10h;A 95%
B n/a
C n/a
...Expand
methyl 2,3-dichloropropionate
3674-09-7, 132854-28-5

methyl 2,3-dichloropropionate

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

Conditions
ConditionsYield
In water; dimethyl sulfoxide at 120℃; for 6h;91%
With 10H-phenothiazine; tetrabutylammomium bromide; sodium hydrogencarbonate In dichloromethane; water for 1.5h; Dehydrochlorination; Heating;66%
beim Erhitzen mit protonierten Kationenaustauschern;
2,3,3-trichloropropene-1-ol

2,3,3-trichloropropene-1-ol

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

Conditions
ConditionsYield
With sulfuric acid In methanol74%
formaldehyd
50-00-0

formaldehyd

methyl chloroacetate
96-34-4

methyl chloroacetate

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

Conditions
ConditionsYield
Stage #1: methyl chloroacetate With Dimethyl oxalate; sodium methylate In dimethyl sulfoxide at 15 - 25℃; for 1h; Inert atmosphere;
Stage #2: formaldehyd With 2,6-di-tert-butyl-4-methyl-phenol In dimethyl sulfoxide at 20 - 25℃; for 1h; Inert atmosphere;		58.1%
methyl-α-bromo-α-chloro-propanoate
166666-36-0

methyl-α-bromo-α-chloro-propanoate

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

Conditions
ConditionsYield
With lithium carbonate; lithium bromide In N,N-dimethyl-formamide at 70℃; for 24h;29%
dichloro-methylsulfanyl-acetic acid methyl ester
77825-46-8

dichloro-methylsulfanyl-acetic acid methyl ester

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

Conditions
ConditionsYield
In tetrachloromethane at 490℃; Yield given;
exo-6-chloro-5-methoxycarbonyl-1,6-diazabicyclo<3.1.0>hexane
89019-24-9, 108392-47-8, 108392-49-0, 113085-27-1, 113158-29-5

exo-6-chloro-5-methoxycarbonyl-1,6-diazabicyclo<3.1.0>hexane

A

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

B

ethene
74-85-1

ethene

Conditions
ConditionsYield
In chloroform-d1 at 40℃; Rate constant; Mechanism; τ1/2 (h);
methyl 2,2-dichloropropionate
17640-02-7

methyl 2,2-dichloropropionate

benzaldehyde
100-52-7

benzaldehyde

A

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

B

methyl 2-chloro-3-hydroxy-2-methyl-3-phenylpropanoate
80532-67-8

methyl 2-chloro-3-hydroxy-2-methyl-3-phenylpropanoate

Conditions
ConditionsYield
With boron trifluoride; zinc In tetrahydrofuran at 0℃; for 24h;A 3 % Chromat.
B 76 % Chromat.
...Expand
benzaldehyde
100-52-7

benzaldehyde

methyl-α-bromo-α-chloro-propanoate
166666-36-0

methyl-α-bromo-α-chloro-propanoate

A

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

B

methyl 2-chloro-3-hydroxy-2-methyl-3-phenylpropanoate
80532-67-8

methyl 2-chloro-3-hydroxy-2-methyl-3-phenylpropanoate

C

dimethyl 2,3-dichloro-2,3-dimethylbutanedioate

dimethyl 2,3-dichloro-2,3-dimethylbutanedioate

Conditions
ConditionsYield
With boron trifluoride; zinc In tetrahydrofuran at 0℃; for 3h;A 1 % Chromat.
B 85 % Chromat.
C 8 % Chromat.
...Expand
methyl-<2.3-dichloro propionate>

methyl-<2.3-dichloro propionate>

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

Conditions
ConditionsYield
With water; sodium carbonate; hydroquinone at 150℃; staendiges Abdestillieren des entstandenen Methyl-<2.3-dichlor-acrylats>;
With quinoline
With sodium acetate; isopropyl alcohol
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

2-[[N-(1,3-thiazol-2-yl)methylene]amino]-3-(1H-pyrazol-1-yl)propanoic acid tert-butyl ester
885264-31-3

2-[[N-(1,3-thiazol-2-yl)methylene]amino]-3-(1H-pyrazol-1-yl)propanoic acid tert-butyl ester

C18H23ClN4O4S

C18H23ClN4O4S

Conditions
ConditionsYield
With triethylamine; lithium bromide In tetrahydrofuran at 20℃; for 17h;100%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

Methyl thioglycolate
2365-48-2

Methyl thioglycolate

α-Chlor-β-<(methoxycarbonylmethyl)thio>propansaeure-methylester
90237-73-3

α-Chlor-β-<(methoxycarbonylmethyl)thio>propansaeure-methylester

Conditions
ConditionsYield
With sodium In dichloromethane at 25℃; for 0.666667h;99%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

benzenecarbothioamide
2227-79-4

benzenecarbothioamide

S-<2-Chlor-2-(methoxycarbonyl)ethyl>thiobenzamid-hydrochlorid
116077-23-7

S-<2-Chlor-2-(methoxycarbonyl)ethyl>thiobenzamid-hydrochlorid

Conditions
ConditionsYield
With hydrogenchloride In dichloromethane for 72h; Ambient temperature;98%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol
335-99-9

2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol

dodecafluoroheptyl 2-chloroacrylate

dodecafluoroheptyl 2-chloroacrylate

Conditions
ConditionsYield
With 10H-phenothiazine; tetrakis(1H,1H,7H-perfluoroheptyl) titanate; hydroquinone In toluene at 80℃; for 3.5h; Large scale;97.1%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

phenylmethanethiol
100-53-8

phenylmethanethiol

2-Chlor-3-(benzylthio)propansaeure-methylester
60741-22-2

2-Chlor-3-(benzylthio)propansaeure-methylester

Conditions
ConditionsYield
With sodium benzylmercaptide In dichloromethane for 4h; Ambient temperature;95%
With sodium methylate
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

methylenecyclohexane
1192-37-6

methylenecyclohexane

Methyl α-chloro-1-cyclohexene-1-butanoate
89398-16-3

Methyl α-chloro-1-cyclohexene-1-butanoate

Conditions
ConditionsYield
With ethylaluminum dichloride In hexane; benzene at 25℃; for 20h;95%
With ethylaluminum dichloride In hexane; benzene at 25℃; for 24h;95%
With 1-menthyloxyaluminium dichloride In benzene Product distribution; Et2AlCl catalyzed ene reactions of α-substituted acrylate esters with trans 1,2-di and trisubstituted alkenes; regio- and stereoselectivity; reactivity of alkenes and acrylate esters; asymmetric induction;22%
With 1-menthyloxyaluminium dichloride22%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

cesium 2-((1-methylcyclohexyl)oxy)-2-oxoacetate

cesium 2-((1-methylcyclohexyl)oxy)-2-oxoacetate

methyl 2-chloro-3-(1-methylcyclohexyl)propanoate

methyl 2-chloro-3-(1-methylcyclohexyl)propanoate

Conditions
ConditionsYield
With Ir[dF(CF3)ppy]2(dtbbpy)PF6 In 1,2-dimethoxyethane; water; N,N-dimethyl-formamide at 40℃; for 24h; Irradiation; Inert atmosphere;94%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

methyl 2-nitroacetate
2483-57-0

methyl 2-nitroacetate

C7H10ClNO6

C7H10ClNO6

Conditions
ConditionsYield
With DBN In N,N-dimethyl-formamide at 60 - 65℃; for 4h; Solvent; Temperature;92.7%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

thiophenol
108-98-5

thiophenol

α-Chlor-β-(phenylthio)propansaeure-methylester
42801-75-2

α-Chlor-β-(phenylthio)propansaeure-methylester

Conditions
ConditionsYield
With sodium thiophenolate In dichloromethane at 25℃; for 5h;91%
With sodium thiophenolate In dichloromethane for 4h; Ambient temperature;91%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

dimethyl phenylphosphonate
2240-41-7

dimethyl phenylphosphonate

phenol
108-95-2

phenol

Methyl 3-(phenyl-methoxyphosphinyl)-2-chloropropionate

Methyl 3-(phenyl-methoxyphosphinyl)-2-chloropropionate

Conditions
ConditionsYield
90.1%
...Expand
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

thioacetamide
62-55-5

thioacetamide

S-<2-Chlor-2-(methoxycarbonyl)ethyl>thioacetamid-hydrochlorid
116077-24-8

S-<2-Chlor-2-(methoxycarbonyl)ethyl>thioacetamid-hydrochlorid

Conditions
ConditionsYield
With hydrogenchloride In dichloromethane for 18h; Ambient temperature;88%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

methylhydrazine
60-34-4

methylhydrazine

1-methyl-1,2-dihydro-3H-pyrazol-3-one
52867-35-3

1-methyl-1,2-dihydro-3H-pyrazol-3-one

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 25℃; for 10h;88%
In tetrahydrofuran at 20℃; for 16.08h;84%
In tetrahydrofuran at 20 - 50℃; for 17h;77%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

nitromethane
75-52-5

nitromethane

orthoformic acid triethyl ester
122-51-0

orthoformic acid triethyl ester

5-nitro-2-hydroxypyridine
5418-51-9

5-nitro-2-hydroxypyridine

Conditions
ConditionsYield
Stage #1: methyl 2-chloroacrylate; nitromethane With 1,8-diazabicyclo[5.4.0]undec-7-ene at 50 - 55℃; for 5h;
Stage #2: orthoformic acid triethyl ester With zinc(II) chloride at 95 - 100℃; for 4h;
Stage #3: With ammonium hydroxide; ammonium chloride In methanol at 50 - 55℃; for 6h;		87.8%
...Expand
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

methylthiol
74-93-1

methylthiol

2-Chlor-3-(methylthio)propansaeure-methylester
20444-25-1

2-Chlor-3-(methylthio)propansaeure-methylester

Conditions
ConditionsYield
With sodium thiomethoxide In dichloromethane for 4h; Ambient temperature;87%
With sodium methylate; benzene
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

ethyl 3-amino-4,4,4-trifluoro-2-butenoate
372-29-2, 141860-78-8

ethyl 3-amino-4,4,4-trifluoro-2-butenoate

6-hydroxy-2-(trifluoromethyl)nicotinic acid

6-hydroxy-2-(trifluoromethyl)nicotinic acid

Conditions
ConditionsYield
Stage #1: methyl 2-chloroacrylate; ethyl 3-amino-4,4,4-trifluoro-2-butenoate With sodium ethanolate In ethanol at 22 - 23℃; for 2.5h; Inert atmosphere;
Stage #2: With water; sodium hydroxide In ethanol at 70 - 75℃;		87%
methanol
67-56-1

methanol

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

α-Chlor-β-methoxypropansaeure-methylester
36997-03-2

α-Chlor-β-methoxypropansaeure-methylester

Conditions
ConditionsYield
With sodium 0 degC, 1 h then r.t., 2 h;86%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

3-Methyl-cis-2-penten
922-62-3

3-Methyl-cis-2-penten

(2S,4R)-2-Chloro-4-methyl-5-methylene-heptanoic acid methyl ester
74964-45-7

(2S,4R)-2-Chloro-4-methyl-5-methylene-heptanoic acid methyl ester

Conditions
ConditionsYield
With ethylaluminum dichloride In benzene at 25℃; for 19.2h;86%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

mercaptoacetic acid
68-11-1

mercaptoacetic acid

3-(Carboxymethylthio)-2-chlorpropansaeure-methylester
116077-17-9

3-(Carboxymethylthio)-2-chlorpropansaeure-methylester

Conditions
ConditionsYield
With sodium hydroxide In water at 10℃; for 24h;86%
2-(2-aminophenyl)-3-cyclohexyl-1H-indole-6-carboxylic acid methyl ester
863578-19-2

2-(2-aminophenyl)-3-cyclohexyl-1H-indole-6-carboxylic acid methyl ester

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

dimethyl 13-cyclohexyl-6,7-dihydro-5H-indolo[1,2-d][1,4]benzodiazepine-6,10-dicarboxylate
956580-06-6

dimethyl 13-cyclohexyl-6,7-dihydro-5H-indolo[1,2-d][1,4]benzodiazepine-6,10-dicarboxylate

Conditions
ConditionsYield
With tetrabutylammomium bromide; potassium carbonate In acetonitrile at 60℃;84%
With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate In acetonitrile at 60℃;75%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

(E)-3-methyl-2-pentene
616-12-6

(E)-3-methyl-2-pentene

(Z)-(2S,4R)-2-Chloro-4,5-dimethyl-hept-5-enoic acid methyl ester
74964-46-8, 80865-34-5, 80865-37-8

(Z)-(2S,4R)-2-Chloro-4,5-dimethyl-hept-5-enoic acid methyl ester

(E)-(2S,4R)-2-Chloro-4,5-dimethyl-hept-5-enoic acid methyl ester
74964-46-8

(E)-(2S,4R)-2-Chloro-4,5-dimethyl-hept-5-enoic acid methyl ester

Conditions
ConditionsYield
With ethylaluminum dichloride In benzene at 25℃; for 14.4h; Yields of byproduct given;A n/a
B 82%
With ethylaluminum dichloride In benzene at 25℃; for 14.4h; Product distribution; Mechanism; regiospecificity; further alkenes;
...Expand
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

methyl chloroacetate
96-34-4

methyl chloroacetate

cis-1,2-Di(methoxycarbonyl)-1-chlorcyclopropan
39822-01-0, 39822-02-1

cis-1,2-Di(methoxycarbonyl)-1-chlorcyclopropan

Conditions
ConditionsYield
With potassium hydride In N,N-dimethyl-formamide at 25℃; for 6h;80%
n-butyl magnesium bromide
693-03-8

n-butyl magnesium bromide

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

1-chloro-2-pentyl-cyclopropane-1,2-dicarboxylic acid dimethyl ester

1-chloro-2-pentyl-cyclopropane-1,2-dicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With copper(l) chloride In diethyl ether at -78℃; Michael addition;80%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

ethylmagnesium bromide
925-90-6

ethylmagnesium bromide

1-chloro-2-propyl-cyclopropane-1,2-dicarboxylic acid dimethyl ester

1-chloro-2-propyl-cyclopropane-1,2-dicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With copper(l) chloride In diethyl ether at -78℃; Michael addition;78%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

isopropylmagnesium chloride
1068-55-9

isopropylmagnesium chloride

1-chloro-2-isobutyl-cyclopropane-1,2-dicarboxylic acid dimethyl ester

1-chloro-2-isobutyl-cyclopropane-1,2-dicarboxylic acid dimethyl ester

Conditions
ConditionsYield
With copper(l) chloride In diethyl ether at -78℃; Michael addition;76%
methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

1,3-dithiapropane
6725-64-0

1,3-dithiapropane

3,3'-bis(2-chlorpropansaeure-methylester)
116077-16-8

3,3'-bis(2-chlorpropansaeure-methylester)

Conditions
ConditionsYield
With triethylamine In diethyl ether at 0℃; for 0.166667h;75%
2-methyl-but-2-ene
513-35-9

2-methyl-but-2-ene

methyl 2-chloroacrylate
80-63-7

methyl 2-chloroacrylate

(2R,4S)-2-Chloro-4,5-dimethyl-hex-5-enoic acid methyl ester
74964-44-6

(2R,4S)-2-Chloro-4,5-dimethyl-hex-5-enoic acid methyl ester

Conditions
ConditionsYield
With ethylaluminum dichloride In benzene at 25℃; for 28.8h;74%

Methyl 2-chloro-2-propenate Chemical Properties

Product Name: Methyl-2-chloroacrylate (CAS NO.80-63-7)


Molecular Formula: C4H5ClO2
Molecular Weight: 120.53g/mol
Mol File: 80-63-7.mol
Einecs: 201-298-7
Appearance: Clear colorless to pale yellow liquid
Boiling point: 124.6 °C at 760 mmHg 
Storage Temperature: 0-6°C
Flash Point: 39.7 °C
Density: 1.155 g/cm3
Refractive index: 1.442-1.444
Surface Tension: 27.8 dyne/cm
Enthalpy of Vaporization: 36.25 kJ/mol
Vapour Pressure: 12.6 mmHg at 25°C
XLogP3-AA: 1.5
H-Bond Donor: 0
H-Bond Acceptor: 2
Product Categories: Monomer

Methyl 2-chloro-2-propenate Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LC50 inhalation 500mg/m3/2H (500mg/m3) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS		 Farmakologiya i Toksikologiya Vol. 19, Pg. 60, 1956.
guinea pig LC50 inhalation 500mg/m3/2H (500mg/m3) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS		 Farmakologiya i Toksikologiya Vol. 19, Pg. 60, 1956.
human TCLo inhalation 5ppm (5ppm) SENSE ORGANS AND SPECIAL SENSES: CONJUNCTIVE IRRITATION: EYE "Practical Toxicology of Plastics," Lefaux, R., Cleveland, OH, Chemical Rubber Co., 1968Vol. -, Pg. 90, 1968.
mouse LC50 inhalation 500mg/m3/2H (500mg/m3) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS

LUNGS, THORAX, OR RESPIRATION: DYSPNEA		 Farmakologiya i Toksikologiya Vol. 19, Pg. 60, 1956.
rabbit LC50 inhalation 500mg/m3/2H (500mg/m3) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS		 Farmakologiya i Toksikologiya Vol. 19, Pg. 60, 1956.
rabbit LD50 skin 270mg/kg (270mg/kg) LUNGS, THORAX, OR RESPIRATION: FIBROSING ALVEOLITIS

KIDNEY, URETER, AND BLADDER: CHANGES IN BOTH TUBULES AND GLOMERULI

LIVER: "HEPATITIS (HEPATOCELLULAR NECROSIS), ZONAL"		 National Technical Information Service. Vol. OTS0535234,
rat LC50 inhalation 500mg/m3/2H (500mg/m3) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS

LUNGS, THORAX, OR RESPIRATION: DYSPNEA		 Farmakologiya i Toksikologiya Vol. 19, Pg. 60, 1956.
rat LD50 intraperitoneal 27mg/kg (27mg/kg) LUNGS, THORAX, OR RESPIRATION: FIBROSING ALVEOLITIS

KIDNEY, URETER, AND BLADDER: CHANGES IN BOTH TUBULES AND GLOMERULI

LIVER: "HEPATITIS (HEPATOCELLULAR NECROSIS), ZONAL"		 National Technical Information Service. Vol. OTS0535234,
rat LD50 oral 68mg/kg (68mg/kg) LUNGS, THORAX, OR RESPIRATION: FIBROSING ALVEOLITIS

LIVER: "HEPATITIS (HEPATOCELLULAR NECROSIS), ZONAL"

KIDNEY, URETER, AND BLADDER: CHANGES IN BOTH TUBULES AND GLOMERULI		 National Technical Information Service. Vol. OTS0535234

Methyl 2-chloro-2-propenate Consensus Reports

EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory.

Methyl 2-chloro-2-propenate Safety Profile

Moderately toxic by inhalation. Human systemic effects by inhalation: conjunctiva irritation. A severe skin irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl−. See also ESTERS.
Safety Information of Methyl-2-chloroacrylate (CAS NO.80-63-7):
Hazard Codes: T+
Risk Statements: 34-26-24/25-10 
10:  Flammable
24:  Toxic in contact with skin 
25:  Toxic if swallowed 
26:  Very Toxic by inhalation 
34:  Causes burns
Safety Statements: 45-38-36/37/39-26-16
16:  Keep away from sources of ignition - No smoking
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing  
37:  Wear suitable gloves 
38:  In case of insufficient ventilation, wear suitable respiratory equipment 
39:  Wear eye/face protection 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

Methyl 2-chloro-2-propenate Specification

 Methyl-2-chloroacrylate ,its CAS NO. is 80-63-7,the synonyms is 2-Chloro-2-propenoicacid,methylester ; 2-Chloro-2-propenoicacimethylester ; 2-Chloroacrylic acid, methyl ester ; 2-Chloroacrylicacid,methylester ; 2-Chloro-acrylicacimethylester ; 2-Chloropropenoic acid, methyl ester ; 2-Propenoic acid, 2-chloro-, methyl ester ; Acrylic acid, 2-chloro-, methyl ester .

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