Conditions | Yield |
---|---|
potassium hydroxide In solid byproducts: H2; 330 °C; with KOH (1:0.05) in N2 atmosphere, the heating rate 6 deg/min; | A 93% B n/a |
in aluminium block at 460-500°C; | A 79% B n/a |
With air In melt 460-500°C, in presence of air; | A 79% B 20% |
Conditions | Yield |
---|---|
In tetrahydrofuran reductive disproportionation;; IR;; | A 48% B 78% |
carbon dioxide
A
potassium carbonate
B
molybdenum hexacarbonyl
Conditions | Yield |
---|---|
In tetrahydrofuran reductive disproportionation, mechanism discussed;; IR;; | A 73% B 42% |
carbon dioxide
A
potassium carbonate
B
chromium(0) hexacarbonyl
Conditions | Yield |
---|---|
In tetrahydrofuran reductive disproportionation;; IR;; | A 68% B 46% |
Conditions | Yield |
---|---|
With KC8 In hexane at 20℃; for 48h; | A 68% B n/a |
Conditions | Yield |
---|---|
In ethanol decompn. with alc. KOH at 35°C in 48h;; | A 24% B n/a |
In ethanol |
D
potassium carbonate
Conditions | Yield |
---|---|
With air In neat (no solvent) sample heating in air up to 1000°C; TG, DTG, DTA, XRD; | A n/a B n/a C 1% D n/a E n/a |
Conditions | Yield |
---|---|
With 2,6-dimethylpyridine In acetonitrile at 55℃; for 4h; Product distribution / selectivity; |
Conditions | Yield |
---|---|
With CO2 In water sepn. and decompn. of the formed K-Zn-double carbonate with hot water; | |
With carbon dioxide In water sepn. and decompn. of the formed K-Zn-double carbonate with hot water; |
Conditions | Yield |
---|---|
With water byproducts: AgCl; | |
With H2O byproducts: AgCl; |
Conditions | Yield |
---|---|
byproducts: SrSO4; Intermediate:K-Sr-double salt; |
Conditions | Yield |
---|---|
In neat (no solvent) carbonisation at 400 up to 500 °C;; | |
In neat (no solvent) carbonisation at 400 up to 500 °C;; |
Conditions | Yield |
---|---|
With carbon monoxide In neat (no solvent) byproducts: K chromate(III); passing of CO at glowing heat;; |
Conditions | Yield |
---|---|
byproducts: NH4Cl; | |
byproducts: NH4Cl; |
B
potassium carbonate
Conditions | Yield |
---|---|
In water with excess of (NH4)2CO3; | |
In water with excess of (NH4)2CO3; |
Conditions | Yield |
---|---|
0% | |
0% |
Conditions | Yield |
---|---|
In not given in a soln. satd. with CO2; | |
In not given in a soln. satd. with CO2; | |
ammonium carbonate In not given |
potassium carbonate
Conditions | Yield |
---|---|
With calcium carbonate byproducts: CaF2; under pressure; | |
With calcium carbonate byproducts: CaF2; | |
With CaCO3 byproducts: CaF2; under pressure; | |
With CaCO3 byproducts: CaF2; |
Conditions | Yield |
---|---|
With water In not given byproducts: NH3; | |
With H2O In not given byproducts: NH3; | |
With water In not given byproducts: NH3; |
potassium carbonate
Conditions | Yield |
---|---|
With calcium carbonate In not given byproducts: calcium tartrate; heating, concn. of Cl(-) free soln., heating at red heat; filtration and addn. of HNO3 and AgNO3 to eliminate Cl(-) impurities from soln.; | |
calcn., extraction with H2O, filtration and evapn.; traces of Cl(1-), Ca(2+), Mg(2+), SiO2; | |
With CaCO3 In not given byproducts: calcium tartrate; heating, concn. of Cl(-) free soln., heating at red heat; filtration and addn. of HNO3 and AgNO3 to eliminate Cl(-) impurities from soln.; | |
calcn., extraction with H2O, filtration and evapn.; traces of Cl(1-), Ca(2+), Mg(2+), SiO2; |
B
potassium carbonate
Conditions | Yield |
---|---|
row potassium hydrogen tartrate; KCN contg. product; | |
row potassium hydrogen tartrate; KCN contg. product; |
potassium carbonate
Conditions | Yield |
---|---|
With oxalic acid with excess of oxalic acid and calcn. of potassium oxalate; | |
With oxalic acid In water | |
With oxalic acid with excess of oxalic acid and calcn. of potassium oxalate; | |
With oxalic acid In water |
Conditions | Yield |
---|---|
With carbon dioxide; ammonia; magnesium chloride In not given with excess of NH3; glowing of precipitate and extraction of residue with water; | |
With NH3; CO2; MgCl2 In not given with excess of NH3; glowing of precipitate and extraction of residue with water; |
Conditions | Yield |
---|---|
In ISOPROPYLAMIDE; toluene | 100% |
3-benzyloxy-5-methyl-1-(2-trifluoromethylphenylsulfonylamino)benzene
6-bromo-hexanoic acid ethyl ester
potassium carbonate
ethyl 6-[3-benzyloxy-5-methylphenyl-(2-trifluoromethylphenyl)-sulfonylamino]hexanoate
Conditions | Yield |
---|---|
In ethyl acetate; N,N-dimethyl-formamide | 100% |
Methyl 4-bromobutyrate
potassium carbonate
1-(3-methoxy-4-hydroxyphenyl)ethanone
methyl 4-(4-acetyl-2-methoxyphenoxy)butanoate
Conditions | Yield |
---|---|
In water; N,N-dimethyl-formamide | 100% |
In water; N,N-dimethyl-formamide | 100% |
Conditions | Yield |
---|---|
n-Bu4 In ethanol | 100% |
Conditions | Yield |
---|---|
In N-methyl-acetamide | 100% |
potassium carbonate
(3R)-N-tert-Butyloxycarbonyl-3-[N-(S)-α-methylbenzyl-N-methyl]aminomethylpyrrolidine
Conditions | Yield |
---|---|
With formaldehyd; sodium cyanoborohydride In methanol; acetic acid | 100% |
4,5-dihydro-6H-cyclopenta[b]thiophen-6-one
d(4)-methanol
potassium carbonate
5,5-Dideutero-4,5-dihydro-6H-cyclopenta[b]thiophen-6-one
Conditions | Yield |
---|---|
In benzene | 100% |
potassium carbonate
2-{3-[4-(4-fluorophenoxy)-1-piperidyl]propyl}-1H-isoindole-1,3(2H)-dione
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide | 100% |
3-(phenoxymethyl)piperidine hydrochloride
potassium carbonate
2-{3-[3-(phenoxymethyl)-1-piperidyl]propyl}-1H-isoindole-1,3(2H)-dione
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide | 100% |
1,2,3,4-tetrahydro-[2]naphthoyl chloride
potassium carbonate
phenethylamine
B
N-(2-phenylethyl) 1,2,3,4-tetrahydro-2-naphthoic amide
Conditions | Yield |
---|---|
In dichloromethane | A 100% B n/a |
salicylonitrile
potassium carbonate
bromoacetic acid methyl ester
B
methyl 2-(2-cyanophenoxy)ethanoate
Conditions | Yield |
---|---|
In acetone | A 100% B n/a |
potassium carbonate
trans-(1S,2R)-6,7-Dimethoxy-1,2,3,4-tetrahydro-1-(2-propyl-thien-4-yl)-2-naphthylamine
Conditions | Yield |
---|---|
In methanol | 100% |
potassium carbonate
ethyl bromoacetate
1,4,7,10-tetraaza-1-[2-(4-nitrophenyl)ethyl]cyclododecane
Conditions | Yield |
---|---|
In diethyl ether; acetonitrile | 100% |
potassium carbonate
p-toluenesulfonyl chloride
2-[p[[3-[3-(3,4-Dimethoxyphenyl)-2-propylamino]-2-hydroxypropoxy]]-phenyl]-4-(2-thienyl)imidazole
Conditions | Yield |
---|---|
In pyridine; water | 100% |
In pyridine; water | 100% |
water
potassium carbonate
A
6-formyl-2-naphthalenecarboxylic acid methyl ester
B
methyl 6-hydroxymethyl-2-naphthalenecarboxylate
Conditions | Yield |
---|---|
In methanol; ethyl acetate | A 100% B n/a |
N-benzyl-4-chlorobenzenesulfonamide
potassium carbonate
2-Chloroethyl chloroformate
2-chloroethyl N-(p-chlorobenzenesulfonyl) N-benzyl carbamate
Conditions | Yield |
---|---|
In water; acetone | 100% |
potassium carbonate
Conditions | Yield |
---|---|
With acetic anhydride | 100% |
Conditions | Yield |
---|---|
In not given pptn.; K2CO3:BaCl2=2:1; | 100% |
In not given pptn.; K2CO3:BaCl2=2:1; | 100% |
With potassium sulfate In not given byproducts: BaSO4; pptn.; | |
With K2SO4 In not given byproducts: BaSO4; pptn.; |
Conditions | Yield |
---|---|
With B2O3 In neat (no solvent) stoichiometric ratio, heating (1520 to 1670 K, 3-7 d); | 100% |
In neat (no solvent) stoichiometric ratio, heating (1520 to 1670 K, 3-7 d); |
Conditions | Yield |
---|---|
In methanol phenol-compd.:Ti-compd.:alkali-compd. molar ratio was 3:2:2, stirring overnight; solvent was removed in vac., residue was purified by filtration through Sephadex LH 20, elem. anal.; | 100% |
Conditions | Yield |
---|---|
In water at 20℃; for 12h; | 100% |
water
potassium carbonate
B
sodium carbonate
C
sodium hydroxide
Conditions | Yield |
---|---|
With tetrahydrofuran | A 100% B n/a C n/a |
trifluorormethanesulfonic acid
potassium carbonate
potassium tetrakis(trifluoromethanesulfonato)aurate
Conditions | Yield |
---|---|
at 150℃; for 24h; Sealed tube; | 100% |
Conditions | Yield |
---|---|
at 750℃; for 72h; | 100% |
potassium carbonate
Conditions | Yield |
---|---|
In methanol for 0.5h; Irradiation; | 100% |
Conditions | Yield |
---|---|
In water | 100% |
potassium carbonate
Conditions | Yield |
---|---|
Stage #1: titanium(IV) oxide bis(2,4-pentanedionate); (butane-1,4-diylbis(oxy))bis(ethane-2,1-diyl) bis(2,3-dihydroxybenzoate) In methanol; dichloromethane for 0.25h; Stage #2: potassium carbonate In methanol; dichloromethane for 24h; | 100% |
potassium carbonate
Conditions | Yield |
---|---|
Stage #1: titanium(IV) oxide bis(2,4-pentanedionate); C25H30O12 In methanol; dichloromethane for 0.25h; Stage #2: potassium carbonate In methanol; dichloromethane for 24h; | 100% |
potassium carbonate
1-methyl-5-mercaptotetrazole
Conditions | Yield |
---|---|
In water at 20 - 80℃; for 3h; | 100% |
Conditions | Yield |
---|---|
In water at 60℃; | 100% |
1、Potassium carbonate was first identified in 1742 by Antonio Campanella and is the primary component of potash and the more refined pearlash or salts of tartar.
2、The first patent issued by the U.S. Patent Office was awarded to Samuel Hopkins in 1790 for an improved method of making potash and pearlash.
3、In late 18th century North America, before the development of baking powder, pearl ash was used as a leavening agent in "quick breads".
Reported in EPA TSCA Inventory.
Potassium carbonate , its CAS NO. is 584-08-7, the synonyms are Carbonic acid, dipotassium salt ; Dipotassium carbonate . Potassium carbonate (K2CO3) is a white salt, soluble in water (insoluble in ethano), which forms a strongly alkaline solution. It is deliquescent, often appearing a damp or wet solid. Potassium carbonate is used in the production of soap and glass.
Properties about Potassium carbonate are: (1)mp: 891 °C(lit.); (2)density: 2.43 g/mL at 25 °C; (3)storage temp.: Store at RT.; (4)solubility H2O: 1 M at 20 °C, clear, colorless; (5)form: powder; (6)Water Solubility: 1120 g/L (20 oC); (7)Sensitive: Hygroscopic; (8)Merck: 14,7619; (9)BRN: 4267587;
Preparation of Potassium carbonate: Today potassium carbonate is prepared commercially by the electrolysis of potassium chloride. The resulting potassium hydroxide is then carbonated using carbon dioxide to form potassium carbonate, which is often used to produce other potassium compounds.
2KOH + CO2 → K2CO3 + H2O
Uses of Potassium carbonate: Potassium carbonate is being used as the electrolyte in many cold fusion experiments. It is sometimes used as a buffering agent in the production of mead or wine. It is also used as a fire suppressant in extinguishing deep fat fryers and various other B class related fires. It is used in reactions to maintain anhydrous conditions without reacting with the reactants and product formed. It may also be used to pre-dry some ketones, alcohols, and amines prior to distillation. It is mixed with distilled water to make a safer electrolyte for oxyhydrogen production than potassium hydroxide, the more commonly used electrolyte. In cuisine, it is used as an ingredient in the production of grass jelly, a food consumed in Chinese and Southeast Asian cuisines.
When you are using this chemical, please be cautious about it as the following:
1. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;
2. Wear suitable protective clothing;
3. Wear suitable gloves and eye/face protection;
You can still convert the following datas into molecular structure:
(1)InChI=1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2;
(2)InChIKey=BWHMMNNQKKPAPP-UHFFFAOYSA-L;
(3)SmilesC(=O)([O-])[O-].[K+].[K+];
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
bird - wild | LD50 | oral | 100mg/kg (100mg/kg) | Archives of Environmental Contamination and Toxicology. Vol. 12, Pg. 355, 1983. | |
mouse | LD50 | oral | 2570mg/kg (2570mg/kg) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 33(5), Pg. 30, 1989. | |
rat | LC | inhalation | > 500mg/m3 (500mg/m3) | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 33(5), Pg. 30, 1989. | |
rat | LD50 | oral | 1870mg/kg (1870mg/kg) | American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969. |
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