Scandium fluoride supplier | CasNO.13709-47-2

Name
Scandium trifluoride
EINECS 237-255-4
CAS No. 13709-47-2
Article Data79
CAS DataBase
Density 2.5
Solubility
Melting Point 1515°C
Formula ScF₃
Boiling Point
Molecular Weight 101.951
Flash Point
Transport Information UN 3288 6.1/PG 3
Appearance powder
Safety 26-36/37/39-45
Risk Codes 23/24/25-32
Molecular Structure
Hazard Symbols T
Synonyms Scandiumfluoride;Scandium trifluoride;Scandium trifluoride (ScF3);
PSA 0.00000
LogP 1.26060

Synthetic route

: scandium(III) oxide

: 7664-39-3
hydrogen fluoride

A: 13709-47-2
scandium(III) fluoride

B: scandium fluoride oxide

C: ScOF*2H2O

Conditions

Conditions	Yield
In water 0°C;

...Expand

: scandium(III) oxide

: cadmium(II) fluoride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
byproducts: CdO;

: 1279123-63-5
potassium hydrogenfluoride

: scandium(III)

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In hydrogenchloride pptn. from 7E-3 molar Sc(3+)-soln. in aq. HCl, 90-95°C, pH=2;; no quantitative react. in presence of Zr(4+), Ti(4+), Al(3+) or Fe(3+);,;	>99

: scandium

: ammonium fluoride

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: H2; Sc:NH4F molar ratio was 1:4, heating up to 400 °C with 2 °C/h rate, 6 weeks, in a Cu-ampoule, under Ar; cooling with 2 °C/h rate;

...Expand

: scandium(III) oxide

: ammonium fluoride

: 7664-39-3
hydrogen fluoride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In hydrogenchloride dissolving Sc2O3 in aq. HCl, addn. of concd. HF-soln., evapn., further addn. of aq. HF and evapn. until complete removal of HCl; addn. of aq. HF, addn. of excess NH4HF, evapn. to dryness;; heating in a dry N2-stream to 700-800°C to remove NH4*HF and moisture (Pt-vessel), pure product;;
In hydrogenchloride dissolving Sc2O3 in aq. HCl, addn. of concd. HF-soln., evapn., further addn. of aq. HF and evapn. until complete removal of HCl; addn. of aq. HF, addn. of excess NH4HF, evapn. to dryness;; heating in a dry N2-stream to 700-800°C to remove NH4*HF and moisture (Pt-vessel), pure product;;

...Expand

: ammonium fluoride

: scandium(III) chloride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In water on addn. of ScCl3-soln. to excess NH4F;;	0%

: potassium fluoride

: scandium(III)

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In water pptn. with aq. KF;;

: scandium(III)

: sodium fluoride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In water pptn. with aq. NaF;;

: scandium(III) oxide

: 13709-36-9
xenon difluoride

A: 13709-47-2
scandium(III) fluoride

B: xenon

Conditions

Conditions	Yield
In neat (no solvent) byproducts: oxygen; explosive convertion at 330-380°C, starting of fluorination at 210°C;

...Expand

: fluoride

: scandium(III)

A: 13709-47-2
scandium(III) fluoride

B: 139890-84-9, 25376-96-9
tetrafluoroscandate(1-)

C: ScF(2+)

D: {ScF2}(2+)

Conditions

Conditions	Yield
In perchloric acid formation in aq. soln.;;

...Expand

: fluoride

: yttrium(III)

A: 13709-47-2
scandium(III) fluoride

B: 139890-84-9, 25376-96-9
tetrafluoroscandate(1-)

C: ScF(2+)

D: ScF2(1+)

Conditions

Conditions	Yield
In water in aq. soln.;;

...Expand

: ScF2(1+)

: fluoride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In water formation in soln., determination of thermodynamic data of formation (enthalpy, free enthalpy, entropy);; not isolated;;
In water formation in soln., determination of complex formation constant;; not isolated;;
In water formation in soln., determination of thermodynamic data of formation (enthalpy, free enthalpy, entropy);; not isolated;;

: fluorosilicic acid

: scandium(III)

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
With water In water byproducts: SiO2, HF; immediate hydrolysis of Sc2(SiF6)3; investigation of react.-mechanism;;
With water In water byproducts: SiO2, HF; immediate hydrolysis of Sc2(SiF6)3;;
With water In hydrogenchloride addn. of H2SiF6 to concd. soln. in HCl while introduction of H2P-vapor;;
In water from the neutral or acidic soln. on addn. of H2SiF6 in the cold or in the warm,;
In not given slow, but complete pptn. on boiling in strongly acid soln.; product is free of rare earth compounds;;	>99

: fluorosilicic acid

: scandium(III)

A: 13709-47-2
scandium(III) fluoride

B: 2Sc(3+)*3{SiF6}(2-)=Sc2{SiF6}3

Conditions

Conditions	Yield
In water pptn. at room temp.;;	A 0% B n/a

...Expand

: potassium hexafluorosilicate

: scandium(III)

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In hydrogenchloride pptn. from 7E-3 molar Sc(3+)-soln. in aq. HCl, 90-95°C, pH=2;; no quantitative react. in presence of Zr(4+), Ti(4+), Al(3+) or Fe(3+);,;	>99

: 7664-39-3
hydrogen fluoride

: scandium(III)

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In hydrogen fluoride pptn. from aq. soln. by addn. of HF-soln., separation of ppt., evapn. (water-bath), addn. of HF-soln., cryst. product;;
In hydrogen fluoride pptn. with aq. HF;;

: sodium hexafluorosilicate

: scandium(III)

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In hydrogenchloride pptn. from 7E-3 molar Sc(3+)-soln. in aq. HCl, 90-95°C, pH=2;; no quantitative react. in presence of Zr(4+), Ti(4+), Al(3+) or Fe(3+);,;	>99

: Si2F6(2-)

: scandium(III)

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In water at room temp.;;

: scandium

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
With fluoroplast-4 In neat (no solvent) byproducts: C; High Pressure; shock compression reaction of Sc with fluoroplast-4; X-ray diffraction;

: scandium

: 7664-39-3
hydrogen fluoride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In neat (no solvent) at increased pressure in an autoclave, 250°C, up to 24h. cooling in the autoclave to 60°C, removal of absorbed HF in vac.;;
In neat (no solvent) at increased pressure in an autoclave, 250°C, up to 24h. cooling in the autoclave to 60°C, removal of absorbed HF in vac.;;

: calcium fluoride

: scandium

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In gas byproducts: Ca, ScF2, ScF; in the gas phase over the solid mixture at 1410K, Ta-Knudsen-cell;;
In neat (no solvent, gas phase) byproducts: Ca, ScF2, ScF; in the gas phase over the solid mixture at 1410K, Ta-Knudsen-cell;;

: 7664-39-3
hydrogen fluoride

: scandium(III) chloride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In hydrogen fluoride aq. HF; reaction of ScCl3 with aq. HF; evapn. of the liquid at 60°C and drying the solid at 80-100°C on a sand bath;

: {ScF2}(2+)

: 7664-39-3
hydrogen fluoride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In water byproducts: H(1+); formation in soln., determination of equilbrium constant and thermodynamic data of formation;;

: scandium(III) nitrate

: 7664-39-3
hydrogen fluoride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
pptn. on hydrofluoric acid addn. to Sc-salt soln.;

: bastnaesite

: 7664-39-3
hydrogen fluoride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In hydrogenchloride byproducts: CO2; pH 1 to <4, heating to 60-100°C for 4h while stirring, washing with H2O until neutral react.;;	>95

: scandium(III) oxide

: 7664-39-3
hydrogen fluoride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In hydrogen fluoride aq. HF; gradual addition of oxide to acid under periodical cooling; ppt. filtering off, drying (150-200°C), grinding; thermogravimetric analysis;

: calcium fluoride

: bastnaesite

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In hydrogenchloride byproducts: CO2, CaCl2; pH 1 to <4, heating to 60-100°C for 4h while stirring, washing with H2O until neutral react.;;	>95

: scandium(III) chloride

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
With HF In water pptn. of aq. soln. of scandium chloride with excess of concd. hydrofluoric acid; ppt. dried and heated in inert atmosphere; chem. anal.;

: scandium cryolite

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In neat (no solvent) thermal decompn. at 350-340°C; intermediate formation of NH4ScF4 at 260-350°C;; pure product;;
In potassium hydroxide aq. KOH; pptn. on potentiometric titration of a 0.01m aq. soln. with aq. KOH at pH about 7.5 to 7.7;;
In hydrogen fluoride byproducts: NH4(+), HF2(-); aq. HF;
In neat (no solvent) byproducts: NH3; heating under 1 bar NH3 pressure; detected by powder X-ray diffractometry;

: scandium tris(trifluoromethanesulfonate)

: 13709-47-2
scandium(III) fluoride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: COF2, SO2; thermal decompn. in inert atmosphere (exclusion of moisture);;
In neat (no solvent) byproducts: COF2, SO2; thermal decompn. in inert atmosphere (exclusion of moisture);;

: 13709-47-2
scandium(III) fluoride

: magnesocene

: tricyclopentadienylscandium(III)

Conditions

Conditions	Yield
anhydr. fluoride, 220-260°C, 3 to 6 h;	83%

: 13709-47-2
scandium(III) fluoride

: scandium(III) chloride

: scandium

Conditions

Conditions	Yield
With potassium chloride; sodium chloride In melt Electrolysis; ScF3 or ScCl3; vac., heating to 300-350°C, filling with Ar, electrolysing at 780-860°C (NaCl electrolyte) or at 720-750°C (NaCl+KCl electrolyte), current density = 0.1-0.5 A/cm**2; detd. by mass spectrography;	65%

: 13709-47-2
scandium(III) fluoride

A: 839684-48-9, 1298-54-0, 51269-38-6
tris(η5-cyclopentadienyl)scandium(III)

B: tris(fluorodicyclopentadienylscandium)

Conditions

Conditions	Yield
With (C5H5)Na In tetrahydrofuran refluxing for 12 h; under argon or vac.;; drying by heating at 110°C under vac. for 7 h; extn. with toluene; concn.; recrystn. from toluene/hexane (2/1); elem. anal.;	A 9% B 14%

: 13709-47-2
scandium(III) fluoride

: scandium

Conditions

Conditions	Yield
With calcium In neat (no solvent) thermal redn, (calcium metal); electrochem. refinement;
With calcium In neat (no solvent) byproducts: CaF2; reduction with Ca under Ar, start of react. at 850-900°C; Ta- or Zr-boride-vessel;; heating to 1400°C, distn. in vac.;;
With calcium In neat (no solvent) reduction with Ca under Ar, start of react. at 700-800°C, heating to 1500°C at 10E-4 Torr (distn. of Sc); Mo-vessel;;

: 13709-47-2
scandium(III) fluoride

: 7732-18-5
water

: scandium fluoride oxide

Conditions

Conditions	Yield
In neat (no solvent) at 900°C, heating slowly;; detected by thermogravimetric and X-ray-measurements;;
With air In neat (no solvent) hydroylsis by moisture in the furnace on heating in dry Ar or He;;
In neat (no solvent) hydroylsis in a stream of moist N2 at 800°C;; not pure, contaminated with oxide;;

: 13709-47-2
scandium(III) fluoride

: 7732-18-5
water

: scandium(III) oxide

Conditions

Conditions	Yield
In neat (no solvent) on fast heating to 300°C;; detected by thermogravimetric and X-ray-measurements;;
In neat (no solvent) 975.-+.25°C, streaming H2O-vapor, 4-30min; increase of react.-rate in presence of U3O8 and/or Cr2O3;;	>99
In neat (no solvent) at 1040°C, heating slowly;; detected by thermogravimetric and X-ray-measurements;;

: rubidium fluoride

: 13709-47-2
scandium(III) fluoride

: rubidium scandium hexafluoride

Conditions

Conditions	Yield
In neat (no solvent, solid phase) solid state reacn. between appropriate amts. of RbF and ScF3 in a sealed Pt tube under Ar;

: 13709-47-2
scandium(III) fluoride

: 13400-13-0
cesium fluoride

: caesium scandium hexafluoride

Conditions

Conditions	Yield
In neat (no solvent, solid phase) solid state reacn. between appropriate amts. of CsF and ScF3 in a sealed Pt tube under Ar;

: 13709-36-9
xenon difluoride

: 13709-47-2
scandium(III) fluoride

: 13708-63-9
terbium(III) fluoride

: 36781-15-4
terbium tetrafluoride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Xe; heating (430-470°C, 0.5-1 h); DTA;

...Expand

: 13709-47-2
scandium(III) fluoride

: fluoride

: 139890-84-9, 25376-96-9
tetrafluoroscandate(1-)

Conditions

Conditions	Yield
In water formation in soln., determination of complex formation constant;; not isolated;;

Scandium fluoride Chemical Properties

Scandium fluoride ,its cas register number is 13709-47-2,is also named as Scadium trifluoride ; Scandium fluoride ; Scandium(III) fluoride ; Scandium fluoride (ScF₃) ; Scandiumfluoride(scf₃) ; Scandium fluoride, anhydrous, 99.99% ; Scandium (III) fluoride (99.9%-SC) (REO) ; CID83678 ; LS-144616 ,and so on. Scandium fluoride (CAS No.13709-47-2) is usually bright white powder.

IUPAC Name: Trifluoroscandium
CAS: 13709-47-2
Molecular Formula: F₃Sc
Molecular Weight: 101.95
Molecular structure:
EINECS: 237-255-4
Melting point: 1515°C
Form: powder
Sensitive: Hygroscopic
H bond acceptors: 0
H bond donors: 0
Freely Rotating Bonds: 0
H-Bond Donor: 0
H-Bond Acceptor: 3
Rotatable Bond Count: 0
Topological Polar Surface Area: 0
Heavy Atom Count: 4
Formal Charge: 0
Complexity: 8
Isotope Atom Count: 0
Covalently-Bonded Unit Count: 1

Scandium fluoride Uses

Scandium fluoride (CAS No.13709-47-2) is commonly used as chemical reagent.

Scandium fluoride Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mammal (species unspecified)	LD	intraperitoneal	> 10gm/kg (10000mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(8), Pg. 43, 1991.
mammal (species unspecified)	LD	oral	> 10gm/kg (10000mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 35(8), Pg. 43, 1991.

RTECS: VQ8930000

Scandium fluoride Safety Profile

Hazard Codes: T,Xi
Risk Statements: 23/24/25-32 (R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. R32:Contact with acid liberates very toxic gas.)
Safety Statements: 26-36/37/39-45 (S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.))
RIDADR: UN 3288 6.1/PG 3
WGK Germany: 3
Hazard Note: Irritant
HazardClass: 6.1
PackingGroup: III

Scandium fluoride Specification

Removal in wastewater treatment of Scandium fluoride (CAS No.13709-47-2) can be stated as follows:
Total removal:1.85 percent
Total biodegradation:0.09 percent
Total sludge adsorption:1.76 percent
Total to Air:0.00 percent
(using 10000 hr Bio P,A,S)

Product Name

Scandium trifluoride

Synthetic route

Scandium fluoride Chemical Properties

Scandium fluoride Uses

Scandium fluoride Toxicity Data With Reference

Scandium fluoride Safety Profile

Scandium fluoride Specification

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