• Name

  MESO-TETRAPHENYL-TETRABENZOPORPHINE

• EINECS
• CAS No. 119654-64-7
• Article Data3
• CAS DataBase
• Density
• Solubility
• Melting Point
• Formula C₆₀H₃₆N₄Pd
• Boiling Point
• Molecular Weight 919.393
• Flash Point
• Transport Information
• Appearance
• Safety
• Risk Codes
• Molecular Structure
• Hazard Symbols
• Synonyms Palladium,[6,13,20,27-tetraphenyl-29H,31H-tetrabenzo[b,g,l,q]porphinato(2-)-N29,N30,N31,N32]-,(SP-4-1)-;29H,31H-Tetrabenzo[b,g,l,q]porphine, 6,13,20,27-tetraphenyl-,palladium complex;29H,31H-Tetrabenzo[b,g,l,q]porphine, palladium deriv.;meso-Tetraphenyl-tetrabenzoporphine;
• PSA 50.50000
• LogP 10.32900

Synthetic route

80529-83-5

cadmium(II) 5,10,15,20-tetraphenyl tetrabenzoporphyrinate

palladium dichloride

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

Conditions

Conditions	Yield
In N,N-dimethyl-formamide for 0.00833333h; Reflux;	80%

3375-31-3

palladium diacetate

80528-89-8

meso-tetraphenyltetrabenzoporphyrin

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

Conditions

Conditions	Yield
In dichloromethane; N,N-dimethyl-formamide at 150℃; for 1h;	64%
In dichloromethane; N,N-dimethyl-formamide at 150℃; for 0.75h; Inert atmosphere;	47.9%

80528-89-8

meso-tetraphenyltetrabenzoporphyrin

palladium dichloride

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

Conditions

Conditions	Yield
In N,N-dimethyl-formamide for 0.0833333h; Reflux;	25%

114-70-5

sodium phenylacetate

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: water / pH 3.0 2: melt / 1 h / 360 °C / Inert atmosphere 3: hydrogenchloride / dichloromethane; water / 0.5 h 4: dichloromethane; N,N-dimethyl-formamide / 0.75 h / 150 °C / Inert atmosphere View Scheme

103-82-2

phenylacetic acid

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

Conditions

Conditions	Yield
Multi-step reaction with 5 steps 1: sodium hydroxide / water / pH 8.0 2: water / pH 3.0 3: melt / 1 h / 360 °C / Inert atmosphere 4: hydrogenchloride / dichloromethane; water / 0.5 h 5: dichloromethane; N,N-dimethyl-formamide / 0.75 h / 150 °C / Inert atmosphere View Scheme
Multi-step reaction with 3 steps 1: 1 h / 360 °C / Inert atmosphere 2: hydrogenchloride / dichloromethane; water / 0.75 h 3: dichloromethane; N,N-dimethyl-formamide / 1 h / 150 °C View Scheme

zinc(II) phenylacetate

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: melt / 1 h / 360 °C / Inert atmosphere 2: hydrogenchloride / dichloromethane; water / 0.5 h 3: dichloromethane; N,N-dimethyl-formamide / 0.75 h / 150 °C / Inert atmosphere View Scheme

140-29-4

phenylacetonitrile

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: sodium hydroxide / water / 5 h / 115 - 120 °C / Inert atmosphere 2: 1 h / 360 °C / Inert atmosphere 3: hydrogenchloride / dichloromethane; water / 0.75 h 4: dichloromethane; N,N-dimethyl-formamide / 1 h / 150 °C View Scheme

80528-89-8

meso-tetraphenyltetrabenzoporphyrin

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: N,N-dimethyl-formamide 2: N,N-dimethyl-formamide / 0.01 h / Reflux View Scheme

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

1215023-72-5

palladium 2-bromo-6,13,20,27-tetraphenyltetrabenzo[b:g:l:q]porphyrin

Conditions

Conditions	Yield
With tetramethylammonium bromide In chloroform for 8h; Reflux; regioselective reaction;	63%

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

1123832-45-0

(22,23,72,73,122,123,172,173-octabromo-5,10,15,20-tetraphenyltetrabenzoporphyrinato)palladium(II)

Conditions

Conditions	Yield
With bromine; tetramethylammonium bromide In chloroform for 4h; Reflux; regioselective reaction;	46%

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

7726-95-6

bromine

64-20-0

tetramethylammonium bromide

(22,23,72,73,122,123,172-heptabromo-5,10,15,20-tetraphenyltetrabenzoporphyrinato)palladium(II)

1123832-45-0

(22,23,72,73,122,123,172,173-octabromo-5,10,15,20-tetraphenyltetrabenzoporphyrinato)palladium(II)

Conditions

Conditions

Yield

In chloroform soln. of Me4NBr in CHCl3 stirred for 10 min; excess of Br2 added; mixt. stirred for 20 min; soln. of Pd complex in CHCl3 added; mixt. heated for2 h with stirring under reflux; cooled to room temp.; washed (Na2S2O3, H2O, satd. NaCl); dried; evapd. ...; cooled to room temp.; washed (Na2S2O3, H2O, satd. NaCl); org. phase dried (Na2SO4); evapd.; monitored by NMR spectroscopy, mass spectroscopy;

A n/a B 43%

...Expand

119654-64-7

palladium(II) 5,10,15,20-tetraphenyltetrabenzoporphyrinate

(22,23,72,73,122,123,172-heptabromo-5,10,15,20-tetraphenyltetrabenzoporphyrinato)palladium(II)

1123832-45-0

(22,23,72,73,122,123,172,173-octabromo-5,10,15,20-tetraphenyltetrabenzoporphyrinato)palladium(II)

Conditions

Conditions	Yield
With bromine; tetramethylammonium bromide In chloroform for 4h; Reflux; regioselective reaction;

meso-Tetraphenyl-tetrabenzoporphine Specification