Encyclopedia

  • Elbs Reaction

    Elbs Reaction K. Elbs, E. Larsen, Ber. 17, 2847 (1884). Formation of polyaromatics (eg. anthracene) by intramolecular condensation of diaryl ketones con

  • Elbs Persulfate Oxidation

    Elbs Persulfate Oxidation K. Elbs, J. Prakt. Chem. 48, 179 (1893). Hydroxylation of monophenols to predominantely p-diphenols or oxidation of methyl-sub

  • Tscherniac-Einhorn Reaction

    Tscherniac-Einhorn Reaction J. Tscherniac, DE 134979; A. Einhorn et al., Ann. 343, 207 (1905); 361, 113 (1908). Introduction of the amidomethyl group in

  • Ehrlich-Sachs Reaction

    Ehrlich-Sachs Reaction P. Ehrlich, F. Sachs, Ber. 32, 2341 (1899). Formation of N-phenylimines by the base-catalyzed condensation of compounds containin

  • Edman Degradation

    Edman Degradation P. Edman, Acta Chem. Scand. 4, 283 (1950). Cyclic degradation of peptides based on the reaction of phenylisothiocyanate with the free

  • Eastwood Reaction

    Eastwood Reaction (Eastwood Deoxygenation) G. Grank, F. W. Eastwood, Aust. J. Chem. 17, 1392 (1964). Stereospecific conversion of vicinal diols into ole

  • Dutt-Wormall Reaction

    Dutt-Wormall Reaction P. K. Dutt, H. R. Whitehead, A. Wormall, J. Chem. Soc. 119, 2088 (1921); P. K. Dutt, ibid. 125, 1463 (1924). Preparation of diazoa

  • Frankland-Duppa Reaction

    Frankland-Duppa Reaction E. Frankland, Ann. 126, 109 (1863); E. Frankland, B. F. Duppa, Ann. 135, 25 (1865). Formation of α-hydroxycarboxylic este

  • Duff Reaction

    Duff Reaction J. C. Duff, E. J. Bills, J. Chem. Soc. 1932, 1987; 1934, 1305; 1941, 547; 1945, 276. Formylation of phenols or aromatic amines with hexame

  • Dötz Reaction

    Dötz Reaction K. H. Dötz, Angew. Chem. Int. Ed. 14, 644 (1975). Three component cyclization of an aromatic or vinylic alkoxy pentacarbonyl chr

  • Doering-LaFlamme Allene Synthesis

    Doering-LaFlamme Allene Synthesis W. von E. Doering, P. M. LaFlamme, Tetrahedron 2, 75 (1958); US 2933544 (1960). Treatment of an olefin with bromoform

  • Doebner Reaction

    Doebner Reaction O. Doebner, Ann. 242, 265 (1887); Ber. 20, 277 (1887); 27, 352, 2020 (1894). Formation of substituted cinchoninic acids from aromatic a

  • Knoevenagel Condensation

    Knoevenagel Condensation; Doebner Modification E. Knoevenagel Ber. 31, 2596 (1898); O. Doebner, Ber. 33, 2140 (1900). Condensation of aldehydes or keton

  • Dimroth Rearrangement

    Dimroth Rearrangement O. Dimroth, Ann. 364, 183 (1909); 459, 39 (1927). Rearrangement whereby exo- and endocyclic heteroatoms on a heterocyclic ring are

  • Dienone-Phenol Rearrangement

    Dienone- Rearrangement K. von Auwers, K. Ziegler, Ann. 425, 217 (1921). Transformation of a 4,4-disubstituted cyclohexadienone into a 3,4-disubstituted

  • Dieckmann Reaction

    Dieckmann Reaction W. Dieckmann, Ber. 27, 102, 965 (1894); 33, 595, 2670, (1900); Ann. 317, 51, 93, (1901). Base-catalyzed cyclization of dicarboxylic a

  • Dess-Martin Oxidation

    Dess-Martin Oxidation D. B. Dess, J. C. Martin, J. Org. Chem. 48, 4155 (1983). Mild oxidation of primary and secondary alcohols to aldehydes and ketones

  • Demjanov Rearrangement

    Demjanov Rearrangement N. J. Demjanov, M. Lushnikov, J. Russ. Phys. Chem. Soc. 35, 26 (1903); Chem. Zentr. 1903, 1, 828. Deamination of primary amines b

  • Tiffeneau-Demjanov Rearrangement

    Tiffeneau-Demjanov Rearrangement M. Tiffeneau et al., Compt. Rend. 205, 54 (1937). Rearrangement of β-amino alcohols upon diazotization with nitrou

  • Delépine Reaction

    Delépine Reaction (Delépine Amine Synthesis) M. Delépine, Compt. Rend. 120, 501 (1895); 124, 292 (1897). Preparation of primary ami

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