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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

1,5-Hexadiene Manufacturer/High quality/Best price/In stock

Cas:592-42-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay (Ursolic acid) 98%min 98.22% ----------------------------------------------------------------

High purity 592-42-7 1,5-Hexadiene

Cas:592-42-7

Min.Order:1 Gram

FOB Price: $100.0 / 500.0

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

1,5-Hexadiene Cas No.:592-42-7 Molecular Structure: EINECS No.: 209-754-7 Molecular Formula: C6H10 M.W: 82.13 Properties: 1) Appearance: Colorless to light yellow transparent liquid 2) M.P: -141°C 3) B.P: 60°C 4) Fl

1,5-Hexadiene

Cas:592-42-7

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Hexa-1,5-diene

Cas:592-42-7

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,5-Hexadiene

Cas:592-42-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Sinotech Import&Export Corporation

Melting point −141 °C(lit.) Boiling point 60 °C(lit.) density 0.692 g/mL at 25 °C(lit.) vapor pressure 367 mm Hg ( 37.7 °C)

1,5-Hexadiene CAS: 592-42-7

Cas:592-42-7

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,5-HEXADIENE

Cas:592-42-7

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1,5-Hexadiene

Cas:592-42-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

1,5-Hexadiene

Cas:592-42-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

1,5-Hexadiene 592-42-7

Cas:592-42-7

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

1,5-Hexadiene

Cas:592-42-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemvon Biotechnology Co. Ltd.

1,5-HEXADIENE fast delivery /best price /on hot selling Hexadiene, CAS Number 592-42-7, Molecular Weight 82.15, Chemical Formula C6H10, Container Size 500mL, Shelf Life 24 mo., Shipping Restrictions UN2458, Hexadiene, 3, PG II Restricted: This it

1,5-HEXADIENE fast delivery /best price /on hot selling

Cas:592-42-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1,5-Hexadiene

Cas:592-42-7

Min.Order:0

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Sealed in a cool ,dry and microtherm place , avoid light . Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:It is an important r

592-42-7 supplier in China

Cas:592-42-7

Min.Order:1 Liter

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,5-Hexadiene

Cas:592-42-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 592-42-7 with competitive price

Cas:592-42-7

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

1,5-HEXADIENEAppearance:clear liquid Storage:Protected from light, stored hermetically and in a dry place Package:Fluoride barrel Application:additives Transportation:By air or courier or sea

1,5-HEXADIENE

Cas:592-42-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

1.High purity, like 99%, 99.9%, 99.95%, 99.99%, 99.999%2.Quality control, test sample before shipping and keep sample for 3 years after shipping;3. Prompt shipment with professional documents;4. Packing as your request, with photo before shipment;5.

1,5-Hexadiene

Cas:592-42-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

1,5-Hexadiene

Cas:592-42-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

HENAN SUNLAKE ENTERPRISE CORPORATION Our company advantages: 1、The highest quality with the competitive price. 2、Professional human services. 3、The fastest and safest delivery service. 4、The faster and safest delivery service. 5、The hig

1,5-HEXADIENE

Cas:592-42-7

Min.Order:50 Gram

Negotiable

Type:Trading Company

inquiry

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

ISO 9001 National Research Platform CAS No. 592-42-7

Cas:592-42-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

WUHAN YING YUAN BEI TECHNOLOGY CO., LTD

in stock Assay:99% white powder dentification(HPLC) :The retention time of the major peak in the chromatogram of the assay preparation corresponds to that in the chromatogram of the Conformal standard preparation, as obtained in the ass

1,5-Hexadiene

Cas:592-42-7

Min.Order:1 Kilogram

FOB Price: $160.0

Type:Trading Company

inquiry

Qingdao Sigma Chemical Co., Ltd.

Qingdao Sigma Chemical Ltd is is a global chemical industry manufacturers and suppliers of pharmaceuticals and intermediates, peptide,Nootropis etc API, food and feed additives, herbal extracts, agrochemicals and fine chemicals etc. Our Labo

High Quality 1,5-HEXADIENE

Cas:592-42-7

Min.Order:1 Gram

FOB Price: $1.0

Type:Trading Company

inquiry

Hangzhou KieRay Chem Co.,Ltd.

Hangzhou KieRaychem Co.,Ltd.is located in Yuhang District of Hangzhou City and specialized in the chemical product customization, development, sales, import and export. Current business is focused on fine chemicals, pharmaceutical materials and int

1,5-HEXADIENE

Cas:592-42-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

1,5-Hexadiene

Cas:592-42-7

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Henan Fine Chemicals Co., Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHenan Fine Chemicals Co., LTD. is a diversified technology - oriented integrated company, which mainly concentrates on fine chemicals. Our company is committed to becom

1,5-Hexadiene Manufacturer/High quality/Best price/In stock

Cas:592-42-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

Cerametek Materials (CMT) is your industrial and R&D supplier: 1. Semiconductor materials: Compounds of II, III, IV, V, VI groups such as Metal Sulfides, Selenides, Tellurides, Arsenide, Antimonide, Phosphide... 2. Advanced ceramic and crys

1,5-Hexadiene

Cas:592-42-7

Min.Order:0

Negotiable

Type:Other

inquiry

AOPHARM

Aopharm is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in modes of tran

1,5-HEXADIENE

Cas:592-42-7

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

1,5-Hexadiene

Cas:592-42-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

1,5-Hexadiene

Cas:592-42-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

1,2-epithio-5-hexene
6766-70-7

1,2-epithio-5-hexene

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
With hydrogen sulfide; triphenylphosphine; methyltrioxorhenium(VII) In [D3]acetonitrile for 1h; Ambient temperature;100%
cis-1,2-Bis(iodomethyl)cyclobutane
77774-05-1

cis-1,2-Bis(iodomethyl)cyclobutane

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
With tert.-butyl lithium In diethyl ether; pentane at -23℃; for 0.5h; Mechanism;98%
dimethylacetylene
503-17-3

dimethylacetylene

Cp(η3-C3H5)2Cr

Cp(η3-C3H5)2Cr

A

Cp(η6-Me6C6)Cr

Cp(η6-Me6C6)Cr

B

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
In pentane under Ar, addn. of the butyne to a suspension of the Cr complex in pentane at -78°C, stirred and allowed to warm to 0°C over 7 h (slow warming to suppress formation of hexamethylbenzene), held for 48 h; filtration, cooled to -78°C, crystn., elem. anal., the diene detn. by GC analysis;A 94.6%
B 86%
trimethyl(allyl)stannane
762-73-2

trimethyl(allyl)stannane

allyl bromide
106-95-6

allyl bromide

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
bis(η3-allyl-μ-chloropalladium(II)) In N,N,N,N,N,N-hexamethylphosphoric triamide Ambient temperature;94%
With bis(η3-allyl-μ-chloropalladium(II)) In N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; for 3h;94%
trimethyl(allyl)stannane
762-73-2

trimethyl(allyl)stannane

allyl bromide
106-95-6

allyl bromide

A

1,5-Hexadien
592-42-7

1,5-Hexadien

B

trimethyltin bromide
1066-44-0

trimethyltin bromide

Conditions
ConditionsYield
With ((π-C3H5)PdCl)2 In N,N,N,N,N,N-hexamethylphosphoric triamide room temp.;A 94%
B n/a
Cp(η3-C3H5)2Cr

Cp(η3-C3H5)2Cr

A

Cr(η(5)-C5H5)(η(6)-cyclooctatetraene)

Cr(η(5)-C5H5)(η(6)-cyclooctatetraene)

B

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
With cyclooctatetraene In pentane under Ar, addn. of the tetraene to a suspension of the Cr complex in pentane at -78°C, stirred for 3 d at -20°C, beige suspension; evapn. to dryness, residue sublimed at 60°C, high vac., elem. anal., detn. of the diene by GC analysis;A 85.7%
B 94%
N-(4-chlorobenzylidene)aniline
2362-79-0

N-(4-chlorobenzylidene)aniline

allyl bromide
106-95-6

allyl bromide

A

1,5-Hexadien
592-42-7

1,5-Hexadien

B

4-chloro-N-phenyl-α-2-propenylbenzenemethanamine

4-chloro-N-phenyl-α-2-propenylbenzenemethanamine

Conditions
ConditionsYield
With tetrabutylammomium bromide; indium(III) chloride In tetrahydrofuran chemo-electrochemical allylation;A n/a
B 93%
3,4-Dimethoxy-benzalanilin
166670-25-3

3,4-Dimethoxy-benzalanilin

allyl bromide
106-95-6

allyl bromide

A

1,5-Hexadien
592-42-7

1,5-Hexadien

B

N-[1-(3,5-dimethoxyphenyl)-3-butenyl]-N-phenylamine

N-[1-(3,5-dimethoxyphenyl)-3-butenyl]-N-phenylamine

Conditions
ConditionsYield
With tetrabutylammomium bromide; indium(III) chloride In tetrahydrofuran chemo-electrochemical allylation;A n/a
B 93%
Li(1+)*((H3C)2NCH2)2*(C5H5)V(C3H5)2(1-)=(Li((H3C)2NCH2)2)((C5H5)V(C3H5)2)
89184-58-7

Li(1+)*((H3C)2NCH2)2*(C5H5)V(C3H5)2(1-)=(Li((H3C)2NCH2)2)((C5H5)V(C3H5)2)

carbon monoxide
201230-82-2

carbon monoxide

A

tetracarbonyl(η(5)-cyclopentadienyl)vanadium(I)

tetracarbonyl(η(5)-cyclopentadienyl)vanadium(I)

B

1,5-Hexadien
592-42-7

1,5-Hexadien

C

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

D

dilithium (η-cyclopentadienyl)tri(carbonyl)vanadate

dilithium (η-cyclopentadienyl)tri(carbonyl)vanadate

Conditions
ConditionsYield
In tetrahydrofuran reaction of CO with (LiTMEDA)(CpV(C3H5)2) in THF (Ar); formation of 1,5-hexadiene in the reaction soln., extn. of the residue with toluene, filtering off the solid and drying to give Li2(CpV(CO)3), evapn. of the filtrate to dryness and subliming the residue in a high vacuum at 80°C to give CpV(CO)4;A 91%
B 46%
C n/a
D n/a
Cp(η3-C3H5)2Cr

Cp(η3-C3H5)2Cr

diphenyl acetylene
501-65-5

diphenyl acetylene

A

Cp(η6-Ph6C6)Cr

Cp(η6-Ph6C6)Cr

B

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
In pentane under Ar, addn. of the acetylene to a suspension of the Cr complex in pentane at -78°C, stirred and allowed to warm to 0°C over 7 h , held for 48 h; filtration, cooled to -78°C, crystn., elem. anal., the diene detn. by GC analysis;A 88.3%
B 65.2%
allyl bromide
106-95-6

allyl bromide

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
With copper acetylacetonate; tetraethylammonium perchlorate In N,N-dimethyl-formamide electrolysis; 2 F/mol;;88%
With copper acetylacetonate; tetraethylammonium perchlorate In N,N-dimethyl-formamide Product distribution; other electrolytic conditions, reagents; other allyl halides;88 % Chromat.
With magnesium In diethyl ether for 0.1h; Product distribution; yield of Wurtz reaction product as a function of the nature of trhe halide and experimental conditions;10 g
allyl phenyl selenide
14370-82-2

allyl phenyl selenide

A

1,5-Hexadien
592-42-7

1,5-Hexadien

B

diphenyl diselenide
1666-13-3

diphenyl diselenide

Conditions
ConditionsYield
at 600℃; under 20 Torr; for 0.0333333h;A 67%
B 88%
(allylsulfonyl)benzene
16212-05-8

(allylsulfonyl)benzene

allylmagnesium bromide
1730-25-2

allylmagnesium bromide

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
With triphenylphosphine; copper dichloride In tetrahydrofuran at 60℃;87%
Cp(η3-C3H5)2Cr

Cp(η3-C3H5)2Cr

acetylene
74-86-2

acetylene

A

Cp(η6-C6H6)Cr

Cp(η6-C6H6)Cr

B

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
In pentane under Ar, react. vessel with suspension of the Cr complex in pentane at -78°C connected with a gas burette filled with acetylene, warmed slowly to 0.degree,C, stirred for 48 h under absorption of acetylene, brown suspension; filtration, cooled to -78°C, crystn., elem. anal., the diene detn. by GC analysis;A 86.2%
B 85%
benzylidene phenylamine
538-51-2

benzylidene phenylamine

allyl bromide
106-95-6

allyl bromide

A

1,5-Hexadien
592-42-7

1,5-Hexadien

B

phenyl-(1-phenyl-but-3-enyl)-amine
66489-79-0

phenyl-(1-phenyl-but-3-enyl)-amine

Conditions
ConditionsYield
With tetrabutylammomium bromide; indium(III) chloride In tetrahydrofuran chemo-electrochemical allylation;A n/a
B 86%
[(C5H5)V(C3H5)2]

[(C5H5)V(C3H5)2]

carbon monoxide
201230-82-2

carbon monoxide

A

tetracarbonyl(η(5)-cyclopentadienyl)vanadium(I)

tetracarbonyl(η(5)-cyclopentadienyl)vanadium(I)

B

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
In tetrahydrofuran reaction of CO with CpV(C3H5)2 in THF (Ar); formation of 1,5-hexadiene in the condensate of the reaction soln., subliming the reaction residue in a high vacuum at 80°C to give CpV(CO)4;A 86%
B 75%
cis-{(PhCH2)2Co(III)(2,2'-bipyridine)2}ClO4

cis-{(PhCH2)2Co(III)(2,2'-bipyridine)2}ClO4

allyl bromide
106-95-6

allyl bromide

A

(Co(bpy)2Br)(1+)
747369-48-8

(Co(bpy)2Br)(1+)

B

1,5-Hexadien
592-42-7

1,5-Hexadien

C

4-Phenyl-1-butene
768-56-9

4-Phenyl-1-butene

D

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

Conditions
ConditionsYield
In [D3]acetonitrile Kinetics; Irradiation (UV/VIS); Degasses condition, 298 K, 11 h;; detected by NMR-spectroscopy;;A n/a
B 36%
C 34%
D 85%
cis-{(PhCH2)2Co(bpy)2}(1+)

cis-{(PhCH2)2Co(bpy)2}(1+)

allyl bromide
106-95-6

allyl bromide

A

(Co(bpy)2Br)(1+)
747369-48-8

(Co(bpy)2Br)(1+)

B

1,5-Hexadien
592-42-7

1,5-Hexadien

C

4-Phenyl-1-butene
768-56-9

4-Phenyl-1-butene

D

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

Conditions
ConditionsYield
In [D3]acetonitrile Kinetics; Irradiation (UV/VIS); Degasses condition, 298 K, 11 h;; detected by NMR-spectroscopy;;A n/a
B 36%
C 34%
D 85%
Cp(η3-C3H5)2Cr

Cp(η3-C3H5)2Cr

buta-1,3-diene
106-99-0

buta-1,3-diene

A

(CpCr)2(μ-η3,η3-C8H12)

(CpCr)2(μ-η3,η3-C8H12)

B

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
In diethyl ether under Ar, soln. of the Cr complex in diethyl ether treated with a 10-fold excess of butadiene at -30°C, warmed to -5°C over 12 h; evapn., extn. of the residue (pentane), cooling to -78°C, crystn., elem. anal., detn. of the diene by GC analysis;A 72%
B 83%
2-(bromomethyl)acrylic acid
72707-66-5

2-(bromomethyl)acrylic acid

allyl bromide
106-95-6

allyl bromide

A

1,5-Hexadien
592-42-7

1,5-Hexadien

B

2-methylene-5-hexenoic acid
73505-05-2

2-methylene-5-hexenoic acid

Conditions
ConditionsYield
With manganese; copper dichloride In tetrahydrofuran; water for 16h; Ambient temperature; Yield given;A n/a
B 79%
With manganese; copper dichloride In tetrahydrofuran; water for 16h; Ambient temperature; Yields of byproduct given;A n/a
B 79%
Cp(η3-C3H5)2Cr

Cp(η3-C3H5)2Cr

hex-3-yne
928-49-4

hex-3-yne

A

Cp(η6-Et6C6)Cr

Cp(η6-Et6C6)Cr

B

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
In pentane under Ar, addn. of the hexyne to a suspension of the Cr complex in pentane at -78°C, stirred and allowed to warm to 0°C over 7 h , held for 48 h; filtration, cooled to -78°C, crystn., elem. anal., the diene detn. by GC analysis;A 77.9%
B 40%
allyl bromide
106-95-6

allyl bromide

p-methoxybenzylidene-phenylamine
836-41-9

p-methoxybenzylidene-phenylamine

A

1,5-Hexadien
592-42-7

1,5-Hexadien

B

N-(1-(4-methoxyphenyl)but-3-enyl)benzenamine

N-(1-(4-methoxyphenyl)but-3-enyl)benzenamine

Conditions
ConditionsYield
With tetrabutylammomium bromide; indium(III) chloride In tetrahydrofuran chemo-electrochemical allylation;A n/a
B 76%
(η5-t-C4H9C5H4)(η3-C3H5)2Cr

(η5-t-C4H9C5H4)(η3-C3H5)2Cr

acetylene
74-86-2

acetylene

A

(η5-t-C4H9C5H4)(η6-C6H6)Cr

(η5-t-C4H9C5H4)(η6-C6H6)Cr

B

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
In diethyl ether under Ar, react. of the Cr complex with acetylene saturated diethyl ether at -78°C, stirred and allowed to warm to 0°C over 7 h , held for 48 h; filtration, cooled to -78°C, crystn., elem. anal., the diene detn. by GC analysis;A 60%
B 75%
1 ,6-dibromohexane
629-03-8

1 ,6-dibromohexane

A

1-hexene
592-41-6

1-hexene

B

hexane
110-54-3

hexane

C

1,5-Hexadien
592-42-7

1,5-Hexadien

D

hexan-1-ol
111-27-3

hexan-1-ol

Conditions
ConditionsYield
With tetramethylammonium perchlorate In 2,2,2-trifluoroethanol; N,N-dimethyl-formamide Electrolysis;A 4%
B 75%
C 5%
D 18%
Pd(η1-C3H5)(η3-C3H5)(TCNE)

Pd(η1-C3H5)(η3-C3H5)(TCNE)

triphenylphosphine
603-35-0

triphenylphosphine

A

[(PPh3)2Pd*tetracyanoethylene]
17764-64-6

[(PPh3)2Pd*tetracyanoethylene]

B

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
In dichloromethane 0°C, then 8 h room temp.; progress of reaction studied by (1)H- and (31)P-NMR; recryst. from CH2Cl2 pentane, dried in vacuo, elem. anal.;A 71.9%
B n/a
Cp(η3-C3H5)2Cr

Cp(η3-C3H5)2Cr

A

((C5H5)CrI2)2

((C5H5)CrI2)2

B

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
With I2 In diethyl ether; pentane under Ar, suspension of the Cr complex in pentane at -78°C, addn. of I2 in diethylether, warming up to 0°C, stirring overnight, liberation of hexadiene, pptn. of the product Cr complex; elem. anal., GC detn. of product gas;A 71.3%
B 33%
(allylsulfonyl)benzene
16212-05-8

(allylsulfonyl)benzene

allylmagnesium iodide
18854-63-2

allylmagnesium iodide

1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
With triphenylphosphine; copper dichloride In tetrahydrofuran at 60℃;70%
1,5-Hexadien
592-42-7

1,5-Hexadien

triphenylmethylacetonitrile oxide
13412-55-0

triphenylmethylacetonitrile oxide

5-(3-Butenyl)-3-(triphenylmethyl)-2-isoxazoline
111379-53-4

5-(3-Butenyl)-3-(triphenylmethyl)-2-isoxazoline

Conditions
ConditionsYield
In benzene for 48h; Heating;100%
In benzene at 25℃; Yield given;
1,5-Hexadien
592-42-7

1,5-Hexadien

phenylsilane
694-53-1

phenylsilane

[(phenylsilyl)methyl]cyclopentane

[(phenylsilyl)methyl]cyclopentane

Conditions
ConditionsYield
With <(CH3)5>2YCH3*THF In cyclohexane for 1h; Mechanism; Ambient temperature; other dienes; other silanes;100%
With (C5Me5)2YCH3*THF In cyclohexane for 1h; Ambient temperature;100%
With <(CpTMS)2YMe>2 In cyclohexane for 4h; Ambient temperature;98%
1,5-Hexadien
592-42-7

1,5-Hexadien

9-bora-bicyclo[3.3.1]nonane
280-64-8

9-bora-bicyclo[3.3.1]nonane

9,9'-hexane-1,6-diyl-bis-9-bora-bicyclo[3.3.1]nonane
88703-69-9

9,9'-hexane-1,6-diyl-bis-9-bora-bicyclo[3.3.1]nonane

Conditions
ConditionsYield
In tetrahydrofuran at 40℃; for 24h; Schlenk technique; Inert atmosphere;100%
In tetrahydrofuran at 20℃; for 3h; Addition;
In tetrahydrofuran at 20℃; for 4.5h; Addition; Hydroboration;
In tetrahydrofuran at 20℃; for 3h;
1,5-Hexadien
592-42-7

1,5-Hexadien

5-chloro-6-(pentafluoro-λ6-sulfanyl)hex-1-ene
860438-41-1

5-chloro-6-(pentafluoro-λ6-sulfanyl)hex-1-ene

Conditions
ConditionsYield
With pentafluorosulfanyl chloride; triethyl borane In hexane at -30 - 20℃;100%
1,5-Hexadien
592-42-7

1,5-Hexadien

[Y(η5:η1-C5Me4SiMe2NCMe3)(THF)(μ-H)]2

[Y(η5:η1-C5Me4SiMe2NCMe3)(THF)(μ-H)]2

[Y(η5:η1-C5Me4SiMe2NCMe3)(CH2CH(CH2)4)(THF)]

[Y(η5:η1-C5Me4SiMe2NCMe3)(CH2CH(CH2)4)(THF)]

Conditions
ConditionsYield
In benzene-d6 reaction in NMR tube, at room temp., for 3 h; solvent was removed in vac.; NMR;100%
1,5-Hexadien
592-42-7

1,5-Hexadien

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; for 16h;99%
With 3-chloro-benzenecarboperoxoic acid at 10 - 20℃; for 19h;95.1%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane87%
1,5-Hexadien
592-42-7

1,5-Hexadien

3-methyl-cyclopentanone
1757-42-2, 6195-92-2

3-methyl-cyclopentanone

Conditions
ConditionsYield
With Pd(II)(15-crown-5-phen)Cl2; dinitrogen monoxide In N,N-dimethyl acetamide; water at 150℃; under 2250.23 Torr; for 18h;99%
1,5-Hexadien
592-42-7

1,5-Hexadien

p-methoxyphenylbutadiene
30448-78-3

p-methoxyphenylbutadiene

1,1'-[(2Z,10Z)-5,8-bis(methylene)dodeca-2,10-diene-1,12-diyl]bis(4-methoxybenzene)
1175163-69-5

1,1'-[(2Z,10Z)-5,8-bis(methylene)dodeca-2,10-diene-1,12-diyl]bis(4-methoxybenzene)

Conditions
ConditionsYield
With cobalt(II) bromide-[1,2-bis(diphenylphosphino)ethane]; zinc(II) iodide; zinc In dichloromethane at 20℃; Inert atmosphere;99%
1,5-Hexadien
592-42-7

1,5-Hexadien

(2E,4E)-hexa-2,4-diene
5194-51-4

(2E,4E)-hexa-2,4-diene

Conditions
ConditionsYield
With Polystyrene-supported 4-tert-butyl-2-(diisopropylphosphino)-1H-imidazole and ruthenium complex In [(2)H6]acetone at 70℃; for 7h; Reagent/catalyst; Inert atmosphere; Glovebox; stereoselective reaction;98%
With tris(η3-allyl)chromium In n-heptane at 59.9℃; Rate constant; Equilibrium constant;
1,5-Hexadien
592-42-7

1,5-Hexadien

(2R,5RS)-1,2,5,6-hexanetetrol

(2R,5RS)-1,2,5,6-hexanetetrol

Conditions
ConditionsYield
With potassium carbonate; potassium hexacyanoferrate(III); potassium osmate(VI); 1,4-bis(9-O-dihydroquinidine)phthalazine In water; tert-butyl alcohol at 0 - 6℃; for 29h; Sharpless dihydroxylation;98%
1,5-Hexadien
592-42-7

1,5-Hexadien

pyridazine-4,5-dicarbonitrile
17412-15-6

pyridazine-4,5-dicarbonitrile

8,9-dicyanotricyclo[4.3.1.03,7]dec-8-ene

8,9-dicyanotricyclo[4.3.1.03,7]dec-8-ene

Conditions
ConditionsYield
In chloroform at 110℃; Diels-Alder reaction;98%
2-tert-butylpyridine
5944-41-2

2-tert-butylpyridine

1,5-Hexadien
592-42-7

1,5-Hexadien

C15H23N

C15H23N

Conditions
ConditionsYield
With tris(pentafluorophenyl)borate; C42H51N3PSc In chlorobenzene at 100℃; for 5h; diastereoselective reaction;98%
1,5-Hexadien
592-42-7

1,5-Hexadien

Phenetole
103-73-1

Phenetole

C14H20O

C14H20O

Conditions
ConditionsYield
With C19H16*C24BF20; C23H40NScSi2 In chlorobenzene at 70℃; for 3h; stereoselective reaction;98%
1,5-Hexadien
592-42-7

1,5-Hexadien

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane
423-39-2

1-iodo-2,2,3,3,4,4,5,5,5-nonafluorobutane

1,1,1,2,2,3,3,4,4,11,11,12,12,13,13,14,14,14-octadecafluoro-6,9-diiodotetradecane
40735-23-7

1,1,1,2,2,3,3,4,4,11,11,12,12,13,13,14,14,14-octadecafluoro-6,9-diiodotetradecane

Conditions
ConditionsYield
With sodiumsulfide nonahydrate; dibenzoyl peroxide at 80℃; for 4h;97.1%
With 2,2'-azobis(isobutyronitrile)
1,5-Hexadien
592-42-7

1,5-Hexadien

2,5-diiodomethyltetrahydrofuran
134692-33-4

2,5-diiodomethyltetrahydrofuran

Conditions
ConditionsYield
With iodine; sodium hydrogencarbonate In tetrahydrofuran; diethyl ether; water at 20℃; for 4h;97%
With iodine; sodium hydrogencarbonate In tetrahydrofuran; water Inert atmosphere;
3,6-bis(trifluoromethyl)-1,2,4,5-tetrazine
16453-18-2

3,6-bis(trifluoromethyl)-1,2,4,5-tetrazine

1,5-Hexadien
592-42-7

1,5-Hexadien

4-(but-3'-enyl)-1,4-dihydro-3,6-bis(trifluoromethyl)-pyridazine

4-(but-3'-enyl)-1,4-dihydro-3,6-bis(trifluoromethyl)-pyridazine

Conditions
ConditionsYield
In dichloromethane Ambient temperature;97%
1,5-Hexadien
592-42-7

1,5-Hexadien

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

2,3,10,11-tetramethyl-5,8-dimethylene-2,10-dodecadiene

2,3,10,11-tetramethyl-5,8-dimethylene-2,10-dodecadiene

Conditions
ConditionsYield
With tetrabutylammonium borohydride; zinc(II) iodide; cobalt(II) bromide-[1,2-bis(diphenylphosphino)ethane] In dichloromethane at 25℃; for 16h;97%
With tetrabutylammonium borohydride; zinc(II) iodide; cobalt(II) bromide-[1,2-bis(diphenylphosphino)ethane] In dichloromethane at 20℃; for 20h;97%
With cobalt(II) bromide-[1,2-bis(diphenylphosphino)ethane]; zinc(II) iodide; zinc In dichloromethane for 20h;57%
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

chlorobis(cyclooctene)rhodium(I) dimer

chlorobis(cyclooctene)rhodium(I) dimer

1,5-Hexadien
592-42-7

1,5-Hexadien

[Rh(4,4'-dimethyl-2,2'-bipyridine)(hexadiene)]BF4
471254-42-9

[Rh(4,4'-dimethyl-2,2'-bipyridine)(hexadiene)]BF4

Conditions
ConditionsYield
In methanol; dichloromethane under N2, excess of diene was added to MeOH suspn. of Rh-complex, stirring at room temp. for 1.5 h, 2 equiv. of N-base was added in CH2Cl2, stirring at room temp. for 1 h, 2 equiv. of AgBF4 was added dropwise in CH2Cl2, stirring at room temp. for 1 h; soln. was filtered, concd., Et2O was added, solid was filtered off, washed with Et2O, dried in vac., elem. anal.;97%
silver(I) hexafluorophosphate
26042-63-7

silver(I) hexafluorophosphate

(2-methylallyl)palladium-chloride dimer

(2-methylallyl)palladium-chloride dimer

1,5-Hexadien
592-42-7

1,5-Hexadien

η(4)-hexa-1,5-diene(η(3)-2-methylallyl)palladium hexafluorophosphate

η(4)-hexa-1,5-diene(η(3)-2-methylallyl)palladium hexafluorophosphate

Conditions
ConditionsYield
In dichloromethane N2-atmosphere; elem. anal.;97%
4-chIoro-2-methylpyridine
3678-63-5

4-chIoro-2-methylpyridine

1,5-Hexadien
592-42-7

1,5-Hexadien

C12H16ClN

C12H16ClN

Conditions
ConditionsYield
With tris(pentafluorophenyl)borate; C42H51N3PSc In chlorobenzene at 100℃; for 12h; diastereoselective reaction;97%
1,5-Hexadien
592-42-7

1,5-Hexadien

1-(tert-butyl)-4-methoxybenzene
5396-38-3

1-(tert-butyl)-4-methoxybenzene

C17H26O

C17H26O

Conditions
ConditionsYield
With C19H16*C24BF20; C23H40NScSi2 In chlorobenzene at 70℃; for 1.5h; stereoselective reaction;97%
1,5-Hexadien
592-42-7

1,5-Hexadien

4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

C13H17ClO

C13H17ClO

Conditions
ConditionsYield
With C19H16*C24BF20; C23H40NScSi2 In chlorobenzene at 70℃; for 2h; stereoselective reaction;97%
3-methoxyphenyl bromide
2398-37-0

3-methoxyphenyl bromide

1,5-Hexadien
592-42-7

1,5-Hexadien

C13H17BrO

C13H17BrO

Conditions
ConditionsYield
With C19H16*C24BF20; C23H40NScSi2 In chlorobenzene at 70℃; for 6h; stereoselective reaction;97%
1,5-Hexadien
592-42-7

1,5-Hexadien

N-methyl-N-ethylaniline
613-97-8

N-methyl-N-ethylaniline

C15H23N

C15H23N

Conditions
ConditionsYield
With C19H16*C24BF20; C23H40NScSi2 In chlorobenzene at 50℃; for 2h; stereoselective reaction;97%
N-methyl-1,2,3,4-tetrahydroquinoline
491-34-9

N-methyl-1,2,3,4-tetrahydroquinoline

1,5-Hexadien
592-42-7

1,5-Hexadien

C16H23N

C16H23N

Conditions
ConditionsYield
With C19H16*C24BF20; C23H40NScSi2 In chlorobenzene at 50℃; for 23h; stereoselective reaction;97%
1,5-Hexadien
592-42-7

1,5-Hexadien

3-bromo-2-picoline
38749-79-0

3-bromo-2-picoline

C12H16BrN

C12H16BrN

Conditions
ConditionsYield
With C42H51N3PSc; trityl tetrakis(pentafluorophenyl)borate In chlorobenzene at 100℃; for 5h; diastereoselective reaction;96%
1,5-Hexadien
592-42-7

1,5-Hexadien

4-methoxylbiphenyl
613-37-6

4-methoxylbiphenyl

C19H22O

C19H22O

Conditions
ConditionsYield
With C19H16*C24BF20; C23H40NScSi2 In chlorobenzene at 70℃; for 1h; stereoselective reaction;96%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

1,5-Hexadien
592-42-7

1,5-Hexadien

C13H17BrO

C13H17BrO

Conditions
ConditionsYield
With C19H16*C24BF20; C23H40NScSi2 In chlorobenzene at 70℃; for 4h; stereoselective reaction;96%
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