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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

1-Methylcyclopentene

Cas:693-89-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:White or

1-Methyl-1-cyclopentene

Cas:693-89-0

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1-Methyl-1-cyclopentene

Cas:693-89-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

1-Methylcyclopentene with good quality and competitive price from Henan Tianfu Chemical: Henan Tianfu Chemical Co.,LTD was built in 2009 with an ISO certificate in the past 5 years, we have grown up as a famous fine chemicals supplier in china an

693-89-0

Cas:693-89-0

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Other

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 693-89-0 with competitive price

Cas:693-89-0

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

Big order best quality Methylcyclopentene 693-89-0 leading factory Application:Big order best quality Methylcyclopentene 693-89-0 leading factory

Hangzhou Fandachem Co.,Ltd

1-Methylcyclopentene cas 693-89-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1-Methylcyclopentene cas 693-89-0

Cas:693-89-0

Min.Order:0

Negotiable

Type:Other

inquiry

SAGECHEM LIMITED

693-89-0 Application:intermediate

Cyclopentene, 1-methyl-

Cas:693-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

Big order best quality Methylcyclopentene 693-89-0 leading factoryAppearance:Colorless liquid Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By exp

Big order best quality Methylcyclopentene 693-89-0 leading factory

Cas:693-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

1-Methylcyclopentene Basic information Product Name: 1-Methylcyclopentene

693-89-0 C6H10 1-Methylcyclopentene

Cas:693-89-0

Min.Order:100 Gram

Negotiable

Type:Trading Company

inquiry

suzhou BetterBioChem Co., Ltd.

Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

1-Methylcyclopentene

Cas:693-89-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Raymon Biotech Co., Ltd.

Quality: 1. Testing before each delivery, including Nuclear Magnetic Resonance(NMR), Gas Chromatography(GC)/High Performance Liquid Chromatography(HPLC), Mass detection(MS), Optical rotation for chiral products. There are many other methods avail

Methylcyclopentene

Cas:693-89-0

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

1-Methylcyclopentene

Cas:693-89-0

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Henan Fine Chemicals Co., Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & CommercialHenan Fine Chemicals Co., LTD. is a diversified technology - oriented integrated company, which mainly concentrates on fine chemicals. Our company is committed to becom

Cyclopentene, 1-methyl-

Cas:693-89-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

AOPHARM

Aopharm is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in modes of tran

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

changchun tuocai technology co.,ltld

Big order best quality Methylcyclopentene 693-89-0 leading factoryAppearance:Colorless liquid Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea

Big order best quality Methylcyclopentene 693-89-0 leading factory

Cas:693-89-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Minshang Biotechnology Co., Ltd

Big order best quality Methylcyclopentene 693-89-0 leading factory Application:Chemical research/pharma intermediate

693-89-0

Cas:693-89-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Skyrun Industrial Co.,Ltd

Adequate stocks available,prompt shipment,Strictly control on quality,Timely after-sales Application:Intermediate

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Yanchu chemicals Co., Ltd

good quality Application:Intermediate

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Yierdechem Co. Ltd

With about ten years experiences in the field of pharmaceutical chemicals, Yierdechem has established solid business cooperation relationships with many large companys worldwide.As a leading supplier of API and pharmaceutical intermediates, holds its

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Other

inquiry

Reliable Pharma Technology (Shanghai) Co., Ltd.

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fenjun Chemical Co Ltd.

Big order best quality Methylcyclopentene 693-89-0 leading factory Application:Big order best quality Methylcyclopentene 693-89-0 leading factory

Big order best quality Methylcyclopentene 693-89-0 leading factory

Cas:693-89-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

KindChem Co.,Ltd,

1-Methylcyclopentene

Cas:693-89-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methylenecyclopentane
1528-30-9

methylenecyclopentane

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
In liquid sulphur dioxide Ambient temperature;99%
With bromine chloride67 % Spectr.
With (allylsulfonyl)benzene In Cyclohexane-d12; toluene at 130℃; for 36.5h; Product distribution; Further Variations:; Reagents; Solvents; Temperatures;95 % Spectr.
With diphenyl disulfone In chloroform-d1 at 80℃; for 1h; Kinetics;
methyllithium
917-54-4

methyllithium

cyclopentanone
120-92-3

cyclopentanone

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
Stage #1: methyllithium; cyclopentanone at -10 - 0℃; for 0.5h;
Stage #2: With toluene-4-sulfonic acid In 1,2-dichloro-ethane Reflux;
96%
With acid
1-methylcyclopentanol
1462-03-9

1-methylcyclopentanol

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
95%
With iodine; oxalic acid87%
With iodine Erhitzen des erhaltenen Gemisches von 1-Methyl-cyclopenten und Methylencyclopentan mit Essigsaeure und wenig Toluol-4-sulfonsaeure;
methyl magnesium iodide
917-64-6

methyl magnesium iodide

cyclopentanone
120-92-3

cyclopentanone

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
Stage #1: methyl magnesium iodide; cyclopentanone In diethyl ether for 1h; Heating;
Stage #2: With iodine In toluene for 3h; Heating;
94%
In diethyl ether for 3h; Ambient temperature;34.8%
2) dehydration; Yield given. Multistep reaction;
methylmagnesium bromide
75-16-1

methylmagnesium bromide

cyclopentanone
120-92-3

cyclopentanone

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
In diethyl ether for 1h;87%
(hex-5-enyl)magnesium bromide
30043-41-5

(hex-5-enyl)magnesium bromide

A

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

B

Bis(η5-cyclopentadienyl)(η3-hexenyl)titan, 16percent

Bis(η5-cyclopentadienyl)(η3-hexenyl)titan, 16percent

Conditions
ConditionsYield
With isopropylmagnesium bromide; bis(cyclopentadienyl)titanium dichloride In diethyl ether at 36℃; for 5h;A 66%
B n/a
Dimethyl ether
115-10-6

Dimethyl ether

cyclopentene
142-29-0

cyclopentene

A

butene isomers; C7 isomers (dimethylcyclopentenes); C6 isomers (methylcyclopentenes); pentene isomers; mixture of

butene isomers; C7 isomers (dimethylcyclopentenes); C6 isomers (methylcyclopentenes); pentene isomers; mixture of

B

propene
187737-37-7

propene

C

ethene
74-85-1

ethene

D

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

E

benzene
71-43-2

benzene

Conditions
ConditionsYield
MFI280 zeolite at 400℃; under 750.075 Torr; for 20h; Product distribution / selectivity; Gas phase;A 59.5%
B 22.9%
C 6%
D 9.5%
E 2.1%
MTT47 zeolite at 400℃; under 750.075 Torr; for 20h; Product distribution / selectivity; Gas phase;A 52.2%
B 6.7%
C 1.4%
D 39.3%
E 0.4%
cyclohexene
110-83-8

cyclohexene

A

hexane
110-54-3

hexane

B

methyl-cyclopentane
96-37-7

methyl-cyclopentane

C

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
ultrastabilized Y zeolite at 350℃; for 0.0333333h;A 5.6%
B 57.7%
C 8.3%
1,5-Hexadien
592-42-7

1,5-Hexadien

A

(E,Z)-2,4-hexadiene
5194-50-3

(E,Z)-2,4-hexadiene

B

(E)-1,4-hexadiene
7319-00-8

(E)-1,4-hexadiene

C

methylenecyclopentane
1528-30-9

methylenecyclopentane

D

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

E

Bis(η5-cyclopentadienyl)(η3-hexenyl)titan, 76 percent

Bis(η5-cyclopentadienyl)(η3-hexenyl)titan, 76 percent

Conditions
ConditionsYield
With isopropylmagnesium bromide; bis(cyclopentadienyl)titanium dichloride In diethyl ether at 20℃; for 3h; Further byproducts given. Yields of byproduct given;A n/a
B n/a
C n/a
D 57%
E n/a
cyclohexene
110-83-8

cyclohexene

A

methylenecyclopentane
1528-30-9

methylenecyclopentane

B

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

C

3-methyl-1-cyclopentene
1120-62-3

3-methyl-1-cyclopentene

Conditions
ConditionsYield
ultrastabilized Y zeolite at 450℃; for 1h;A 1.7%
B 54.4%
C 9.9%
cyclohexene
110-83-8

cyclohexene

A

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

B

4-methylcyclopentene
1759-81-5

4-methylcyclopentene

C

3-methyl-1-cyclopentene
1120-62-3

3-methyl-1-cyclopentene

Conditions
ConditionsYield
ultrastabilized Y zeolite at 450℃; for 1h;A 54.4%
B 4.9%
C 9.9%
aluminum hydroxide contg. TiO2 and Na2O at 350℃; Kinetics;
With hydrogenchloride; water In decalin at 225℃; for 49h; Product distribution; Mechanism; in sealed tube; also with DCl/D2O, deuteration investigated; also at 175 deg C;A 45.2 % Chromat.
B n/a
C n/a
cyclohexene
110-83-8

cyclohexene

A

hexane
110-54-3

hexane

B

methylenecyclopentane
1528-30-9

methylenecyclopentane

C

methyl-cyclopentane
96-37-7

methyl-cyclopentane

D

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

E

4-methylcyclopentene
1759-81-5

4-methylcyclopentene

F

3-methyl-1-cyclopentene
1120-62-3

3-methyl-1-cyclopentene

Conditions
ConditionsYield
ultrastabilized pprotonic Y zeolite In gas at 350℃; for 1h; Product distribution; Kinetics; other temperatures, other products;A 0.5%
B 1.4%
C 1%
D 19.6%
E 1.8%
F 3.6%
D-sorbitol
50-70-4

D-sorbitol

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
With formaldehyd; ruthenium (III) bromide; hydrogen bromide; hydrogen; tetrabutyl phosphonium bromide In water at 200℃; under 30003 Torr; for 8h;13%
D-sorbitol
50-70-4

D-sorbitol

A

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

B

hexanoic acid
142-62-1

hexanoic acid

Conditions
ConditionsYield
With formaldehyd; ruthenium (III) bromide; hydrogen bromide; hydrogen; tetrabutyl phosphonium bromide In water at 200℃; under 30003 Torr; for 8h;A 12%
B 7%
quinoline
91-22-5

quinoline

1-bromo-1-methyl-cyclopentane
19872-99-2

1-bromo-1-methyl-cyclopentane

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
at 190 - 200℃;
methyl magnesium iodide
917-64-6

methyl magnesium iodide

1-chloro-1-methylcyclopentane
6196-85-6

1-chloro-1-methylcyclopentane

A

1,1-Dimethylcyclopentane
1638-26-2

1,1-Dimethylcyclopentane

B

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

1-bromo-1-methyl-cyclopentane
19872-99-2

1-bromo-1-methyl-cyclopentane

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
With quinoline at 190 - 200℃;
With 1,3,5-triphenylverdasyl at 25℃; Rate constant; other solvents;
In ethanol at 25℃; Kinetics; Further Variations:; Solvents;
1-chloro-1-methylcyclopentane
6196-85-6

1-chloro-1-methylcyclopentane

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
With water at 35℃;
With quinoline at 160 - 190℃;
With sodium hydroxide In water at 20℃; for 2h; Dehydrochlorination; elimination;
With 1,3,5-triphenylverdazyl In acetonitrile at 25℃; Kinetics; Further Variations:; Solvents; Temperatures;
With 1,3,5-triphenylverdazyl In methanol at 25℃; Kinetics; Further Variations:; Solvents;
1-chloro-1-methylcyclopentane
6196-85-6

1-chloro-1-methylcyclopentane

A

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

B

1-methylcyclopentanol
1462-03-9

1-methylcyclopentanol

Conditions
ConditionsYield
With water In ethanol at 30℃; Rate constant; solvolysis reaction;
With calcium hydroxide; water at 35℃;
1-methylcyclopentyl acetate
26600-59-9

1-methylcyclopentyl acetate

A

methylenecyclopentane
1528-30-9

methylenecyclopentane

B

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
at 450℃;
1-methylcyclopentyl acetate
26600-59-9

1-methylcyclopentyl acetate

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
at 450℃;
3-methylcyclopentanol
18729-48-1

3-methylcyclopentanol

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
With sulfuric acid
1-chloro-2-methyl-cyclopentane
53501-51-2

1-chloro-2-methyl-cyclopentane

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
With quinoline at 160 - 190℃;
cyclopentylmethyl acetate
26600-49-7

cyclopentylmethyl acetate

A

methylenecyclopentane
1528-30-9

methylenecyclopentane

B

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
at 450 - 570℃;
1-methyl-cyclopentanecarboxylic acid phenyl ester
859181-91-2

1-methyl-cyclopentanecarboxylic acid phenyl ester

A

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
at 390℃; im Rohr;
1-methylcyclopentanol
1462-03-9

1-methylcyclopentanol

oxalic acid
144-62-7

oxalic acid

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
at 90 - 120℃;
cyclobutylmethylcarbinol
7515-29-9

cyclobutylmethylcarbinol

oxalic acid
144-62-7

oxalic acid

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
Erhitzen des Reaktionsprodukts mit Chinolin auf 190-200grad;
1-methylcyclopentanol
1462-03-9

1-methylcyclopentanol

toluene-4-sulfonic acid
104-15-4

toluene-4-sulfonic acid

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

methyl cyclohexane
82166-21-0

methyl cyclohexane

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
With chromium (III)-oxide-aluminium oxide contacts at 550℃;
cyclohexene
110-83-8

cyclohexene

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Conditions
ConditionsYield
at 200 - 300℃; Leiten ueber zuvor mit Phosphorsaeure behandeltes Kieselgur;
at 400 - 500℃; Leiten ueber γ-Aluminiumoxyd;
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

propionaldehyde
123-38-6

propionaldehyde

(methyl-2' cyclopentyl)-1 propanone-1
81977-75-5

(methyl-2' cyclopentyl)-1 propanone-1

Conditions
ConditionsYield
With dibenzoyl peroxide at 90℃; for 10h;100%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

1,2-epoxy-1-methylcyclopentane
16240-42-9

1,2-epoxy-1-methylcyclopentane

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 5 - 20℃; Inert atmosphere;99%
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 24℃; for 4h;84%
With gallium oxide; dihydrogen peroxide; acetonitrile at 89.84℃; for 4h; Sealed tube;53%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

trifluoromethylpyruvate

trifluoromethylpyruvate

(R)-methyl 2-(cyclopentenylmethyl)-3,3,3-trifluoro-2-hydroxypropanoate
1198746-23-4

(R)-methyl 2-(cyclopentenylmethyl)-3,3,3-trifluoro-2-hydroxypropanoate

Conditions
ConditionsYield
With 2,6-bis[(3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine; indium(III) chloride; silver hexafluoroantimonate In 1,2-dichloro-ethane at 20℃; Ionic liquid; Molecular sieve; optical yield given as %ee; enantioselective reaction;98%
glyoxylic acid ethyl ester
924-44-7

glyoxylic acid ethyl ester

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

ethyl (R)-3-(cyclopent-1-en-1-yl)-2-hydroxypropanoate
208242-85-7

ethyl (R)-3-(cyclopent-1-en-1-yl)-2-hydroxypropanoate

Conditions
ConditionsYield
With 2,6-bis[(3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl]pyridine; silver hexafluoroantimonate; indium(III) chloride In 1,2-dichloro-ethane at 20℃; for 16h; Molecular sieve; Inert atmosphere; stereoselective reaction;98%
1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

((2-methylcyclopent-1-enyl)methylene)dibenzene
1352552-71-6

((2-methylcyclopent-1-enyl)methylene)dibenzene

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In ethylene dibromide at 60℃; Air atmosphere; regioselective reaction;96%
With N-octadecyl-N-(4-sulfobutyl)pyrrolidinium trifluoromethanesulfonate In dichloromethane at 80℃; for 6h;92%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

2-Iodo-2-cyanopent-4-ynenitrile
130575-06-3

2-Iodo-2-cyanopent-4-ynenitrile

trans-Propargyl-(2-iodo-2-methylcyclopentyl)-malononitrile
141517-23-9

trans-Propargyl-(2-iodo-2-methylcyclopentyl)-malononitrile

Conditions
ConditionsYield
In benzene at 80℃; for 24h;95%
methylthiol
74-93-1

methylthiol

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

diborane
19287-45-7

diborane

bis(trans-2-methylcyclopentyl)(methylthio)borane

bis(trans-2-methylcyclopentyl)(methylthio)borane

Conditions
ConditionsYield
With air In tetrahydrofuran byproducts: methylcyclopentane; N2-atmosphere; treatment of B2H6 with olefin, addn. of MeSH (stirring), injecting small amt. of air (in two steps during 2 h), stirring for 12 h; evapn. of volatiles (reduced pressure), fractional distn. (reduced pressure);95%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

Benzylidenemalononitrile
2700-22-3

Benzylidenemalononitrile

C16H16N2

C16H16N2

Conditions
ConditionsYield
With 9-(2-mesityl)-10-methylacridinium perchlorate In 1,2-dichloro-ethane at 20℃; Irradiation; Green chemistry; regioselective reaction;94%
carbon monoxide
201230-82-2

carbon monoxide

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

trans-2-Methylcyclopentanecarbaldehyde
20106-44-9

trans-2-Methylcyclopentanecarbaldehyde

Conditions
ConditionsYield
With dicarbonylacetylacetonato rhodium (I); C37H50NO4P; hydrogen In toluene at 100℃; under 15001.5 Torr; for 12h; Autoclave; regioselective reaction;92%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

1,3-Dimethoxybenzene
151-10-0

1,3-Dimethoxybenzene

2,4-dimethoxy-1-(1-methylcyclopentyl)benzene
1258741-73-9

2,4-dimethoxy-1-(1-methylcyclopentyl)benzene

Conditions
ConditionsYield
With calcium(II) bis(trifluoromethanesulfonyl)imide; tert-butylammonium hexafluorophosphate(V) In dichloromethane at 20℃; for 1h;91%
trichloro-acetyl bromide
34069-94-8

trichloro-acetyl bromide

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

7,7-dichloro-1-methylbicyclo[3.2.0]heptan-6-one
51284-43-6

7,7-dichloro-1-methylbicyclo[3.2.0]heptan-6-one

Conditions
ConditionsYield
With zinc In diethyl ether Heating;90%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

5-cyano-1H-pyrazole-4-carboxylic acid, ethyl ester
119741-57-0

5-cyano-1H-pyrazole-4-carboxylic acid, ethyl ester

5-cyano-1-(1-methylcyclopentyl)-1H-pyrazole-4-carboxylic acid, ethyl ester
119741-58-1

5-cyano-1-(1-methylcyclopentyl)-1H-pyrazole-4-carboxylic acid, ethyl ester

Conditions
ConditionsYield
With sulfuric acid In dichloromethane; acetonitrile for 2h; Ambient temperature;90%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

trichloroacetonitrile
545-06-2

trichloroacetonitrile

2,2,2-Trichloro-1-(2-methyl-cyclopent-2-enyl)-ethanone
97963-20-7

2,2,2-Trichloro-1-(2-methyl-cyclopent-2-enyl)-ethanone

Conditions
ConditionsYield
With boron trifluoride; water In dichloromethane at -78℃;90%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

[Chloro-(3,4-dichloro-phenylsulfanyl)-methyl]-trimethyl-silane
114124-63-9

[Chloro-(3,4-dichloro-phenylsulfanyl)-methyl]-trimethyl-silane

1,2-Dichloro-4-[2-methyl-cyclopent-(E)-ylidenemethylsulfanyl]-benzene

1,2-Dichloro-4-[2-methyl-cyclopent-(E)-ylidenemethylsulfanyl]-benzene

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane at -20℃; for 0.5h;90%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

(1S,2S)-trans-2-methylcyclopentanol
39947-48-3

(1S,2S)-trans-2-methylcyclopentanol

Conditions
ConditionsYield
With (R,R)-C6H12BH2(1-)*Li(1+)*OEt2; methyl iodide In diethyl ether for 9.5h; Ambient temperature;89%
potassium iodomethyltrifluoroborate

potassium iodomethyltrifluoroborate

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

1-methylbicyclo[3.1.0]hexane

1-methylbicyclo[3.1.0]hexane

Conditions
ConditionsYield
With dichlorobis(tri-O-tolylphosphine)palladium; potassium carbonate In N,N-dimethyl acetamide; ethylene glycol at 75℃; for 22h; Schlenk technique; Inert atmosphere; Sealed tube;88%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

5-oxohexanal
505-03-3

5-oxohexanal

Conditions
ConditionsYield
Stage #1: 1-methylcyclopent-1-ene With ozone In dichloromethane at -78℃;
Stage #2: With triphenylphosphine In dichloromethane at -78 - 20℃; for 10h;
87%
Stage #1: 1-methylcyclopent-1-ene With ozone In dichloromethane at -78 - 20℃;
Stage #2: With dimethylsulfide In dichloromethane at 20℃; for 5h;
Stage #3: With triphenylphosphine In dichloromethane at 20℃; for 5h; Further stages.;
87%
Stage #1: 1-methylcyclopent-1-ene With osmium(VIII) oxide; 4-methylmorpholine N-oxide; tert-butyl alcohol In acetone at 20℃; for 4h;
Stage #2: With sodium periodate In water at 20℃; for 1h;
85%
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

phenol
108-95-2

phenol

4-(1-methylcyclopentan-1-yl)phenol
1562-25-0

4-(1-methylcyclopentan-1-yl)phenol

Conditions
ConditionsYield
With zeolite-P at 80℃; for 3h;86.4%
cationite KU-23 at 80℃; for 5h; Product distribution; other alkyl- and alkenylcyclenes; var. temp. and time;
cationite KU-23 at 80℃; for 5h;
diiodomethane
75-11-6

diiodomethane

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

1-methylbicyclo[3.1.0]hexane
4625-24-5

1-methylbicyclo[3.1.0]hexane

Conditions
ConditionsYield
With diethylzinc In cyclohexane for 120h; Ambient temperature;86%
With iodine; copper; zinc In diethyl ether
methanol
67-56-1

methanol

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

1,1-dimethoxy-5-oxo-hexane
36727-63-6

1,1-dimethoxy-5-oxo-hexane

Conditions
ConditionsYield
With Lindlar's catalyst; ozone-containing oxygen; ammonium chloride; sodium methylate 1) -75 Deg C, 2) room temperature, 3) 48 h.;86%
With dimethylsulfide; ozone 1.) methylene chloride, -78 deg C, 2.) room temperature, 3 h; Multistep reaction;
1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

4-nitrosonitrobenzene
4485-08-9

4-nitrosonitrobenzene

A

N-[2-methyl-2-cyclopentenyl]-N-4-nitrophenyl hydroxylamine

N-[2-methyl-2-cyclopentenyl]-N-4-nitrophenyl hydroxylamine

B

N-[2-methenylcyclopentyl]-N-4-nitrophenyl hydroxylamine

N-[2-methenylcyclopentyl]-N-4-nitrophenyl hydroxylamine

Conditions
ConditionsYield
In dichloromethane at 0℃; for 24h; Title compound not separated from byproducts.;A 85%
B 15%
{IrH2(acetone)2(PPh3)2}SbF6
110077-68-4, 89509-77-3

{IrH2(acetone)2(PPh3)2}SbF6

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

hydrido(η-methylcyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate
106864-47-5

hydrido(η-methylcyclopentadienyl)bis(triphenylphosphine)iridium(III) hexafluoroantimonate

Conditions
ConditionsYield
In 1,2-dichloro-benzene refluxed for 6 h under inert atmosphere; cooled, evapd., residue recrystd. from CH2Cl2-Et2O;85%
bis[bis(pentamethylcyclopentadienyl)(μ-hydride)yttrium]

bis[bis(pentamethylcyclopentadienyl)(μ-hydride)yttrium]

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

(C5(CH3)5)Y(η(3)-C5H6CH3)
500569-41-5

(C5(CH3)5)Y(η(3)-C5H6CH3)

Conditions
ConditionsYield
In further solvent(s) under inert atm. using Schlenk techniques; 1-methylcyclopentene added to((C5Me5)YH)2 dissolved in C6D11CD3 at -196°C; mixt. warmed to 0. degree.C; monitored by NMR (about 4 h);85%
isocyanate de chlorosulfonyle
1189-71-5

isocyanate de chlorosulfonyle

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

cis-5-methyl-6-azabicyclo[3.2.0]heptan-7-one

cis-5-methyl-6-azabicyclo[3.2.0]heptan-7-one

Conditions
ConditionsYield
In diethyl ether for 8h; Cycloaddition; Heating;84.7%
methanol
67-56-1

methanol

1-methylcyclopent-1-ene
693-89-0

1-methylcyclopent-1-ene

A

7-Methoxy-7-methyl-1,2-dioxepan-3-ol
159335-79-2

7-Methoxy-7-methyl-1,2-dioxepan-3-ol

B

cis/trans-7-methoxy-3-methyl-1,2-dioxepane-3-ol

cis/trans-7-methoxy-3-methyl-1,2-dioxepane-3-ol

C

1-hydroperoxy-1-methoxy-5-oxo-hexane
116972-39-5

1-hydroperoxy-1-methoxy-5-oxo-hexane

Conditions
ConditionsYield
With ozone at -78℃; Yields of byproduct given;A 84%
B n/a
C n/a
With ozone at -78℃; Yield given. Title compound not separated from byproducts;A 84%
B n/a
C n/a

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