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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

High purity Trichloroacetonitrile 98% TOP1 supplier in China

Cas:545-06-2

Min.Order:100 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hefei TNJ chemical industry co.,ltd

CAS No.: 545-06-2 Other Names: Cyanotrichloromethane MF: C2Cl3N EINECS No.: 208-885-7 Place of Origin: China (Mainland) Type: Agrochemical Intermediates Purity: 98% Brand Name: TNJ Application: Agrochemical Interm

545-06-2 TRICHLOROACETONITRILE

Cas:545-06-2

Min.Order:18 Metric Ton

Negotiable

Type:Trading Company

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

Trichloroacetonitrile

Cas:545-06-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Trichloroacetonitrile

Cas:545-06-2

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Trichloroacetonitrile

Cas:545-06-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: Trichloroacetonitrile Synonyms: trichloromethylcarbonitrile;Trichlroacetonitrile;TRICHLOROACETONITRILE, 1000MG, NEAT;Trichloroacetonitrile,97%;TRICHLORACETONITRILE;2,2,2-Trichloroacetonitrile;Trichlorocyanomethane;Trichloroacetonitri

545-06-2 Trichloroacetonitrile

Cas:545-06-2

Min.Order:1 Kilogram

FOB Price: $230.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Trichloroacetonitrile

Cas:545-06-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Trichloroacetonitrile

Cas:545-06-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Trichloroacetonitrile/High quality/Best price

Cas:545-06-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Siwei Development Group Ltd.

Product name: Trichloroacetonitrile CAS No.:545-06-2 Molecule Formula:C2Cl3N Molecule Weight:144.39 Purity: 98.0% Package: 200kg/drum Description:Colorless transparent liquid Manufacture Standards:Enterprise Standard

Best Quality Trichloroacetonitrile

Cas:545-06-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

TrichloroacetonitrileCAS NO.: 545-06-2

Cas:545-06-2

Min.Order:1 Gram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Sealed in a cool ,dry and microtherm place , avoid light . Package: 1kg/drum or 25kg/drum or as per your request. Application: pesticide Transportation:By

Trichloroacetonitrile

Cas:545-06-2

Min.Order:100 Gram

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Trichloroacetonitrile

Cas:545-06-2

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Trichloroacetonitrile

Cas:545-06-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Trichloroacetonitrile

Cas:545-06-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city?in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new api,?intermediat

Trichloroacetonitrile

Cas:545-06-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 545-06-2 with competitive price

Cas:545-06-2

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Trichloroacetonitrile

Cas:545-06-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Luyunjia Chemistry Xiamen Limited

Xiamen Luyunjia Trading Co.,Ltd Package:1kg/bag; 5156kg/drum, or as customer's request. Application:Xiamen Luyunjia Trading Co.,Ltd Transportation:DHL, EMS, FedEx, TNT, AIR, SEA Port:Beijing,Shanghai,Guangzhou ,China main port

TRICHLOROACETONITRILE

Cas:545-06-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

Trichloroacetonitrile manufacture

Cas:545-06-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

Trichloroacetonitrile

Cas:545-06-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Beantown Chemical

in stock Application:545-06-2

Trichloroacetonitrile, 98%

Cas:545-06-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HWRK Chem

in storeAppearance:Colorless - very pale yellow transparent liquid Package:100g Application:Organic Chemicals

Trichloroacetonitrile

Cas:545-06-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Trichloroacetonitrile Basic information Product Name: Trichloroacetonitrile Synonyms: TRIBROMOACETONITRILE;TRICHLOROACETONITRILE;trichloromethyl cyanide;acetonitril

545-06-2 C2Cl3N Trichloroacetonitrile

Cas:545-06-2

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Shanghai AngewChem Co., Ltd.

Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale production. Com

Trichloro acetonitrile

Cas:545-06-2

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Trichloroacetonitrile

Cas:545-06-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

suzhou BetterBioChem Co., Ltd.

Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

Trichloroacetonitrile

Cas:545-06-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Ruishun Trade Co.,Ltd

Profile Hebei Ruishun Trade Co.LTD, registered capital of $1 million ,have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center,Seek development by credit reputation. Our products have a large

Trichloroacetonitrile

Cas:545-06-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Xiamen BaiFuchem Co.,Ltd

BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

High Purity Trichloroacetonitrile

Cas:545-06-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Jiangsu Eubo Biological Technology Co., Ltd

1) Provide costomers with "one-stop"packaging service,from research,development,production,export and so on. 2) We have our own R&D and production base,equipped with advanced production equipment and precision testing the Unitef Stat

Organic Reagent Trichloroacetonitrile CAS 545-06-2

Cas:545-06-2

Min.Order:1 Gram

FOB Price: $150.0 / 200.0

Type:Trading Company

inquiry

Synthetic route

N-{2-[2,2,2-Trichloro-eth-(E)-ylidene-hydrazinocarbonyl]-phenyl}-benzamide
76716-10-4

N-{2-[2,2,2-Trichloro-eth-(E)-ylidene-hydrazinocarbonyl]-phenyl}-benzamide

A

2-phenyl-4(3H)-quinazolinone
1022-45-3

2-phenyl-4(3H)-quinazolinone

B

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
at 200 - 240℃; under 1 Torr;A n/a
B 64%
trichloroacetamide
594-65-0

trichloroacetamide

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
With trichlorophosphate
With phosphorus pentaoxide
With phosphorus pentaoxide
trichloroacetyl-triphenoxyphosphoranyliden-amine
94578-40-2

trichloroacetyl-triphenoxyphosphoranyliden-amine

A

phosphoric acid triphenyl ester
115-86-6

phosphoric acid triphenyl ester

B

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
at 300℃;
2,2,2-trichloro-acetimidic acid phenyl ester
409110-43-6

2,2,2-trichloro-acetimidic acid phenyl ester

A

trichloroacetonitrile
545-06-2

trichloroacetonitrile

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
at 180℃;
(2,2,2-trichloro-1-phenoxy-ethyliden)-amidophosphoric acid diphenyl ester
111499-29-7

(2,2,2-trichloro-1-phenoxy-ethyliden)-amidophosphoric acid diphenyl ester

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
at 250 - 300℃;
chloroacetonitrile
107-14-2

chloroacetonitrile

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
With chlorine at 60℃;
With hydrogenchloride; chlorine
acetonitrile
75-05-8

acetonitrile

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
With sulfuryl dichloride; platinum at 200 - 500℃;
With chlorine; platinum at 200 - 500℃;
With hydrogenchloride; chlorine
<2,2,2-trichloro-1-<(pentachloroethyl)imino>ethyl>phosphorimidic trichloride
74067-78-0

<2,2,2-trichloro-1-<(pentachloroethyl)imino>ethyl>phosphorimidic trichloride

A

trichloroacetamide
594-65-0

trichloroacetamide

B

trichloroacetonitrile
545-06-2

trichloroacetonitrile

C

trichloroacetic acid
76-03-9

trichloroacetic acid

Conditions
ConditionsYield
With water for 0.25h; Heating;
acetonitrile
75-05-8

acetonitrile

A

chloroacetonitrile
107-14-2

chloroacetonitrile

B

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
With chlorine; iron(III) chloride at 24.9℃; for 168h; Product distribution; also in the presence of 2, various conc.;
acetonitrile
75-05-8

acetonitrile

A

dichloroacetonitrile
3018-12-0

dichloroacetonitrile

B

chloroacetonitrile
107-14-2

chloroacetonitrile

C

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
With chlorine at 22.9℃; under 700 Torr; Irradiation; Yield given. Title compound not separated from byproducts;
With chlorine at 22.9℃; under 700 Torr; Kinetics; Irradiation; different reaction temperature and pressure;
chlorine
7782-50-5

chlorine

acetonitrile
75-05-8

acetonitrile

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
at 60℃; Irradiation;
acetonitrile
75-05-8

acetonitrile

A

trichloroacetonitrile
545-06-2

trichloroacetonitrile

B

trimer(ic) and tetramer(ic) trichloroacetonitrile

trimer(ic) and tetramer(ic) trichloroacetonitrile

Conditions
ConditionsYield
With chlorine; pyrographite at 300℃;
trichloroacetamide
594-65-0

trichloroacetamide

phosphoric acid anhydride

phosphoric acid anhydride

trichloroacetonitrile
545-06-2

trichloroacetonitrile

trichloroacetamide
594-65-0

trichloroacetamide

POCl3 (0.5 mol)

POCl3 (0.5 mol)

trichloroacetonitrile
545-06-2

trichloroacetonitrile

dichloroacetonitrile
3018-12-0

dichloroacetonitrile

NOCl

NOCl

A

dichloroacethyl chloride
79-36-7

dichloroacethyl chloride

B

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
at 200℃;
trichlorophosphazotrichlorooxoethane
14335-48-9

trichlorophosphazotrichlorooxoethane

A

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
at 260℃;
tetrachloroethyliden-amidophosphoryl chloride
28460-70-0

tetrachloroethyliden-amidophosphoryl chloride

A

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
at 220℃;
(1S)-1-[3,5-bis(trifluoromethyl)phenyl]ethyl-2,2,2-trichloroethanimidoate
849674-12-0

(1S)-1-[3,5-bis(trifluoromethyl)phenyl]ethyl-2,2,2-trichloroethanimidoate

C20H31FO7S2
920025-44-1

C20H31FO7S2

A

C30H37F7O7S2
920025-45-2

C30H37F7O7S2

B

C30H37F7O7S2
920025-46-3

C30H37F7O7S2

C

trichloroacetonitrile
545-06-2

trichloroacetonitrile

Conditions
ConditionsYield
Stage #1: (1S)-1-[3,5-bis(trifluoromethyl)phenyl]ethyl-2,2,2-trichloroethanimidoate; C20H31FO7S2 With tetrafluorohydroboric acid In dichloromethane; cyclohexane at -17 - 20℃; for 23.6667h;
Stage #2: With sodium hydroxide In dichloromethane; cyclohexane; water at 18 - 20℃; for 0.25h;
2-phenylethanol
60-12-8

2-phenylethanol

trichloroacetonitrile
545-06-2

trichloroacetonitrile

β-phenylethyl trichloroacetimidate
99421-73-5

β-phenylethyl trichloroacetimidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane100%
With sodium
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 20℃;
trichloroacetonitrile
545-06-2

trichloroacetonitrile

benzyl alcohol
100-51-6

benzyl alcohol

O-benzyl 2,2,2-trichloroacetimidate
81927-55-1

O-benzyl 2,2,2-trichloroacetimidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In n-heptane at 0℃; for 0.25h; Solvent;100%
With tetra(n-butyl)ammonium hydrogensulfate; potassium hydroxide In dichloromethane; water at -15 - 20℃; for 1.5h;99%
With potassium hydroxide; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane at -15 - 25℃; for 1h;97%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

trichloroacetamide
594-65-0

trichloroacetamide

Conditions
ConditionsYield
With sulfuric acid In nitrobenzene; chlorobenzene at 60℃; Rate constant; Thermodynamic data; Mechanism; various temperatures, ΔG (excit.), ΔH (excit.), ΔS (excit.);100%
With sulfuric acid at 25℃;100%
With C19H23Cl2N6PRuS3*3ClH; water at 100℃; for 1h; Inert atmosphere; Schlenk technique;86%
3,4-dihydro-isoquinoline 2-oxide
24423-87-8

3,4-dihydro-isoquinoline 2-oxide

trichloroacetonitrile
545-06-2

trichloroacetonitrile

2-Trichloromethyl-5,9b-dihydro-4H-3-oxa-1,3a-diaza-cyclopenta[a]naphthalene
121994-35-2

2-Trichloromethyl-5,9b-dihydro-4H-3-oxa-1,3a-diaza-cyclopenta[a]naphthalene

Conditions
ConditionsYield
In toluene at 100℃; for 0.0333333h;100%
2,3,4-tri-O-benzyl-6-deoxy-α-L-galactopyranose
33639-75-7

2,3,4-tri-O-benzyl-6-deoxy-α-L-galactopyranose

trichloroacetonitrile
545-06-2

trichloroacetonitrile

O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)trichloroacetimidate
120703-59-5

O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)trichloroacetimidate

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃; for 2h; Molecular sieve;100%
With 4 A molecular sieve; sodium hydride; potassium carbonate 1.) dichloromethane, 6.5 h; 2.) dichloromethane, 5 h, r.t.; Yield given. Multistep reaction;
trichloroacetonitrile
545-06-2

trichloroacetonitrile

2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate
74808-09-6

2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

Conditions
ConditionsYield
In dichloromethane at 0℃; for 1h; Molecular sieve;100%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0℃; for 2h;98%
With sodium hydride In dichloromethane for 2.5h; Ambient temperature;96%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

O-(2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl)trichloroacetimidate
74808-10-9

O-(2,3,4,6-Tetra-O-acetyl-α-D-glucopyranosyl)trichloroacetimidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane for 1h;100%
polystyrene supported organic base (PS-DBU) In dichloromethane at 20℃; for 1.5h;99%
1,8-diazabicyclo[5.4.0]undec-7-ene at 0℃; for 1.5h; Addition;95%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

2,3,4,6-tetra-O-acetyl-α-galactopyranosyl trichloroacetimidate
86520-63-0

2,3,4,6-tetra-O-acetyl-α-galactopyranosyl trichloroacetimidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane for 1h;100%
With potassium carbonate In dichloromethane at 20℃;96.1%
1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0℃; for 1.5h; Addition;95%
C-phenyl-N-methylnitrone
3376-23-6, 7372-59-0, 59862-60-1

C-phenyl-N-methylnitrone

trichloroacetonitrile
545-06-2

trichloroacetonitrile

5-trichloromethyl-2-methyl-3-phenyl-2,3-dihydro-1,2,4-oxadiazole
121994-37-4

5-trichloromethyl-2-methyl-3-phenyl-2,3-dihydro-1,2,4-oxadiazole

Conditions
ConditionsYield
In toluene at 110℃; for 0.0333333h;100%
2,3,4-tri-O-benzyl-L-rhamnopyranose
210426-02-1

2,3,4-tri-O-benzyl-L-rhamnopyranose

trichloroacetonitrile
545-06-2

trichloroacetonitrile

(2S,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-methyltetrahydro-2H-pyran-2-yl 2,2,2-trichloroacetimidate
83866-10-8

(2S,3R,4R,5S,6S)-3,4,5-tris(benzyloxy)-6-methyltetrahydro-2H-pyran-2-yl 2,2,2-trichloroacetimidate

Conditions
ConditionsYield
With caesium carbonate In dichloromethane for 3.5h;100%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0 - 20℃; for 1h; Inert atmosphere;86%
With sodium hydride In dichloromethane for 0.5h; Ambient temperature;85%
With sodium hydride In dichloromethane at 20℃; for 1.5h;81%
Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 20℃; for 18h;100%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0 - 20℃; for 1h; Inert atmosphere;92%
With sodium hydride In dichloromethane for 30h; Ambient temperature;86%
(2R,3S)-2,3-epoxynerol
62777-72-4

(2R,3S)-2,3-epoxynerol

trichloroacetonitrile
545-06-2

trichloroacetonitrile

2,2,2-Trichloro-acetimidic acid (2R,3S)-3-methyl-3-(4-methyl-pent-3-enyl)-oxiranylmethyl ester
125414-25-7

2,2,2-Trichloro-acetimidic acid (2R,3S)-3-methyl-3-(4-methyl-pent-3-enyl)-oxiranylmethyl ester

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0℃; for 1h;100%
6-O-acetyl-2,3,4-tri-O-benzyl-α/β-D-galactopyranoside
88567-49-1, 88567-50-4, 93361-01-4, 101802-94-2, 101802-97-5, 127875-38-1

6-O-acetyl-2,3,4-tri-O-benzyl-α/β-D-galactopyranoside

trichloroacetonitrile
545-06-2

trichloroacetonitrile

6-O-acetyl-2,3,4-tri-O-benzyl-α/β-D-galactopyranosyl trichloroacetimidate
125164-10-5, 125164-11-6, 143826-39-5, 143826-40-8

6-O-acetyl-2,3,4-tri-O-benzyl-α/β-D-galactopyranosyl trichloroacetimidate

Conditions
ConditionsYield
With potassium carbonate In dichloromethane for 4.5h;100%
2-oxo-3-(ethoxycarbonyl)-3,4-dihydro-β-carboline
106544-20-1

2-oxo-3-(ethoxycarbonyl)-3,4-dihydro-β-carboline

trichloroacetonitrile
545-06-2

trichloroacetonitrile

(4R,10bR)-2-Trichloromethyl-4,5,10,10b-tetrahydro-3-oxa-1,3a,10-triaza-cyclopenta[a]fluorene-4-carboxylic acid ethyl ester
121994-30-7

(4R,10bR)-2-Trichloromethyl-4,5,10,10b-tetrahydro-3-oxa-1,3a,10-triaza-cyclopenta[a]fluorene-4-carboxylic acid ethyl ester

Conditions
ConditionsYield
In toluene at 80℃; for 0.0333333h;100%
O-(2,3,4-tri-O-benzyl-α-D-xylopyranosyl)-(1-3)-O-(2,4-di-O-benzyl-α-D-xylopyranosyl)-(1-3)-2,4,6-tri-O-acetyl-D-glucopyranose

O-(2,3,4-tri-O-benzyl-α-D-xylopyranosyl)-(1-3)-O-(2,4-di-O-benzyl-α-D-xylopyranosyl)-(1-3)-2,4,6-tri-O-acetyl-D-glucopyranose

trichloroacetonitrile
545-06-2

trichloroacetonitrile

O-(2,3,4-tri-O-benzyl-α-D-xylopyranosyl)-(1-3)-O-(2,4-di-O-benzyl-α-D-xylopyranosyl)-(1-3)-2,4,6-tri-O-acetyl-α,β-D-glucopyranosyl trichloroacetimidate
140420-64-0, 140420-75-3

O-(2,3,4-tri-O-benzyl-α-D-xylopyranosyl)-(1-3)-O-(2,4-di-O-benzyl-α-D-xylopyranosyl)-(1-3)-2,4,6-tri-O-acetyl-α,β-D-glucopyranosyl trichloroacetimidate

Conditions
ConditionsYield
With CsCO3 In dichloromethane for 2h; Ambient temperature;100%
3-O-<3-O-(2,3,4,6-tetra-O-benzoyl-α-D-galactopyranosyl)-6-O-acetyl-2,4-di-O-benzoyl-β-D-galactopyranosyl>-6-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-α/β-D-glucopyranose
143826-53-3, 143826-54-4

3-O-<3-O-(2,3,4,6-tetra-O-benzoyl-α-D-galactopyranosyl)-6-O-acetyl-2,4-di-O-benzoyl-β-D-galactopyranosyl>-6-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-α/β-D-glucopyranose

trichloroacetonitrile
545-06-2

trichloroacetonitrile

3-O-<3-O-(2,3,4,6-tetra-O-benzoyl-α-D-galactopyranosyl)-6-O-acetyl-2,4-di-O-benzoyl-β-D-galactopyranosyl>-6-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-α/β-D-glucopyranosyl trichloroacetimidate
143826-70-4, 143826-71-5

3-O-<3-O-(2,3,4,6-tetra-O-benzoyl-α-D-galactopyranosyl)-6-O-acetyl-2,4-di-O-benzoyl-β-D-galactopyranosyl>-6-O-acetyl-4-O-benzyl-2-deoxy-2-phthalimido-α/β-D-glucopyranosyl trichloroacetimidate

Conditions
ConditionsYield
With potassium carbonate In dichloromethane for 4.5h; Ambient temperature;100%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

4-Methoxybenzyl alcohol
105-13-5

4-Methoxybenzyl alcohol

O-(4-methoxybenzyl)-trichloroacetimidate
89238-99-3

O-(4-methoxybenzyl)-trichloroacetimidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In hexane at 0℃; for 0.25h; Solvent;100%
Stage #1: 4-Methoxybenzyl alcohol With sodium hydride In diethyl ether at 20℃; for 0.25h; Inert atmosphere;
Stage #2: trichloroacetonitrile In diethyl ether at 0℃;
98%
Stage #1: 4-Methoxybenzyl alcohol With sodium hydride In diethyl ether at 20℃; for 0.5h;
Stage #2: trichloroacetonitrile In diethyl ether at 0 - 20℃; Further stages.;
96%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

(2E)-3-phenyl-2-propen-1-ol
4407-36-7

(2E)-3-phenyl-2-propen-1-ol

1-(1-imino-2,2,2-trichloroethoxy)-3-phenyl-2(E)-propene
59874-81-6

1-(1-imino-2,2,2-trichloroethoxy)-3-phenyl-2(E)-propene

Conditions
ConditionsYield
With sodium hydride In diethyl ether at -10℃;100%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0℃; for 0.25h;98%
Stage #1: (2E)-3-phenyl-2-propen-1-ol With sodium hydride In diethyl ether; mineral oil at 20℃;
Stage #2: trichloroacetonitrile In diethyl ether; mineral oil at -10 - 20℃;
97%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

O--(2<*>3)-O-2-acetamido-3,4,6-tri-O-acetyl-2...

O--(2<*>3)-O-2-acetamido-3,4,6-tri-O-acetyl-2...

O--(2<*>3)-O-2-acetamido-3,4,6-tri-O-acetyl-2...

O--(2<*>3)-O-2-acetamido-3,4,6-tri-O-acetyl-2...

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0℃; for 0.5h;100%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

C115H116O33

C115H116O33

O-(3-O-allyl-6-O-levulinoyl-2,4-di-O-toluoyl-β-D-glucopyranosyl)-(1->6)-O-(2,3,4-tri-O-toluoyl-β-D-glucopyranosyl)-(1->6)-O-(3-O-allyl-2,4-di-O-toluoyl-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-toluoyl-α-D-glucopyranosyl trichloroacetimidate
187863-32-7

O-(3-O-allyl-6-O-levulinoyl-2,4-di-O-toluoyl-β-D-glucopyranosyl)-(1->6)-O-(2,3,4-tri-O-toluoyl-β-D-glucopyranosyl)-(1->6)-O-(3-O-allyl-2,4-di-O-toluoyl-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-toluoyl-α-D-glucopyranosyl trichloroacetimidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane for 24h; Ambient temperature;100%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate
132201-75-3

2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate

Conditions
ConditionsYield
With potassium carbonate In dichloromethane at 20℃; for 23h; Esterification;100%
With PTBD In dichloromethane at 20℃; for 2h;100%
With potassium carbonate In dichloromethane at 20℃; for 4h; Inert atmosphere;100%
biphenyl-4-yl methanol
3597-91-9

biphenyl-4-yl methanol

trichloroacetonitrile
545-06-2

trichloroacetonitrile

4-phenylbenzyl trichloroacetimidate
200057-74-5

4-phenylbenzyl trichloroacetimidate

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydrogensulfate; potassium hydroxide In dichloromethane; water at 0 - 25℃;100%
Stage #1: biphenyl-4-yl methanol With sodium hydride In diethyl ether; oil at 20℃; for 0.0833333h;
Stage #2: trichloroacetonitrile In diethyl ether; oil at 20℃; for 2h;
97%
With sodium hydride In diethyl ether 1.) 20 min, 2.) r.t., 1 h;69%
With sodium hydride In diethyl ether at 20℃; for 1h;
Stage #1: biphenyl-4-yl methanol With sodium hydride In tetrahydrofuran at 20℃; for 0.5h;
Stage #2: trichloroacetonitrile In tetrahydrofuran at 20℃; for 2h;
trichloroacetonitrile
545-06-2

trichloroacetonitrile

2-O-benzoyl-3,4,6-tri-O-benzyl-β-D-glucopyranoside
148926-02-7

2-O-benzoyl-3,4,6-tri-O-benzyl-β-D-glucopyranoside

O-(2-O-benzoyl-3,4,6-tri-O-benzyl-D-glucopyranosyl)trichloroacetimidate
213681-58-4

O-(2-O-benzoyl-3,4,6-tri-O-benzyl-D-glucopyranosyl)trichloroacetimidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 0℃; for 0.25h;100%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at -30℃; for 0.5h; Addition;90%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

methyl O-(2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-3,4,6-tri-O-acetyl-β-D-galactopyranosyl-(1->2)-3,4-di-O-acetyl-α-D-glucopyranuronate

methyl O-(2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-3,4,6-tri-O-acetyl-β-D-galactopyranosyl-(1->2)-3,4-di-O-acetyl-α-D-glucopyranuronate

methyl O-(2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-3,4,6-tri-O-acetyl-β-D-galactopyranosyl-(1->2)-3,4-di-O-acetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate
208709-53-9

methyl O-(2,3,4-tri-O-acetyl-α-L-rhamnopyranosyl)-(1->2)-3,4,6-tri-O-acetyl-β-D-galactopyranosyl-(1->2)-3,4-di-O-acetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at -5℃; for 2h; Addition;100%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at -5℃; for 2h; Yield given;
6-O-acetyl-1,5-anhydro-2,3-dideoxy-D-erythro-hex-2-enitol
128318-79-6

6-O-acetyl-1,5-anhydro-2,3-dideoxy-D-erythro-hex-2-enitol

trichloroacetonitrile
545-06-2

trichloroacetonitrile

6-O-acetyl-1,5-anhydro-2,3-dideoxy-4-O-(1-imino-2,2,2-trichloroethyl)-D-erythro-hex-2-enitol
197449-41-5

6-O-acetyl-1,5-anhydro-2,3-dideoxy-4-O-(1-imino-2,2,2-trichloroethyl)-D-erythro-hex-2-enitol

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane Addition;100%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

p-methoxyphenyl 6-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside
197449-37-9

p-methoxyphenyl 6-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

p-methoxyphenyl 6-O-acetyl-2,3-dideoxy-4-O-(1-imino-2,2,2-trichloroethyl)-α-D-erythro-hex-2-enopyranoside
197449-38-0

p-methoxyphenyl 6-O-acetyl-2,3-dideoxy-4-O-(1-imino-2,2,2-trichloroethyl)-α-D-erythro-hex-2-enopyranoside

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at -17℃; for 0.25h; Addition;100%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

6-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl 6-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside
197449-39-1

6-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl 6-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

6-O-acetyl-2,3-dideoxy-4-O-(1-imino-2,2,2-trichloroethyl)-α-D-erythro-hex-2-enopyranosyl 6-O-acetyl-2,3-dideoxy-4-O-(1-imino-2,2,2-trichloroethyl)-α-D-erythro-hex-2-enopyranoside
197449-40-4

6-O-acetyl-2,3-dideoxy-4-O-(1-imino-2,2,2-trichloroethyl)-α-D-erythro-hex-2-enopyranosyl 6-O-acetyl-2,3-dideoxy-4-O-(1-imino-2,2,2-trichloroethyl)-α-D-erythro-hex-2-enopyranoside

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane Addition;100%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

6-O-benzyl-3-O-[(S)-3-(benzyloxy)tetradecanoyl]-2-deoxy-4-O-(1,5-dihydro-3-oxo-3λ5-3H-2,4,3-benzodioxaphosphepin-3-yl)-2-(2,2,2-trichloroethoxycarbonylamino)-D-glucopyranose

6-O-benzyl-3-O-[(S)-3-(benzyloxy)tetradecanoyl]-2-deoxy-4-O-(1,5-dihydro-3-oxo-3λ5-3H-2,4,3-benzodioxaphosphepin-3-yl)-2-(2,2,2-trichloroethoxycarbonylamino)-D-glucopyranose

6-O-benzyl-3-O-[(S)-3-(benzyloxy)tetradecanoyl]-2-deoxy-4-O-(1,5-dihydro-3-oxo-3λ5-3H-2,4,3-benzodioxaphosphepin-3-yl)-2-(2,2,2-trichloroethoxycarbonylamino)-D-glucopyranosyl trichloroacetimidate
192444-70-5

6-O-benzyl-3-O-[(S)-3-(benzyloxy)tetradecanoyl]-2-deoxy-4-O-(1,5-dihydro-3-oxo-3λ5-3H-2,4,3-benzodioxaphosphepin-3-yl)-2-(2,2,2-trichloroethoxycarbonylamino)-D-glucopyranosyl trichloroacetimidate

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃; for 0.5h; Addition;100%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

6-O-benzyl-3-O-[(R)-3-(benzyloxy)tetradecanoyl]-2-deoxy-4-O-(1,5-dihydro-3-oxo-3λ5-3H-2,4,3-benzodioxaphosphepin-3-yl)-2-(2,2,2-trichloroethoxycarbonylamino)-D-glucopyranose

6-O-benzyl-3-O-[(R)-3-(benzyloxy)tetradecanoyl]-2-deoxy-4-O-(1,5-dihydro-3-oxo-3λ5-3H-2,4,3-benzodioxaphosphepin-3-yl)-2-(2,2,2-trichloroethoxycarbonylamino)-D-glucopyranose

6-O-benzyl-3-O-[(R)-3-(benzyloxy)tetradecanoyl]-2-deoxy-4-O-(1,5-dihydro-3-oxo-3λ5-3H-2,4,3-benzodioxaphosphepin-3-yl)-2-(2,2,2-trichloroethoxycarbonylamino)-D-glucopyranosyl trichloroacetimidate
192196-09-1

6-O-benzyl-3-O-[(R)-3-(benzyloxy)tetradecanoyl]-2-deoxy-4-O-(1,5-dihydro-3-oxo-3λ5-3H-2,4,3-benzodioxaphosphepin-3-yl)-2-(2,2,2-trichloroethoxycarbonylamino)-D-glucopyranosyl trichloroacetimidate

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃; for 1h; Addition;100%
trichloroacetonitrile
545-06-2

trichloroacetonitrile

3-O,4-S-Dibenzoyl-2,6-dideoxy-4-thio-D-ribo-hexopyranose

3-O,4-S-Dibenzoyl-2,6-dideoxy-4-thio-D-ribo-hexopyranose

3-O,4-S-Dibenzoyl-2,6-dideoxy-4-thio-D-ribo-hexopyranosyl trichloroacetimidate
330450-30-1

3-O,4-S-Dibenzoyl-2,6-dideoxy-4-thio-D-ribo-hexopyranosyl trichloroacetimidate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 20℃; for 1h;100%
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane for 1h; Ambient temperature;

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