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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

tert-Butyl 4-bromobenzoate

Cas:59247-47-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

Tert-Butyl 4-bromobenzoate

Cas:59247-47-1

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

tert-Butyl 4-bromobenzoate

Cas:59247-47-1

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 59247-47-1 with competitive price

Cas:59247-47-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

TERT-BUTYL-4-BROMOBENZOATECAS NO.:59247-47-1

Cas:59247-47-1

Min.Order:1 Gram

FOB Price: $4.0

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

TERT-BUTYL-4-BROMOBENZOATE CAS:59247-47-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organ

TERT-BUTYL-4-BROMOBENZOATE CAS:59247-47-1

Cas:59247-47-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzoic acid, 4-bromo-,1,1-dimethylethyl ester

Cas:59247-47-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

TERT-BUTYL4-BROMOBENZOATE

Cas:59247-47-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzoic acid, 4-bromo-,1,1-dimethylethyl ester

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

tert-Butyl 4-bromobenzoate

Cas:59247-47-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

TERT-BUTYL-4-BROMOBENZOATE

Cas:59247-47-1

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

TERT-BUTYL-4-BROMOBENZOATE

Cas:59247-47-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Tert-butyl-4-bromobenzoate cas no. 59247-47-1 98%

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

tert-Butyl 4-bromobenzoate

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

tert-butyl 4-bromobenzoate

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec TERT-BUTYL 4-BROMOBENZOATE 100g

Cas:59247-47-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high qualityAppearance:white crystalline powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4-Amino-2-(4-methylphenyl)-6-(methylthio)pyrimidine-5-carbonitrile, 97%

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Benzoic acid, 4-bromo-,1,1-dimethylethyl ester

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

tert-butyl 4-bromobenzoate

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzoic acid, 4-broMo-,1,1-diMethylethyl ester

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

Benzoic acid, 4-bromo-, 1,1-dimethylethyl esterAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:pharmaceutical intermediate Transportation:by air, by sea, by express

Benzoic acid, 4-bromo-, 1,1-dimethylethyl ester

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Other

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

tert-Butyl 4-bromobenzoate

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TERT-BUTYL-4-BROMOBENZOATE

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

TERT-BUTYL-4-BROMOBENZOATE

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

4-Bromo-benzoic acid tert-butyl ester

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

59247-47-1

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

tert-Butyl 4-bromobenzoate 59247-47-1

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

AstaTech ( Chengdu) BioPharmaceutical Corp.

Quality assurance, stable process and affordable priceAppearance:detailed see specifications Storage:enquiry Package:according to the clients requirement Application:Pharmaceutical intermediates Transportation:Normal Port:chengdu

tert-Butyl 4-bromobenzoate

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Appearance:White powder Storage:keep sealed and keep from direct light Package:According client's requirements Application:pharmaceutica

Tert-Butyl-4-Bromobenzoate manufacturer

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

TERT-BUTYL-4-BROMOBENZOATE

Cas:59247-47-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

potassium tert-butylate
865-47-4

potassium tert-butylate

4-chlorobenzoyl chloride
586-75-4

4-chlorobenzoyl chloride

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; for 2h; Inert atmosphere;100%
In diethyl ether for 1h; Substitution;95%
In tetrahydrofuran at -78 - 20℃; for 2h;95%
1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
Stage #1: 1.4-dibromobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -5℃;
Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -5℃;
Stage #3: With citric acid In tetrahydrofuran; hexane; toluene Further stages.;
98%
Stage #1: 1.4-dibromobenzene With n-butyllithium; butyl magnesium bromide In tetrahydrofuran; hexane; toluene at -5℃; for 1h; Inert atmosphere;
Stage #2: di-tert-butyl dicarbonate In tetrahydrofuran; hexane; toluene at -5℃; for 2h; Inert atmosphere;
98%
di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;89%
4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

potassium tert-butylate
865-47-4

potassium tert-butylate

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
Stage #1: 4-Bromobenzoic acid With 1,1'-carbonyldiimidazole In tetrahydrofuran at 25℃;
Stage #2: potassium tert-butylate In tetrahydrofuran at 25℃; for 2h;
89%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

4-Bromophenylacetonitrile
16532-79-9

4-Bromophenylacetonitrile

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
With Zr6(μ3-O)4(μ3-OH)4(OH)6(H2O)6(IDA)3; potassium hydroxide In acetonitrile at 80℃; for 10h;87%
In water; acetonitrile at 60℃; for 16h; Molecular sieve; Schlenk technique; Inert atmosphere;83%
4-bromobenzenemethanol
873-75-6

4-bromobenzenemethanol

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
With 1H-imidazole; tert.-butylhydroperoxide; tetra-(n-butyl)ammonium iodide In water at 80℃; for 7h; Green chemistry; chemoselective reaction;87%
carbon monoxide
201230-82-2

carbon monoxide

4-bromo-aniline
106-40-1

4-bromo-aniline

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
Stage #1: 4-bromo-aniline With tetrafluoroboric acid; acetic acid; isopentyl nitrite In water at 20℃; for 0.0833333h;
Stage #2: carbon monoxide; tert-butyl alcohol With Eosin Y at 18℃; under 37503.8 Torr; for 4h; Inert atmosphere; Darkness; Irradiation;
79%
Stage #1: 4-bromo-aniline With tetrafluoroboric acid; sodium nitrite In water at 0℃; for 0.75h;
Stage #2: carbon monoxide; tert-butyl alcohol With sodium formate In acetonitrile at 20℃; under 37503.8 Torr; for 3h;
146.6 mg
4-chlorobenzoyl chloride
586-75-4

4-chlorobenzoyl chloride

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
With pyridine In dichloromethane for 48h; Ambient temperature;78%
With pyridine In dichloromethane for 48h;70%
With n-butyllithium In diethyl ether; hexane Ambient temperature;
With pyridine In dichloromethane8.9 g (70%)
4-bromobenzoyl cyanide
6048-21-1

4-bromobenzoyl cyanide

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dichloromethane at 20℃; for 2h; Inert atmosphere;66%
4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
With dmap In tert-butyl alcohol at 40℃;63%
With dmap In tert-butyl alcohol at 20℃; for 12h; Concentration; Time;62%
With dmap In tert-butyl alcohol at 20℃; for 12h; Concentration;62%
With dmap In tert-butyl alcohol at 50℃;21%
4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
With dmap; di-tert-butyl dicarbonate at 20℃; for 12h;62%
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In chloroform at 20℃; for 18h;55%
With dmap; diisopropyl-carbodiimide In dichloromethane at 35℃; for 5h;49 g
N-tert-butoxy-4-chlorobenzamide
1450732-52-1

N-tert-butoxy-4-chlorobenzamide

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid; copper(ll) bromide In 1,4-dioxane at 70℃; for 3h;51%
With N-Bromosuccinimide In toluene at 80℃; for 1h;50%
4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

sodium t-butanolate
865-48-5

sodium t-butanolate

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
In toluene at 80℃; for 0.25h; transesterification;
4-Bromobenzoic acid
586-76-5

4-Bromobenzoic acid

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: N,N-dimethyl-formamide / 3 h / 43 °C / Inert atmosphere
2: 1,8-diazabicyclo[5.4.0]undec-7-ene / N,N-dimethyl-formamide / 48 h / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: thionyl chloride; N,N-dimethyl-formamide / 1 h / Reflux
2: tetrahydrofuran / 1 h / 0 - 5 °C
View Scheme
Multi-step reaction with 3 steps
1.1: thionyl chloride; N,N-dimethyl-formamide / 3 h / 60 °C
2.1: potassium carbonate / ethyl acetate; water
2.2: 4 h / 0 - 20 °C
3.1: N-Bromosuccinimide / toluene / 1 h / 80 °C
View Scheme
Multi-step reaction with 2 steps
1: thionyl chloride; N,N-dimethyl-formamide / 1 h / Inert atmosphere; Reflux; Schlenk technique
2: tetrahydrofuran / 0 °C
View Scheme
N-(4-bromobenzoyl)imidazole
82892-00-0

N-(4-bromobenzoyl)imidazole

tert-butyl alcohol
75-65-0

tert-butyl alcohol

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In N,N-dimethyl-formamide for 48h; Inert atmosphere;2.15 g
4-chlorobenzoyl chloride
586-75-4

4-chlorobenzoyl chloride

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: potassium carbonate / ethyl acetate; water
1.2: 4 h / 0 - 20 °C
2.1: N-Bromosuccinimide / toluene / 1 h / 80 °C
View Scheme
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
With 1,2,3-Benzotriazole; potassium iodide In water; 1,2-dichloro-ethane at 100℃; for 12h; High pressure;
4-Bromophenylacetonitrile
16532-79-9

4-Bromophenylacetonitrile

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: C56H53ClN3P2Ru(1+)*F6P(1-); tert.-butylhydroperoxide / benzene / 18 h / 40 °C / Inert atmosphere
2: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 2 h / 20 °C / Inert atmosphere
View Scheme
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

benzoic acid tert-butyl ester
774-65-2

benzoic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: tert-butyl-4-bromobenzoate With sec.-butyllithium In tetrahydrofuran; hexane; cyclohexane at -58℃; for 0.000105556h;
Stage #2: With tert-butyl alcohol In tetrahydrofuran; hexane; cyclohexane at -58℃; for 0.000638889h;
99%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

(1,5-anhydro-2-deoxy-4,6-O-bis(tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabino-hex-1-enitol)boronic acid pinacol ester
842132-50-7

(1,5-anhydro-2-deoxy-4,6-O-bis(tert-butylsilylidene)-3-O-triisopropylsilyl-D-arabino-hex-1-enitol)boronic acid pinacol ester

4-(1,5-anhydro-2-deoxy-4,6-O-di(tert-butyl)silanediyl-3-O-triisopropylsilyl-D-arabino-hex-1-enitolyl)benzoic acid tert-butyl ester
1384173-54-9

4-(1,5-anhydro-2-deoxy-4,6-O-di(tert-butyl)silanediyl-3-O-triisopropylsilyl-D-arabino-hex-1-enitolyl)benzoic acid tert-butyl ester

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In 1,2-dimethoxyethane; water for 4h; Reflux;99%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-benzoic acid tert-butyl ester

4-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-benzoic acid tert-butyl ester

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; potassium acetate In 1,4-dioxane at 80℃; for 4.5h; Inert atmosphere;98%
With meso-tetra(p-tolyl)porphinato-palladium(II); potassium acetate In 1,4-dioxane at 110℃; for 6h; Miyaura Borylation Reaction; chemoselective reaction;85%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In 1,4-dioxane Inert atmosphere; Reflux; Schlenk technique;80%
1,3,4-oxathiazinane 3,3-dioxide
863015-82-1

1,3,4-oxathiazinane 3,3-dioxide

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

tert-butyl 4-(3,3-dioxido-1,3,4-oxathiazinan-4-yl)benzoate
1609356-28-6

tert-butyl 4-(3,3-dioxido-1,3,4-oxathiazinan-4-yl)benzoate

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; for 2h; Buchwald-Hartwig Coupling; Inert atmosphere; Microwave irradiation;98%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

4-bromo-2-iodo-benzoic acid tert-butyl ester
944276-64-6

4-bromo-2-iodo-benzoic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: tert-butyl-4-bromobenzoate In tetrahydrofuran; hexane; pentane at 20℃; for 3h;
Stage #2: With iodine In tetrahydrofuran; hexane; pentane at 20℃; for 1h; Further stages.;
97%
Stage #1: tert-butyl-4-bromobenzoate In tetrahydrofuran at -20℃; for 1h;
Stage #2: With iodine In tetrahydrofuran at 0 - 25℃; Further stages.;
71%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

4,5-dimethyl-9-phenyl-9H-fluoren-9-ol

4,5-dimethyl-9-phenyl-9H-fluoren-9-ol

C32H30O3

C32H30O3

Conditions
ConditionsYield
With chloro(2’-amino-1,1’-biphenyl-2-yl)palladium(II) dimer; C60H54NO5P; sodium hydride In toluene at 80℃; for 12h; Inert atmosphere; enantioselective reaction;97%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

carbamic acid 2-trimethylsilylethyl ester
3124-37-6

carbamic acid 2-trimethylsilylethyl ester

4-(2-trimethylsilanylethoxycarbonylamino)benzoic acid tert-butyl ester
1257310-84-1

4-(2-trimethylsilanylethoxycarbonylamino)benzoic acid tert-butyl ester

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; for 15h; Inert atmosphere; Sealed;96%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

acrylic acid
79-10-7

acrylic acid

C14H16O4

C14H16O4

Conditions
ConditionsYield
With tributyl-amine; palladium diacetate; tris-(o-tolyl)phosphine In N,N-dimethyl acetamide at 100℃;96%
dibenzoazepine
256-96-2

dibenzoazepine

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

tert-butyl 4-(5H-dibenzo[b,f]azepin-5-yl)benzoate

tert-butyl 4-(5H-dibenzo[b,f]azepin-5-yl)benzoate

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 80℃; for 16h; Inert atmosphere;94%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

(1S,4R,5R)-5-[(tert-butyldiphenylsilyl)oxy]-2-azabicyclo[2.2.1]heptan-3-one

(1S,4R,5R)-5-[(tert-butyldiphenylsilyl)oxy]-2-azabicyclo[2.2.1]heptan-3-one

tert-butyl 4-[(1S,4R,5R)-5-[(tert-butyldiphenylsilyl)oxy]-3-oxo-2-azabicyclo[2.2.1]heptan-2-yl]benzoate

tert-butyl 4-[(1S,4R,5R)-5-[(tert-butyldiphenylsilyl)oxy]-3-oxo-2-azabicyclo[2.2.1]heptan-2-yl]benzoate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 105℃;94%
4-(2-amino-2-methyl-propoxy)-phenylamine
860032-57-1

4-(2-amino-2-methyl-propoxy)-phenylamine

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

C21H28N2O3

C21H28N2O3

Conditions
ConditionsYield
With [(π-cinnamyl)Pd(tBuXPhos)]OTf In water at 45℃; for 20h;94%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

phenyl trimethylsiloxane
2996-92-1

phenyl trimethylsiloxane

biphenyl-4-carboxylic acid t-butyl ester
220333-86-8

biphenyl-4-carboxylic acid t-butyl ester

Conditions
ConditionsYield
With potassium fluoride; propylene glycol; chloro-[2-(9-phenyl-1,10-phenanthrolin-2-yl)phenyl]palladium In dichloromethane at 100℃; for 12h; Hiyama Coupling; Inert atmosphere;94%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

benzylamine
100-46-9

benzylamine

N-benzyl-4,4'-di-tert-butylcarboxydiphenylamine
386218-09-3

N-benzyl-4,4'-di-tert-butylcarboxydiphenylamine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; sodium t-butanolate; palladium diacetate In toluene at 50℃; for 17h;93%
2-(hydroxydimethylsilyl)-1-[[2-(trimethylsilyl)ethoxy]methyl]-1H-indole sodium salt

2-(hydroxydimethylsilyl)-1-[[2-(trimethylsilyl)ethoxy]methyl]-1H-indole sodium salt

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

2-(4-[(1,1-dimethylethoxy)carbonyl]phenyl)-1-[[2-(trimethylsilyl)ethoxy]methyl]-1H-indole

2-(4-[(1,1-dimethylethoxy)carbonyl]phenyl)-1-[[2-(trimethylsilyl)ethoxy]methyl]-1H-indole

Conditions
ConditionsYield
tri(tert-butyl)phosphine palladium complex In toluene at 50℃; for 12h;93%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

4-(N-phenylamino)benzoic acid tert-butyl ester

4-(N-phenylamino)benzoic acid tert-butyl ester

N,N-di(4-(tert-butyl)benzoate)phenylamine
1372812-49-1

N,N-di(4-(tert-butyl)benzoate)phenylamine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butylphosphonium tetrafluoroborate; potassium tert-butylate In toluene at 20℃; for 2h;93%
With tris-(dibenzylideneacetone)dipalladium(0); potassium tert-butylate; tri tert-butylphosphoniumtetrafluoroborate In toluene at 80℃; for 1h;90%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

sodium (Z)-2-buten-1-yl-diethylsilanolate
1327162-50-4

sodium (Z)-2-buten-1-yl-diethylsilanolate

4-(1-methyl-2-propen-1-yl)benzoic acid, 1,1-dimethylethyl ester
1092390-68-5

4-(1-methyl-2-propen-1-yl)benzoic acid, 1,1-dimethylethyl ester

Conditions
ConditionsYield
With dicyclohexyl(1,1-dimethylethyl)phosphine-trihydridoboron; bis(dibenzylideneacetone)-palladium(0) In toluene at 22 - 70℃; Inert atmosphere; Sealed tube;91%
3-benzyl-3H-quinazolin-4-one
5388-11-4

3-benzyl-3H-quinazolin-4-one

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

tert-butyl 4-(3-Benzyl-4-oxo-3,4-dihydroquinazolin-2-yl)benzoate

tert-butyl 4-(3-Benzyl-4-oxo-3,4-dihydroquinazolin-2-yl)benzoate

Conditions
ConditionsYield
Stage #1: 3-benzyl-3H-quinazolin-4-one With copper(l) iodide; lithium tert-butoxide In N,N-dimethyl-formamide at 120℃; for 0.166667h; Microwave irradiation; Inert atmosphere; Sealed tube;
Stage #2: tert-butyl-4-bromobenzoate With palladium diacetate; triphenylphosphine In N,N-dimethyl-formamide at 60 - 120℃; for 0.5h; Inert atmosphere; Microwave irradiation; Sealed tube; regiospecific reaction;
90%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

3,4,5-Trimethoxyaniline
24313-88-0

3,4,5-Trimethoxyaniline

C20H25NO5

C20H25NO5

Conditions
ConditionsYield
With [(π-cinnamyl)Pd(tBuXPhos)]OTf In water at 45℃; for 26h;90%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

4-tert-butoxycarbonyl-4'-methoxy-1,1'-biphenyl
944385-73-3

4-tert-butoxycarbonyl-4'-methoxy-1,1'-biphenyl

Conditions
ConditionsYield
Stage #1: tert-butyl-4-bromobenzoate With chloro-trimethyl-silane; magnesium; ethylene dibromide; lithium chloride In tetrahydrofuran at 25℃; for 1h; Inert atmosphere;
Stage #2: 1-bromo-4-methoxy-benzene With 1,1'-bis-(diphenylphosphino)ferrocene; caesium carbonate; palladium dichloride In ethanol; N,N-dimethyl-formamide at 65℃; for 12h; Suzuki-Miyaura cross coupling reaction; Inert atmosphere;
89%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

(1S,4R,5R)-5-[[5-cyclopropyl-3-(2-fluoro-6-methylphenyl)-1,2-oxazol-4-yl]methoxy]-2-azabicyclo[2.2.1]heptan-3-one

(1S,4R,5R)-5-[[5-cyclopropyl-3-(2-fluoro-6-methylphenyl)-1,2-oxazol-4-yl]methoxy]-2-azabicyclo[2.2.1]heptan-3-one

tert-butyl 4-[(1S,4R,5R)-5-[[5-cyclopropyl-3-(2-fluoro-6-methylphenyl)-1,2-oxazol-4-yl]methoxy]-3-oxo-2-azabicyclo[2.2.1]heptan-2-yl]benzoate

tert-butyl 4-[(1S,4R,5R)-5-[[5-cyclopropyl-3-(2-fluoro-6-methylphenyl)-1,2-oxazol-4-yl]methoxy]-3-oxo-2-azabicyclo[2.2.1]heptan-2-yl]benzoate

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 105℃;89%
bromochlorobenzene
106-39-8

bromochlorobenzene

tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

2-allyl-5-methoxy-phenylamine
59816-85-2

2-allyl-5-methoxy-phenylamine

4-[1-(4-chlorophenyl)-6-methoxy-2,3-dihydro-1H-indol-2-ylmethyl]benzoic acid tert-butyl ester

4-[1-(4-chlorophenyl)-6-methoxy-2,3-dihydro-1H-indol-2-ylmethyl]benzoic acid tert-butyl ester

Conditions
ConditionsYield
Stage #1: bromochlorobenzene; 2-allyl-5-methoxy-phenylamine With tris(dibenzylideneacetone)dipalladium (0); johnphos; sodium t-butanolate In toluene at 80℃;
Stage #2: tert-butyl-4-bromobenzoate With bis[2-(diphenylphosphino)phenyl] ether In toluene at 105℃;
88%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

allyl bromide
106-95-6

allyl bromide

tert-butyl 4-allylbenzoate

tert-butyl 4-allylbenzoate

Conditions
ConditionsYield
Stage #1: tert-butyl-4-bromobenzoate With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; TurboGrignard In tetrahydrofuran at -10℃; for 24h;
Stage #2: allyl bromide With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone In tetrahydrofuran at 0℃; for 1h;
88%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

4,4,5,5-tetramethyl-2-((E)-styryl)-[1,3,2]dioxaborolane
83947-56-2

4,4,5,5-tetramethyl-2-((E)-styryl)-[1,3,2]dioxaborolane

tert-butyl 4-(1-phenylvinyl)benzoate

tert-butyl 4-(1-phenylvinyl)benzoate

Conditions
ConditionsYield
With trans-bis(triphenylphosphine)palladium dichloride; sodium carbonate In 1,4-dioxane; water at 90℃; for 18h; Inert atmosphere;87.5%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,4-dioxane at 90℃; for 18h; Inert atmosphere;87.5%
tert-butyl-4-bromobenzoate
59247-47-1

tert-butyl-4-bromobenzoate

butyl[2-(2-hydroxyprop-2-yl)phenyl]diisopropylsilane
1239384-08-7

butyl[2-(2-hydroxyprop-2-yl)phenyl]diisopropylsilane

A

3,3-dimethyl-1,1-diisopropyl-1,3-dihydrobenzo[c][1,2]oxasilole
1239384-09-8

3,3-dimethyl-1,1-diisopropyl-1,3-dihydrobenzo[c][1,2]oxasilole

B

4-butylbenzoic acid t-butyl ester
1239384-28-1

4-butylbenzoic acid t-butyl ester

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; potassium phosphate; bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)copper(II) monohydrate; palladium diacetate In tetrahydrofuran at 100℃; for 1h; Inert atmosphere;A 94 %Chromat.
B 87%

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