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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Iminostilbene Manufacturer/High quality/Best price/In stock

Cas:256-96-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Iminostilbene supplier in China

Cas:256-96-2

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 5H-dibenz[b,f]azepine

Cas:256-96-2

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Iminostilbene

Cas:256-96-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hubei DiBo chemical co., LTD

Name:Iminostilbene The alias:Iminostilbene CAS NO:256-96-2 Molecular formula:C14H11N Molecular weight:193.2438 Product Quality 12 years of chemical raw materials Mature operation of the industry System stability Data storage Security wi

Iminostilbene/CAS:256-96-2/with best price

Cas:256-96-2

Min.Order:25 Kilogram

FOB Price: $1.0 / 2.0

Type:Other

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Iminostilbene

Cas:256-96-2

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU CHEM--Iminostilbene

Cas:256-96-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 256-96-2 with best quality

Cas:256-96-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

Iminostilbene CAS:256-96-2

Cas:256-96-2

Min.Order:1 Metric Ton

FOB Price: $20.0 / 30.0

Type:Trading Company

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:Yellow to orange-yellow fine powder Storage:Room temperature Package:25kg/drum Application:Chemicals Transportation:Express/Sea/Air Port:Any port in china

High Quality Factory Supply Iminostilbene

Cas:256-96-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

Advantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best s

API Manufacturer Iminostilbene 256-96-2 Carbamazepine Intermediate

Cas:256-96-2

Min.Order:10 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

5H-Dibenz[b,f]azepine 256-96-2

Cas:256-96-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

Iminostilbene CAS:256-96-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates

Iminostilbene CAS:256-96-2

Cas:256-96-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

5H-Dibenz[b,f]azepine

Cas:256-96-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:256-96-2

Cas:256-96-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Iminostilbene

Cas:256-96-2

Min.Order:0

Negotiable

Type:Manufacturers

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Iminostilbene

Cas:256-96-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Iminostilbene

Cas:256-96-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

IMINOSTILBENE

Cas:256-96-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Iminostilbene

Cas:256-96-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

advantage: 1. The best price, satisfactory quality; 2. customers have the right to choose the delivery of parcels (EMS, DHL, FedEx, UPS); 3. customers have the right to choose from the recent effective packaging methods of their products packaging

Iminostilbene Best price/In stock

Cas:256-96-2

Min.Order:1 Gram

Negotiable

Type:Other

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products Iminostilbene

Cas:256-96-2

Min.Order:100 Gram

Negotiable

Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Iminostilbene

Cas:256-96-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

Iminostilbene

Cas:256-96-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Hebei Kunsui Technology Co., Ltd.

1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m

Pharmaceutical Intermediate Iminostilbene Powder CAS 256-96-2

Cas:256-96-2

Min.Order:1 Kilogram

FOB Price: $8.2 / 8.8

Type:Trading Company

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Siwei Development Group Ltd.

Product name: Iminostilbene CAS No.:256-96-2 Molecule Formula:C14H11N Molecule Weight:193.24 Purity: 99.0% Package: 25kg/drum Description:Orange yellow crystalline powder Manufacture Standards:Enterprise standard T

High Quality Iminostilbene

Cas:256-96-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Best OfferIminostilbene

Cas:256-96-2

Min.Order:0

Negotiable

Type:Trading Company

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Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Iminostilbene

Cas:256-96-2

Min.Order:1 Milligram

Negotiable

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

Iminostilbene Basic information Product Name: Iminostilbene Synonyms: 2,3,6,7-Dibenzazepine;5-Azadibenzo(a,e)cycloheptatriene;Iminostibene carbonyl chloride;5H-Dibenz[b,f]azepine;Iminostilbene;o,o'-Iminostilbene;IMINOSTILBENECARBAMAZEPINE;

Iminostilbene

Cas:256-96-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Iminostilbene

Cas:256-96-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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Synthetic route

2-bromostyrene
2039-88-5

2-bromostyrene

2-Chloroaniline
95-51-2

2-Chloroaniline

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); sodium t-butanolate; DavePhos In 1,4-dioxane at 110℃; for 6h; Inert atmosphere;99%
N-acetyl iminostilbene
19209-60-0

N-acetyl iminostilbene

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With triethyl borane; sodium hydroxide In tert-butyl methyl ether at 80℃; for 6h; Inert atmosphere; Sealed tube;99%
Stage #1: N-acetyl iminostilbene With Triethoxysilane; sodium triethylborohydride In tert-butyl methyl ether at 80℃; for 6h;
Stage #2: With hydrogenchloride In tert-butyl methyl ether; water at 20℃; for 1h; chemoselective reaction;
99%
Multi-step reaction with 2 steps
1: potassium hydroxide; triethyl borane / tetrahydrofuran / 24 h / 100 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: sodium hydroxide; water / tetrahydrofuran / 1 h / 25 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
2-(2-phenylethenyl)benzenamine
13066-19-8

2-(2-phenylethenyl)benzenamine

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With phosphoric acid at 100 - 300℃; for 2h; Temperature; Reagent/catalyst; Inert atmosphere; Industrial scale;98.9%
9,10-dihydrodibenzazepine
494-19-9

9,10-dihydrodibenzazepine

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With 1-methyl-2-nitrobenzene; palladium on activated charcoal at 230℃; for 1.5h; Rate constant; Kinetics; Thermodynamic data; var. hydrogen acceptors (also without acceptor); ΔH(excit.), ΔS(excit.); var. temp. and time;98.2%
With oxygen; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium nitrite In toluene at 120℃; under 9750.98 Torr; for 8h;24%
Stage #1: 9,10-dihydrodibenzazepine With N-Bromosuccinimide
Stage #2: With pyridine
N-benzyl-5H-dibenzoazepine
78943-58-5

N-benzyl-5H-dibenzoazepine

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With 5%-palladium/activated carbon; hydrogen In methanol at 35 - 40℃; under 1500.15 - 2250.23 Torr; for 5h; Autoclave;97%
5H-N-benzyl-10,11-dihydrobenzazepin-10-one
10464-31-0

5H-N-benzyl-10,11-dihydrobenzazepin-10-one

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With 5%-palladium/activated carbon; hydrogen In methanol at 45 - 50℃; under 7500.75 - 9000.9 Torr; for 5h; Autoclave;94.5%
Multi-step reaction with 2 steps
1: sodium tetrahydroborate; methanol / 4 h / 40 - 45 °C
2: 5%-palladium/activated carbon; hydrogen / methanol / 5 h / 35 - 40 °C / 1500.15 - 2250.23 Torr / Autoclave
View Scheme
5H-dibenz[b,f]azepine-5-carbonylchloride
33948-22-0

5H-dibenz[b,f]azepine-5-carbonylchloride

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
In acetonitrile electrolysis (Et4NClO4, Hg-dropelectrode);92%
10-bromo-dibenz[b,f]azepine
75272-34-3

10-bromo-dibenz[b,f]azepine

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With tetraethylammonium perchlorate In water; N,N-dimethyl-formamide cathode: Hg, working potential: -1.85 V, charge: 2.0-2.1 F/mol, 4-5 h;89%
carbamazepin
298-46-4

carbamazepin

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With tetraethoxy tellurium(IV) In tetrachloromethane for 3h; Heating;85%
With hydrogenchloride In water for 12h; Reagent/catalyst; Darkness;
With carbon dioxide at 160 - 200℃;
1-phenyl-1H-indole
16096-33-6

1-phenyl-1H-indole

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With methanesulfonic acid at 90℃; for 7h; Temperature;83.4%
With polyphosphoric acid at 100℃;67%
With PPA at 75 - 85℃; for 55h; Mechanism; substituent effect discussed;43%
With PPA at 75 - 85℃; for 55h;43%
With methanesulfonic acid; phosphorus pentoxide In toluene at 120℃; for 6h;
1,2-Bis(5H-dibenzazepin-5-yl)ethan-1,2-dion
119872-39-8

1,2-Bis(5H-dibenzazepin-5-yl)ethan-1,2-dion

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
In acetonitrile electrolysis (Et4NClO4, Hg-dropelectrode);80%
10,11-dihydro-5H-dibenzo[b,f]azepin-10-ol
4014-77-1

10,11-dihydro-5H-dibenzo[b,f]azepin-10-ol

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With toluene-4-sulfonic acid In toluene at 25℃; Dean-Stark; Reflux;78%
5-Propa-1,2-dienyl-5H-dibenzo[b,f]azepine
152700-38-4

5-Propa-1,2-dienyl-5H-dibenzo[b,f]azepine

3,5-Dichloro-2,4,6-trimethyl-benzonitrile N-oxide
13456-86-5

3,5-Dichloro-2,4,6-trimethyl-benzonitrile N-oxide

A

dibenzoazepine
256-96-2

dibenzoazepine

B

5-[3-(3,5-Dichloro-2,4,6-trimethyl-phenyl)-4-methylene-4,5-dihydro-isoxazol-5-yl]-5H-dibenzo[b,f]azepine

5-[3-(3,5-Dichloro-2,4,6-trimethyl-phenyl)-4-methylene-4,5-dihydro-isoxazol-5-yl]-5H-dibenzo[b,f]azepine

5-[(5S,6S)-3,9-Bis-(3,5-dichloro-2,4,6-trimethyl-phenyl)-1,7-dioxa-2,8-diaza-spiro[4.4]nona-2,8-dien-6-yl]-5H-dibenzo[b,f]azepine

5-[(5S,6S)-3,9-Bis-(3,5-dichloro-2,4,6-trimethyl-phenyl)-1,7-dioxa-2,8-diaza-spiro[4.4]nona-2,8-dien-6-yl]-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
In tetrachloromethane for 2h; Heating;A 48%
B 30%
C 12%
bromobenzene
108-86-1

bromobenzene

bicyclo[2.2.1]hepta-2,5-diene
121-46-0

bicyclo[2.2.1]hepta-2,5-diene

2-bromoaniline
615-36-1

2-bromoaniline

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; triphenylphosphine In N,N-dimethyl-formamide at 105 - 130℃; Inert atmosphere;45%
N-benzyl-5H-dibenzoazepine
78943-58-5

N-benzyl-5H-dibenzoazepine

A

9-methyl-acridine
611-64-3

9-methyl-acridine

B

dibenzoazepine
256-96-2

dibenzoazepine

C

pyrrolo<3,2,1-jk>carbazole
208-71-9

pyrrolo<3,2,1-jk>carbazole

D

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

Conditions
ConditionsYield
at 750℃; under 0.04 Torr; for 0.333333h;A 2%
B 20%
C n/a
D n/a
ethanol
64-17-5

ethanol

5-Azidocarbonyldibenzazepin
116822-14-1

5-Azidocarbonyldibenzazepin

A

acridine
260-94-6

acridine

B

dibenzoazepine
256-96-2

dibenzoazepine

C

1,2-Dihydrobenzimidazo<1,7-a,b><1>benzazepin-1-on
118794-84-6

1,2-Dihydrobenzimidazo<1,7-a,b><1>benzazepin-1-on

D

5-(N-Ethoxycarbonylamino)-dibenzazepin
118794-86-8

5-(N-Ethoxycarbonylamino)-dibenzazepin

Conditions
ConditionsYield
Mechanism; Product distribution; Irradiation; photolyse reactions with different alcohols and CH3CN as educts to different products, also with other reagents; also thermolysis reactions;A n/a
B n/a
C n/a
D 10%
N-methyldibenzazepine
52249-32-8

N-methyldibenzazepine

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With 5,10,15,20-tetraphenyl-21H,23H-porphine iron(lll) chloride; sodium dithionite; air; tetramethyl ammoniumhydroxide In methanol; dichloromethane; water for 0.333333h; Ambient temperature;170 % Chromat.
9,10-dihydrodibenzazepine
494-19-9

9,10-dihydrodibenzazepine

A

acridine
260-94-6

acridine

B

9-methyl-acridine
611-64-3

9-methyl-acridine

C

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
iron(III) oxide at 550℃; for 1h; Product distribution; selectivity, activity of catalysts, variation of catalyst and temperature;A 20.0 % Chromat.
B 5.9 % Chromat.
C 40.8 % Chromat.
manganese(III) oxide; magnesium oxide; potassium carbonate; tin(IV) oxide at 550℃; for 6h; Title compound not separated from byproducts;
diphenylamine-2,2′-dicarboxaldehyde
49579-63-7

diphenylamine-2,2′-dicarboxaldehyde

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
With hydrazine hydrate In acetic acid for 2h; Heating;3.8 g
C34H26N2O2
107185-55-7

C34H26N2O2

A

acridine
260-94-6

acridine

B

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
In ethanol Quantum yield; Irradiation;
C34H28Cl2N2O2
117176-56-4

C34H28Cl2N2O2

A

acridine
260-94-6

acridine

B

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
In ethanol Quantum yield; Irradiation;
9,18-diacetyl-4b,4c,9,13b,13c,18-hexahydro-tetrabenzo[b,f,b',f']cyclobuta[1,2-d;3,4-d']bisazepine
41217-00-9

9,18-diacetyl-4b,4c,9,13b,13c,18-hexahydro-tetrabenzo[b,f,b',f']cyclobuta[1,2-d;3,4-d']bisazepine

A

acridine
260-94-6

acridine

B

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
In ethanol Quantum yield; Irradiation;
9,18-dipropionyl-4b,4c,9,13b,13c,18-hexahydro-tetrabenzo[b,f,b',f']cyclobuta[1,2-d;3,4-d']bisazepine
41217-01-0, 52646-98-7

9,18-dipropionyl-4b,4c,9,13b,13c,18-hexahydro-tetrabenzo[b,f,b',f']cyclobuta[1,2-d;3,4-d']bisazepine

A

acridine
260-94-6

acridine

B

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
In ethanol Quantum yield; Irradiation;
9,18-dibenzoyl-4b,4c,9,13b,13c,18-hexahydro-tetrabenzo[b,f,b',f']cyclobuta[1,2-d;3,4-d']bisazepine
41217-03-2, 52647-00-4

9,18-dibenzoyl-4b,4c,9,13b,13c,18-hexahydro-tetrabenzo[b,f,b',f']cyclobuta[1,2-d;3,4-d']bisazepine

A

acridine
260-94-6

acridine

B

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
In ethanol Quantum yield; Irradiation;
9,10-dihydrodibenzazepine
494-19-9

9,10-dihydrodibenzazepine

1-methyl-2-nitrobenzene
88-72-2

1-methyl-2-nitrobenzene

A

dibenzoazepine
256-96-2

dibenzoazepine

B

o-toluidine
95-53-4

o-toluidine

Conditions
ConditionsYield
palladium on activated charcoal at 230℃; Kinetics; Rate constant; other hydrogen acceptor, var. temp., var. solvents;
9,10-dihydrodibenzazepine
494-19-9

9,10-dihydrodibenzazepine

1,1'-(1,2-ethanediyl)bisbenzene
103-29-7

1,1'-(1,2-ethanediyl)bisbenzene

A

dibenzoazepine
256-96-2

dibenzoazepine

B

(E)-1,2-diphenyl-ethene
103-30-0

(E)-1,2-diphenyl-ethene

Conditions
ConditionsYield
palladium on activated charcoal Kinetics; Rate constant; Thermodynamic data; var. temp, ΔH(excit.), ΔS(excit.);
diphenylamine-2,2'-dicarbonyl chloride
32621-46-8

diphenylamine-2,2'-dicarbonyl chloride

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: H2 / Palladium-Barium sulphate; Quinolin sulphate / xylene / 2.5 h / Heating
2: 3.8 g / Hydrazine hydrate / acetic acid / 2 h / Heating
View Scheme
Vanadox
579-92-0

Vanadox

dibenzoazepine
256-96-2

dibenzoazepine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 11.8 g / Thionyl chloride; Pyridine / 5 h / Heating
2: H2 / Palladium-Barium sulphate; Quinolin sulphate / xylene / 2.5 h / Heating
3: 3.8 g / Hydrazine hydrate / acetic acid / 2 h / Heating
View Scheme
dibenzoazepine
256-96-2

dibenzoazepine

benzyl bromide
100-39-0

benzyl bromide

N-benzyl-5H-dibenzoazepine
78943-58-5

N-benzyl-5H-dibenzoazepine

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane; water for 48h;100%
In dimethyl sulfoxide for 1.5h;35%
With sodium hydroxide; Aliquat 336 In dichloromethane at 20℃;32%
dibenzoazepine
256-96-2

dibenzoazepine

acetyl chloride
75-36-5

acetyl chloride

N-acetyl iminostilbene
19209-60-0

N-acetyl iminostilbene

Conditions
ConditionsYield
Stage #1: dibenzoazepine With sodium hydride In N,N-dimethyl-formamide; mineral oil Inert atmosphere;
Stage #2: acetyl chloride In N,N-dimethyl-formamide; mineral oil at 23℃; for 1h; Inert atmosphere;
100%
In toluene at 80℃; for 2h; Inert atmosphere;93%
In toluene at 80℃; for 2h; Inert atmosphere;93%
dibenzoazepine
256-96-2

dibenzoazepine

allyl bromide
106-95-6

allyl bromide

5-allyl-5H-dibenzo[b,f]azepine
74074-19-4

5-allyl-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With sodium hydroxide; tetra(n-butyl)ammonium hydrogensulfate In dichloromethane; water for 48h;100%
Stage #1: dibenzoazepine With tetrabutylammomium bromide; sodium hydroxide In water; toluene at 20℃; for 0.25h;
Stage #2: allyl bromide In water; toluene at 20 - 55℃; for 4h;
95%
In dimethyl sulfoxide for 1.5h;46%
With potassium carbonate In methanol for 5h; Heating;
With sodium hydroxide; N,N-didecyl-N,N-dimethylammonium bromide In toluene at 55℃; for 4h;
dibenzoazepine
256-96-2

dibenzoazepine

chloroacetyl chloride
79-04-9

chloroacetyl chloride

2-chloro-1-(5H-dibenzo[b,f]azepin-5-yl)ethan-1-one
41216-96-0

2-chloro-1-(5H-dibenzo[b,f]azepin-5-yl)ethan-1-one

Conditions
ConditionsYield
With N,N-dimethyl-aniline In tetrahydrofuran for 1h; Heating;100%
In benzene for 3h; Heating;94.3%
In toluene at 90℃; for 4h; Inert atmosphere;88%
With pyridine In acetonitrile at 20℃; for 24h; Acylation;80%
In toluene for 12h; Heating;
dibenzoazepine
256-96-2

dibenzoazepine

3-bromo-9H-carbazole
1592-95-6

3-bromo-9H-carbazole

N-[3-(9H-carbazolyl)]iminostilbene

N-[3-(9H-carbazolyl)]iminostilbene

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 80℃; for 16h; Inert atmosphere;100%
dibenzoazepine
256-96-2

dibenzoazepine

tert-butyl 6-oxohexylcarbamate
80860-42-0

tert-butyl 6-oxohexylcarbamate

(Z)-tert-Butyl 6-(5H-dibenzo[b,f]azepin-5-yl)hexylcarbamate
960129-50-4

(Z)-tert-Butyl 6-(5H-dibenzo[b,f]azepin-5-yl)hexylcarbamate

Conditions
ConditionsYield
With dibutyltin chloride; HSiPh3 In tetrahydrofuran at 20℃;99%
dibenzoazepine
256-96-2

dibenzoazepine

mesitylene-2-carboxylic acid chloride
938-18-1

mesitylene-2-carboxylic acid chloride

5-(2,4,6-trimethylbenzoyl)-5H-dibenz[b,f]azepine

5-(2,4,6-trimethylbenzoyl)-5H-dibenz[b,f]azepine

Conditions
ConditionsYield
Stage #1: dibenzoazepine With potassium hexamethylsilazane In tetrahydrofuran at 0℃; Inert atmosphere;
Stage #2: mesitylene-2-carboxylic acid chloride In tetrahydrofuran at 0 - 23℃; for 1h; Inert atmosphere;
99%
bromobenzene
108-86-1

bromobenzene

dibenzoazepine
256-96-2

dibenzoazepine

N-phenyldibenzazepine
78943-59-6

N-phenyldibenzazepine

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;99%
With nickel(II) oxide; potassium tert-butylate; triphenylphosphine In tetrahydrofuran at 100℃; for 24h; Inert atmosphere; Sealed tube; Green chemistry;85%
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 80℃; for 18h; Reagent/catalyst; Inert atmosphere;71%
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 80℃; for 18h; Solvent; Sealed tube; Inert atmosphere;71%
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tri-tert-butyl phosphine; sodium t-butanolate In toluene at 110℃; Buchwald-Hartwig Coupling; Inert atmosphere;
dibenzoazepine
256-96-2

dibenzoazepine

2-Bromobiphenyl
2052-07-5

2-Bromobiphenyl

N-(2-biphenyl)iminostilbene

N-(2-biphenyl)iminostilbene

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;99%
dibenzoazepine
256-96-2

dibenzoazepine

o-trifluoromethylphenyl bromide
392-83-6

o-trifluoromethylphenyl bromide

N-[2-(trifluoromethyl)phenyl]iminostilbene

N-[2-(trifluoromethyl)phenyl]iminostilbene

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane for 16h; Inert atmosphere;99%
dibenzoazepine
256-96-2

dibenzoazepine

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

5-(4-fluorophenyl)-5H-dibenzo[b,f]azepine
1414856-37-3

5-(4-fluorophenyl)-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;99%
5-bromo-1H-indole
10075-50-0

5-bromo-1H-indole

dibenzoazepine
256-96-2

dibenzoazepine

N-(3-indazolyl)iminostilbene

N-(3-indazolyl)iminostilbene

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 80℃; for 16h; Inert atmosphere;99%
dibenzoazepine
256-96-2

dibenzoazepine

hexanoic acid
142-62-1

hexanoic acid

C20H23N*ClH

C20H23N*ClH

Conditions
ConditionsYield
Stage #1: hexanoic acid With sodium tetrahydroborate In toluene at 0 - 5℃;
Stage #2: dibenzoazepine With sodium tetrahydroborate In toluene at 25 - 80℃; for 4h;
Stage #3: With hydrogenchloride In water; isopropyl alcohol
99%
dibenzoazepine
256-96-2

dibenzoazepine

2,2-dichloropropane
594-20-7

2,2-dichloropropane

C17H17N

C17H17N

Conditions
ConditionsYield
Stage #1: dibenzoazepine With C29H35Br2CoN3; zinc dibromide; zinc In tetrahydrofuran at 22℃; for 0.25h; Simmons-Smith Cyclopropanation; Inert atmosphere; Glovebox;
Stage #2: 2,2-dichloropropane In tetrahydrofuran at 22℃; for 24h; Simmons-Smith Cyclopropanation; Inert atmosphere; Glovebox; regioselective reaction;
99%
dibenzoazepine
256-96-2

dibenzoazepine

5-(cyano)dibenzothiophenium triflate

5-(cyano)dibenzothiophenium triflate

5-cyanodibenzazepine
42787-75-7

5-cyanodibenzazepine

Conditions
ConditionsYield
With caesium carbonate In dichloromethane at 20℃; for 6h; Inert atmosphere;99%
dibenzoazepine
256-96-2

dibenzoazepine

sodium isocyanate
917-61-3

sodium isocyanate

carbamazepin
298-46-4

carbamazepin

Conditions
ConditionsYield
In water; acetic acid at 15 - 60℃; for 4h; Product distribution / selectivity;98.8%
In acetic acid at 18 - 60℃; for 5h; Product distribution / selectivity;95.9%
In ethanol; acetic acid at 60 - 80℃; for 1.5h; Product distribution / selectivity;93.7%
dibenzoazepine
256-96-2

dibenzoazepine

benzoyl chloride
98-88-4

benzoyl chloride

(5H-dibenzo[b,f]azepin-5-yl)(phenyl)methanone
41216-97-1

(5H-dibenzo[b,f]azepin-5-yl)(phenyl)methanone

Conditions
ConditionsYield
Stage #1: dibenzoazepine With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 0.25h;
Stage #2: benzoyl chloride In dichloromethane at 20℃; Further stages.;
98%
In benzene96%
In benzene for 3h; Heating;85.6%
dibenzoazepine
256-96-2

dibenzoazepine

2,4,6-trichlorobenzoyl chloride
4136-95-2

2,4,6-trichlorobenzoyl chloride

5-(2,4,6-trichlorobenzoyl)-5H-dibenz[b,f]azepine

5-(2,4,6-trichlorobenzoyl)-5H-dibenz[b,f]azepine

Conditions
ConditionsYield
Stage #1: dibenzoazepine With potassium hexamethylsilazane In tetrahydrofuran at 0℃; Inert atmosphere;
Stage #2: 2,4,6-trichlorobenzoyl chloride In tetrahydrofuran at 0 - 23℃; for 1h; Inert atmosphere;
98%
dibenzoazepine
256-96-2

dibenzoazepine

2-Bromo-m-xylene
576-22-7

2-Bromo-m-xylene

N-(2,6-dimethylphenyl)iminostilbene

N-(2,6-dimethylphenyl)iminostilbene

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;98%
dibenzoazepine
256-96-2

dibenzoazepine

chlorobenzene
108-90-7

chlorobenzene

N-phenyldibenzazepine
78943-59-6

N-phenyldibenzazepine

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;98%
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 80℃; for 18h; Inert atmosphere;72%
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 80℃; for 18h; Solvent; Sealed tube; Inert atmosphere;72%
dibenzoazepine
256-96-2

dibenzoazepine

2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

5-(o-tolyl)-5H-dibenzo[b,f]azepine
152019-98-2

5-(o-tolyl)-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;98%
dibenzoazepine
256-96-2

dibenzoazepine

9-bromophenanthrene
573-17-1

9-bromophenanthrene

N-(9-phenanthryl)iminostilbene

N-(9-phenanthryl)iminostilbene

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;98%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

dibenzoazepine
256-96-2

dibenzoazepine

5-(4-methoxyphenyl)-5H-dibenzo[b,f]azepine
152019-82-4

5-(4-methoxyphenyl)-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;98%
2-bromo-1-benzothiophene
5394-13-8

2-bromo-1-benzothiophene

dibenzoazepine
256-96-2

dibenzoazepine

N-(2-benzothiophenyl)iminostilbene

N-(2-benzothiophenyl)iminostilbene

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 80℃; for 16h; Inert atmosphere;98%
2-chloropyridine
109-09-1

2-chloropyridine

dibenzoazepine
256-96-2

dibenzoazepine

5-(pyridin-2-yl)-5H-dibenzo[b,f]azepine
1385022-02-5

5-(pyridin-2-yl)-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 1-methyl-2-(2-(dicyclohexylphosphino)phenyl)-1H-benzoimidazole; sodium t-butanolate In toluene at 20 - 135℃; for 24h; Buchwald-Hartwig reaction; Inert atmosphere;97%
dibenzoazepine
256-96-2

dibenzoazepine

2,6-dimethyl-1-chlorobenzene
6781-98-2

2,6-dimethyl-1-chlorobenzene

N-(2,6-dimethylphenyl)iminostilbene

N-(2,6-dimethylphenyl)iminostilbene

Conditions
ConditionsYield
With C30H43O2P*C13H12N(1-)*CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;97%

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