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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

10-Methoxyiminostilbene Manufacturer/High quality/Best price/In stock

Cas:4698-11-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 10-Methoxy Iminostilbene (10-Misb)

Cas:4698-11-7

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 4698-11-7 10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

10-Methoxyiminostilbene CAS 4698-11-7 10-METHOXY IMINOSTILBENE CAS no 4698-11-7 10-Methoxy-5H-dibenzo[b,f]azepine 10-Methoxyiminostilbene 10-Methoxy-5H-dibenzo[b,f]azepine 10-Methoxy-5H-dibenz[b,f]azepine 10-METHOXY IMINOSTILBENE 10-Methox

Henan Tianfu Chemical Co., Ltd.

10-Methoxyiminostilbene Basic information Product Name: 10-Methoxyiminostilbene Synonyms: 10-METHOXY-5H-DIBENZ[B,F]AZEPINE;10-METHOXY IMINOSTILBENE;10-Methoxyiminostibene;MethoxyIminosti

10-Methoxy Iminostilbene_

Cas:4698-11-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturing

Pharmaceutical Intermediates 10-Methoxyiminostilbene CAS 4698-11-7

Cas:4698-11-7

Min.Order:1 Kilogram

FOB Price: $25.0 / 55.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 4698-11-7 with best quality

Cas:4698-11-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

Factory supply 10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Manufacturers

inquiry

Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta

high quality 4698-11-7 10-Methoxyiminostilbene with best price

Cas:4698-11-7

Min.Order:10 Gram

Negotiable

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

10-Methoxyiminostilbene 4698-11-7

Cas:4698-11-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:1 Kilogram

FOB Price: $88.0 / 100.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

trans-2,5-Dimethylpiperazine CAS: 4698-11-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality orga

trans-2,5-Dimethylpiperazine CAS: 4698-11-7

Cas:4698-11-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Appearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:As customer request Port:Qingda

10-Methoxy-5H-dibenz(b,f)azepine 4698-11-7

Cas:4698-11-7

Min.Order:1 Kilogram

FOB Price: $10.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

10-Methoxy Iminostilbene

Cas:4698-11-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

10-Methoxy iminostilbene

Cas:4698-11-7

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

10-METHOXY IMINOSTILBENE

Cas:4698-11-7

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 10-Methoxy Iminostilbene (10-Misb)

Cas:4698-11-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

10-Methoxy IminostilbeneAppearance:Light yellow to white crystals Storage:Store in cool and dry palce. Keep away from strong light ,high temperature. Package:according to customers' requirements Application:Used for the preparation of drug oqa xiping

10-Methoxy Iminostilbene

Cas:4698-11-7

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

TaiChem Taizhou Limited

Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site

10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Kunsui Technology Co., Ltd.

1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m

Pharmaceutical Intermediate 10-Methoxy Iminostilbene Powder CAS 4698-11-7

Cas:4698-11-7

Min.Order:1 Kilogram

FOB Price: $8.2 / 8.8

Type:Trading Company

inquiry

Siwei Development Group Ltd.

Product name: 10-Methoxy Iminostilbene CAS No.:4698-11-7 Molecule Formula:C15H13NO Molecule Weight:223.27 Purity: 99.0% Package: 25kg/drum Description:Bright yellow crystalline powder Manufacture Standards:Enterprise Standard

High Quality 10-Methoxy Iminostilbene

Cas:4698-11-7

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Factory Supplier10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

10-Methoxyiminostilbene Basic information Product Name: 10-Methoxyiminostilbene Synonyms: 10-METHOXY-5H-DIBENZO[B,F]AZEPINE,98.0+%(LC)(N);10-Methoxyiminostibene;MethoxyIminostilbene;10-Methoxy-5H-dibenzo[b,f]azepine;10-METHOXY-5H-DIBENZ[B,F]AZ

10-Methoxyiminostilbene

Cas:4698-11-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

10-methoxy-5H-dibenz[b,f]azepine-5-carboxylic acid methyl ester
353497-37-7

10-methoxy-5H-dibenz[b,f]azepine-5-carboxylic acid methyl ester

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With sodium hydroxide In various solvent(s) at 100℃; for 4h;98%
With sodium hydroxide In water98%
With sodium hydroxide In methanol; water at 105 - 110℃; for 2.5h;97%
10-methoxy-dibenzo[b,f]azepine-5-carboxylic acid phenyl ester
731851-94-8

10-methoxy-dibenzo[b,f]azepine-5-carboxylic acid phenyl ester

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With sodium hydroxide In various solvent(s) at 100℃; for 4h;96%
5-benzyl-10-methoxyiminostilbene
10465-66-4

5-benzyl-10-methoxyiminostilbene

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With 5%-palladium/activated carbon; hydrogen at 35 - 40℃; under 1500.15 - 2250.23 Torr; for 5h; Autoclave;93.5%
5-acetyl-10-methoxy-5H-dibenzazepine
153261-62-2

5-acetyl-10-methoxy-5H-dibenzazepine

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With potassium hydroxide In ethylene glycol for 5h; Heating;80%
With triethyl borane; sodium hydroxide In tert-butyl methyl ether at 80℃; for 6h; Inert atmosphere; Sealed tube;67%
Stage #1: 5-acetyl-10-methoxy-5H-dibenzazepine With Triethoxysilane; sodium triethylborohydride In tert-butyl methyl ether at 80℃; for 6h;
Stage #2: With hydrogenchloride In tert-butyl methyl ether; water at 20℃; for 1h; chemoselective reaction;
59%
5-allyl-10-methoxy-5H-dibenzo[b,f]azepine

5-allyl-10-methoxy-5H-dibenzo[b,f]azepine

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With potassium tert-butylate In dimethyl sulfoxide
5-formyl-10-bromo-11-methoxy-10,11-dihydro-5H-dibenzo[b,f]azepine

5-formyl-10-bromo-11-methoxy-10,11-dihydro-5H-dibenzo[b,f]azepine

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Stage #1: 5-formyl-10-bromo-11-methoxy-10,11-dihydro-5H-dibenzo[b,f]azepine With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene for 0.5h; Heating / reflux;
Stage #2: With Deloxan ASP I/7; potassium hydroxide In toluene Product distribution / selectivity; Heating / reflux;
(2-phenylamino-phenyl)-acetic acid methyl ester
39507-06-7

(2-phenylamino-phenyl)-acetic acid methyl ester

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: pyridine / toluene / 24 h / 50 °C
1.2: pyridine / 22 h / 100 °C
2.1: 90 percent / aq. NaOH / methanol / 24 h / 25 °C
3.1: 70 percent / polyphosphoric acid / 3 h / 95 °C
4.1: 81 percent / p-TsOH / methanol / 5 h / Heating
5.1: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C
View Scheme
Multi-step reaction with 6 steps
1: pyridine / toluene / 24 h / 50 °C
2: pyridine / 22 h / 100 °C
3: sodium hydroxide / water; methanol / 24 h / 20 °C
4: polyphosphoric acid / 3 h / 90 - 95 °C
5: water / 0 - 98 °C
6: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C
View Scheme
10,11-dihydro-10-oxo-5H-dibenz[b,f]azepine-5-carboxylic acid methyl ester
353497-31-1

10,11-dihydro-10-oxo-5H-dibenz[b,f]azepine-5-carboxylic acid methyl ester

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 81 percent / p-TsOH / methanol / 5 h / Heating
2: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C
View Scheme
Multi-step reaction with 2 steps
1: water / 0 - 98 °C
2: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C
View Scheme
[2-(methoxycarbonyl-phenyl-amino)-phenyl]-acetic acid methyl ester
805236-74-2

[2-(methoxycarbonyl-phenyl-amino)-phenyl]-acetic acid methyl ester

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 90 percent / aq. NaOH / methanol / 24 h / 25 °C
2: 70 percent / polyphosphoric acid / 3 h / 95 °C
3: 81 percent / p-TsOH / methanol / 5 h / Heating
4: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C
View Scheme
Multi-step reaction with 4 steps
1: sodium hydroxide / water; methanol / 24 h / 20 °C
2: polyphosphoric acid / 3 h / 90 - 95 °C
3: water / 0 - 98 °C
4: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C
View Scheme
2-[(methoxycarbonyl)phenylamino]benzeneacetic acid
353497-35-5

2-[(methoxycarbonyl)phenylamino]benzeneacetic acid

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 70 percent / polyphosphoric acid / 3 h / 95 °C
2: 81 percent / p-TsOH / methanol / 5 h / Heating
3: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C
View Scheme
Multi-step reaction with 3 steps
1: polyphosphoric acid / 3 h / 90 - 95 °C
2: water / 0 - 98 °C
3: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C
View Scheme
10-oxo-10,11-dihydro-dibenzo[b,f]azepine-5-carboxylic acid phenyl ester

10-oxo-10,11-dihydro-dibenzo[b,f]azepine-5-carboxylic acid phenyl ester

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 99 percent / p-TsOH / methanol / 5 h / 60 °C
2: 96 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C
View Scheme
2-bromo-N,N-dimethyl benzamide
54616-47-6

2-bromo-N,N-dimethyl benzamide

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 91 percent / NaOtBu / Pd(OAc)2; rac-BINAP / toluene
2: 82 percent / NaH / dimethylformamide
3: 70 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 1 h / -20 °C
4: p-TsOH / methanol
5: t-BuOK / dimethylsulfoxide
View Scheme
2-bromo-N,N-diethylbenzamide
76041-86-6

2-bromo-N,N-diethylbenzamide

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 88 percent / NaOtBu / Pd(OAc)2; rac-BINAP / toluene
2: 85 percent / NaH / dimethylformamide
3: 72 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 2 h / -20 °C
4: p-TsOH / methanol
5: t-BuOK / dimethylsulfoxide
View Scheme
o-toluidine
95-53-4

o-toluidine

-thiocarbamide

-thiocarbamide

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 91 percent / NaOtBu / Pd(OAc)2; rac-BINAP / toluene
2: 82 percent / NaH / dimethylformamide
3: 70 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 1 h / -20 °C
4: p-TsOH / methanol
5: t-BuOK / dimethylsulfoxide
View Scheme
Multi-step reaction with 5 steps
1: 88 percent / NaOtBu / Pd(OAc)2; rac-BINAP / toluene
2: 85 percent / NaH / dimethylformamide
3: 72 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 2 h / -20 °C
4: p-TsOH / methanol
5: t-BuOK / dimethylsulfoxide
View Scheme
N,N-dimethyl-2-(2-toluidino)benzamide
353497-28-6

N,N-dimethyl-2-(2-toluidino)benzamide

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 82 percent / NaH / dimethylformamide
2: 70 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 1 h / -20 °C
3: p-TsOH / methanol
4: t-BuOK / dimethylsulfoxide
View Scheme
5,11-dihydro-5-(2-propen-1-yl)-10H-dibenz[b,f]azepin-10-one
332081-70-6

5,11-dihydro-5-(2-propen-1-yl)-10H-dibenz[b,f]azepin-10-one

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: p-TsOH / methanol
2: t-BuOK / dimethylsulfoxide
View Scheme
N,N-diethyl-2-(2-toluidino)benzamide
1027035-99-9

N,N-diethyl-2-(2-toluidino)benzamide

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 85 percent / NaH / dimethylformamide
2: 72 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 2 h / -20 °C
3: p-TsOH / methanol
4: t-BuOK / dimethylsulfoxide
View Scheme
2-(allyl-o-tolyl-amino)-N,N-dimethyl-benzamide
332081-66-0

2-(allyl-o-tolyl-amino)-N,N-dimethyl-benzamide

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 70 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 1 h / -20 °C
2: p-TsOH / methanol
3: t-BuOK / dimethylsulfoxide
View Scheme
2-(allyl-o-tolyl-amino)-N,N-diethyl-benzamide
332081-67-1

2-(allyl-o-tolyl-amino)-N,N-diethyl-benzamide

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 72 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 2 h / -20 °C
2: p-TsOH / methanol
3: t-BuOK / dimethylsulfoxide
View Scheme
5-acetyl-10,11-epoxy-10,11-dihydro-5H-dibenzazepine
66849-39-6

5-acetyl-10,11-epoxy-10,11-dihydro-5H-dibenzazepine

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 67 percent / LiI / CHCl3 / 0.33 h / Heating
2: 90 percent / HCl, MeOH, i-PrOH / 2 h / Heating
3: 80 percent / KOH / ethane-1,2-diol / 5 h / Heating
View Scheme
N-acetyl iminostilbene
19209-60-0

N-acetyl iminostilbene

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 75.1 percent / NaOCl, silica gel / acetonitrile / 1.5 h / Heating
2: 67 percent / LiI / CHCl3 / 0.33 h / Heating
3: 90 percent / HCl, MeOH, i-PrOH / 2 h / Heating
4: 80 percent / KOH / ethane-1,2-diol / 5 h / Heating
View Scheme
5-acetyl-10-oxo-10,11-dihydro-5H-dibenzazepine
28291-63-6

5-acetyl-10-oxo-10,11-dihydro-5H-dibenzazepine

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 90 percent / HCl, MeOH, i-PrOH / 2 h / Heating
2: 80 percent / KOH / ethane-1,2-diol / 5 h / Heating
View Scheme
methanol
67-56-1

methanol

10,11-dibromo-10,11-dihydro-5H-dibenzo[b,f]azepine-5-carbonyl chloride
40421-03-2

10,11-dibromo-10,11-dihydro-5H-dibenzo[b,f]azepine-5-carbonyl chloride

sodium methylate
124-41-4

sodium methylate

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Stage #1: methanol; 10,11-dibromo-10,11-dihydro-5H-dibenzo[b,f]azepine-5-carbonyl chloride; sodium methylate at 30 - 55℃; for 0.75 - 1h;
Stage #2: methanol; sodium methylate at 30 - 93℃; for 12 - 16h; Product distribution / selectivity;
methyl 10-bromo-dibenz[b,f]azepine-5-carbamate
866874-00-2

methyl 10-bromo-dibenz[b,f]azepine-5-carbamate

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With sodium methylate at 20 - 93℃; for 12 - 16h; Product distribution / selectivity;
C16H14ClNO3

C16H14ClNO3

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: pyridine / 22 h / 100 °C
2: sodium hydroxide / water; methanol / 24 h / 20 °C
3: polyphosphoric acid / 3 h / 90 - 95 °C
4: water / 0 - 98 °C
5: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C
View Scheme
1-phenyl-1,3-dihydro-indol-2-one
3335-98-6

1-phenyl-1,3-dihydro-indol-2-one

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: sodium hydroxide / tetrahydrofuran / 5 h / 67 °C
1.2: 2 h / -10 °C
2.1: polyphosphoric acid / 3 h / 90 - 95 °C
3.1: water / 0 - 98 °C
4.1: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C
View Scheme
Multi-step reaction with 4 steps
1.1: sodium hydroxide / tetrahydrofuran / 5 h / 67 °C
1.2: 2 h / -40 °C
2.1: polyphosphoric acid / 3 h / 90 - 95 °C
3.1: water / 0 - 98 °C
4.1: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C
View Scheme
Multi-step reaction with 7 steps
1.1: sodium hydroxide / water; ethanol / 1 h / 50 °C
1.2: 4 h / 20 °C
2.1: pyridine / toluene / 24 h / 50 °C
3.1: pyridine / 22 h / 100 °C
4.1: sodium hydroxide / water; methanol / 24 h / 20 °C
5.1: polyphosphoric acid / 3 h / 90 - 95 °C
6.1: water / 0 - 98 °C
7.1: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C
View Scheme
o-cyanobromobenzene
2042-37-7

o-cyanobromobenzene

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: potassium carbonate / N,N-dimethyl-formamide / 5 h / 95 - 100 °C
2.1: sodium ethanolate / 2-methyltetrahydrofuran / 4 h / 50 - 60 °C
2.2: 3 h / 80 - 85 °C
3.1: potassium carbonate / methanol / 4 h / 95 - 100 °C / Autoclave
4.1: 5%-palladium/activated carbon; hydrogen / 5 h / 35 - 40 °C / 1500.15 - 2250.23 Torr / Autoclave
View Scheme
2-<(phenylmethyl)amino>benzeneacetonitrile
118671-07-1

2-<(phenylmethyl)amino>benzeneacetonitrile

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: potassium carbonate / N,N-dimethyl-formamide / 5 h / 95 - 100 °C
2.1: sodium ethanolate / 2-methyltetrahydrofuran / 4 h / 50 - 60 °C
2.2: 3 h / 80 - 85 °C
3.1: potassium carbonate / methanol / 4 h / 95 - 100 °C / Autoclave
4.1: 5%-palladium/activated carbon; hydrogen / 5 h / 35 - 40 °C / 1500.15 - 2250.23 Torr / Autoclave
View Scheme
N-benzyl-N-2′-cyanophenyl-2-aminophenylacetonitrile

N-benzyl-N-2′-cyanophenyl-2-aminophenylacetonitrile

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: sodium ethanolate / 2-methyltetrahydrofuran / 4 h / 50 - 60 °C
1.2: 3 h / 80 - 85 °C
2.1: potassium carbonate / methanol / 4 h / 95 - 100 °C / Autoclave
3.1: 5%-palladium/activated carbon; hydrogen / 5 h / 35 - 40 °C / 1500.15 - 2250.23 Torr / Autoclave
View Scheme
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

chloroacetyl chloride
79-04-9

chloroacetyl chloride

5-(chloroacetyl)-10-methoxy-5H-dibenz[b,f]azepine

5-(chloroacetyl)-10-methoxy-5H-dibenz[b,f]azepine

Conditions
ConditionsYield
With N,N-dimethyl-aniline In tetrahydrofuran for 1h; Heating;100%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

4-chloro-benzoyl chloride
122-01-0

4-chloro-benzoyl chloride

5-(4-chlorobenzoyl)-10-methoxy-5H-dibenz[b,f]azepine

5-(4-chlorobenzoyl)-10-methoxy-5H-dibenz[b,f]azepine

Conditions
ConditionsYield
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine With potassium hexamethylsilazane In tetrahydrofuran at 0℃; Inert atmosphere;
Stage #2: 4-chloro-benzoyl chloride In tetrahydrofuran at 0 - 23℃; for 1h; Inert atmosphere;
100%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

10,11-dihydro-5H-dibenzo[b,f]azepin-10-one
21737-58-6

10,11-dihydro-5H-dibenzo[b,f]azepin-10-one

Conditions
ConditionsYield
With sodium hydroxide In water at 100℃; for 4h;98%
With hydrogenchloride; water In acetone at 20℃; for 1 - 1.5h;97%
With hydrogenchloride In isopropyl alcohol at 25 - 65℃; for 3.25h;93%
With hydrogenchloride In water; isopropyl alcohol at 25 - 65℃;85.4%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

acetyl chloride
75-36-5

acetyl chloride

5-acetyl-10-methoxy-5H-dibenzazepine
153261-62-2

5-acetyl-10-methoxy-5H-dibenzazepine

Conditions
ConditionsYield
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine With sodium hydride In N,N-dimethyl-formamide; mineral oil Inert atmosphere;
Stage #2: acetyl chloride In N,N-dimethyl-formamide; mineral oil at 23℃; for 1h; Inert atmosphere;
96%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

2,4,6-trichlorobenzoyl chloride
4136-95-2

2,4,6-trichlorobenzoyl chloride

10-methoxy-5-(2,4,6-trichlorobenzoyl)-5H-dibenz[b,f]azepine

10-methoxy-5-(2,4,6-trichlorobenzoyl)-5H-dibenz[b,f]azepine

Conditions
ConditionsYield
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine With potassium hexamethylsilazane In tetrahydrofuran at 0℃; Inert atmosphere;
Stage #2: 2,4,6-trichlorobenzoyl chloride In tetrahydrofuran at 0 - 23℃; for 1h; Inert atmosphere;
96%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

mesitylene-2-carboxylic acid chloride
938-18-1

mesitylene-2-carboxylic acid chloride

10-methoxy-5-(2,4,6-trimethylbenzoyl)-5H-dibenz[b,f]azepine

10-methoxy-5-(2,4,6-trimethylbenzoyl)-5H-dibenz[b,f]azepine

Conditions
ConditionsYield
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine With potassium hexamethylsilazane In tetrahydrofuran at 0℃; Inert atmosphere;
Stage #2: mesitylene-2-carboxylic acid chloride In tetrahydrofuran at 0 - 23℃; for 1h; Inert atmosphere;
95%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

allyl bromide
106-95-6

allyl bromide

5,11-dihydro-5-(2-propen-1-yl)-10H-dibenz[b,f]azepin-10-one
332081-70-6

5,11-dihydro-5-(2-propen-1-yl)-10H-dibenz[b,f]azepin-10-one

Conditions
ConditionsYield
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 0.5h;
Stage #2: allyl bromide In N,N-dimethyl-formamide; mineral oil at 20℃; for 4h;
Stage #3: With hydrogenchloride In water; N,N-dimethyl-formamide; mineral oil for 1h;
94%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

bis(trichloromethyl) carbonate
32315-10-9

bis(trichloromethyl) carbonate

10-methoxy-5H-dibenz[b,f]azepine-5-carboxamide
28721-09-7

10-methoxy-5H-dibenz[b,f]azepine-5-carboxamide

Conditions
ConditionsYield
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With triethylamine In toluene at 10 - 15℃; for 6h;
Stage #2: With ammonia In water; toluene at 20℃; for 1h;
85%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

bis(trichloromethyl) carbonate
32315-10-9

bis(trichloromethyl) carbonate

10-methoxyiminostilbene carbonyl chloride
28721-08-6

10-methoxyiminostilbene carbonyl chloride

Conditions
ConditionsYield
With 2,3-Dimethylaniline In chloroform at 0 - 10℃; for 6h; Product distribution / selectivity;82%
With triethylamine In chloroform at 0 - 30℃; for 10 - 14h; Product distribution / selectivity;80%
With triethylamine In 1,2-dichloro-ethane at 0 - 20℃; for 16h;57%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

sodium isocyanate
917-61-3

sodium isocyanate

oxcarbazepine
28721-07-5

oxcarbazepine

Conditions
ConditionsYield
With hydrogenchloride80%
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; sodium isocyanate With water; Pyridine hydrobromide In toluene at 22℃; for 7 - 8h;
Stage #2: With hydrogenchloride In water; toluene at 55 - 89℃; for 3 - 4h; Heating / reflux;
44%
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; sodium isocyanate With water; quinoline hydrochloride In toluene at 20℃; for 18h;
Stage #2: With hydrogenchloride In water; toluene at 89℃; for 2h; Heating / reflux;
35%
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; sodium isocyanate With acetic acid at 25 - 35℃; for 1.33333 - 1.5h;
Stage #2: With sulfuric acid; water at 33 - 35℃; for 1 - 2h;
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

9-fluorenylmethoxycarbonyl isocyanate
232951-82-5

9-fluorenylmethoxycarbonyl isocyanate

10-methoxy-5H-dibenz[b,f]azepine-5-carboxamide
28721-09-7

10-methoxy-5H-dibenz[b,f]azepine-5-carboxamide

Conditions
ConditionsYield
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; 9-fluorenylmethoxycarbonyl isocyanate In dichloromethane at 20℃; for 16h; Inert atmosphere;
Stage #2: With piperidine In dichloromethane Inert atmosphere;
80%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

bis(trichloromethyl) carbonate
32315-10-9

bis(trichloromethyl) carbonate

oxcarbazepine
28721-07-5

oxcarbazepine

Conditions
ConditionsYield
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With triethylamine In toluene at 10 - 15℃; for 6h;
Stage #2: With ammonia In water; toluene at 20℃; for 1h;
Stage #3: With formic acid; water for 1h; Product distribution / selectivity; Heating / reflux;
76.6%
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With pyridine In toluene at 10 - 15℃; for 6h;
Stage #2: With ammonia In water; toluene at 20℃; for 1h;
Stage #3: With sulfuric acid; water for 1h; Product distribution / selectivity; Heating / reflux;
72.7%
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With triethylamine In dichloromethane Heating / reflux;
Stage #2: With ammonia In dichloromethane; water at 20℃; for 1h;
Stage #3: With sulfuric acid; water for 1h; Product distribution / selectivity; Heating / reflux;
68.7%
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With 1,4-diaza-bicyclo[2.2.2]octane In toluene at 10 - 15℃; for 6h;
Stage #2: With ammonia In water; toluene at 20℃; for 1h;
Stage #3: With formic acid; water for 1h; Product distribution / selectivity; Heating / reflux;
67.3%
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With triethylamine In toluene at 10 - 15℃; for 2 - 6h;
Stage #2: With ammonia In water; toluene at 20℃; for 1h;
Stage #3: With sulfuric acid; water for 1h; Product distribution / selectivity; Heating / reflux;
64%
bromobenzene
108-86-1

bromobenzene

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

C21H17NO

C21H17NO

Conditions
ConditionsYield
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 100℃; for 18h; Reagent/catalyst; Inert atmosphere;69%
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 100℃; for 18h; Solvent; Sealed tube; Inert atmosphere;69%
With nickel(II) oxide; potassium tert-butylate; triphenylphosphine In tetrahydrofuran at 120℃; for 24h; Inert atmosphere; Sealed tube; Green chemistry;63%
iodobenzene
591-50-4

iodobenzene

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

C21H17NO

C21H17NO

Conditions
ConditionsYield
With potassium tert-butylate; copper(II) oxide In N,N-dimethyl-formamide at 100℃; for 18h; Solvent; Sealed tube; Inert atmosphere;64%
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 100℃; for 18h; Reagent/catalyst; Inert atmosphere;63%
With nickel(II) oxide; potassium tert-butylate; triphenylphosphine In tetrahydrofuran at 120℃; for 24h; Inert atmosphere; Sealed tube; Green chemistry;57%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

chlorobenzene
108-90-7

chlorobenzene

C21H17NO

C21H17NO

Conditions
ConditionsYield
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 100℃; for 18h; Inert atmosphere;59%
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 100℃; for 18h; Solvent; Sealed tube; Inert atmosphere;59%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

9-fluorenylmethoxycarbonyl isothiocyanate
199915-38-3

9-fluorenylmethoxycarbonyl isothiocyanate

10-methoxy-5H-dibenz[b,f]azepine-5-carbothioamide

10-methoxy-5H-dibenz[b,f]azepine-5-carbothioamide

Conditions
ConditionsYield
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; 9-fluorenylmethoxycarbonyl isothiocyanate In dichloromethane at 80℃; for 24h; Inert atmosphere;
Stage #2: With piperidine In dichloromethane
57%
bromobenzene
108-86-1

bromobenzene

10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

5-(4-bromophenyl)-10-methoxy-5H-dibenzo[b,f]azepine

5-(4-bromophenyl)-10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 8h; Inert atmosphere; Reflux;54%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

sodium isocyanate
917-61-3

sodium isocyanate

10-methoxy-5H-dibenz[b,f]azepine-5-carboxamide
28721-09-7

10-methoxy-5H-dibenz[b,f]azepine-5-carboxamide

Conditions
ConditionsYield
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; sodium isocyanate With pyridinium p-toluenesulfonate In acetonitrile at 20℃; for 4h;
Stage #2: With water In acetonitrile at 20℃; for 0.25h;
50%
With acetic acid at 25℃; for 7h;
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; sodium isocyanate With Pyridine hydrobromide In toluene at 22℃; for 7 - 8h;
Stage #2: With water In toluene for 0.25h;
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

1,4-bromoiodobenzene
589-87-7

1,4-bromoiodobenzene

5-(4-bromophenyl)-10-methoxy-5H-dibenzo[b,f]azepine

5-(4-bromophenyl)-10-methoxy-5H-dibenzo[b,f]azepine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 8h; Buchwald-Hartwig Coupling; Reflux; Inert atmosphere;50%
10-methoxy-5H-dibenzo[b,f]azepine
4698-11-7

10-methoxy-5H-dibenzo[b,f]azepine

oxcarbazepine
28721-07-5

oxcarbazepine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: AcOH / 7 h / 25 °C
2: H2SO4 / 17 h / 25 °C
View Scheme
With hydrogenchloride; benzoic acid In water; toluene
With sulfuric acid In water; toluene
Multi-step reaction with 2 steps
1: acetic acid / 6.17 h / 20 - 45 °C / Inert atmosphere
2: hydrogenchloride / water; acetone / 2 h / 40 °C
View Scheme

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