Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:4698-11-7
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Cas:4698-11-7
Min.Order:1
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inquiry1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
Cas:4698-11-7
Min.Order:1 Gram
FOB Price: $0.1
Type:Manufacturers
inquiry10-Methoxyiminostilbene CAS 4698-11-7 10-METHOXY IMINOSTILBENE CAS no 4698-11-7 10-Methoxy-5H-dibenzo[b,f]azepine 10-Methoxyiminostilbene 10-Methoxy-5H-dibenzo[b,f]azepine 10-Methoxy-5H-dibenz[b,f]azepine 10-METHOXY IMINOSTILBENE 10-Methox
Cas:4698-11-7
Min.Order:5 Kiloliter
FOB Price: $3.5 / 5.0
Type:Manufacturers
inquiry10-Methoxyiminostilbene Basic information Product Name: 10-Methoxyiminostilbene Synonyms: 10-METHOXY-5H-DIBENZ[B,F]AZEPINE;10-METHOXY IMINOSTILBENE;10-Methoxyiminostibene;MethoxyIminosti
Cas:4698-11-7
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryWith our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturing
Cas:4698-11-7
Min.Order:1 Kilogram
FOB Price: $25.0 / 55.0
Type:Trading Company
inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:4698-11-7
Min.Order:1 Kilogram
FOB Price: $139.0 / 210.0
Type:Trading Company
inquiryHebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car
Cas:4698-11-7
Min.Order:1 Metric Ton
FOB Price: $1.0 / 2.0
Type:Manufacturers
inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta
Cas:4698-11-7
Min.Order:10 Gram
Negotiable
Type:Other
inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:4698-11-7
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese
Cas:4698-11-7
Min.Order:1 Kilogram
FOB Price: $88.0 / 100.0
Type:Trading Company
inquirytrans-2,5-Dimethylpiperazine CAS: 4698-11-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality orga
Cas:4698-11-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:4698-11-7
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
Appearance:off-white to white solid Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for Synthesis API and Research Transportation:As customer request Port:Qingda
Cas:4698-11-7
Min.Order:1 Kilogram
FOB Price: $10.0
Type:Lab/Research institutions
inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:4698-11-7
Min.Order:0 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryCompany Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
Cas:4698-11-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Cas:4698-11-7
Min.Order:4 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryMassive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Cas:4698-11-7
Min.Order:1 Gram
FOB Price: $1.0
Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:4698-11-7
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiry10-Methoxy IminostilbeneAppearance:Light yellow to white crystals Storage:Store in cool and dry palce. Keep away from strong light ,high temperature. Package:according to customers' requirements Application:Used for the preparation of drug oqa xiping
Established in May 2015, TaiChem Ltd. is initially invested by a British research and development company and started by PhDs back from aboard. The company is registered in China Medical City (CMC), Taizhou, Jiangsu Province, and the production site
Cas:4698-11-7
Min.Order:10 Gram
Negotiable
Type:Lab/Research institutions
inquiry1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m
Cas:4698-11-7
Min.Order:1 Kilogram
FOB Price: $8.2 / 8.8
Type:Trading Company
inquiryProduct name: 10-Methoxy Iminostilbene CAS No.:4698-11-7 Molecule Formula:C15H13NO Molecule Weight:223.27 Purity: 99.0% Package: 25kg/drum Description:Bright yellow crystalline powder Manufacture Standards:Enterprise Standard
Cas:4698-11-7
Min.Order:1 Kilogram
Negotiable
Type:Trading Company
inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:4698-11-7
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryOur Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an
Cas:4698-11-7
Min.Order:0
Negotiable
Type:Trading Company
inquiryGMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,
10-Methoxyiminostilbene Basic information Product Name: 10-Methoxyiminostilbene Synonyms: 10-METHOXY-5H-DIBENZO[B,F]AZEPINE,98.0+%(LC)(N);10-Methoxyiminostibene;MethoxyIminostilbene;10-Methoxy-5H-dibenzo[b,f]azepine;10-METHOXY-5H-DIBENZ[B,F]AZ
Cas:4698-11-7
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiry10-methoxy-5H-dibenz[b,f]azepine-5-carboxylic acid methyl ester
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With sodium hydroxide In various solvent(s) at 100℃; for 4h; | 98% |
With sodium hydroxide In water | 98% |
With sodium hydroxide In methanol; water at 105 - 110℃; for 2.5h; | 97% |
10-methoxy-dibenzo[b,f]azepine-5-carboxylic acid phenyl ester
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With sodium hydroxide In various solvent(s) at 100℃; for 4h; | 96% |
5-benzyl-10-methoxyiminostilbene
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With 5%-palladium/activated carbon; hydrogen at 35 - 40℃; under 1500.15 - 2250.23 Torr; for 5h; Autoclave; | 93.5% |
5-acetyl-10-methoxy-5H-dibenzazepine
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With potassium hydroxide In ethylene glycol for 5h; Heating; | 80% |
With triethyl borane; sodium hydroxide In tert-butyl methyl ether at 80℃; for 6h; Inert atmosphere; Sealed tube; | 67% |
Stage #1: 5-acetyl-10-methoxy-5H-dibenzazepine With Triethoxysilane; sodium triethylborohydride In tert-butyl methyl ether at 80℃; for 6h; Stage #2: With hydrogenchloride In tert-butyl methyl ether; water at 20℃; for 1h; chemoselective reaction; | 59% |
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With potassium tert-butylate In dimethyl sulfoxide |
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Stage #1: 5-formyl-10-bromo-11-methoxy-10,11-dihydro-5H-dibenzo[b,f]azepine With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene for 0.5h; Heating / reflux; Stage #2: With Deloxan ASP I/7; potassium hydroxide In toluene Product distribution / selectivity; Heating / reflux; |
(2-phenylamino-phenyl)-acetic acid methyl ester
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: pyridine / toluene / 24 h / 50 °C 1.2: pyridine / 22 h / 100 °C 2.1: 90 percent / aq. NaOH / methanol / 24 h / 25 °C 3.1: 70 percent / polyphosphoric acid / 3 h / 95 °C 4.1: 81 percent / p-TsOH / methanol / 5 h / Heating 5.1: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C View Scheme | |
Multi-step reaction with 6 steps 1: pyridine / toluene / 24 h / 50 °C 2: pyridine / 22 h / 100 °C 3: sodium hydroxide / water; methanol / 24 h / 20 °C 4: polyphosphoric acid / 3 h / 90 - 95 °C 5: water / 0 - 98 °C 6: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme |
10,11-dihydro-10-oxo-5H-dibenz[b,f]azepine-5-carboxylic acid methyl ester
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 81 percent / p-TsOH / methanol / 5 h / Heating 2: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C View Scheme | |
Multi-step reaction with 2 steps 1: water / 0 - 98 °C 2: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme |
[2-(methoxycarbonyl-phenyl-amino)-phenyl]-acetic acid methyl ester
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 90 percent / aq. NaOH / methanol / 24 h / 25 °C 2: 70 percent / polyphosphoric acid / 3 h / 95 °C 3: 81 percent / p-TsOH / methanol / 5 h / Heating 4: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C View Scheme | |
Multi-step reaction with 4 steps 1: sodium hydroxide / water; methanol / 24 h / 20 °C 2: polyphosphoric acid / 3 h / 90 - 95 °C 3: water / 0 - 98 °C 4: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme |
2-[(methoxycarbonyl)phenylamino]benzeneacetic acid
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 70 percent / polyphosphoric acid / 3 h / 95 °C 2: 81 percent / p-TsOH / methanol / 5 h / Heating 3: 98 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C View Scheme | |
Multi-step reaction with 3 steps 1: polyphosphoric acid / 3 h / 90 - 95 °C 2: water / 0 - 98 °C 3: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme |
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 99 percent / p-TsOH / methanol / 5 h / 60 °C 2: 96 percent / aq. NaOH / various solvent(s) / 4 h / 100 °C View Scheme |
2-bromo-N,N-dimethyl benzamide
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: 91 percent / NaOtBu / Pd(OAc)2; rac-BINAP / toluene 2: 82 percent / NaH / dimethylformamide 3: 70 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 1 h / -20 °C 4: p-TsOH / methanol 5: t-BuOK / dimethylsulfoxide View Scheme |
2-bromo-N,N-diethylbenzamide
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: 88 percent / NaOtBu / Pd(OAc)2; rac-BINAP / toluene 2: 85 percent / NaH / dimethylformamide 3: 72 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 2 h / -20 °C 4: p-TsOH / methanol 5: t-BuOK / dimethylsulfoxide View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: 91 percent / NaOtBu / Pd(OAc)2; rac-BINAP / toluene 2: 82 percent / NaH / dimethylformamide 3: 70 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 1 h / -20 °C 4: p-TsOH / methanol 5: t-BuOK / dimethylsulfoxide View Scheme | |
Multi-step reaction with 5 steps 1: 88 percent / NaOtBu / Pd(OAc)2; rac-BINAP / toluene 2: 85 percent / NaH / dimethylformamide 3: 72 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 2 h / -20 °C 4: p-TsOH / methanol 5: t-BuOK / dimethylsulfoxide View Scheme |
N,N-dimethyl-2-(2-toluidino)benzamide
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 82 percent / NaH / dimethylformamide 2: 70 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 1 h / -20 °C 3: p-TsOH / methanol 4: t-BuOK / dimethylsulfoxide View Scheme |
5,11-dihydro-5-(2-propen-1-yl)-10H-dibenz[b,f]azepin-10-one
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: p-TsOH / methanol 2: t-BuOK / dimethylsulfoxide View Scheme |
N,N-diethyl-2-(2-toluidino)benzamide
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 85 percent / NaH / dimethylformamide 2: 72 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 2 h / -20 °C 3: p-TsOH / methanol 4: t-BuOK / dimethylsulfoxide View Scheme |
2-(allyl-o-tolyl-amino)-N,N-dimethyl-benzamide
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 70 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 1 h / -20 °C 2: p-TsOH / methanol 3: t-BuOK / dimethylsulfoxide View Scheme |
2-(allyl-o-tolyl-amino)-N,N-diethyl-benzamide
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 72 percent / LDA; TMEDA; n-BuLi / tetrahydrofuran; hexane / 2 h / -20 °C 2: p-TsOH / methanol 3: t-BuOK / dimethylsulfoxide View Scheme |
5-acetyl-10,11-epoxy-10,11-dihydro-5H-dibenzazepine
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 67 percent / LiI / CHCl3 / 0.33 h / Heating 2: 90 percent / HCl, MeOH, i-PrOH / 2 h / Heating 3: 80 percent / KOH / ethane-1,2-diol / 5 h / Heating View Scheme |
N-acetyl iminostilbene
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 75.1 percent / NaOCl, silica gel / acetonitrile / 1.5 h / Heating 2: 67 percent / LiI / CHCl3 / 0.33 h / Heating 3: 90 percent / HCl, MeOH, i-PrOH / 2 h / Heating 4: 80 percent / KOH / ethane-1,2-diol / 5 h / Heating View Scheme |
5-acetyl-10-oxo-10,11-dihydro-5H-dibenzazepine
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 90 percent / HCl, MeOH, i-PrOH / 2 h / Heating 2: 80 percent / KOH / ethane-1,2-diol / 5 h / Heating View Scheme |
methanol
10,11-dibromo-10,11-dihydro-5H-dibenzo[b,f]azepine-5-carbonyl chloride
sodium methylate
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Stage #1: methanol; 10,11-dibromo-10,11-dihydro-5H-dibenzo[b,f]azepine-5-carbonyl chloride; sodium methylate at 30 - 55℃; for 0.75 - 1h; Stage #2: methanol; sodium methylate at 30 - 93℃; for 12 - 16h; Product distribution / selectivity; |
methyl 10-bromo-dibenz[b,f]azepine-5-carbamate
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
With sodium methylate at 20 - 93℃; for 12 - 16h; Product distribution / selectivity; |
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: pyridine / 22 h / 100 °C 2: sodium hydroxide / water; methanol / 24 h / 20 °C 3: polyphosphoric acid / 3 h / 90 - 95 °C 4: water / 0 - 98 °C 5: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: sodium hydroxide / tetrahydrofuran / 5 h / 67 °C 1.2: 2 h / -10 °C 2.1: polyphosphoric acid / 3 h / 90 - 95 °C 3.1: water / 0 - 98 °C 4.1: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme | |
Multi-step reaction with 4 steps 1.1: sodium hydroxide / tetrahydrofuran / 5 h / 67 °C 1.2: 2 h / -40 °C 2.1: polyphosphoric acid / 3 h / 90 - 95 °C 3.1: water / 0 - 98 °C 4.1: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme | |
Multi-step reaction with 7 steps 1.1: sodium hydroxide / water; ethanol / 1 h / 50 °C 1.2: 4 h / 20 °C 2.1: pyridine / toluene / 24 h / 50 °C 3.1: pyridine / 22 h / 100 °C 4.1: sodium hydroxide / water; methanol / 24 h / 20 °C 5.1: polyphosphoric acid / 3 h / 90 - 95 °C 6.1: water / 0 - 98 °C 7.1: sodium hydroxide / water; methanol / 2.5 h / 105 - 110 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: potassium carbonate / N,N-dimethyl-formamide / 5 h / 95 - 100 °C 2.1: sodium ethanolate / 2-methyltetrahydrofuran / 4 h / 50 - 60 °C 2.2: 3 h / 80 - 85 °C 3.1: potassium carbonate / methanol / 4 h / 95 - 100 °C / Autoclave 4.1: 5%-palladium/activated carbon; hydrogen / 5 h / 35 - 40 °C / 1500.15 - 2250.23 Torr / Autoclave View Scheme |
2-<(phenylmethyl)amino>benzeneacetonitrile
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: potassium carbonate / N,N-dimethyl-formamide / 5 h / 95 - 100 °C 2.1: sodium ethanolate / 2-methyltetrahydrofuran / 4 h / 50 - 60 °C 2.2: 3 h / 80 - 85 °C 3.1: potassium carbonate / methanol / 4 h / 95 - 100 °C / Autoclave 4.1: 5%-palladium/activated carbon; hydrogen / 5 h / 35 - 40 °C / 1500.15 - 2250.23 Torr / Autoclave View Scheme |
10-methoxy-5H-dibenzo[b,f]azepine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: sodium ethanolate / 2-methyltetrahydrofuran / 4 h / 50 - 60 °C 1.2: 3 h / 80 - 85 °C 2.1: potassium carbonate / methanol / 4 h / 95 - 100 °C / Autoclave 3.1: 5%-palladium/activated carbon; hydrogen / 5 h / 35 - 40 °C / 1500.15 - 2250.23 Torr / Autoclave View Scheme |
Conditions | Yield |
---|---|
With N,N-dimethyl-aniline In tetrahydrofuran for 1h; Heating; | 100% |
Conditions | Yield |
---|---|
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine With potassium hexamethylsilazane In tetrahydrofuran at 0℃; Inert atmosphere; Stage #2: 4-chloro-benzoyl chloride In tetrahydrofuran at 0 - 23℃; for 1h; Inert atmosphere; | 100% |
10-methoxy-5H-dibenzo[b,f]azepine
10,11-dihydro-5H-dibenzo[b,f]azepin-10-one
Conditions | Yield |
---|---|
With sodium hydroxide In water at 100℃; for 4h; | 98% |
With hydrogenchloride; water In acetone at 20℃; for 1 - 1.5h; | 97% |
With hydrogenchloride In isopropyl alcohol at 25 - 65℃; for 3.25h; | 93% |
With hydrogenchloride In water; isopropyl alcohol at 25 - 65℃; | 85.4% |
10-methoxy-5H-dibenzo[b,f]azepine
acetyl chloride
5-acetyl-10-methoxy-5H-dibenzazepine
Conditions | Yield |
---|---|
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine With sodium hydride In N,N-dimethyl-formamide; mineral oil Inert atmosphere; Stage #2: acetyl chloride In N,N-dimethyl-formamide; mineral oil at 23℃; for 1h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine With potassium hexamethylsilazane In tetrahydrofuran at 0℃; Inert atmosphere; Stage #2: 2,4,6-trichlorobenzoyl chloride In tetrahydrofuran at 0 - 23℃; for 1h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine With potassium hexamethylsilazane In tetrahydrofuran at 0℃; Inert atmosphere; Stage #2: mesitylene-2-carboxylic acid chloride In tetrahydrofuran at 0 - 23℃; for 1h; Inert atmosphere; | 95% |
10-methoxy-5H-dibenzo[b,f]azepine
allyl bromide
5,11-dihydro-5-(2-propen-1-yl)-10H-dibenz[b,f]azepin-10-one
Conditions | Yield |
---|---|
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 0.5h; Stage #2: allyl bromide In N,N-dimethyl-formamide; mineral oil at 20℃; for 4h; Stage #3: With hydrogenchloride In water; N,N-dimethyl-formamide; mineral oil for 1h; | 94% |
10-methoxy-5H-dibenzo[b,f]azepine
bis(trichloromethyl) carbonate
10-methoxy-5H-dibenz[b,f]azepine-5-carboxamide
Conditions | Yield |
---|---|
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With triethylamine In toluene at 10 - 15℃; for 6h; Stage #2: With ammonia In water; toluene at 20℃; for 1h; | 85% |
10-methoxy-5H-dibenzo[b,f]azepine
bis(trichloromethyl) carbonate
10-methoxyiminostilbene carbonyl chloride
Conditions | Yield |
---|---|
With 2,3-Dimethylaniline In chloroform at 0 - 10℃; for 6h; Product distribution / selectivity; | 82% |
With triethylamine In chloroform at 0 - 30℃; for 10 - 14h; Product distribution / selectivity; | 80% |
With triethylamine In 1,2-dichloro-ethane at 0 - 20℃; for 16h; | 57% |
Conditions | Yield |
---|---|
With hydrogenchloride | 80% |
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; sodium isocyanate With water; Pyridine hydrobromide In toluene at 22℃; for 7 - 8h; Stage #2: With hydrogenchloride In water; toluene at 55 - 89℃; for 3 - 4h; Heating / reflux; | 44% |
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; sodium isocyanate With water; quinoline hydrochloride In toluene at 20℃; for 18h; Stage #2: With hydrogenchloride In water; toluene at 89℃; for 2h; Heating / reflux; | 35% |
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; sodium isocyanate With acetic acid at 25 - 35℃; for 1.33333 - 1.5h; Stage #2: With sulfuric acid; water at 33 - 35℃; for 1 - 2h; |
10-methoxy-5H-dibenzo[b,f]azepine
9-fluorenylmethoxycarbonyl isocyanate
10-methoxy-5H-dibenz[b,f]azepine-5-carboxamide
Conditions | Yield |
---|---|
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; 9-fluorenylmethoxycarbonyl isocyanate In dichloromethane at 20℃; for 16h; Inert atmosphere; Stage #2: With piperidine In dichloromethane Inert atmosphere; | 80% |
10-methoxy-5H-dibenzo[b,f]azepine
bis(trichloromethyl) carbonate
oxcarbazepine
Conditions | Yield |
---|---|
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With triethylamine In toluene at 10 - 15℃; for 6h; Stage #2: With ammonia In water; toluene at 20℃; for 1h; Stage #3: With formic acid; water for 1h; Product distribution / selectivity; Heating / reflux; | 76.6% |
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With pyridine In toluene at 10 - 15℃; for 6h; Stage #2: With ammonia In water; toluene at 20℃; for 1h; Stage #3: With sulfuric acid; water for 1h; Product distribution / selectivity; Heating / reflux; | 72.7% |
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With triethylamine In dichloromethane Heating / reflux; Stage #2: With ammonia In dichloromethane; water at 20℃; for 1h; Stage #3: With sulfuric acid; water for 1h; Product distribution / selectivity; Heating / reflux; | 68.7% |
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With 1,4-diaza-bicyclo[2.2.2]octane In toluene at 10 - 15℃; for 6h; Stage #2: With ammonia In water; toluene at 20℃; for 1h; Stage #3: With formic acid; water for 1h; Product distribution / selectivity; Heating / reflux; | 67.3% |
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; bis(trichloromethyl) carbonate With triethylamine In toluene at 10 - 15℃; for 2 - 6h; Stage #2: With ammonia In water; toluene at 20℃; for 1h; Stage #3: With sulfuric acid; water for 1h; Product distribution / selectivity; Heating / reflux; | 64% |
Conditions | Yield |
---|---|
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 100℃; for 18h; Reagent/catalyst; Inert atmosphere; | 69% |
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 100℃; for 18h; Solvent; Sealed tube; Inert atmosphere; | 69% |
With nickel(II) oxide; potassium tert-butylate; triphenylphosphine In tetrahydrofuran at 120℃; for 24h; Inert atmosphere; Sealed tube; Green chemistry; | 63% |
Conditions | Yield |
---|---|
With potassium tert-butylate; copper(II) oxide In N,N-dimethyl-formamide at 100℃; for 18h; Solvent; Sealed tube; Inert atmosphere; | 64% |
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 100℃; for 18h; Reagent/catalyst; Inert atmosphere; | 63% |
With nickel(II) oxide; potassium tert-butylate; triphenylphosphine In tetrahydrofuran at 120℃; for 24h; Inert atmosphere; Sealed tube; Green chemistry; | 57% |
Conditions | Yield |
---|---|
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 100℃; for 18h; Inert atmosphere; | 59% |
With potassium tert-butylate; copper(II) oxide In dimethyl sulfoxide at 100℃; for 18h; Solvent; Sealed tube; Inert atmosphere; | 59% |
10-methoxy-5H-dibenzo[b,f]azepine
9-fluorenylmethoxycarbonyl isothiocyanate
Conditions | Yield |
---|---|
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; 9-fluorenylmethoxycarbonyl isothiocyanate In dichloromethane at 80℃; for 24h; Inert atmosphere; Stage #2: With piperidine In dichloromethane | 57% |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 8h; Inert atmosphere; Reflux; | 54% |
10-methoxy-5H-dibenzo[b,f]azepine
sodium isocyanate
10-methoxy-5H-dibenz[b,f]azepine-5-carboxamide
Conditions | Yield |
---|---|
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; sodium isocyanate With pyridinium p-toluenesulfonate In acetonitrile at 20℃; for 4h; Stage #2: With water In acetonitrile at 20℃; for 0.25h; | 50% |
With acetic acid at 25℃; for 7h; | |
Stage #1: 10-methoxy-5H-dibenzo[b,f]azepine; sodium isocyanate With Pyridine hydrobromide In toluene at 22℃; for 7 - 8h; Stage #2: With water In toluene for 0.25h; |
Conditions | Yield |
---|---|
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 8h; Buchwald-Hartwig Coupling; Reflux; Inert atmosphere; | 50% |
10-methoxy-5H-dibenzo[b,f]azepine
oxcarbazepine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: AcOH / 7 h / 25 °C 2: H2SO4 / 17 h / 25 °C View Scheme | |
With hydrogenchloride; benzoic acid In water; toluene | |
With sulfuric acid In water; toluene | |
Multi-step reaction with 2 steps 1: acetic acid / 6.17 h / 20 - 45 °C / Inert atmosphere 2: hydrogenchloride / water; acetone / 2 h / 40 °C View Scheme |
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