Encyclopedia

  • de Mayo Reaction

    de Mayo Reaction P. de Mayo et al., Proc. Chem. Soc. London 1962, 119; P. de Mayo, H. Takeshita, Can. J. Chem. 41, 440 (1963). Synthesis of 1,5-diketone

  • Darzens-Nenitzescu Synthesis of Ketones

    Darzens-Nenitzescu Synthesis of Ketones G. Darzens, Compt. Rend. 150, 707 (1910); C. D. Nenitzescu, I. P. Cantuniari, Ann. 510, 269 (1934); C. D. Nenitzescu, C. Cioranescu

  • Darzens Synthesis of Tetralin Derivatives

    Darzens Synthesis of Tetralin Derivatives G. Darzens, Compt. Rend. 183, 748 (1926). Cyclization of α-benzyl-α-allylacetic acid type compound

  • Dakin-West Reaction

    Dakin-West Reaction H. D. Dakin, R. West, J. Biol. Chem. 78, 91, 745, 757 (1928). Reaction of α-amino acids with acetic anhydride in the presence

  • Dakin Reaction

    Dakin Reaction H. D. Dakin, Am. Chem. J. 42, 477 (1909). Replacement of the formyl or acetyl groups in phenolic aldehydes or ketones by a hydroxyl group

  • D-Homo Rearrangement of Steroids

    L. Ruzicka, H. Meldahl, Helv. Chim. Acta 21, 1760 (1938); 22, 421 (1939). Originally discovered in 17β-hydroxy-20-ketosteroids, but thoroughly stu

  • Curtius Rearrangement

    Curtius Rearrangement; Curtius Reaction T. Curtius, Ber. 23, 3023 (1890); idem, J. Prakt. Chem. [2] 50, 275 (1894). Formation of isocyanates by thermal

  • Kolbe Electrolytic Synthesis

    Kolbe Electrolytic Synthesis; Crum Brown-Walker Reaction H. Kolbe, Ann. 69, 257 (1849). Formation of symmetrical dimers by the electrolysis of carboxyla

  • Criegee Reaction

    Criegee Reaction R. Criegee, Ber. 64, 260 (1931). Oxidative cleavage of vicinal glycols by lead tetraacetate: Rev

  • Craig Method

    Craig Method L. C. Craig, J. Am. Chem. Soc. 56, 231 (1934). Introduction of a halogen into the α-position of aminos by treatment with sodium nitri

  • Friedel-Crafts Reaction

    Friedel-Crafts Reaction C. Friedel, J. M. Crafts, Compt. Rend. 84, 1392, 1450 (1877). The alkylation or acylation of aromatic compounds catalyzed by alu

  • Perkin Rearrangement

    Perkin Rearrangement (Coumarin-Benzofuran Ring Contraction) W. H. Perkin, J. Chem. Soc. 23, 368 (1870). Formation of benzofuran-2-carboxylic acids and b

  • Cornforth Rearrangement

    Cornforth Rearrangement J. W. Cornforth, The Chemistry of (Princeton University Press, New Jersey, 1949) p 700. Thermal rearrangement of 4-carbonyl sub

  • Corey-Winter Olefin Synthesis

    Corey-Winter Olefin Synthesis E. J. Corey, R. A. E. Winter, J. Am. Chem. Soc. 85, 2677 (1963). Synthesis of olefins from 1,2-diols and thiocarbonyldiimi

  • Corey-Kim Oxidation

    Corey-Kim Oxidation E. J. Corey, C. U. Kim, J. Am. Chem. Soc. 94, 7586 (1972). Oxidation of primary and secondary alcohols via their alkoxysulfonium sal

  • Cope Rearrangement

    Cope Rearrangement; Oxy-Cope Rearrangement A. C. Cope et al., J. Am. Chem. Soc. 62, 441 (1940). Highly stereoselective [3,3]-sigmatropic rearrangement o

  • Cope Elimination Reaction

    Cope Elimination Reaction A. C. Cope et al., J. Am. Chem. Soc. 71, 3929 (1949); idem et al., ibid. 75, 3212 (1953). Formation of an olefin and a hydroxy

  • Sandmeyer Reaction

    Sandmeyer Reaction; Gattermann Reaction; Körner-Contardi Reaction T. Sandmeyer, Ber. 17, 1633, 2650 (1884); L. Gattermann, Ber. 23, 1218 (1890); G. Körner, A. Co

  • Conrad-Limpach Cyclization

    Conrad-Limpach Cyclization M. Conrad, L. Limpach, Ber. 20, 944 (1887); 24, 2990 (1891). Thermal condensation of arylamines with β-ketoesters follow

  • Combes Quinoline Synthesis

    Combes Synthesis A. Combes, Bull. Soc. Chim. France 49, 89 (1888). Formation of quinolines by condensation of β-diketones with primary arylamines

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