Encyclopedia

  • Oppenauer Oxidation

    Oppenauer Oxidation R. V. Oppenauer, Rec. Trav. Chim. 56, 137 (1937). The aluminum or potassium alkoxide-catalyzed oxidation of a secondary alcohol to t

  • Peterson Reaction

    Peterson Reaction (Olefination) D. J. Peterson, J. Org. Chem. 33, 780 (1968). Reaction of α-silyl carbanions with carbonyl compounds yielding &bet

  • Olefin Metathesis

    Olefin Metathesis -carbon bond rearrangements in presence of metal carbene catalyst complexes especially those of molybdenum and ruthenium:

  • Noyori Hydrogenation

    Noyori ation T. Ikariya et al., Chem. Commun. 1985, 922; R. Noyori et al., J. Am. Chem. Soc. 108, 7117 (1986). Homogeneous asymmetric catalytic hydrogen

  • Norrish Type Cleavage

    Norrish Type Cleavage R. G. W. Norrish, C. H. Bamford, Nature 138, 1016 (1936); 140, 195 (1937). Norrish Type I Cleavage: Homolytic cleavage of aldehyde

  • Nierenstein Reaction

    Nierenstein Reaction D. A. Clibbens, M. Nierenstein, J. Chem. Soc. 107, 1491 (1915). Formation of ω-chloroacetophenones by reaction of diazomethan

  • Niementowski Quinoline Synthesis

    Niementowski Synthesis S. v. Niementowski, Ber. 27, 1394 (1894); 28, 2809 (1895); 38, 2044 (1905); 40, 4285 (1907). Formation of γ-hydroxyquinoli

  • Niementowski Quinazoline Synthesis

    Niementowski Synthesis S. v. Niementowski, J. Prakt. Chem. [2] 51, 564 (1895). Formation of 4-oxo-3,4-dihydroquinazolines by cyclization of the reactio

  • Nicholas Reaction

    Nicholas Reaction R. F. Lockwood, K. M. Nicholas, Tetrahedron Letters 1977, 4163. The reaction of dicobalthexacarbonyl-stabilized propargyl cations with

  • Nenitzescu Reductive Acylation

    Nenitzescu Reductive Acylation C. D. Nenitzescu, E. Cioranescu, Ber. 69, 1820 (1936). ative acylation of cycloolefins with acid chlorides in the presenc

  • Nenitzescu Indole Synthesis

    Nenitzescu Synthesis C. D. Nenitzescu, Bull. Soc. Chim. Romania 11, 37 (1929). Synthesis of 5-hydroxyindole derivatives by condensation of with β

  • Nencki Reaction

    Nencki Reaction M. Nencki, N. Sieber, J. Prakt. Chem. (2) 23, 147 (1881). The ring acylation of phenols with acids in the presence of zinc chloride, or

  • Negishi Cross Coupling

    Negishi Cross Coupling E. Negishi et al., J. Org. Chem. 42, 1821 (1977). Formation of unsymmetric biaryls by cross coupling arylhalides with arylzinc re

  • Nef Synthesis

    Nef Synthesis J. U. Nef, Ann. 308, 281 (1899). Addition of sodium acetylides to aldehydes and ketones to yield acetylenic carbinols; occasionally and er

  • Nef Reaction

    Nef Reaction J. U. Nef, Ann. 280, 263 (1894). Formation of aldehydes and ketones from primary and secondary nitroalkanes, respectively, by treatment of

  • Neber Rearrangement

    Neber Rearrangement P. W. Neber, A. v. Friedolsheim, Ann. 449, 109 (1926); P. W. Neber, G. Huh, ibid. 515, 283 (1935). Formation of α-amino ketone

  • Nazarov Cyclization Reaction

    Nazarov Cyclization Reaction I. N. Nazarov et al., Izv. Akad. Nauk S.S.S.R., Otd. Khim. Nauk 1942, 200. Protic or Lewis acid-catalyzed electrocyclic rin

  • Ziegler-Natta Polymerization

    Ziegler-Natta Polymerization K. Ziegler et al., Angew. Chem. 67, 426, 541 (1955); G. Natta, ibid. 68, 393 (1956). Polymerization of vinyl monomers under

  • Nametkin Rearrangement

    Nametkin Rearrangement S. S. Nametkin, Ann. 432, 207 (1923). A special case of carbonium ion rearrangement in camphene hydrochloride derivatives involvi

  • Nagata Hydrocyanation

    Nagata Hydrocyanation W. Nagata et al., Tetrahedron Letters 1962, 461. Alkylaluminum-mediated 1,4-addition of hydrogen cyanide to α,β-unsatur

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