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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Chloro-3-Nitroanisole

Cas:10298-80-3

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Chloro-3-nitroanisole Manufacturer/High quality/Best price/In stock

Cas:10298-80-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Assay 99.9%min 99.9% Hangzhou Dingyan Chem is a leading manufacturer and supplier of che

High quality 10298-80-3 4-Chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:1 Kilogram

FOB Price: $1300.0 / 1600.0

Type:Trading Company

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com Product Name 2-Nitro-4-methoxychlorobenzene CAS No. 10298-80-3

4-Chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

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Hangzhou Think Chemical Co. Ltd

4-Chloro-3-nitroanisole CAS No.:10298-80-3 Name: 4-Chloro-3-nitroanisole Synonyms: 1-Chloro-4-methoxy-2-nitrobenzene; 2-Nitro-4-methoxychlorobenzene; 4-Chloro-3-nitroanisole Molecular Structure Molecular

High purity 4-Chloro-3-nitroanisole CAS No.:10298-80-3

Cas:10298-80-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Other

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

4-Chloro-3-Nitroanisole

Cas:10298-80-3

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

4-chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 10298-80-3 with fast shipping

Cas:10298-80-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 1-Chloro-4-methoxy-2-nitrobenzene CAS:10298-80-3 MF: C7H6ClNO3 Appearance:White Powder Storage:Store in cool and dry place, away from sun light. Package:25kg Application:Intermediates of Iguratimod Transportation:By sea or by air Port:Qingda

1-Chloro-4-methoxy-2-nitrobenzene

Cas:10298-80-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Hangzhou Sartort Biopharma Co., Ltd

Appearance:White to Amber????????powder Storage:room temperature Package:25kg/drum Application:Chemicals Transportation:Express/Sea/Air Port:any port in china

4-Chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:clear, colorless - pale yellow Storage:Store in sealed conta

4-Chloro-3-nitroanisole 10298-80-3 C7H6ClNO3

Cas:10298-80-3

Min.Order:100 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-chloro-4-methoxy-2-nitro- 10298-80-3

Cas:10298-80-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

4-Chloro-3-nitroanisole CAS:10298-80-3 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

4-Chloro-3-nitroanisole CAS:10298-80-3

Cas:10298-80-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-chloro-4-methoxy-2-nitro-

Cas:10298-80-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

4-Chloro-3-nitroanisole CAS:10298-80-3

Cas:10298-80-3

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1-chloro-4-methoxy-2-nitro-

Cas:10298-80-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Appearance:white powder Storage:Store in a cool,dry place and keep away from direct strong light Package:packaged in foil bags or tins Application:Use only for laboratory research Transportation:Sea,Air,DHL/TNT/FEdex/UPS/EMS Por

4-Chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:10 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-Chloro-3-Nitro Anisole

Cas:10298-80-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

4-Chloro-3-nitroanisole hot salesAppearance:Showed in specifications Storage:Keep in dry Package:according to customers' requirements Application:industry use Transportation:By air(EMS or EUB or FedEx or TNT ect...) or by sea(FOB or CIF or CNF ect...

4-Chloro-3-nitroanisole hot sales

Cas:10298-80-3

Min.Order:1 Gram

Negotiable

Type:Other

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:Slight yellow crystalline powder Storage:In Room Temperature Package:1kg/bag,or as your request Application:For medicine , pesticide intermediates Transportation:as your request Port

4-Chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Siwei Development Group Ltd.

Product name: 4-Chloro-3-Nitroanisole CAS No.:10298-80-3 Molecule Formula:C7H6ClNO3 Molecule Weight:187.58 Purity: 99.0% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING

Best Quality 4-Chloro-3-Nitroanisole

Cas:10298-80-3

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

4-CHLORO-3-NITROANISOLE,98%

Cas:10298-80-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 4-Chloro-3-nitroanisole Synonyms: 2-Nitro-4-methoxychlorobenzene;2-CHLORO-5-METHOXYNITROBENZENE;4-CHLORO-3-NITROANISOLE;1-CHLORO-4-METHOXY-2-NITROBENZENE;4-chloro-3-nitro-anisol;4-Chloro-3-Nitroanisole98%(Gc);Benzene, 1-chloro-4-m

4-Chloro-3-nitroanisole 10298-80-3 C7H6ClNO3

Cas:10298-80-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

Appearance:powder or granule ( refer to COA) Application:Librium, Valium

Factory Supply 4-Chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:0

Negotiable

Type:Other

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-Chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

10298-80-3 CAS NO.10298-80-3

Cas:10298-80-3

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Hangzhou Zhongqi chem Co.,Ltd.

Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service and h

Benzene,1-chloro-4-methoxy-2-nitro-

Cas:10298-80-3

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

4-Chloro-3-nitroanisole

Cas:10298-80-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Synthetic route

4-methoxy-2-nitroaniline
96-96-8

4-methoxy-2-nitroaniline

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

Conditions
ConditionsYield
Stage #1: 4-methoxy-2-nitroaniline With hydrogenchloride; sodium nitrite In water; acetonitrile at 20℃; for 0.25h;
Stage #2: With copper(l) chloride In water; acetonitrile at 60℃; for 3h;
99%
With hydrogenchloride; copper(l) chloride; cobalt(II) chloride; palladium dichloride; sodium nitrite In water at 0 - 5℃; Catalytic behavior; Reagent/catalyst; Concentration;96%
Stage #1: 4-methoxy-2-nitroaniline With potassium hydrogensulfate; phosphoric acid In water at 8 - 9℃; for 0.833333h;
Stage #2: With potassium chloride; tin(II) bromide In water at 19 - 70℃; Temperature;
93%
3-nitro-4-chlorophenol
610-78-6

3-nitro-4-chlorophenol

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

Conditions
ConditionsYield
With magnesium oxide In N,N-dimethyl-formamide at 170℃; for 0.5h; Microwave irradiation; Green chemistry;84%
2-nitro-4-methoxybenzoic acid
33844-21-2

2-nitro-4-methoxybenzoic acid

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

Conditions
ConditionsYield
With 2.9-dimethyl-1,10-phenanthroline; oxygen; copper (I) acetate; silver sulfate; sodium chloride In dimethyl sulfoxide at 160℃; for 24h; Schlenk technique;53%
With 2.9-dimethyl-1,10-phenanthroline; oxygen; copper diacetate; silver sulfate; sodium chloride In dimethyl sulfoxide at 160℃; under 760.051 Torr; for 20h; Schlenk technique;53%
With copper(l) iodide; oxygen; copper(l) chloride In dimethyl sulfoxide at 160℃; under 760.051 Torr; for 30h; Schlenk technique; Sealed tube;46%
3-nitro-4-chlorobenzenediazonium cation
30930-62-2

3-nitro-4-chlorobenzenediazonium cation

sodium methylate
124-41-4

sodium methylate

A

2-Nitroanisole
91-23-6

2-Nitroanisole

B

2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

C

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

Conditions
ConditionsYield
for 16h; Mechanism; Ambient temperature; also reaction with sodium deuteriomethoxide;
potassium methyl sulfate
562-54-9

potassium methyl sulfate

potassium-<4-chloro-3-nitro-phenolate>

potassium-<4-chloro-3-nitro-phenolate>

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

Conditions
ConditionsYield
With glycerol at 170 - 190℃;
3-nitroanisole
555-03-3

3-nitroanisole

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

Conditions
ConditionsYield
With Oxone; ammonium chloride In acetonitrile at 20℃; for 48h;31 % Chromat.
2-nitro-4-methoxybenzoic acid
33844-21-2

2-nitro-4-methoxybenzoic acid

A

4-bromo-3-nitroanizole
5344-78-5

4-bromo-3-nitroanizole

B

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

Conditions
ConditionsYield
With Bromotrichloromethane; trichloroisocyanuric acid; bromine at 10 - 120℃; for 18h; Photolysis;
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

2-[(2-amino-4-methoxyphenyl)disulfanyl]-4-methoxyaniline
36210-53-4

2-[(2-amino-4-methoxyphenyl)disulfanyl]-4-methoxyaniline

Conditions
ConditionsYield
With sodiumsulfide nonahydrate In water at 100℃;100%
carbon disulfide
75-15-0

carbon disulfide

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

5-methoxybenzo[d]thiazole-2-thiol
55690-60-3

5-methoxybenzo[d]thiazole-2-thiol

Conditions
ConditionsYield
With sodium sulfide at 80℃; for 10h; Temperature; Microwave irradiation;99%
Stage #1: carbon disulfide; 2-chloro-5-methoxynitrobenzene for 5h; Reflux;
Stage #2: With hydrogenchloride In water
93.1%
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

2-amino-4-methoxybenzenethiol
14482-32-7

2-amino-4-methoxybenzenethiol

Conditions
ConditionsYield
Stage #1: 2-chloro-5-methoxynitrobenzene With sodium sulfide In water for 20h; Heating / reflux;
Stage #2: With hydrogenchloride In water at 20℃; pH=7;
98.9%
(i) Na2S, sulfur, (ii) Sn, aq. HCl; Multistep reaction;
Multi-step reaction with 2 steps
1: ethanol; Na2S2
2: tin; aq.-ethanolic HCl
View Scheme
With sodium sulfide; water for 24h; Reflux;
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

2-chloro-5-methoxyaniline
2401-24-3

2-chloro-5-methoxyaniline

Conditions
ConditionsYield
With iron; ammonium chloride In ethanol; water at 95℃; for 12h;98%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; 1,10-Phenanthroline; isopropyl alcohol; potassium hydroxide at 100℃; for 15h; Inert atmosphere; Schlenk technique;96%
With maghemite; methylhydrazine In ethanol at 60℃; for 1h; Sealed tube; Inert atmosphere; chemoselective reaction;95%
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

3-nitro-4-chlorophenol
610-78-6

3-nitro-4-chlorophenol

Conditions
ConditionsYield
With hydrogen bromide In acetic acid for 41h; Heating;96%
With acetic anhydride; acetic acid In water; ethyl acetate83.6%
With pyridine hydrochloride at 200℃;
With hydrogen bromide In acetic acid at 120℃; for 24h;
With hydrogen bromide In acetic acid for 41h; Heating;
phenylmethanethiol
100-53-8

phenylmethanethiol

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

2-Nitro-4-methoxy-1-benzylmercapto-benzol
22057-42-7

2-Nitro-4-methoxy-1-benzylmercapto-benzol

Conditions
ConditionsYield
With sodium carbonate In ethanol; water for 5h; Heating;96%
With potassium hydroxide
allyltributylstanane
24850-33-7

allyltributylstanane

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

1-allyl-4-methoxy-2-nitrobenzene
848492-86-4

1-allyl-4-methoxy-2-nitrobenzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride In 1,2-dichloro-ethane at 120℃; for 0.75h; Microwave irradiation;95%
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

5-methoxybenzo[d]thiazole-2-thiol
55690-60-3

5-methoxybenzo[d]thiazole-2-thiol

Conditions
ConditionsYield
Stage #1: 2-chloro-5-methoxynitrobenzene With carbon disulfide for 5h; Reflux;
Stage #2: With hydrogenchloride In water
93.1%
diethylamine
109-89-7

diethylamine

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

N-ethyl-(4-methoxy-2-nitrophenyl)amine
3360-85-8

N-ethyl-(4-methoxy-2-nitrophenyl)amine

Conditions
ConditionsYield
In water at 105℃; for 24h;92%
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

(6-methoxy-2-naphthalene)boronic acid
156641-98-4

(6-methoxy-2-naphthalene)boronic acid

2-methoxy-6-(4-methoxy-2-nitrophenyl)naphthalene

2-methoxy-6-(4-methoxy-2-nitrophenyl)naphthalene

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene for 5h; Suzuki Coupling; Inert atmosphere; Reflux;91%
ethylamine
75-04-7

ethylamine

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

N-ethyl-(4-methoxy-2-nitrophenyl)amine
3360-85-8

N-ethyl-(4-methoxy-2-nitrophenyl)amine

Conditions
ConditionsYield
In water at 100℃; for 12h;90%
In ethanol
hexan-1-amine
111-26-2

hexan-1-amine

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

N-hexyl-4-methoxy-2-nitroaniline
117703-19-2

N-hexyl-4-methoxy-2-nitroaniline

Conditions
ConditionsYield
In water at 75℃; for 12h;90%
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

6-methoxy-1H-benzo[d][1,2,3]triazol-1-ol
26198-31-2

6-methoxy-1H-benzo[d][1,2,3]triazol-1-ol

Conditions
ConditionsYield
With hydrazine hydrate In n-heptan1ol at 110 - 120℃; for 5h;90%
With hydrazine hydrate In ethanol at 20℃; for 20h; Reflux;
carbamic acid 2-trimethylsilylethyl ester
3124-37-6

carbamic acid 2-trimethylsilylethyl ester

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

(4-methoxy-2-nitrophenyl)carbamic acid 2-trimethylsilanylethyl ester
1257310-77-2

(4-methoxy-2-nitrophenyl)carbamic acid 2-trimethylsilanylethyl ester

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 120℃; for 15h; Inert atmosphere;88%
ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

ethyl 2-cyano-2-(4-methoxy-2-nitrophenyl)acetate
65547-98-0

ethyl 2-cyano-2-(4-methoxy-2-nitrophenyl)acetate

Conditions
ConditionsYield
Stage #1: ethyl 2-cyanoacetate With sodium hydride In N,N-dimethyl-formamide; mineral oil at 20℃; for 1h;
Stage #2: 2-chloro-5-methoxynitrobenzene In N,N-dimethyl-formamide; mineral oil at 70℃;
87%
With sodium hydride In N,N-dimethyl-formamide at 100℃;62%
Stage #1: ethyl 2-cyanoacetate With sodium hydride In dimethyl sulfoxide; mineral oil at 0 - 20℃; for 1.5h;
Stage #2: 2-chloro-5-methoxynitrobenzene In dimethyl sulfoxide; mineral oil at 90℃; for 16h;
32%
With sodium hydride In dimethyl sulfoxide at 5 - 90℃; for 8h;
With sodium hydride; cesium fluoride In N,N-dimethyl-formamide at 70℃; for 18h;
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

phenol
108-95-2

phenol

4-methoxy-2-nitro-1-phenoxybenzene
84594-95-6

4-methoxy-2-nitro-1-phenoxybenzene

Conditions
ConditionsYield
With potassium tert-butylate In N,N-dimethyl-formamide at 110℃; for 4h; Substitution;84%
With potassium carbonate In N,N-dimethyl-formamide at 100℃; Inert atmosphere;38%
benzyl chloride
100-44-7

benzyl chloride

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

5-methoxy-2-phenyl-1,3-benzothiazole

5-methoxy-2-phenyl-1,3-benzothiazole

Conditions
ConditionsYield
With N-methylcyclohexylamine; sulfur at 110℃; for 24h; Sealed tube; Inert atmosphere;83%
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

benzylamine
100-46-9

benzylamine

5-methoxy-2-phenyl-1,3-benzothiazole

5-methoxy-2-phenyl-1,3-benzothiazole

Conditions
ConditionsYield
With sulfur In neat (no solvent) at 130℃; for 24h; Sealed tube; Inert atmosphere;80%
With sulfur In pyridine at 100℃; for 16h; Inert atmosphere;66%
benzoyl chloride
98-88-4

benzoyl chloride

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

N-(2-chloro-5-methoxyphenyl)benzamide

N-(2-chloro-5-methoxyphenyl)benzamide

Conditions
ConditionsYield
With water; iron at 60℃; for 36h;78%
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

para-methylbenzylamine
104-84-7

para-methylbenzylamine

5-methoxy-2-(4′-tolyl)benzo[d]thiazole
101078-50-6

5-methoxy-2-(4′-tolyl)benzo[d]thiazole

Conditions
ConditionsYield
With sulfur In neat (no solvent) at 130℃; for 24h; Sealed tube; Inert atmosphere;76%
acetophenone
98-86-2

acetophenone

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

(5-methoxybenzothiazol-2-yl)(phenyl)methanone

(5-methoxybenzothiazol-2-yl)(phenyl)methanone

Conditions
ConditionsYield
With 4-methyl-morpholine; sulfur at 120℃; for 16h; Inert atmosphere;76%
2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

diethyl malonate
105-53-3

diethyl malonate

diethyl 2-(4-methoxy-2-nitrophenyl)malonate
10565-15-8

diethyl 2-(4-methoxy-2-nitrophenyl)malonate

Conditions
ConditionsYield
Stage #1: diethyl malonate With sodium hydride In N,N-dimethyl-formamide at 20 - 100℃; for 0.666667h;
Stage #2: 2-chloro-5-methoxynitrobenzene In N,N-dimethyl-formamide at 20 - 100℃; for 1.5h;
75%
Stage #1: diethyl malonate With sodium hydride In dimethyl sulfoxide at 0 - 83℃; for 3h;
Stage #2: 2-chloro-5-methoxynitrobenzene In dimethyl sulfoxide at 50 - 106℃; for 55h;
34%
Stage #1: diethyl malonate With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.333333h;
Stage #2: 2-chloro-5-methoxynitrobenzene With cesium fluoride In N,N-dimethyl-formamide at 20 - 105℃;
28%
With sodium hydride 1) DMSO, 100 deg C, 40 min, 2a) RT, 30 min, 2b) 100 deg C, 1 h; Yield given. Multistep reaction;
4-(aminomethyl)pyridine
3731-53-1

4-(aminomethyl)pyridine

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

5-methoxy-2-(pyridin-4-yl)benzo[d]thiazole
51643-53-9

5-methoxy-2-(pyridin-4-yl)benzo[d]thiazole

Conditions
ConditionsYield
With sulfur In neat (no solvent) at 130℃; for 24h; Sealed tube; Inert atmosphere;75%
2-(trimethylsilyl)ethanesulfonamide
125486-96-6

2-(trimethylsilyl)ethanesulfonamide

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

2-(trimethylsilanyl)ethanesulfonic acid (4-methoxy-2-nitrophenyl)amide
1045771-65-0

2-(trimethylsilanyl)ethanesulfonic acid (4-methoxy-2-nitrophenyl)amide

Conditions
ConditionsYield
With caesium carbonate; palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 120℃; for 15h;74%
sodium diethylmalonate
996-82-7, 34727-00-9, 73177-21-6

sodium diethylmalonate

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

diethyl 2-(4-methoxy-2-nitrophenyl)malonate
10565-15-8

diethyl 2-(4-methoxy-2-nitrophenyl)malonate

Conditions
ConditionsYield
In N,N-dimethyl-formamide Heating;70%
1,2,3,4-tetrahydroisoquinoline
91-21-4

1,2,3,4-tetrahydroisoquinoline

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

10-methoxy-5,6-dihydrobenzo[4,5]imidazo[2,1-a]isoquinoline

10-methoxy-5,6-dihydrobenzo[4,5]imidazo[2,1-a]isoquinoline

Conditions
ConditionsYield
at 130℃; for 24h; Inert atmosphere;70%
1,3-dihydro-imidazole-2-thione
872-35-5

1,3-dihydro-imidazole-2-thione

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

2-(4-methoxy-2-nitrophenylthio)imidazole
88251-67-6

2-(4-methoxy-2-nitrophenylthio)imidazole

Conditions
ConditionsYield
With sodium ethanolate In ethanol for 4h; Heating;68%
4-methoxy-phenol
150-76-5

4-methoxy-phenol

2-chloro-5-methoxynitrobenzene
10298-80-3

2-chloro-5-methoxynitrobenzene

4-methoxy-1-(4-methoxyphenoxy)-2-nitrobenzene

4-methoxy-1-(4-methoxyphenoxy)-2-nitrobenzene

Conditions
ConditionsYield
Stage #1: 4-methoxy-phenol With sodium hydride In N,N-dimethyl-formamide; Petroleum ether at 0℃; for 0.5h;
Stage #2: 2-chloro-5-methoxynitrobenzene In N,N-dimethyl-formamide; Petroleum ether at 95℃; for 48h;
67%
With potassium tert-butylate In N,N-dimethyl-formamide at 110℃; for 4h; Substitution;
With sodium hydride In N,N-dimethyl-formamide at 20 - 95℃; for 72h;

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