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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis according to the contract research and development services for the fine chemicals, ph

3-Methylbenzenepropanol

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

3-M-TOLYL-PROPAN-1-OL CAS:111171-94-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

3-M-TOLYL-PROPAN-1-OL CAS:111171-94-9

Cas:111171-94-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzenepropanol,3-methyl-

Cas:111171-94-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzenepropanol,3-methyl-

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis: Trading(Raw Mater

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:0 Metric Ton

FOB Price: $18.0 / 20.0

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzenepropanol,3-methyl-

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

3-(3-methylphenyl)propan-1-ol

Cas:111171-94-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

We produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp

Benzenepropanol,3-methyl-

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Benzenepropanol,3-methyl-

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

Benzenepropanol, 3-Methyl-

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Benzenepropanol,3-methyl-

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing HuaNuo Bio-Pharmacuetical Co.,Ltd

Independent research and development of impurities, familiar with the market and impurity characteristics; We can ship out on the same day if the products are in stock; Focus on impurity development of new products in the market; Expert in customizi

Cinacalcet Impurity 1

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzenepropanol,3-methyl-

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

3-M-TOLYL-PROPAN-1-OL Application:3-M-TOLYL-PROPAN-1-OL

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Other

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as primary a

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

111171-94-9

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

3-M-TOLYL-PROPAN-1-OLAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Newgreat Chemical Co., Ltd

Wuhan Xinweiye Chemical Co., Ltd. is mainly engaged in the process development and production of customized synthesis and pharmaceutical intermediates. We have professional researchers in organic synthesis, analytical chemistry and production process

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

3-M-TOLYL-PROPAN-1-OLAppearance:solid or liquid Storage:Protected from light, stored hermetically and in a dry place Package:1g,5g,10g...1kg,5kg...more Application:Intermediate Transportation:By express (Door to door) such as FEDEX, DHL, EMS for smal

3-M-TOLYL-PROPAN-1-OL

Cas:111171-94-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

3-(3-methylphenyl)propanoic acid
3751-48-2

3-(3-methylphenyl)propanoic acid

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; Reflux; Inert atmosphere;99%
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 2h; Inert atmosphere;76%
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 1h; Reflux;0.84 g
With dimethylsulfide borane complex In tetrahydrofuran at 0 - 20℃; for 18h;
With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
3-m-tolyl-acrylic acid ethyl ester
50556-03-1

3-m-tolyl-acrylic acid ethyl ester

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran for 0.333333h;92%
With pentan-1-ol; sodium
ethanol
64-17-5

ethanol

3-methylbenzyl alcohol
587-03-1

3-methylbenzyl alcohol

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; potassium tert-butylate In tetrahydrofuran at 100℃; for 24h; Inert atmosphere;83%
3-methyldihydrocinnamic acid methyl ester
29417-96-7

3-methyldihydrocinnamic acid methyl ester

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
With lithium aluminium tetrahydride In diethyl ether for 1h; Heating;
1-methyl-3-<γ-chloro-propyl>-benzene

1-methyl-3-<γ-chloro-propyl>-benzene

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
With potassium acetate; acetic acid durch Verseifen mit alkoh. Kalilauge;
oxirane
75-21-8

oxirane

3-methyl-benzyl magnesium bromide

3-methyl-benzyl magnesium bromide

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
With diethyl ether
m-tolyl aldehyde
620-23-5

m-tolyl aldehyde

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: potassium tert-butoxide / dimethylformamide / 1 h / 0 °C
1.2: 82 percent / dimethylformamide / 24 h / 20 °C
2.1: 92 percent / lithium aluminium hydride / tetrahydrofuran / 0.33 h
View Scheme
(E)-methyl 3-methylcinnamate
82444-40-4, 118315-74-5, 95416-56-1

(E)-methyl 3-methylcinnamate

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: H2 / 5percent Pd/C / methanol / 1 h / Ambient temperature
2: LiAlH4 / diethyl ether / 1 h / Heating
View Scheme
(methyloxycarbonylmethyl)triphenylphosphonium bromide
1779-58-4

(methyloxycarbonylmethyl)triphenylphosphonium bromide

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: NaOCH3 / CH2Cl2 / Ambient temperature
2: H2 / 5percent Pd/C / methanol / 1 h / Ambient temperature
3: LiAlH4 / diethyl ether / 1 h / Heating
View Scheme
ethyl 3-(3-methylphenyl)-propionate
7297-13-4

ethyl 3-(3-methylphenyl)-propionate

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
Stage #1: ethyl 3-(3-methylphenyl)-propionate With lithium aluminium tetrahydride In tetrahydrofuran at 0 - 20℃; for 1.5h;
Stage #2: With water; ammonium chloride In tetrahydrofuran
3-methylcinnamic acid
3029-79-6

3-methylcinnamic acid

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran
formaldehyd
50-00-0

formaldehyd

3-methylstyrene
100-80-1

3-methylstyrene

A

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

B

2-(3-methylphenyl)propan-1-ol

2-(3-methylphenyl)propan-1-ol

Conditions
ConditionsYield
Stage #1: formaldehyd; 3-methylstyrene With chloro(1,5-cyclooctadiene)rhodium(I) dimer; (R,R)-1,2-bis(2,5-diphenylphospholanyl)ethane In toluene at 80℃; Inert atmosphere;
Stage #2: With sodium tetrahydroborate In methanol at 0℃; Inert atmosphere;
formic acid
64-18-6

formic acid

3-methylstyrene
100-80-1

3-methylstyrene

carbon monoxide
201230-82-2

carbon monoxide

A

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

B

C11H14O2

C11H14O2

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; 1,10-Phenanthroline; triethylamine In 1,2-dichloro-ethane at 120℃; under 3750.38 - 22502.3 Torr; for 16h; Autoclave; Sealed tube;
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

3-(3-methylphenyl)propanal
95416-60-7

3-(3-methylphenyl)propanal

Conditions
ConditionsYield
With sIBX In tetrahydrofuran for 5h; Reflux;89%
With pyridinium chlorochromate In dichloromethane at 0 - 20℃; for 3h;87%
With oxalyl dichloride; dimethyl sulfoxide; triethylamine 1.) CH2Cl2, -40 deg C, 25 min, 2.) CH2Cl2, -40 deg C, 5 min; Multistep reaction;
With pyridinium chlorochromate In dichloromethane
With Dess-Martin periodane In dichloromethane at 0 - 20℃; Inert atmosphere;
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

1-Phenyl-1H-tetrazole-5-thiol
86-93-1

1-Phenyl-1H-tetrazole-5-thiol

5-(3-m-tolylpropylthio)-1-phenyl-1H-tetrazole
871095-06-6

5-(3-m-tolylpropylthio)-1-phenyl-1H-tetrazole

Conditions
ConditionsYield
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran at 0℃; for 1h; Mitsunobu reaction;83%
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

3-(5-methylcyclohexa-1,4-dien-1-yl)propan-1-ol

3-(5-methylcyclohexa-1,4-dien-1-yl)propan-1-ol

Conditions
ConditionsYield
With lithium; isopropyl alcohol In ammonia Birch Reduction; Reflux; liquid NH3;71%
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

1-iodo-3-(m-methylphenyl)propane
111171-85-8

1-iodo-3-(m-methylphenyl)propane

Conditions
ConditionsYield
With phosphorus; iodine at 145 - 150℃; for 5h; Heating;56%
With 1H-imidazole; iodine; triphenylphosphine In dichloromethane at 0℃; for 1.5h;
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

1-(3-bromopropyl)-3- methylbenzene
103324-39-6

1-(3-bromopropyl)-3- methylbenzene

Conditions
ConditionsYield
With sulfuric acid; hydrogen bromide
With N-Bromosuccinimide; triphenylphosphine In dichloromethane for 13h; Ice-cooling;
With carbon tetrabromide; triphenylphosphine In dichloromethane at 0 - 20℃; for 18h;
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

phenyl isocyanate
103-71-9

phenyl isocyanate

phenyl-carbamic acid-(3-m-tolyl-propyl ester)

phenyl-carbamic acid-(3-m-tolyl-propyl ester)

3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

5-(3-m-tolylpropylsulfonyl)-1-phenyl-1H-tetrazole
871094-99-4

5-(3-m-tolylpropylsulfonyl)-1-phenyl-1H-tetrazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 83 percent / triphenylphosphine; DEAD / tetrahydrofuran / 1 h / 0 °C
2: 91 percent / sodium hydrogen carbonate; mCPBA / CH2Cl2 / 14 h
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentanal
871095-07-7

5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentanal

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: 83 percent / triphenylphosphine; DEAD / tetrahydrofuran / 1 h / 0 °C
2.1: 91 percent / sodium hydrogen carbonate; mCPBA / CH2Cl2 / 14 h
3.1: KHMDS / 1,2-dimethoxy-ethane; toluene / 0.75 h / -60 °C
3.2: 95.4 percent / 1,2-dimethoxy-ethane; toluene / -60 - 20 °C
4.1: 85 percent / DDQ; H2O / CH2Cl2 / 0.5 h
5.1: 100 percent / oxalyl chloride; DMSO; triethylamine / CH2Cl2 / 2.5 h / -78 - 0 °C
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentan-1-ol
871095-01-1

5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentan-1-ol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: 83 percent / triphenylphosphine; DEAD / tetrahydrofuran / 1 h / 0 °C
2.1: 91 percent / sodium hydrogen carbonate; mCPBA / CH2Cl2 / 14 h
3.1: KHMDS / 1,2-dimethoxy-ethane; toluene / 0.75 h / -60 °C
3.2: 95.4 percent / 1,2-dimethoxy-ethane; toluene / -60 - 20 °C
4.1: 85 percent / DDQ; H2O / CH2Cl2 / 0.5 h
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentanoic acid
871095-02-2

5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentanoic acid

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1.1: 83 percent / triphenylphosphine; DEAD / tetrahydrofuran / 1 h / 0 °C
2.1: 91 percent / sodium hydrogen carbonate; mCPBA / CH2Cl2 / 14 h
3.1: KHMDS / 1,2-dimethoxy-ethane; toluene / 0.75 h / -60 °C
3.2: 95.4 percent / 1,2-dimethoxy-ethane; toluene / -60 - 20 °C
4.1: 85 percent / DDQ; H2O / CH2Cl2 / 0.5 h
5.1: 100 percent / oxalyl chloride; DMSO; triethylamine / CH2Cl2 / 2.5 h / -78 - 0 °C
6.1: 99 percent / 2,3-dimethyl-2-butene; sodium chlorite; potassium dihydrogen phosphate / 2-methyl-propan-2-ol; H2O / 0 - 20 °C
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

tert-butyl((1R,2R,3aS,6aS)-5-(5-(4-methoxybenzyloxy)pentyl)-1-((E)-4-m-tolylbut-1-enyl)-1,2,3,3a,6,6a-hexahydropentalen-2-yloxy)dimethylsilane
871095-00-0

tert-butyl((1R,2R,3aS,6aS)-5-(5-(4-methoxybenzyloxy)pentyl)-1-((E)-4-m-tolylbut-1-enyl)-1,2,3,3a,6,6a-hexahydropentalen-2-yloxy)dimethylsilane

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: 83 percent / triphenylphosphine; DEAD / tetrahydrofuran / 1 h / 0 °C
2.1: 91 percent / sodium hydrogen carbonate; mCPBA / CH2Cl2 / 14 h
3.1: KHMDS / 1,2-dimethoxy-ethane; toluene / 0.75 h / -60 °C
3.2: 95.4 percent / 1,2-dimethoxy-ethane; toluene / -60 - 20 °C
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

5-((3aS,5R,6R,6aS)-5-hydroxy-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentanoic acid

5-((3aS,5R,6R,6aS)-5-hydroxy-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentanoic acid

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1.1: 83 percent / triphenylphosphine; DEAD / tetrahydrofuran / 1 h / 0 °C
2.1: 91 percent / sodium hydrogen carbonate; mCPBA / CH2Cl2 / 14 h
3.1: KHMDS / 1,2-dimethoxy-ethane; toluene / 0.75 h / -60 °C
3.2: 95.4 percent / 1,2-dimethoxy-ethane; toluene / -60 - 20 °C
4.1: 85 percent / DDQ; H2O / CH2Cl2 / 0.5 h
5.1: 100 percent / oxalyl chloride; DMSO; triethylamine / CH2Cl2 / 2.5 h / -78 - 0 °C
6.1: 99 percent / 2,3-dimethyl-2-butene; sodium chlorite; potassium dihydrogen phosphate / 2-methyl-propan-2-ol; H2O / 0 - 20 °C
7.1: 96 percent / TBAF / tetrahydrofuran / 96 h / 20 °C
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

(3S,4S)-3-Hydroxymethyl-4-(2-m-tolyl-ethyl)-oxetan-2-one

(3S,4S)-3-Hydroxymethyl-4-(2-m-tolyl-ethyl)-oxetan-2-one

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: 1.) (COCl)2, DMSO, 2.) Et3N / 1.) CH2Cl2, -40 deg C, 25 min, 2.) CH2Cl2, -40 deg C, 5 min
2: 1.) LDA / 1.) THF, hexane, from -78 to -20 deg C, 20 min, 2.) THF, hexane, 50 min
3: 4-dimethylaminopyridine, Et3N / CH2Cl2 / Ambient temperature
4: 1N KOH / ethanol / Ambient temperature
5: p-TsCl, pyridine / 0 - 5 °C
6: CF3COOH / butan-1-ol / 2 h / Ambient temperature
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

3-Hydroxy-2-hydroxymethyl-5-m-tolyl-pentanoic acid ethyl ester

3-Hydroxy-2-hydroxymethyl-5-m-tolyl-pentanoic acid ethyl ester

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 1.) (COCl)2, DMSO, 2.) Et3N / 1.) CH2Cl2, -40 deg C, 25 min, 2.) CH2Cl2, -40 deg C, 5 min
2: 1.) LDA / 1.) THF, hexane, from -78 to -20 deg C, 20 min, 2.) THF, hexane, 50 min
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

(3S,4S)-4-(2-m-Tolyl-ethyl)-3-trityloxymethyl-oxetan-2-one

(3S,4S)-4-(2-m-Tolyl-ethyl)-3-trityloxymethyl-oxetan-2-one

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 1.) (COCl)2, DMSO, 2.) Et3N / 1.) CH2Cl2, -40 deg C, 25 min, 2.) CH2Cl2, -40 deg C, 5 min
2: 1.) LDA / 1.) THF, hexane, from -78 to -20 deg C, 20 min, 2.) THF, hexane, 50 min
3: 4-dimethylaminopyridine, Et3N / CH2Cl2 / Ambient temperature
4: 1N KOH / ethanol / Ambient temperature
5: p-TsCl, pyridine / 0 - 5 °C
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

3-Hydroxy-5-m-tolyl-2-trityloxymethyl-pentanoic acid

3-Hydroxy-5-m-tolyl-2-trityloxymethyl-pentanoic acid

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 1.) (COCl)2, DMSO, 2.) Et3N / 1.) CH2Cl2, -40 deg C, 25 min, 2.) CH2Cl2, -40 deg C, 5 min
2: 1.) LDA / 1.) THF, hexane, from -78 to -20 deg C, 20 min, 2.) THF, hexane, 50 min
3: 4-dimethylaminopyridine, Et3N / CH2Cl2 / Ambient temperature
4: 1N KOH / ethanol / Ambient temperature
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

3-Hydroxy-5-m-tolyl-2-trityloxymethyl-pentanoic acid ethyl ester

3-Hydroxy-5-m-tolyl-2-trityloxymethyl-pentanoic acid ethyl ester

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 1.) (COCl)2, DMSO, 2.) Et3N / 1.) CH2Cl2, -40 deg C, 25 min, 2.) CH2Cl2, -40 deg C, 5 min
2: 1.) LDA / 1.) THF, hexane, from -78 to -20 deg C, 20 min, 2.) THF, hexane, 50 min
3: 4-dimethylaminopyridine, Et3N / CH2Cl2 / Ambient temperature
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

3-Hydroxy-5-m-tolyl-2-trityloxymethyl-pentanoic acid ethyl ester

3-Hydroxy-5-m-tolyl-2-trityloxymethyl-pentanoic acid ethyl ester

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 1.) (COCl)2, DMSO, 2.) Et3N / 1.) CH2Cl2, -40 deg C, 25 min, 2.) CH2Cl2, -40 deg C, 5 min
2: 1.) LDA / 1.) THF, hexane, from -78 to -20 deg C, 20 min, 2.) THF, hexane, 50 min
3: 4-dimethylaminopyridine, Et3N / CH2Cl2 / Ambient temperature
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

6-methyl-3,4-dihydronaphthalen-1(2H)-one
51015-29-3

6-methyl-3,4-dihydronaphthalen-1(2H)-one

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 56 percent / red P, iodine / 5 h / 145 - 150 °C / Heating
2: 42 percent / BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / 1.) 0 deg C, 30 min; 2.) 2 h, room temp.
3: 92 percent / AgOTf / CH2Cl2 / 20 h / Ambient temperature
View Scheme
3-(3-methylphenyl)propan-1-ol
111171-94-9

3-(3-methylphenyl)propan-1-ol

4-(m-methylphenyl)-1,1-bis(phenylthio)-1-butene
111171-89-2

4-(m-methylphenyl)-1,1-bis(phenylthio)-1-butene

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 56 percent / red P, iodine / 5 h / 145 - 150 °C / Heating
2: 42 percent / BuLi / tetrahydrofuran; hexamethylphosphoric acid triamide / 1.) 0 deg C, 30 min; 2.) 2 h, room temp.
3: 30 percent / Cu(CH3CN)4BF4 / benzene / 1 h / 70 °C
View Scheme

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