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inquiryb-Caryophyllene oxide cas 1139-30-6Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express
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Methyltriphenylphosphonium bromide
(1R,4R,6R,10S)-4,12,12-trimethyl-5-oxatricyclo[8.2.0.04,6]dodcan-9-one
caryophyllene oxide
Conditions | Yield |
---|---|
Stage #1: Methyltriphenylphosphonium bromide With n-butyllithium In tetrahydrofuran at -78 - 0℃; for 0.166667h; Stage #2: (1R,4R,6R,10S)-4,12,12-trimethyl-5-oxatricyclo[8.2.0.04,6]dodcan-9-one In tetrahydrofuran at -78 - 20℃; for 24h; | 74% |
Conditions | Yield |
---|---|
With 4-methyloxetan-2-one; CpLIP2 Y179F (ipase/acyltransferase) from Candida parapsilosis; dihydrogen peroxide In aq. phosphate buffer; water at 20℃; for 24h; pH=6.5; Reagent/catalyst; Enzymatic reaction; | 67% |
With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; for 2h; | 66% |
With peracetic acid; sodium acetate In dichloromethane | |
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃; for 0.5h; | 75 % Chromat. |
Conditions | Yield |
---|---|
With chloroform |
Conditions | Yield |
---|---|
With diethyl ether |
β-caryophyllene
A
(1R,4R,5R,9S,11R)-4,5-epoxy-12-nor-8(14)-caryophyllene-11-ol
B
(1R,4R,5R,9S,11R)-4,5-epoxy-caryophyll-8(14)-en-12-oic acid
C
15-hydroxycaryophyllene oxide
D
caryophyllene oxide
Conditions | Yield |
---|---|
for 72h; Diplodia gossypina ATCC 10936; Further byproducts given; | A 220 mg B 900 mg C 300 mg D 65 mg |
β-caryophyllene
A
caryophyllene oxide
B
(5S,6S)-5,6-epoxy-5,6-dihydrocaryophyllene
Conditions | Yield |
---|---|
With peracetic acid; sodium acetate In dichloromethane at 0℃; Yield given. Yields of byproduct given; | |
With 3-chloro-benzenecarboperoxoic acid In dichloromethane for 2h; Title compound not separated from byproducts; | A 81 % Spectr. B 19 % Spectr. |
With peracetic acid; sodium acetate In dichloromethane at 0℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
β-caryophyllene
A
caryophyllene oxide
B
(2R,5R,6R)-2,12:5,6-diepoxycaryophyllane
C
(1R,4R,6R,9S,10S)-4,12,12-trimethylspiro(5-oxatricyclo[8.2.0.04,6]dodecane-9,2'-oxirane)
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0℃; for 0.5h; Product distribution; effect of stoichiometry, temperature, reaction time; | A 52 % Chromat. B 21 % Chromat. C 21 % Chromat. |
5,6-epoxy-2-hydroxymethyl-6,10,10-trimethyl-bicyclo[7.2.0]undecan-2-ol
caryophyllene oxide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: sodium periodate / water; methanol / 4.33 h / 20 °C / Inert atmosphere 2.1: n-butyllithium / tetrahydrofuran / 0.17 h / -78 - 0 °C 2.2: 24 h / -78 - 20 °C View Scheme |
caryophyllene oxide
1,5,5,8-tetramethyl-[1R-(1R*,3E,7E,11R*)]-12-oxabicyclo[9.1.0]dodeca-3,7-diene
Conditions | Yield |
---|---|
With phenylsilane In benzene for 2h; | 100% |
With (+/-)-trans-Co(III)-salen-Cl; phenylsilane In benzene for 2h; | 100% |
With C32H46ClCoN2O2; phenylsilane In benzene at 22℃; for 5h; Inert atmosphere; | 95% |
caryophyllene oxide
Conditions | Yield |
---|---|
With (+/-)-trans-Co(III)-salen-Cl; phenylsilane In benzene for 2h; | 100% |
caryophyllene oxide
(1R,4R,6R,10S)-4,12,12-trimethyl-5-oxatricyclo[8.2.0.04,6]dodcan-9-one
Conditions | Yield |
---|---|
Stage #1: caryophyllene oxide With ozone In dichloromethane at -78℃; Stage #2: With acetic acid; zinc In dichloromethane; water at 20℃; for 18h; Inert atmosphere; | 98% |
With ruthenium trichloride; sodium periodate In water; ethyl acetate; acetonitrile for 6h; | 61% |
With ruthenium trichloride; sodium periodate; water In ethyl acetate; acetonitrile for 6h; | 61% |
6-(trimethylsilyl)hex-5-yn-1-yl 2-cyano-2-diazoacetate
caryophyllene oxide
Conditions | Yield |
---|---|
With Rh2(esp)2 In dichloromethane at 22℃; for 4h; Inert atmosphere; diastereoselective reaction; | 94% |
caryophyllene oxide
1R,5S,9S-11,11-dimethyl-4,8-bismethylenebicyclo<7.2.0>undecan-5-ol
Conditions | Yield |
---|---|
With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane Heating; | 90% |
With n-butyllithium In diethyl ether | |
With ethenetetracarbonitrile; lithium bromide In acetone | |
With ethenetetracarbonitrile; lithium bromide In acetone |
caryophyllene oxide
Conditions | Yield |
---|---|
Stage #1: caryophyllene oxide With 9-bora-bicyclo[3.3.1]nonane In tetrahydrofuran for 8h; Inert atmosphere; Cooling with ice; Stage #2: With dihydrogen peroxide; sodium hydroxide In tetrahydrofuran at 20℃; for 2h; | 90% |
Conditions | Yield |
---|---|
With silica gel regioselective reaction; | 89% |
caryophyllene oxide
5,6-epoxy-2-hydroxymethyl-6,10,10-trimethyl-bicyclo[7.2.0]undecan-2-ol
Conditions | Yield |
---|---|
With osmium(VIII) oxide; 4-methylmorpholine N-oxide In water; tert-butyl alcohol at 20℃; for 70h; | 82% |
Conditions | Yield |
---|---|
With formic acid; tributyl-amine; tris[2-phenylpyridinato-C2,N]iridium(III) In acetonitrile at 45℃; for 19h; Inert atmosphere; Irradiation; Sealed tube; diastereoselective reaction; | 71% |
caryophyllene oxide
A
(1R,2S,5R,8S,9R)-1,4,4,8-tetramethyltricyclo[6.3.0.02,5]undecan-9-ol
B
(1S,2S,5R,8R,9R)-1,4,4,8-tetramethyltricyclo[6.3.0.02,5]undecan-9-ol
Conditions | Yield |
---|---|
With 2,4,6-trimethyl-pyridine; manganese; chloro-trimethyl-silane; bis(cyclopentadienyl)titanium dichloride In tetrahydrofuran at 20℃; for 0.666667h; | A 65% B 30% |
caryophyllene oxide
2-methylpropan-2-thiol
A
clovanediol
C
4,10,10-trimethyl-7-methylene-1β,8α-bicyclo[6.2.0]decene-4-carboxaldehyde
Conditions | Yield |
---|---|
With zinc(II) chloride In dichloromethane Reflux; | A 6% B 63% C 7% |
Conditions | Yield |
---|---|
With ethenetetracarbonitrile at 25℃; | 62% |
caryophyllene oxide
4,9,12,12-tetramethyl-5-oxatricyclo[8.2.0.04,6]dodecan-9-ol
Conditions | Yield |
---|---|
With iron(III)-acetylacetonate; methyl 4-nitrobenzenesulfonate; phenylsilane; sodium hydrogencarbonate In methanol at 0 - 20℃; for 12h; Schlenk technique; Inert atmosphere; diastereoselective reaction; | 62% |
caryophyllene oxide
(1R,5S,8R,9R)-4,4,8-trimethylbicyclo<6.3.1.01,5>dodeca-2-en-9-ol
Conditions | Yield |
---|---|
With bithmuth(III) triflate hydrate In dichloromethane for 0.166667h; Wagner-Meerwein rearrangement; Reflux; | 60% |
With methanol; fluorosulfonylchloride; fluorosulphonic acid 1.) -100 deg C, 2.) diethyl ether; Yield given. Multistep reaction; |
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In chloroform for 5h; Reflux; | A 21% B 25% C 51% |
caryophyllene oxide
2-methylpropan-2-thiol
A
caryophylla-2(12),6(13)-dien-5β-ol
B
clovanediol
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In dichloromethane Reflux; | A 10% B 7% C 35% D 48% |
Conditions | Yield |
---|---|
With tin(II) trifluoromethanesulfonate at 80℃; for 24h; | A 5% B 47% |
caryophyllene oxide
A
caryophylla-2(12),6(13)-dien-5β-ol
B
1R,5S,9S-11,11-dimethyl-4,8-bismethylenebicyclo<7.2.0>undecan-5-ol
Conditions | Yield |
---|---|
With ethenetetracarbonitrile In dimethyl sulfoxide for 96h; Ambient temperature; | A 46% B 19% C 2% |
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In chloroform at 20℃; for 2h; | A 46% B 13% C 26% |
caryophyllene oxide
Conditions | Yield |
---|---|
at 550℃; under 0.5 Torr; | 45% |
at 550℃; under 0.1 - 2 Torr; for 0.000277778h; Product distribution; Thermodynamic data; flash vacuum thermolysis; further stereoisomers; variation of temperature; activation energy; | 43% |
caryophyllene oxide
phenylmethanethiol
A
4α,11,11-trimethyl-8-methylene-1β,9α-bicyclo[7.2.0]undecan-5-one
B
clovanediol
Conditions | Yield |
---|---|
With zinc(II) chloride In chloroform for 5h; Reflux; | A 12% B 26% C 10% D 45% |
caryophyllene oxide
2-methylpropan-2-thiol
A
4α,11,11-trimethyl-8-methylene-1β,9α-bicyclo[7.2.0]undecan-5-one
B
clovanediol
D
4,10,10-trimethyl-7-methylene-1β,8α-bicyclo[6.2.0]decene-4-carboxaldehyde
Conditions | Yield |
---|---|
With zinc(II) chloride In dichloromethane at 20℃; Catalytic behavior; | A 8% B 21% C 44% D 7% |
Conditions | Yield |
---|---|
With ethenetetracarbonitrile at 25℃; | 43% |
methanol
caryophyllene oxide
A
caryophylla-2(12),6(13)-dien-5β-ol
B
9α-hydroxy-2β-methoxyclovane
Conditions | Yield |
---|---|
With ethenetetracarbonitrile for 24h; Ambient temperature; Further byproducts given; | A 20% B 42% C 11% D 6% |
methanol
caryophyllene oxide
A
caryophylla-2(12),6(13)-dien-5β-ol
B
9α-hydroxy-2β-methoxyclovane
Conditions | Yield |
---|---|
With ethenetetracarbonitrile for 24h; Ambient temperature; Further byproducts given; | A 20% B 42% C 3% D 6% |
caryophyllene oxide
A
caryophylla-2(12),6(13)-dien-5β-ol
B
9α-hydroxy-2β-methoxyclovane
Conditions | Yield |
---|---|
With ethenetetracarbonitrile In methanol for 24h; Ambient temperature; Further byproducts given; | A 20% B 42% C 11% D 6% |
Conditions | Yield |
---|---|
With tin(II) trifluoromethanesulfonate at 80℃; for 24h; | A 2% B 42% |
Conditions | Yield |
---|---|
With tin(II) trifluoromethanesulfonate at 80℃; for 24h; | 39% |
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