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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. As a leading manufacturer and supplier of chemicals in China, Day

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Kilogram

FOB Price: $4.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Kilogram

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Wuhan Fortuna Chemical Co.,Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; ...... Appearance:Off-white powder Storage:0-6°C Package:1kg/foil bag; 25kg/dru

Good quality 4-tert-Butylphenylboronic acid CAS 123324-71-0 with reasonable price

Cas:123324-71-0

Min.Order:1 Kilogram

FOB Price: $400.0 / 500.0

Type:Trading Company

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Kilogram

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Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 123324-71-0 4-tert-Butylphenylboronicacid Manufacturer

Cas:123324-71-0

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-tert-Butylbenzeneboronic acid

Cas:123324-71-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

4-tert-Butylphenylboronic acid Basic information Product Name: 4-tert-Butylphenylboronic acid Synonyms: AKOS BRN-0058;4-T-BUTYLPHENYLBORONIC ACID;4-TERT-BUTYLBENZENEBORONIC ACID;4-TERT-B

123324-71-0 4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

4-Tert-Butylphenylboronic Acid CAS 123324-71-0

Cas:123324-71-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 123324-71-0 with best quality

Cas:123324-71-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 4-tert-Butylphenylboronic acid CAS:123324-71-0 MF: C7H7BO4 Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg Application:OLED organic electroluminescence materials Transportation:By sea or by air

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

4-tert-Butylphenylboronic acid 123324-71-0

Cas:123324-71-0

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

Pharmaceutical Intermediate, 4-tert-Butylphenylboronic acid CAS:123324-71-0

Cas:123324-71-0

Min.Order:1 Kilogram

FOB Price: $41.9 / 48.2

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

4-tert-Butylphenylboronic acid CAS: 123324-71-0 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality

4-tert-Butylphenylboronic acid CAS: 123324-71-0

Cas:123324-71-0

Min.Order:1 Gram

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Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Kilogram

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Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

4-tert-Butylphenylboronic acid supplier in China CAS NO.123324-71-0

Cas:123324-71-0

Min.Order:10 Gram

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Type:Trading Company

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/44.html Product Name 4-tert-Butylphenylboronic acid CAS No. 123324-71-0

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Gram

FOB Price: $52.0

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:0

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Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

4-Tert-Butylphenylboronic Acid

Cas:123324-71-0

Min.Order:0

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:0 Metric Ton

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Hangzhou Lingrui Chemical Co.,Ltd.

our strengths: 1: Fast and guaranteed shipment (TNT;EMS;FEDEX;DHL;UPS;EUB, special line) 2: Various payment items accepted (Btc; MoneyGram; WU) 3: Valued package (Paraffin coating; Double aluminum foil bag; Vacuum packaging) 4: Efficient delivery

4-tert-Butylphenylboronic acid manufacturer

Cas:123324-71-0

Min.Order:1 Gram

Negotiable

Type:Other

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-tert-Butylbenzeneboronic acid

Cas:123324-71-0

Min.Order:0

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Type:Lab/Research institutions

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:100 Gram

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Type:Other

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-Tert-Butylphenylboronic Acid

Cas:123324-71-0

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply 4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:0

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Type:Other

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

[4-(1,1-Dimethylethyl)phenyl]boronic acid

Cas:123324-71-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: 4-tert-Butylphenylboronic acid CAS: 123324-71-0 MF: C10H15BO2 MW: 178.04 EINECS: 602-928-7 Mol File: 123324-71-0.mol 4-tert-Butylphenylboronic acid Structure 4-tert-Butylphenylboronic acid Chemical Properties Melting

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

4-tert-Butylphenylboronic acid

Cas:123324-71-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

BEST PRICE/4-tert-Butylphenylboronic acid CAS NO.123324-71-0

Cas:123324-71-0

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

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Synthetic route

1-bromo-4-tert-butylbenzene
3972-65-4

1-bromo-4-tert-butylbenzene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-4-tert-butylbenzene With n-butyllithium In tetrahydrofuran at -78 - -45℃; for 3h;
Stage #2: With boric acid tributyl ester In tetrahydrofuran at -78 - 20℃;
Stage #3: Acid hydrolysis;
90%
Stage #1: 1-bromo-4-tert-butylbenzene With magnesium In tetrahydrofuran Heating;
Stage #2: With Trimethyl borate In tetrahydrofuran at -78 - 20℃;
Stage #3: With hydrogenchloride
80%
Stage #1: 1-bromo-4-tert-butylbenzene With Trimethyl borate In tetrahydrofuran at -20 - 0℃; Inert atmosphere;
Stage #2: With sulfuric acid In tetrahydrofuran at 0 - 10℃; for 10h; Inert atmosphere;
72.8%
water
7732-18-5

water

potassium (4-tert-butyl)phenyltrifluoroborate

potassium (4-tert-butyl)phenyltrifluoroborate

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

Conditions
ConditionsYield
With 1H-imidazole; iron(III) chloride at 20℃; for 0.25h; Inert atmosphere;85%
Trimethyl borate
121-43-7

Trimethyl borate

1-bromo-4-tert-butylbenzene
3972-65-4

1-bromo-4-tert-butylbenzene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

Conditions
ConditionsYield
Stage #1: 1-bromo-4-tert-butylbenzene With magnesium In tetrahydrofuran
Stage #2: Trimethyl borate In tetrahydrofuran; diethyl ether at -70 - 20℃;
83.4%
With magnesium In tetrahydrofuran; diethyl ether aryl bromide soln. dropped to Mg in THF, filtered, Grignard soln. added dropwise to soln. of calcd. amt. of B compd. in Et2O at -70°C, warming to room temp. overnight; mixt. added to ice cold and concd. aq. H2SO4, stirred for 30 min, extd. with ether (repeatedly), dried with Na2SO4, evapn., dried in vac., elem.anal.;83.4%
With Mg; H2SO4 In tetrahydrofuran; diethyl ether aryl bromide in THF was added to Mg turnings, filtered, added dropwise with stirring to trimethyl borate in ether at -70°C, the suspn. was allowed to warm to room temp. overnight, added with stirring to ice, concd. H2SO4, stirred for 30 min (Ar); shaken with ether, dried over Na2SO4, evapd., filtered, dried in vac.; elem. anal.;83.4%
boric acid tributyl ester
688-74-4

boric acid tributyl ester

1-bromo-4-tert-butylbenzene
3972-65-4

1-bromo-4-tert-butylbenzene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

Conditions
ConditionsYield
With sulfuric acid; magnesium In diethyl ether; water10%
tert-butylbenzene
253185-03-4, 253185-04-5

tert-butylbenzene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: 100 percent / Br2; I2 / 0 °C
2.1: n-BuLi / tetrahydrofuran / 3 h / -78 - -45 °C
2.2: tributyl borate / tetrahydrofuran / -78 - 20 °C
2.3: 90 percent / Acid hydrolysis
View Scheme
4-tert-butylphenylboronic dimethyl ester
1092730-06-7

4-tert-butylphenylboronic dimethyl ester

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

Conditions
ConditionsYield
With hydrogenchloride; water In tetrahydrofuran; hexane at 20℃; pH=3 - 5;
C20H25BO2

C20H25BO2

A

4-tert-Butylcatechol
98-29-3

4-tert-Butylcatechol

B

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

Conditions
ConditionsYield
In chloroform-d1 at 25℃; Equilibrium constant; Sealed tube;
C20H27BN2

C20H27BN2

A

4-(tert-butyl)-1,2-diaminobenzene
68176-57-8

4-(tert-butyl)-1,2-diaminobenzene

B

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

Conditions
ConditionsYield
In chloroform-d1 at 25℃; Equilibrium constant; Sealed tube;
tetrahydroxydiboron
13675-18-8

tetrahydroxydiboron

1-bromo-4-tert-butylbenzene
3972-65-4

1-bromo-4-tert-butylbenzene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

Conditions
ConditionsYield
With potassium tert-butylate In methanol at 0 - 20℃;
4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

4-tert-butylphenylboronic acid sodium hydroxide salt

4-tert-butylphenylboronic acid sodium hydroxide salt

Conditions
ConditionsYield
With sodium hydroxide In toluene100%
ethyl 2-iodobenzoate
1829-28-3

ethyl 2-iodobenzoate

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

4'-tert-butylbiphenyl-2-carboxylic acid ethyl ester
863492-39-1

4'-tert-butylbiphenyl-2-carboxylic acid ethyl ester

Conditions
ConditionsYield
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In N,N-dimethyl-formamide for 18h; Heating / reflux;100%
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane for 90h; Heating / reflux;
3-(nitromethylene)oxetane
922500-95-6

3-(nitromethylene)oxetane

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

3-(4-tert-butylphenyl)-3-(nitromethyl)oxetane
1221819-55-1

3-(4-tert-butylphenyl)-3-(nitromethyl)oxetane

Conditions
ConditionsYield
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; water; potassium hydroxide In 1,4-dioxane at 20℃; for 2h;100%
para-bromotoluene
106-38-7

para-bromotoluene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

1-(4-tert-butylphenyl)-4-methylbenzene

1-(4-tert-butylphenyl)-4-methylbenzene

Conditions
ConditionsYield
With C21H26Cl2N2Pd; potassium carbonate In toluene at 110℃; for 18h; Suzuki Coupling; Inert atmosphere; Sealed tube;100%
With C21H15ClN2O2Pd; potassium carbonate In water at 50℃; for 0.0833333h; Suzuki-Miyaura Coupling;98%
With C22H26N2O6Pd2; potassium carbonate In isopropyl alcohol at 20℃; for 17h; Suzuki-Miyaura Coupling;98%
4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

para-tert-butylphenol
98-54-4

para-tert-butylphenol

Conditions
ConditionsYield
With water; 3-chloro-benzenecarboperoxoic acid In ethanol at 20℃; for 6h;100%
With dihydrogen peroxide In water at 20℃; for 0.166667h;98%
With 3,4,5-trihydroxybenzoic acid; sodium hydrogencarbonate In ethanol; water at 20℃; for 24h; Reagent/catalyst; Solvent; Green chemistry;98%
7-chloro-2-cyclohexylmethylindan-1-one
1147270-21-0

7-chloro-2-cyclohexylmethylindan-1-one

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

7-(4'-tert-butylphenyl)-2-cyclohexylmethylindan-1-one
1147270-22-1

7-(4'-tert-butylphenyl)-2-cyclohexylmethylindan-1-one

Conditions
ConditionsYield
With trisodium tris(3-sulfophenyl)phosphine; sodium carbonate; palladium diacetate In water; ethylene glycol at 125℃; Inert atmosphere;100%
With trisodium tris(3-sulfophenyl)phosphine; palladium diacetate; sodium carbonate In water; ethylene glycol at 125℃; for 4h; Inert atmosphere;100%
7-chloro-2-(2,2-dimethylpropyl)indan-1-one
1147270-30-1

7-chloro-2-(2,2-dimethylpropyl)indan-1-one

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

7-(4'-tert-butylphenyl)-2-(2,2-dimethylpropyl)indan-1-one
1147270-31-2

7-(4'-tert-butylphenyl)-2-(2,2-dimethylpropyl)indan-1-one

Conditions
ConditionsYield
With trisodium tris(3-sulfophenyl)phosphine; sodium carbonate; palladium diacetate In water; ethylene glycol at 125℃; Inert atmosphere;100%
With trisodium tris(3-sulfophenyl)phosphine; palladium diacetate; sodium carbonate In water; ethylene glycol at 125℃; for 4h; Inert atmosphere;100%
7-chloro-2-(1-adamantylmethyl)-indan-1-one

7-chloro-2-(1-adamantylmethyl)-indan-1-one

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

7-(4'-tert-butyl-phenyl)-2-(1-adamantylmethyl)-indan-1-one

7-(4'-tert-butyl-phenyl)-2-(1-adamantylmethyl)-indan-1-one

Conditions
ConditionsYield
With trisodium tris(3-sulfophenyl)phosphine; sodium carbonate; palladium diacetate In water; ethylene glycol at 125℃; Inert atmosphere;100%
8-methyl-1,5-naphthyridin-4-yl trifluoromethanesulfonate
1446863-36-0

8-methyl-1,5-naphthyridin-4-yl trifluoromethanesulfonate

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

4-(4-(tert-butyl)phenyl)-8-methyl-1,5-naphthyridine
1446863-38-2

4-(4-(tert-butyl)phenyl)-8-methyl-1,5-naphthyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane at 80℃; for 1h; Suzuki Coupling;100%
Stage #1: 8-methyl-1,5-naphthyridin-4-yl trifluoromethanesulfonate; p-tert-butylphenylboronic acid With sodium carbonate In 1,2-dimethoxyethane for 0.25h;
Stage #2: With tetrakis(triphenylphosphine) palladium(0) In 1,2-dimethoxyethane at 80℃; for 1h;
100%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane at 80℃; for 1h; Inert atmosphere;100%
o-iodo-methyl-benzoic acid
610-97-9

o-iodo-methyl-benzoic acid

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

methyl 4′-(tert butyl)-[1,1′-biphenyl]-2-carboxylate
1528793-37-4

methyl 4′-(tert butyl)-[1,1′-biphenyl]-2-carboxylate

Conditions
ConditionsYield
With bis(triphenylphosphine)palladium(II) dichloride; sodium carbonate In tetrahydrofuran; water at 80℃; for 14h; Suzuki-Miyaura Coupling; Schlenk technique; Inert atmosphere; Sealed tube;100%
With palladium diacetate; sodium carbonate In water; acetonitrile at 60℃; Suzuki-Miyaura Coupling; Inert atmosphere;90%
With bis-triphenylphosphine-palladium(II) chloride; sodium carbonate In tetrahydrofuran; water at 20 - 80℃; Suzuki Coupling; Schlenk technique; Inert atmosphere;
With potassium phosphate; palladium diacetate; triphenylphosphine In toluene at 80℃; Inert atmosphere; Schlenk technique;
3-methoxy-thiophene
17573-92-1

3-methoxy-thiophene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

C15H18OS

C15H18OS

Conditions
ConditionsYield
Stage #1: 3-methoxy-thiophene With N-Bromosuccinimide In tetrahydrofuran
Stage #2: p-tert-butylphenylboronic acid With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; sodium hydroxide; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran at 60℃;
100%
Stage #1: 3-methoxy-thiophene With N-Bromosuccinimide Inert atmosphere;
Stage #2: p-tert-butylphenylboronic acid With bis(tri-t-butylphosphine)palladium(0) Inert atmosphere;
1-((1R,2R,3S,4S)-2,3-dihydroxy-1,2,3,4-tetrahydro-1,4-epiminonaphthalen-9-yl)-3-(4-(triisopropylsilyl)-1H-1,2,3-triazol-1-yl)propan-1-one

1-((1R,2R,3S,4S)-2,3-dihydroxy-1,2,3,4-tetrahydro-1,4-epiminonaphthalen-9-yl)-3-(4-(triisopropylsilyl)-1H-1,2,3-triazol-1-yl)propan-1-one

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

1-((4R,9S,9aS)-2-(4-(tert-butyl)phenyl)-3a,4,9,9a-tetrahydro-4,9-epiminonaphtho[2,3-d][1,3,2]dioxaborol-10-yl)-3-(4-(triisopropylsilyl)-1H-1,2,3-triazol-1-yl)propan-1-one

1-((4R,9S,9aS)-2-(4-(tert-butyl)phenyl)-3a,4,9,9a-tetrahydro-4,9-epiminonaphtho[2,3-d][1,3,2]dioxaborol-10-yl)-3-(4-(triisopropylsilyl)-1H-1,2,3-triazol-1-yl)propan-1-one

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.166667h;100%
7-chloro-2-(1-adamantylmethyl)indan-1-one
1147270-34-5

7-chloro-2-(1-adamantylmethyl)indan-1-one

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

7-(4'-tert-butylphenyl)-2-(1-adamantylmethyl)indan-1-one
1147270-35-6

7-(4'-tert-butylphenyl)-2-(1-adamantylmethyl)indan-1-one

Conditions
ConditionsYield
With trisodium tris(3-sulfophenyl)phosphine; palladium diacetate; sodium carbonate In water at 125℃; for 6h; Inert atmosphere;100%
C21H18BrNOS

C21H18BrNOS

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

C31H31NOS

C31H31NOS

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; toluene at 80℃; for 24h;100%
bromobenzene
108-86-1

bromobenzene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

4-tert-butylbiphenyl
1625-92-9

4-tert-butylbiphenyl

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 0.0833333h; Suzuki cross-coupling;99%
With potassium carbonate In ethanol; water at 50℃; for 0.75h; Catalytic behavior; Suzuki Coupling; Microwave irradiation;99.5%
With potassium carbonate In ethanol; water at 80℃; for 10h; Catalytic behavior; Suzuki Coupling;99.5%
cyclohexenone
930-68-7

cyclohexenone

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

(R)-3-(4-(tert-butyl)phenyl)cyclohexan-1-one
846606-25-5

(R)-3-(4-(tert-butyl)phenyl)cyclohexan-1-one

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; (R)-(6-(tert-butylsulfinyl)-2,3-dimethoxyphenyl)diphenylphosphine; potassium hydroxide In water; toluene at 20 - 40℃; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
Stage #1: p-tert-butylphenylboronic acid With chlorobis(ethylene)rhodium(I) dimer; (S)-cinnamyl-2,3-dihydro-1,2-benzoisothiazole 1-oxide In 1,4-dioxane at 40℃; for 0.5h; Inert atmosphere; Sealed tube;
Stage #2: cyclohexenone With potassium phosphate In 1,4-dioxane; water at 40℃; for 3h; Inert atmosphere; Sealed tube; enantioselective reaction;
98%
With potassium fluoride; chlorobis(ethylene)rhodium(I) dimer; (R)-1-(tert-butylsulfinyl)-2-(prop-1-en-2-yl)benzene In methanol; dichloromethane; water at 40℃; for 3h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;97%
4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

4,4'-di-tert-butylbiphenyl
1625-91-8

4,4'-di-tert-butylbiphenyl

Conditions
ConditionsYield
With iodine; oxygen; potassium carbonate In PEG-400 at 140℃; for 48h;99%
With copper fluorapatite In methanol at 20℃; for 2h; Green chemistry;96%
With copper(II) choride dihydrate; sodium carbonate In methanol at 25℃; for 0.25h; Catalytic behavior; Reagent/catalyst; Solvent; Green chemistry;95%
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

4-tert-butyl-4'-methoxylbiphenyl

4-tert-butyl-4'-methoxylbiphenyl

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 0.0833333h; Suzuki cross-coupling;99%
With 4Pd(2+)*8NO3(1-)*4C12H10*4C24H18N6O4; potassium carbonate In ethanol; water at 55℃; for 10h; Reagent/catalyst; Suzuki-Miyaura Coupling;99%
With C21H20N2O2Pd; potassium carbonate In water; isopropyl alcohol at 25℃; for 0.5h; Suzuki-Miyaura Coupling;98%
N-acetyl-2-bromoaniline
614-76-6

N-acetyl-2-bromoaniline

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

N-(4'-(tert-butyl)-[1,1'-biphenyl]-2-yl)acetamide

N-(4'-(tert-butyl)-[1,1'-biphenyl]-2-yl)acetamide

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; potassium phosphate In toluene at 90℃; for 4h; Suzuki-Miyaura coupling;99%
(4-bromophenyl)-(9H-β-carbolin-1-yl)-methanone
906067-45-6

(4-bromophenyl)-(9H-β-carbolin-1-yl)-methanone

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

C28H24N2O
922525-74-4

C28H24N2O

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene at 90℃; for 24h; Suzuki-Miyaura coupling;99%
(3-bromophenyl)-(9H-β-carbolin-1-yl)-methanone
906067-46-7

(3-bromophenyl)-(9H-β-carbolin-1-yl)-methanone

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

C28H24N2O
922525-73-3

C28H24N2O

Conditions
ConditionsYield
With potassium carbonate; tetrakis(triphenylphosphine) palladium(0) In ethanol; toluene at 90℃; for 24h; Suzuki-Miyaura coupling;99%
4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

phenylacetylene
536-74-3

phenylacetylene

[(4-tert-butylphenyl)ethynyl]benzene
29778-26-5

[(4-tert-butylphenyl)ethynyl]benzene

Conditions
ConditionsYield
With sodium perchlorate; palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; 2,2,6,6-tetramethyl-4-benzoyloxypiperidine-1-oxide In water; acetonitrile at 20℃; Inert atmosphere; Electrochemical reaction;99%
2-bromo-pyridine
109-04-6

2-bromo-pyridine

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

2-(4-tert-butylphenyl)pyridine

2-(4-tert-butylphenyl)pyridine

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 70℃; for 15h; Inert atmosphere;99%
With di-μ-bromobis(tri-tert-butylphosphino)dipalladium(I); potassium hydroxide In tetrahydrofuran for 0.666667h; Reflux;97%
With potassium phosphate tribasic heptahydrate; oxygen; palladium diacetate In isopropyl alcohol at 80℃; Suzuki Coupling;80%
1-methoxy-4-(2-nitro-vinyl)-benzene
3179-10-0

1-methoxy-4-(2-nitro-vinyl)-benzene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

1-(1-(4-tert-butylphenyl)-2-nitroethyl)-4-methoxybenzene

1-(1-(4-tert-butylphenyl)-2-nitroethyl)-4-methoxybenzene

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; tert-butanesulfinylphosphine; triethylamine In ethanol at 40℃; for 10h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;99%
cyclohexenone
930-68-7

cyclohexenone

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

(S)-3-(4-(tert-butyl)phenyl)cyclohexanone
141632-33-9

(S)-3-(4-(tert-butyl)phenyl)cyclohexanone

Conditions
ConditionsYield
With chlorobis(ethylene)rhodium(I) dimer; C16H23NO3S; potassium hydroxide In 1,4-dioxane; water at 70℃; for 10h; Inert atmosphere; enantioselective reaction;99%
With potassium fluoride; chlorobis(ethylene)rhodium(I) dimer; (R,E)-1-(tert-butylsulfinyl)-2-(prop-1-enyl)benzene In methanol; dichloromethane; water at 40℃; for 3h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;98%
Stage #1: cyclohexenone; p-tert-butylphenylboronic acid With C50H48Cl2O2Rh2S2 In 1,4-dioxane at 40℃; for 0.5h; Inert atmosphere; Glovebox;
Stage #2: With caesium carbonate In 1,4-dioxane at 40℃; Inert atmosphere; Glovebox;
97%
Stage #1: cyclohexenone; p-tert-butylphenylboronic acid With chlorobis(ethylene)rhodium(I) dimer; (R)-N-cinnamyl-2-methyl-N-phenylpropane-2-sulfinamide In 1,4-dioxane at 40℃; for 0.5h; Inert atmosphere;
Stage #2: With potassium phosphate In 1,4-dioxane at 40℃; for 3h; Inert atmosphere; enantioselective reaction;
89%
2-(5-bromo-pyridin-3-yl)-3,3-dimethyl-1,2,3,4-tetrahydro-quinoline-6-carboxylic acid ethyl ester
1343455-35-5

2-(5-bromo-pyridin-3-yl)-3,3-dimethyl-1,2,3,4-tetrahydro-quinoline-6-carboxylic acid ethyl ester

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

2-[5-(4-tert-butyl-phenyl)-pyridin-3-yl]-3,3-dimethyl-1,2,3,4-tetrahydro-quinoline-6-carboxylic acid ethyl ester
1343455-37-7

2-[5-(4-tert-butyl-phenyl)-pyridin-3-yl]-3,3-dimethyl-1,2,3,4-tetrahydro-quinoline-6-carboxylic acid ethyl ester

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 110℃; for 1h; Suzuki Coupling; Microwave irradiation;99%
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In 1,4-dioxane; water at 110℃; for 1h; microwave irradiation;99%
4-bromobenzenecarbonitrile
623-00-7

4-bromobenzenecarbonitrile

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

4'-tert-butyl-biphenyl-4-carbonitrile
192699-51-7

4'-tert-butyl-biphenyl-4-carbonitrile

Conditions
ConditionsYield
With potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 0.0833333h; Suzuki cross-coupling;99%
With 4C27H21N9O6*12NO3(1-)*6Pd(2+)*6C12H10; potassium carbonate In ethanol; water at 55℃; for 10h; Suzuki-Miyaura Coupling;95%
With potassium carbonate In ethyl acetate at 90℃; for 1.5h; Catalytic behavior; Suzuki-Miyaura Coupling;95%
4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

trifluoromethanesulfonic acid 4-formylnaphthalen-1-yl ester
219685-17-3

trifluoromethanesulfonic acid 4-formylnaphthalen-1-yl ester

4-(4-(t-butyl)phenyl)-1-naphthaldehyde
1353555-90-4

4-(4-(t-butyl)phenyl)-1-naphthaldehyde

Conditions
ConditionsYield
With potassium carbonate; palladium diacetate; XPhos In water; acetonitrile at 90℃; for 6h; Suzuki Coupling; Inert atmosphere;99%
With palladium diacetate; potassium carbonate; XPhos In 1,4-dioxane; water at 100℃; for 1h; Suzuki Coupling;88%
1-bromo-2,3-dimethoxy-5-nitronaphthalene
1235871-28-9

1-bromo-2,3-dimethoxy-5-nitronaphthalene

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

1-(4-(t-butyl)phenyl)-2,3-dimethoxy-5-nitronaphthalene
1353556-07-6

1-(4-(t-butyl)phenyl)-2,3-dimethoxy-5-nitronaphthalene

Conditions
ConditionsYield
With sodium carbonate; tetrakis(triphenylphosphine) palladium(0) In water; acetonitrile at 100℃; Suzuki Coupling;99%
5-([1,3]dioxolo[4,5-g]quinolin-7-yl)-2,3-dimethoxyphenyl trifluoromethanesulfonate
1353555-71-1

5-([1,3]dioxolo[4,5-g]quinolin-7-yl)-2,3-dimethoxyphenyl trifluoromethanesulfonate

4-tert-butylphenylboronic acid
123324-71-0

4-tert-butylphenylboronic acid

C28H27NO4
1353554-65-0

C28H27NO4

Conditions
ConditionsYield
With potassium carbonate; palladium diacetate; XPhos In water; acetonitrile at 90℃; for 3h; Suzuki Coupling; Inert atmosphere;99%

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