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Cas:141109-14-0
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inquiryProduct Description Product website: http://www.finerchem.com/pro01en/id/937.html Product Name (S)-(+)-2-Chlorophenylglycine methyl ester CAS No. 141109-14-0 Appearance Yellowish Liquid Assay
Cas:141109-14-0
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inquiryhigh quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiry1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
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inquiry1. made in GMP plant, commerially 2. Normal Stock: 500kgs 3. Audit accepted. Related documents are available to offer and audited by many clients, such as Lupin, MSN, Dr reddy etc 4. Chromatographic Purity (HPLC): not less than 99.0% Appearan
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inquiryDayangChem exported this product to many countries and regions at best price in China. If you are looking for the product’s supplier in China, DayangChem is your best choice. As a leading manufacturer and supplier of chemicals in China, Day
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inquiryOur main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
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inquiryOur Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
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inquiry1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W
Cas:141109-14-0
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inquiryName: L-2-Chlorophenylglycine methyl ester Synonyms: L(+)-2-Chlorophenylglycine Methyl HCL CAS: 141109-14-0 MF: C9H11Cl2NO2 Appearance: White powder Storage:Store in cool and dry place, away from sun light. Package:25KG/Drum Application:Organic Ch
Cas:141109-14-0
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inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:141109-14-0
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
Cas:141109-14-0
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
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inquiryOur company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present
Cas:141109-14-0
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inquiryAppearance:white powder Storage:Store in a cool,dry place and keep away from direct strong light Package:packaged in foil bags or tins Application:Use only for laboratory research Transportation:Sea,Air,DHL/TNT/FEdex/UPS/EMS Por
Cas:141109-14-0
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inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
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inquiryCompany Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments
Cas:141109-14-0
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inquiryA substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
Cas:141109-14-0
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inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
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inquiryChemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff
Cas:141109-14-0
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inquiryMassive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and
Cas:141109-14-0
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:141109-14-0
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inquiry(+)-(S)-Methyl alpha-[[2-(2-thienyl)ethyl]amino]-alpha-(2-chlorophenyl)acetateAppearance:white powder Storage:Kept in a cool, dry and ventilated place Package:according to customers' requirements Application:research chemicals antineoplastic drugs T
Cas:141109-14-0
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inquirySuperior quality, moderate price & quick delivery. Appearance:white powder Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermediate
Cas:141109-14-0
Min.Order:1 Kilogram
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inquiryProduct name: L-2-Chlorophenylglycine Methyl Ester CAS No.:141109-14-0 Molecule Formula:C9H11Cl2NO2 Molecule Weight:236.10 Purity: 99.0% Package: 200kg/drum Description:Light yellow liquid Manufacture Standards:Enterprise Standard
Cas:141109-14-0
Min.Order:1 Kilogram
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inquiry(S) - (+) - 2-Chlorophenylglycine Methyl Ester tartaric acid; L (+) - 2-Chlorophenyl Glycine Methyl Ester Tartarate; Chlorophenyl glycine methyl ester tartrate; (S) -Methyl 2-amino-2- (2-chlorophenyl) aceta
Cas:141109-14-0
Min.Order:100 Gram
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inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:141109-14-0
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inquiry2-chlorophenylglycine methyl ester L-(+)-tartaric acid
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
In methanol for 0.5h; Reflux; | 95% |
With ammonia In dichloromethane; water at 40℃; pH=6.9 - 7.2; | 70% |
With ammonia In dichloromethane; water for 0.5h; pH=7.0 - 7.2; | |
With sodium hydroxide In water; toluene at 0 - 10℃; pH=9; |
methanol
(S)-2-(2-chlorophenyl)glycinamide hydrochloride
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
Stage #1: methanol With sulfuric acid Cooling with ice; Reflux; Stage #2: (S)-2-(2-chlorophenyl)glycinamide hydrochloride at 20℃; Reflux; Stage #3: With sodium hydroxide In water | 94% |
methanol
(2S)-2-(2-chlorophenyl)glycine hydrochloride
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
With sulfuric acid at 0℃; for 5h; Reflux; | 85% |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In dichloromethane; water at 5℃; for 1.66667h; pH=7.46; |
(S)-methyl 2-((tert-butoxycarbonyl)amino)-2-(2-chlorophenyl)acetate
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
Stage #1: (S)-methyl 2-((tert-butoxycarbonyl)amino)-2-(2-chlorophenyl)acetate With trifluoroacetic acid In dichloromethane at 20℃; for 3h; Stage #2: With ammonium hydroxide In water pH=7; | 0.315 g |
methyl 2-((tert-butoxycarbonyl)amino)-2-(2-chlorophenyl)acetate
A
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
B
α-amino-(2-chlorophenyl)acetic acid methyl ester
Conditions | Yield |
---|---|
With protease from Bacillus licheniformis for 12h; pH=7.5; aq. buffer; Resolution of racemate; optical yield given as %ee; |
2-chloro-benzaldehyde
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: methanol; water / 16 h / 25 - 30 °C 2: water; hydrogenchloride / diethyl ether / 4 h / 90 °C 3: sulfuric acid / 5 h / 0 °C / Reflux View Scheme |
(2S)-(2-chlorophenyl){[(1S)-1-(4-methoxyphenyl)ethyl]amino}acetonitrile hydrochloride
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: water; hydrogenchloride / diethyl ether / 4 h / 90 °C 2: sulfuric acid / 5 h / 0 °C / Reflux View Scheme |
2-(2-chlorophenyl)glycine methyl ester hydrochloride
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: methanol; acetonitrile; butanone / 11.5 h / Reflux 2: methanol / 0.5 h / Reflux View Scheme | |
Multi-step reaction with 2 steps 1: sulfuric acid / methanol; acetone / 20 h / 10 - 30 °C 2: ammonia / water; dichloromethane / 40 °C / pH 6.9 - 7.2 View Scheme |
2-amino-(2-chlorophenyl)ethanoic acid
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: thionyl chloride / -10 - 35 °C 2: methanol; acetonitrile; butanone / 11.5 h / Reflux 3: methanol / 0.5 h / Reflux View Scheme | |
Multi-step reaction with 3 steps 1: sulfuric acid / 21 h / 35 - 65 °C 2: sulfuric acid / methanol; acetone / 20 h / 10 - 30 °C 3: ammonia / water; dichloromethane / 40 °C / pH 6.9 - 7.2 View Scheme |
methanol
(S)-2-amino-(2-chlorophenyl)ethanoic acid
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
With thionyl chloride In methanol at 20℃; under 760.051 Torr; for 24h; Reflux; | 5 g |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
With sodium carbonate In dichloromethane; water |
methanol
A
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
B
α-amino-(2-chlorophenyl)acetic acid methyl ester
Conditions | Yield |
---|---|
Stage #1: methanol; C20H16ClN2OP With hydrogenchloride at 80℃; for 15h; Stage #2: With sodium carbonate In water Overall yield = 54 percent; enantioselective reaction; | A n/a B n/a |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
1,1,1,3,3,3-hexamethyl-disilazane
Conditions | Yield |
---|---|
In 1,2-dichloro-ethane at 60 - 80℃; | 100% |
2-thienylacetaldehyde
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
With ammonium acetate In toluene at 40℃; Solvent; Temperature; Reagent/catalyst; | 93.5% |
2-(2-thienyl)ethyl tosylate
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
Stage #1: 2-(2-thienyl)ethyl tosylate; methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate With sodium hydrogencarbonate; potassium iodide In acetonitrile at 85℃; for 27h; Stage #2: With hydrogenchloride In water at 20℃; for 2h; | 91% |
Stage #1: 2-(2-thienyl)ethyl tosylate; methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate With potassium dihydrogen phosphate trihydrate In water at 45 - 100℃; for 15h; Stage #2: With hydrogenchloride at 0 - 3℃; for 1h; pH=1.2 - 1.5; | 89% |
Stage #1: 2-(2-thienyl)ethyl tosylate; methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate With dipotassium hydrogenphosphate In acetic acid tert-butyl ester at 92.5℃; for 30h; Stage #2: With hydrogenchloride In water; ethyl acetate at 12.5℃; for 0.416667h; Product distribution / selectivity; | 66.3% |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
(S)-methyl 2-amino-2-(2-chlorophenyl)acetate hydrochloride salt
Conditions | Yield |
---|---|
With hydrogenchloride at 0 - 5℃; | 88.9% |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
With fluorosulfonyl azide; potassium hydrogencarbonate In tert-butyl methyl ether; water; N,N-dimethyl-formamide at 20℃; for 0.0833333h; | 83% |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
3-(2'-iodoethyl) thiophene
methyl (S)-(+)-2-(2-(thiophen-3-yl)ethylamino)-2-(2-chlorophenyl)acetate
Conditions | Yield |
---|---|
With triethylamine In acetonitrile Reflux; | 80.68% |
2-(3-hydroxymethylthiophen-2-yl)ethanol
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
(S)-(+)-clopidogrel
Conditions | Yield |
---|---|
With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; Bis(p-nitrophenyl) phosphate In toluene at 100℃; for 36h; Solvent; Time; Temperature; Sealed tube; Molecular sieve; Green chemistry; | 80% |
2-(2-thienyl)ethyl tosylate
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
methyl (S)-2-(2-chlorophenyl)-2-[2-(thien-2-yl)ethylamino]acetate
Conditions | Yield |
---|---|
With sodium hydrogencarbonate; potassium iodide In acetonitrile for 12h; Reflux; | 70% |
With triethylamine at 78 - 82℃; for 8 - 10h; Product distribution / selectivity; |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
5-(2-methylbenzothiazol-5-yloxymethyl)isoxazole-3-carboxylic acid
(2-chlorophenyl){[5-(2-methylbenzothiazol-5-yloxymethyl)isoxazole-3-carbonyl]-(S)-amino}acetic acid methyl ester
Conditions | Yield |
---|---|
Stage #1: 5-(2-methylbenzothiazol-5-yloxymethyl)isoxazole-3-carboxylic acid With dmap; benzotriazol-1-ol In N,N-dimethyl-formamide at 20℃; for 0.5h; Molecular sieve; Stage #2: methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In N,N-dimethyl-formamide | 59.4% |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
3,4,5-tribenzyloxybenzoic acid
Conditions | Yield |
---|---|
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine In N,N-dimethyl-formamide | 8% |
2-(2-bromoethyl)-3-(bromomethyl)thiophene
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
(S)-(+)-clopidogrel
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In acetonitrile Reflux; | |
Stage #1: 2-(2-bromoethyl)-3-(bromomethyl)thiophene; methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate In ethyl acetate; acetonitrile at 25 - 30℃; for 0.25h; Stage #2: With N-ethyl-N,N-diisopropylamine In ethyl acetate; acetonitrile Reflux; |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
4-nitrobenzaldehdye
Conditions | Yield |
---|---|
With (R)-3,3'-bis(9-anthracenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate In toluene at 25℃; for 1h; Molecular sieve; |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
(S)-(+)-clopidogrel bisulfate
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: sodium hydrogencarbonate / toluene / 25 - 30 °C 1.2: 85 - 90 °C 2.1: water / 25 - 35 °C 2.2: pH 7 - 8 3.1: sulfuric acid / acetone; methanol / 0 - 30 °C View Scheme | |
Multi-step reaction with 3 steps 1.1: sodium hydrogencarbonate; potassium iodide / acetonitrile / 27 h / 85 °C 1.2: 2 h / 20 °C 2.1: 4 h / 40 °C / Darkness 3.1: sulfuric acid / methanol / 25 °C View Scheme | |
Multi-step reaction with 3 steps 1.1: ammonium acetate / toluene / 40 °C 2.1: sodium tetrahydroborate / tetrahydrofuran / 25 °C 3.1: sulfuric acid / chloroform / 20 °C 3.2: 2 h / 10 °C View Scheme | |
Multi-step reaction with 4 steps 1: 1,2-dichloro-ethane / 60 - 80 °C 2: potassium carbonate / acetonitrile / 70 - 80 °C 3: hydrogenchloride / water 4: water / 36 - 44 °C View Scheme |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
(S)-(+)-clopidogrel
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: sodium hydrogencarbonate / toluene / 25 - 30 °C 1.2: 85 - 90 °C 2.1: water / 25 - 35 °C 2.2: pH 7 - 8 View Scheme | |
Multi-step reaction with 2 steps 1.1: sodium hydrogencarbonate; potassium iodide / acetonitrile / 27 h / 85 °C 1.2: 2 h / 20 °C 2.1: 4 h / 40 °C / Darkness View Scheme | |
Multi-step reaction with 2 steps 1.1: potassium dihydrogen phosphate trihydrate / water / 15 h / 45 - 100 °C 1.2: 1 h / 0 - 3 °C / pH 1.2 - 1.5 2.1: methanol / 37 - 39 °C View Scheme |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
methyl (S)-(+)-2-(2-chlorophenyl)-2-(4,5-dihydrothieno[2,3-c]pyridin-6(7H)-yl)acetate
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: triethylamine / acetonitrile / Reflux 2: hydrogenchloride / water / 25 - 55 °C View Scheme |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
methyl (S)-(+)-2-(2-chlorophenyl)-2-(4,5-dihydrothieno[2,3-c]pyridine-6(7H)-yl)acetate hydrochloride
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: triethylamine / acetonitrile / Reflux 2: hydrogenchloride / water / 25 - 55 °C 3: hydrogenchloride / water; acetone / 25 °C View Scheme |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
1,1,2,2-tetradeutero-2-(thiophen-2-yl)ethyl 4-methylbenzenesulfonate
(S)-methyl 2-(2-chlorophenyl)-2-(1,1,2,2-tetradeutero-2-(thiophen-2-yl)ethylamino)acetate
Conditions | Yield |
---|---|
With potassium hydrogencarbonate In acetonitrile at 80℃; for 24h; Sealed tube; |
methyl (S)-(+)-2-amino-2-(2-chlorophenyl)acetate
(S)-2-amino-2-(2-chlorophenyl) acetamide
Conditions | Yield |
---|---|
With ammonium hydroxide In methanol; water at 20℃; under 760.051 Torr; for 72h; Inert atmosphere; | 3 g |
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