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Cas:14699-99-1
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:14699-99-1
Min.Order:10 Gram
Negotiable
Type:Lab/Research institutions
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou
Cas:14699-99-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?sale Application:healing drugs
Cas:14699-99-1
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryfactory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin
Cas:14699-99-1
Min.Order:0
Negotiable
Type:Trading Company
inquiryPackage:according to the clients requirement Transportation:by sea or by air
Cas:14699-99-1
Min.Order:0
Negotiable
Type:Trading Company
inquiryConditions | Yield |
---|---|
With methytrioxorhenium(VII) at -30℃; for 3h; polystyrene bead; | 100% |
1,2-Dimethylhydrazine
ozone
A
trioxidane
B
water
C
dihydrogen peroxide
Conditions | Yield |
---|---|
In [(2)H6]acetone byproducts: 1,2-dimethyldiazene, 1,2-dimethyldiazene-N-oxide, nitromethane; ozonation od 1,2-dimethylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in acetone-d6 at -78°C; monitoring by GC/MS and NMR; | A 45% B n/a C 55% |
Conditions | Yield |
---|---|
In acetic acid methyl ester ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in methyl acetate at -78°C; | 45% |
ozone
diphenyl hydrazine
A
trioxidane
B
water
C
dihydrogen peroxide
Conditions | Yield |
---|---|
In [(2)H6]acetone byproducts: PhN(O)NPh; ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in acetone-d6 at -60°C; monitoring by NMR; | A 45% B n/a C n/a |
In further solvent(s) byproducts: 1,2-diphenyldiazene-N-oxide, 1,2-diphenyldiazene; ozonation od 1,2-diphenylhydrazine with ozone-nitrogen or ozone-oxygen mixt. in tert-butyl methyl ether at -78°C; | A 30% B n/a C 10% |
Conditions | Yield |
---|---|
In further solvent(s) react. germanium compd. with ozone at -78°C in t-butyl methyl ether; not isolated, detected by NMR; | |
In [(2)H6]acetone react. germanium compd. with ozone at -78°C in acetone-d6; not isolated, detected by NMR; | |
In acetic acid methyl ester react. germanium compd. with ozone at -78°C in methyl acetate; not isolated, detected by NMR; |
Conditions | Yield |
---|---|
rate constant;; | |
In neat (no solvent) | |
rate constant;; |
ozone
trioxidane
Conditions | Yield |
---|---|
With cumene In [(2)H6]acetone byproducts: C6H5C(CH3)(CH2); ozonization at -40°C with ozone-oxygen or O3-N2 mixt. in acetone-d6 or methyl acetate ort-butyl methel ether; not isolated; monitored by NMR; | |
With triphenylmethane In [(2)H6]acetone byproducts: (C6H5)3COOOH; ozonization at -60°C with ozone-oxygen or O3-N2 mixt. in acetone-d6 or methyl acetate ort-butyl methel ether; | 0% |
Conditions | Yield |
---|---|
With oxygen In water passage of a stream of ozone/oxygen gas through a soln. of aq. H2O2 ca.96% w/w, generated either by vacuum distillation of commercially available HOOH or pure HOOH generated by reduction of O2 in (D6)acetone or (D10)THF at -78°C; not isolated, detected by NMR-spectroscopy; |
Conditions | Yield |
---|---|
In gas MS;; |
Conditions | Yield |
---|---|
In water byproducts: HO2; other Radiation; acidic with O2 satd. water was treated with electron beam of high intensity at 23°C; yield depending on the pH;; | |
In water byproducts: HO2; other Radiation; acidic with O2 satd. water was treated with electron beam of high intensity at 23°C; yield depending on the pH;; |
Conditions | Yield |
---|---|
In water in pulsed discharge nozzle; discharging a gas mixt. of O2 and Ar passed through 30% H2O2 soln.; detd. by Fourier transform microwave spectroscopy; |
dihydrogen peroxide
trioxidane
Conditions | Yield |
---|---|
With potassium permanganate In sulfuric acid mixing of H2SO4 containing aq. KMnO4 soln. with H2O2 soln. at -12 °C;; | 0% |
With potassium permanganate In sulfuric acid mixing of H2SO4 containing aq. KMnO4 soln. with H2O2 soln. at -12 °C;; | |
With KMnO4 In sulfuric acid aq. H2SO4; mixing of H2SO4 containing aq. KMnO4 soln. with H2O2 soln. at -12 °C;; | |
With KMnO4 In sulfuric acid aq. H2SO4; mixing of H2SO4 containing aq. KMnO4 soln. with H2O2 soln. at -12 °C;; | 0% |
dimethylphenylgermane
ozone
A
trioxidane
B
(CH3)2C6H5GeOOOH
Conditions | Yield |
---|---|
In [(2)H6]acetone react. germanium compd. with ozone at -78°C in acetone-d6; not isolated, detected by NMR; | |
In further solvent(s) react. germanium compd. with ozone at -78°C in t-butyl methyl ether; not isolated, detected by NMR; | |
In acetic acid methyl ester react. germanium compd. with ozone at -78°C in methyl acetate; not isolated, detected by NMR; |
hydrogen
oxygen
A
trioxidane
B
hydroxyperoxide
C
water
D
dihydrogen peroxide
Conditions | Yield |
---|---|
In neat (no solvent, gas phase) byproducts: ozone; other Radiation; mixt. of H2 and O2 (flow rate 3.2 L/h, pressure 0.85-1.0 Torr) passed through electrodeless microwave discharge (2450 MHz, 12 W); condensation on cold-finger (77 K); not isolated, detected by Raman-spectroscopy; | |
at -195℃; under 0.675068 Torr; Electric arc; |
A
trioxidane
trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II)
Conditions | Yield |
---|---|
In (2)H8-toluene at -78 - -60℃; Temperature; Photolysis; Cooling with ice; |
[(2)H6]acetone
A
trioxidane
trans-chlorobis(triethylphosphine)(p-trifluoromethylphenyl)platinum(II)
E
dihydrogen peroxide
Conditions | Yield |
---|---|
at -78 - -60℃; Photolysis; Cooling with ice; |
trioxidane
water
Conditions | Yield |
---|---|
With hydrogen cation; iron(II) In water Kinetics; byproducts: Fe(3+); decay mechanism of H2O3 in acidic aq. O2 satd. soln. in presence of Fe(2+) at 23°C; rate constants depending on the pH;; |
Conditions | Yield |
---|---|
In [(2)H6]acetone Kinetics; | |
In acetic acid methyl ester Kinetics; | |
In further solvent(s) Kinetics; in tert-butyl methyl ether at -10 - 30°C; monitoring by NMR; |
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